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Atomic layer deposited (ALD) tantalum nitride (TaxNy) is evaluated as a barrier against aluminum inside gate metal stacks of metal-oxide-semiconductor field effect transistor (MOSFET) devices. When deposited on hygroscopic oxides, like HfO2, amorphous tantalum nitride (a-TaxNy) is obtained, while deposition on Si or TiN results in polycrystalline Ta3N5. The low conductivity of both phases is not attractive for gate metal applications; however, a-TaxNy is crystallized to bixbyite Ta2N3 at 500 °C, improving its conductivity to ∼130 Ω−1 cm−1. For thicknesses below 10 nm, crystallization did not happen, but thin a-TaxNy barriers still obtain conductivity improvements to ∼500 Ω−1 cm−1 when Al diffuses into the film. In metal gate stacks, a-TaxNy screens the low work function of ALD TiAl more effectively than TiN. A barrier thickness reduction of 50% is achieved for n-MOSFET devices with an effective work function at 4.2–4.3 eV and low gate leakage. Slower diffusion of Al into TaxNy is observed by secondary ion mass spectroscopy; however, the cause of EWF lowering as a result of Al diffusion could not be confirmed. Instead, restoration of high EWF after removal of TiAl occurs, enabling an NMOS-first process integration with the use of 1 nm thin TaxNy barriers. [ABSTRACT FROM AUTHOR]

Background and aims: Induction of apoptosis of cancer cells through ligands of nuclear hormone receptors (NHRs) is a new approach in cancer therapy. Recently, one of the NHRs, peroxisome Proliferator [...]

Fin height and width dependence of negative and positive Bias Temperature Instability (N/PBTI) on logic for memory high- $\kappa $ metal gate (HKMG) FinFET transistors is reported for the first time. It was observed that NBTI degradation is less severe when increasing the physical height of the silicon fin. The increased fin height results in a lower effective defect density, believed to be related to a reduced role of the defective fin corners and/or top surface. In addition, activation energies for the capture process in tall fins during NBTI stress show lower values while charge trapping in standard height fins is highly temperature dependent. PBTI results reveal a similar, albeit less severe, impact of fin height, suggesting an impact of fin height on the high- $\kappa $ layer, with again an increased defectivity at the fin corners and/or top surface, whose effective role is reduced in the case of taller fin. On the other hand, PBTI shows limited temperature dependence, independent of fin height. [ABSTRACT FROM AUTHOR]

Continued scaling of DRAM technologies has required a limitation of the power dissipation from the logic components on-chip, while downscaling both transistor oxide thickness and gate length. One route to enable further scaling, while circumventing excessive leakage currents, is the integration of high-permittivity (${\kappa }$) metal-gate (HKMG) components into the logic and high-voltage (e.g., I/O) devices. The requirement of a gate-first flow for devices in the peripheral region introduces significant reliability challenges. Even though Negative Bias Temperature Instability (NBTI) performance of CMOS and memory thermal budget compatible transistors are aligned with conventional HKMG integration with thin oxide devices, it is not the case for thick oxide devices. In particular, it will be shown that strong NBTI lifetime degradation is observed as soon as high- ${\kappa }$ layers are deposited on top of the thick interfacial layer. In this work, a review of the impact of these high- ${\kappa }$ layers on the NBTI high voltage logic for memory devices is presented. The stress induced degradation is correlated to a diffusion of metal atoms from the HKMG gate stack towards the silicon surface. Directions for reliability improvements are then defined. The presence of Nitrogen throughout the HKMG stack can originate either from high- ${\kappa }$ processing or metal-nitride gate electrode. It is shown that preventing nitrogen diffusion towards the Si/SiO2 interface region, together with AlOx and/or F incorporation at the HKMG interface, can tune device threshold voltage and modulate access to donor trap-defect bands. The result of these effects is a vast improvement in NBTI performance. A detailed study of NBTI-degradation, supported by physical analysis, assessing the impact of various tuning components within the stack (interface layer, high- $\kappa $ fluorination and/or cap, metal gate) will be presented. Potential solutions for this reliability challenge will be reported. [ABSTRACT FROM AUTHOR]

This article reports Si-passivated Ge nFinFETs with significantly improved GmSAT/SSSAT and positive bias temperature instability (PBTI) reliability enabled by an improved replacement metal gate (RMG) high-k last process. SiO2 dummy gate oxide (DGO) deposition on Ge fin is shown to form (Six)Ge1-xOy, which is, compared to a pure SiO2, more difficult to remove completely during the dry clean prior to the gate-stack formation. By extending the DGO removal clean, improved PBTI reliability, reduced DIT, and increased electron mobility are demonstrated. Moreover, by suppressing the Ge channel oxidation through the choice of less-oxidizing DGO or inserting an Si-cap layer prior to the DGO deposition, a greatly improved long-channel electron mobility is obtained at a scaled fin width. Finally, together with the PBTI maximum VOV of 0.13 V, the best GmSAT/SSSAT of 5.4 is achieved, which is today’s record value among the sub-100-nm-Lg n-channel Ge Fin and gate-all-around nanowire FETs. These results clearly show the importance of the pre-gate-stack channel surface preparation on the scaled Ge FinFETs to benefit from a previously optimized Si-passivated Ge gate-stack. [ABSTRACT FROM AUTHOR]

