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Extrinsic p-type doping of long wavelength infrared-HgCdTe double layer heterostructure for p-on-n device application requires good control of the p-type dopant, regardless of the doping technique. The approach is to place the electrical junction ahead of the compositional interface, thus avoiding quantum efficiency reduction. This research addresses the As and P doping of HgCdTe by an implant/diffusion process. The data demonstrates an enhanced atomic diffusion process for As and P from an ion implanted source, within the single phase domain, with a diffusion rate orders of magnitude higher than the rate under Hg-saturated conditions at the same temperature. This work also reveals a new phenomenon, namely, a transition in the enhanced diffusion of both As and P from an exponential to a Gaussian redistribution. This transition is controlled by temperature at a given PHg. Gaussian diffusion dominates at high temperatures, T >400°C. The diffusion coefficient of the Gaussian mechanism decreases as the PHg increases, from Dp ~2 x 10-11 cm2/s at PHg ~0.02 atm to Dp ~3 x 10-14 cm2/ s under Hg-saturated conditions (quartz ampoule) at 440°C. The difference in the diffusion coefficients between open tube and closed tube (quartz ampoule), under nominally Hg-saturated conditions, indicates that PHg is undersaturated regardless of the Hg-source proximity. The deviation of PHg from saturation is estimated from the annealing furnace temperature profile up to a maximum of 50%. Variation of the diffusion coefficient close to Hg saturation appears to be sharply dependent on the actual PHg value (example: Dp ~1 x 10-12 cm2/s in open-tube anneal vs Dp ~3 x 10-14 cm2/s in closed tube at nominally the same temperature, T = 440°C). Comparative anneals of As and P showed faster diffusion rates for P than for As in both mechanisms.

The authors have fabricated p-on-n LWIR HgCdTe diodes by extrinsically doping a double-layer heterostructure grown by metalorganic chemical vapour deposition (MOCVD) using the interdiffused multilayer process (IMP) on GaAs substrates. The p-side of the junction was obtained by a fast As diffusion, from an ion-implanted source, ahead of the heterointerface when the annealing was performed at very low partial pressure of Hg. Examples of photodiodes fabricated by this process are given. Thus, for devices processed by As implant/diffusion, an R0A of 24.2 Omega cm2 for a cut-off wavelength of 11.7 mu m at 77 K and a quantum efficiency of 51% were obtained for a mesa unpassivated structure, and an R0A of 91 Omega cm2 for a cut-off wavelength of 10.3 at 77 K and a quantum efficiency of 50% were obtained for a planar structure. At 77 K the transport mechanisms limiting the device performance near zero bias have appeared to be thermal processes (ideality factor n between 1 and 2). However, other mechanisms evident in reverse bias such as shunt and tunnelling, may also operate.

Ballistic-electron-emission microscopy (BEEM) and spectroscopy have been used to investigate the properties of Au/GaN interfaces.

The critical steps in the development of MOVPE for the fabrication of MCT focal plane arrays (FPAs) are outlined. Improved purity of the source organometallics has enabled background donor concentrations in the mid 1014 cm-3 to be achieved, together with controlled back doping with donors or acceptors. Large area alloy uniformity is possible by the interdiffused multilayer process (IMP). However, large FPAs will need to be grown onto Si substrates to avoid thermal stress on the hybridized structure. Preliminary results are presented on a 256*256 element MWIR array. Results are also presented on optical in situ monitoring that will form the basis of improved epitaxial control in the future.

Hybrid HgCdTe 256*256 focal plane arrays have been developed to meet the sensitivity, resolution, and field-of-view requirements of high-performance medium-wavelength infrared (MWIR) imaging systems. The detector arrays for these hybrids are fabricated on substrates that reduce or eliminate the thermal expansion mismatch to the silicon readout circuit. The readouts are foundry-processed CMOS switched-FET circuits that have charge capacities greater than 10/sup 7/ electrons and a single video output capable of 20-MHz data rates. The high quantum efficiency, tunable absorption wavelength, and broad operating temperature range of these large HgCdTe staring focal plane arrays give them significant advantages over competing sensors. The mature Producible Alternative to CdTe for Epitaxy-1 (PACE-1) technology, using sapphire detector substrates, has demonstrated 256*256 MWIR arrays with mean laboratory noise equivalent temperature difference (NETD) of 9 mK for a 4.9- mu m cutoff wavelength, 40- mu m pixel size, and 80-K operating temperature. RMS detector response nonuniformities are less than 4%, and pixel yields are greater than 99%. The newly developed PACE-3 process uses silicon for the detector substrate to eliminate completely the thermal mismatch with the silicon readout circuit. It has the potential for similar performance in even larger array sizes. A 640*480 hybrid array is under development. >

