1. Perovskite-type oxide thin film integrated fiber optic sensor for high-temperature hydrogen measurement
- Author
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Tang, Xiling, Remmel, Kurtis, Lan, Xinwei, Deng, Jiangdong, Xiao, Hai, and Dong, Junhang
- Subjects
Thin film devices -- Research ,Hydrogen -- Identification and classification ,Fiber optics -- Equipment and supplies ,Fiber optics -- Research ,Chemistry - Abstract
Small size fiber optic devices integrated with chemically sensitive photonic materials are emerging as a new class of high-performance optical chemical sensor that have the potential to meet many analytical challenges in future clean energy systems and environmental management. Here, we report the integration of a proto on conducting perovskite oxide thin film with a long-period fiber grating (LPFG) device for high-temperature in situ measurement of bulk hydrogen in fossil- and biomass-derived syngas. The perovsldte-type Sr([Ce.sub.0.8][Zr.sub.0.1])[Y.sub.0.1][O.sub.2.95] (SCZY) nanocrystalline thin film is coated on the 125 [micro]m diameter LPFG by a facile polymeric precursor route. This fiber optic sensor (FOS) operates by monitoring the LPFG resonant wavelength ([[lambda].sub.R]), which is a function of the refractive index of the perovskite oxide overcoat. At high temperature, the types and population of the ionic and electronic defects in the SCZY structure depend on the surrounding hydrogen partial pressure. Thus, varying the [H.sub.2] concentration changes the SCZY film refractive index and light absorbing characteristics that in turn shifts the [[lambda].sub.R] of the LPFG. The SCZY-coated LPFG sensor has been demonstrated for bulk hydrogen measurement at 500[degrees]C for its sensitivity, stability/ reversibility, and [H.sub.2]-selectivity over other relevant small gases including CO, [CH.sub.4], [CO.sub.2], [H.sub.2]O, and [H.sub.2]S, etc.
- Published
- 2009