We investigate bias temperature instability (BTI) charge trapping trends in high- $k$ metal gate (HKMG) stacks with a variety of work function metals (WFMs). Most BTI models suggest charge trapping in oxide defects is modulated by the applied oxide electric field, which controls the energy barrier for the capture process, irrespective of the gate work function. However, experimental data on capacitors show enhanced or reduced charge trapping at a constant oxide electric field for different WFM stacks. We ascribe this to a different chemical interaction of the metals with the dielectric, which yields different defect profiles depending on the process thermal budget, and not to the gate work function per se. This observation is confirmed by comparing BTI degradation in nMOS and pMOS replacement gate planar transistors with three selected WFM stacks (representative of high-, standard-, and low- $V_{\mathrm{ th}}$ device flavors), and two different process thermal budgets. Furthermore, by employing the imec/T.U. Wien physics-based BTI simulation framework “Comphy,” we also show that, on top of the unavoidable chemical interaction of different metals with the underlying SiO2/HfO2 dielectric stack, different gate work functions within a typical range of relevance (4.35–4.75 eV) can yield a different charge state of the deep high- $k$ defects, and can therefore have an impact on charge trapping kinetics during BTI stress, particularly in nMOSFETs. [ABSTRACT FROM AUTHOR]

The performance of n-type silicon nanosheets, nanowires, and FinFETs is benchmarked by Monte Carlo (MC) device simulation. Measurements of nanowire transfer characteristics are provided to validate the MC model supplemented by a corresponding comparison for nanosheets with literature data. At an OFF-current per effective gate width of 10 nA/ $\mu \text{m}$ , the ON-currents of nanowires, FinFETs, and nanosheets are 500, 545, and 570 $\mu \text{A}/\mu \text{m}$ , respectively. A major reason for this inferior nanowire performance is found to be the stronger impact of surface roughness scattering in nanowires due to a higher surface-to-volume ratio. However, the nanowires' performance disadvantage is reduced for shorter gate lengths due to their better electrostatic control and reduced impact of surface roughness upon scaling. [ABSTRACT FROM AUTHOR]

SiGe quantum-well pMOSFETs have recently been introduced for enhanced performance of transistors. Quite surprisingly, a significant reduction in negative bias temperature instability (NBTI) was also found in these devices. Furthermore, a stronger oxide field acceleration of the degradation in SiGe devices compared with Si devices was reported. These observations were speculated to be a consequence of the energetical realignment of the SiGe channel with respect to the dielectric stack. As these observations were made on large-area devices, only the average contribution of many defects to NBTI could be studied. In order to reveal the microscopic reasons responsible for the improved reliability, a detailed study of single defects is performed in nanoscale devices. To provide a detailed picture of single charge trapping, the step-height distributions for different device variants are measured and found to follow a unimodal and bimodal distribution. This finding suggests two conducting channels, one in the SiGe and one in the thin Si cap layer. We, furthermore, demonstrate that similar trap depth distributions are present among the device variants supported by a similar stress bias dependence of the capture times of the identified single defects. We conclude that NBTI is primarily determined by the dielectric stack and not by the device technology. [ABSTRACT FROM AUTHOR]

The susceptibility of conventional silicon p-channel MOS transistors to negative bias temperature instabilities (NBTIs) is a serious threat to further device scaling. One possible solution to this problem is the use of a SiGe quantum-well channel. The introduction of a SiGe layer, which is separated from the insulator by a thin Si cap layer, not only results in high mobilities but also superior reliability with respect to NBTI. In part one of this paper, we provide experimental evidence for reduced NBTI by thoroughly studying single traps in nanoscale devices. In this paper, we present detailed TCAD simulations and employ the four-state nonradiative multiphonon model to determine the energetical and spatial positions of the identified single traps. The found trap levels agree with the defect bands estimated in large-area devices. Our conclusions are also supported by the observation of similar activation energies for defects present in transistors of various device geometries. From the calibrated TCAD simulations data, an impressive boost of the time-to-failure for the SiGe transistor can be predicted and explained. [ABSTRACT FROM AUTHOR]

Mapping and visualization of all degradation modes in both n- and p-channel field effect transistors, specifically devices for dynamic random access memory periphery, is performed in the (VG, VD) bias space applicable for complementary metal-oxide-semiconductor operation. This "all-in-one" approach allows for tracking and studying in parallel all degradation regimes, including bias temperature instability, hot carrier degradation, and off-state stress, as well as the transitions between them. It should prove beneficial when developing new very large-scale integrated technologies, since it allows for simultaneous comparison and checking of all degradation regimes and promptly identifying "weak spots" of each technology option. It also allows to choose the correct criteria (voltages or fields) at a later time and postprocessing the data as necessary. [ABSTRACT FROM AUTHOR]

For scaling of bulk Si Fin field-effect transistor (FinFET), suppression of short-channel effects is required without ON-state current degradation. In this letter, solid-source doping for channel doping using 1-nm phosphosilicate glass was demonstrated on both p-type (100) Si substrate and p-type bulk Si FinFET. The profile of phosphorus in p-type (100) Si substrate was analyzed by secondary ion mass spectrometry and it was diffused deeper with higher thermal budget of anneal. Fabricated bulk Si FinFETs with using 1-nm phosphosilicate glass showed threshold voltage shift with several anneals at 1- \mu \textm and 70-nm gate lengths. Hole mobility at 1- \mu \textm gate length and transconductance at 70-nm gate length were also reduced due to increase in impurity concentration of phosphorus diffused by anneals into Fins. Phosphorus diffusion into Fins with using 1-nm phosphosilicate glass was investigated and phosphorus behavior after anneal was clarified by electrical data of p-type bulk Si FinFETs. [ABSTRACT FROM PUBLISHER]