The authors compare the material properties of conventional- and interdiffused-grown layers of Hg1-xCdxTe/GaAs grown by metalorganic chemical vapour deposition (MOCVD). These results are also compared with those of state-of-the-art LPE HgCdTe/CdZnTe grown from Te-rich solutions. Data are presented on surface morphology, compositional uniformity, double-crystal X-ray diffraction, chemical defect etching, Hall effect, minority carrier lifetime and laser-beam-induced current (LBIC) characterisation on (111)B, (221) and (100) orientations. The compositional uniformity is 3.3% for 3 in diameter HgCdTe/GaAs. The interdiffused growth method results in better compositional uniformity than the conventional method, while the structural quality of layers grown by both techniques is similar. Etch pit densities of (1-2)*106 cm-2 are routinely obtained for (111)B and (221) orientations, while values as low as 5*105 cm-2 have been occasionally observed. Initial data are also presented for HgCdTe layers grown on (100)GaAs/Si substrates.

Layers of epitaxial Hg1−xCdxTe have been grown by metalorganic chemical vapor deposition (MOCVD) on GaAs/Si substrates. Data is presented on surface morphology, compositional uniformity, double crystal x‐ray diffraction, chemical defect etching, laser beam induced current imaging, and Hall effect. Compositional uniformity is 6% for 3 in. diam areas and 0.6% for the interior 2 in. diam area. The material characteristics of these layers are in the range suitable for fabrication of infrared detectors. The material characteristics are compared with those of similar layers grown on bulk GaAs substrates.

In this paper we report on p‐type arsenic doping of CdTe and HgTe/CdTe superlattices by photoassisted and conventional molecular‐beam epitaxy (MBE). We also report on some of the problems involved in doping and growing the HgTe/CdTe superlattice system by theoretically examining two key aspects of its growth: (i) growth of CdTe at low temperatures under Cd‐stabilized conditions, and (ii) effect of laser excitation on the growing CdTe surface. p‐Type arsenic‐doped CdTe and HgTe/CdTe superlattice epilayers were grown on (100) CdTe and CdZnTe substrates at low temperatures under cation‐stabilized conditions obtained either with excess Cd, or excess Hg fluxes. As‐grown arsenic‐doped CdTe layers had room temperature carrier concentrations in the 1014–1016 cm−3 range, and hole mobilities of about 35–65 cm2/V s. Low‐temperature photoluminescence spectra of arsenic‐doped CdTe epilayers grown by photoassisted MBE showed an emission peak at 1.51 eV, which is associated to the AsTe acceptor (arsenic occupying a Te site) with a 92 meV ionization energy. CdTe epilayers grown at low temperatures with photoassisted MBE have superior structural, optical, and electrical properties than those grown by conventional MBE. Arsenic doping of the HgTe/CdTe superlattice structure has resulted in in situ growth of p‐type modulation‐doped superlattices with enhanced mobilities. Undoped superlattices grown under the same conditions are n‐type. These results represent a significant step towards the in situ fabrication of photodiodes and other advanced devices based on HgTe/CdTe doped superlattice structures.

Low-leakage high-performance photovoltaic detectors were fabricated from long-wavelength infrared (LWIR) HgCdTe epitaxial material grown by metal-organic chemical vapour deposition (MOCVD) on GaAs substrates. Layers were grown by two different MOCVD techniques, a conventional alloy growth and an interdiffused multiple-layer growth. MOCVD HgCdTe layers were characterised by background electron concentrations of (1-3)*1015 cm-3 with electron mobilities up to 200000 cm2 V-1 s-1 at 77 K. Surface and cross-section dislocation densities were 106-107 cm-2 and occasionally (4-5)*105 cm-2. GaAs substrates were (100) and (111B) misoriented towards 110. The layer structure in which the devices were fabricated consisted of an absorbing LWIR HgCdTe layer grown on a buffer of CdTe. A thin layer (1-2 mu m) of wide-band-gap HgCdTe was grown last. Devices were fabricated in a single as well as double layers using a mesa geometry with a native oxide passivation. Junctions were formed at 2-3 mu m depth by a low-energy arsenic implant ( approximately 100 keV) which behaved as a finite diffusion source during the post-implant anneal. The best measured zero-bias resistance-area products (R0A) at 77 K were 1.67 Omega cm2 for the alloy layers for a cut-off wavelength of lambda c=14.94 mu m and 7.22 Omega cm2 for the interdiffused multiple layers for lambda c=15.92 mu m at 77 K. The results indicated a definite device performance improvement in double-layer compared to single-layer structures. Analysis of the transport properties for a device fabricated in a single layer with a cut-off wavelength of lambda c=8.35 mu m at 77 K and 9.1 mu m at 40 K suggested that the deviation from thermal processes occurs at temperatures of approximately 40 K.

Ballistic-electron-emission microscopy (BEEM) spectroscopy and imaging have been applied to the Au/GaN interface. In contrast to previous BEEM measurements, spectra yield a Schottky barrier height of 1.04 eV that agrees well with the highest values measured by conventional methods. A second threshold is observed in the spectra at about 0.2 V above the first threshold. Imaging of the Au/GaN interface reveals transmission in nearly all areas, although the magnitude is small and varies by an order of magnitude. BEEM of other GaN material shows no transmission in any areas.

GaAsSb is a low band gap, lattice matched to InP, alternative to GaInAs. Growth and doping using diethyltellurium and carbon tetrachloride were investigated. Hole concentrations up to 1.3×1020 cm−3 have been achieved in as‐grown carbon‐doped GaAsSb [i.e., no postgrowth annealing was necessary for dopant activation, a key requirement for n‐p‐n heterojunction bipolar transistor (HBT) structures]. This is a sevenfold improvement over the best carbon‐doped InGaAs reported by metalorganic chemical vapor deposition. Hall measurements indicate that GaAsSb’s hole mobility is 55%–60% of GaInAs’s, for a given carrier concentration. InP HBTs with carbon‐doped GaAsSb base are demonstrated.

`The demand for high detectivity LWIR IR focal plane arrays that operate at low backgrounds is shown to drive the HgCdTe technology toward increased detector performance. Reduced operating temperature together with advanced material technology and detector design are presented as solutions. High performance MWIR, MLWIR and LWIR HgCdTe detector test arrays and variable area test structures were recently demonstrated through the joint collaboration of Aerojet Electronic Systems Division and Rockwell International. These devices are based on the innovative buried planar heterostructure (BPH) detector architecture grown by liquid phase epitaxy of HgCdTe on II-VI substrates. The major features of the BPH design include planar geometry, heterostructure wide gap p-type on narrow gap n-type HgCdTe and a buried LWIR electrical junction. Excellent 78K median R(omicron )A performance across the IR spectrum from 5.2 micrometers to 12 micrometers is reported and shown to follow the diffusion trend line. Excellent 40K median R(omicron )A performance for devices with cutoffs ranging from 9 micrometers to 19 micrometers are also presented. LWIR R(omicron )A statistical performance data at both 78K and 40K from fanout test arrays are presented with median R(omicron )A values of 100 ohm-cm2 at 78K and > 106 ohm-cm2 at 40K for cutoffs of 10.4 micrometers and 11.4 micrometers respectively. The 90% test array operability was found to exceed 5 x 105 ohm-cm2 at 40K. Devices with median R(omicron )As of 20 ohm-cm2 at 78K and 7 x 105 ohm-cm2 at 40K were measured for cutoffs of 12 micrometers and 13 micrometers respectively. Uniform and high quantum efficiencies were measured at 40K with a median of approximately equals 70%.© (1994) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

Ballistic-electron-emission microscopy (BEEM) and spectroscopy have been used to characterize the Pd/GaN and Au/GaN interfaces. BEEM spectra yield a Schottky barrier height for Au/GaN of ∼1.05 eV that agrees well with the highest values measured by conventional methods. For both Pd and Au, a second threshold is observed in the spectra at about 0.2–0.3 V above the first threshold. Imaging of these metal/GaN interfaces reveals transmission in nearly all areas, although the magnitude is small and spatially varies. Attempts to perform BEEM measurements on other GaN material have resulted in no detectable transmission in any areas, even at voltages as high as 3.5 V.

Extensive data are presented on the arsenic doping characteristics of Hg1−xCdxTe layers grown by metalorganic chemical vapor deposition using the dopant source tertiarybutylarsine (TBAs). The incorporation of arsenic in the layer is proportional to the II–VI alkyl ratio during TBAs injection. High arsenic concentrations significantly increase the layer dislocation density. Acceptor activation efficiency (taken to be the 77 K carrier concentration divided by the layer arsenic concentration) is ∼50% for a wide range of conditions, but decreases for arsenic concentrations approaching 1018 cm−3. For arsenic concentrations below low‐1017 cm−3, the 77 K carrier concentration is stable even for sample annealing at 400 °C on the Te‐rich side of the phase boundary. 77 K hole mobility strongly depends on composition x. Variable temperature Hall effect measurements show that one layer exhibits the expected carrier freeze‐out with an ionization energy of 4.8 meV, but three other layers exhibit a much smaller degree o...

The causes for variations in quantum efficiency (QE) for boron‐implanted midwave infrared diodes formed in mercury cadmium telluride on CdTe buffered GaAs/Si substrates have been investigated. Smooth layers have QE≳30% with many of the diodes in the 50%–60% range. Layers having a faceted morphology produce diodes with QE

The Gal-xInxSb alloy system is a potentially important material for the fabrication of middle wavelength infrared detectors and emitters. In order to develop the use of this material we have investigated the liquid phase epitaxial growth of Ga1−xInxSb on GaSb via stepwise grading in the range of 400–600°C using a horizontal slider boat in a transparent furnace. Single crystal layers of Ga1−xInxSb have been obtained for the composition range 0

The imaging cathodoluminescence capability of a scanning electron microscope (SEM) was complemented by etch pit (EP) measurements and secondary ion mass spectroscopy (SIMS) to characterize structures of HgCdTe LPE grown both on CdTe and CdTe/sapphire (PACE‐1) (Ref. 1: W. E. Tennant, IEDM Technical Digest 1983, 704) substrates. In addition to providing the source for luminescence, the high‐power‐density SEM beam was exploited to perform in situ annealing which improved the CL efficiency and aided in the analysis. Selected CL/SEM data are shown for substrates, epilayers and interfaces. CdTe Bridgman grown substrates exhibited defect structures (twins, dislocations, precipitates, subgrain structure) and substantial differences in CL efficiency and response to electron beam (EB) annealing. Cd annealing of Bridgman substrates increases CL efficiency, removes sensitivity to EB annealing, and causes impurity redistribution as measured by SIMS. PACE‐1 substrates show higher defect density, an absence of subgrains...

Variable temperature Hall effect measurements have been made down to 9–10K on p-type Hg1−xCdxTe grown by liquid phase epitaxy on both CdTe and sapphire substrates. Carrier freeze-out was usually observed throughout the measured temperature range. For most samples, the hole mobility was well-behaved and exhibited a maximum at ˜ 35K. Values of acceptor ionization energy EA and donor concentration ND were estimated from the data, using a model assuming significant compensation, which provided a good fit to the low temperature data. In addition, values of ND were also estimated from an analysis of the low temperature mobility using the hole effective mass as a parameter to provide reasonable agreement between the ND values calculated from the Hall coefficient and mobility data. The measured carrier concentration is a result of close compensation between stoichiometric acceptors and donors, with ND usually in the low-1017 cm−3 range. Average values of EA for as-grown, undoped x = 0.32 layers on CdTe and sapphire substrates are 7.4 and 6.6 meV, respectively. An activation energy of 0.84 meV was determined for a Cu-doped x = 0.32 layer that was annealed in Hg vapor to reduce the number of Hg vacancies. The average EA for undoped Hg-annealed x = 0.22 layers on CdTe substrates is 2.35 meV. Layers with x = 0.32 grown on sapphire substrates have average carrier concentrations of 2.92 (σ = 0.54) × 1016 cm−3, compared with 4.64 (θ = 1.26) × 1016 cm−3 for the same composition layers grown on CdTe substrates.

The isothermal vapor‐phase‐epitaxial (ISOVPE) growth of device‐quality HgCdTe layers on both CdTe and CdTe/Al2O3 substrates has been demonstrated. The material and device properties on both types of substrates have been studied and compared with reported values for HgCdTe grown by other techniques. The as‐grown ISOVPE Hg1−xCdxTe (x≂0.3) epilayers are always p type with carrier concentrations of ∼5×1015 to 3×1016 cm−3 and mobilities of ∼230–260 cm2/V s at 77 K. The temperature and compositional dependence of electrical properties of ISOVPE Hg1−xCdxTe are somewhat different from those of liquid‐phase epitaxy (LPE) and bulk HgCdTe. In particular, the acceptor ionization energy, EA =7 meV, is about half that obtained in midwavelength infrared LPE or bulk HgCdTe, and nearly independent of composition x. The R0A product of a representative photodiode (λc ≂4.65 μm, 77 K) is 2×106 and 4 Ω cm2 at 77 and 195 K, respectively, with comparable device qualities seen on both CdTe and CdTe/Al2O3 substrates.

Reported here, for the first time, is the lattice matched growth of InAs1-xSbx on GaSb. The thermodynamic incompatibility of the system, i.e., the strong tendency for the In-As-Sb liquid to dissolve the GaSb substrate, was solved via a novel liquid phase epitaxial growth technique. Liquid compositions for lattice matching conditions have been determined in the 400-600°C range. Epitaxial growth has been examined for (100), (111)B and (111)A orientations. Dislocation etch pit densities for lattice matched, and near lattice matched conditions are shown to be less than 104-cm−2 and 105-cm−4, respectively. The composition of the epitaxial layers are determined by the Gandolfi X-ray diffraction technique and compositional homogeneity has been confirmed by SEM X-ray analysis. Some material related device properties which demonstrate the reproducibility of the growth technique are presented.

The liquid phase epitaxial technique in a horizontal boat is used to grow large area epitaxial layers of Hg1−xCdxTe on CdTe substrates with x=1 to x=0.15. Areas as large as 25 cm2 have been grown from Te‐rich melts that have excellent compositional uniformity (Δx=0.001–0.0028) and run‐to‐run reproducibility (Δx=0.003–0.004). Results are presented on surface morphology, compositional grading, and electrical properties. Histograms are presented showing run‐to‐run wavelength reproducibility and uniformity across the epilayers for both 10–15 and 20–25 cm2 areas for selected wavelengths with x≂0.3. Data are presented showing run‐to‐run uniformity of carrier concentration (4.5±0.66×1016 cm−3) and hole mobility (272±15 cm2/Vs) at 77 K for x≂0.3, including their dependence on wavelength.

High quality InAsxSbyPl-x-y quaternary layers, which are lattice matched to InAs, have been grown successfully on InAs substrates by liquid phase epitaxy. Both Graded and constant composition InAsxSbyPl-x-y layers have been grown. In addition, the graded InAsxSbyPl-x-y layer has been used as a buffer layer for the growth of InAsl-xSbx on an InAs substrate.

Long and middle wavelength infrared (LWIR, MWIR) p+‐n photodiodes have been fabricated with Hg1−xCdxTe (0.20

To alleviate the lattice mismatch for InAs1−xSbx (0

This letter reports the achievement of a high‐performance, broad‐spectral‐band infrared detector with the InAs1−xSbx alloy system using a backside‐illuminated heterostructure approach. The basic structure of the detector is obtained with InAs1−xSbx grown by a liquid phase epitaxy technique on a GaSb substrate under lattice‐matched or nearly lattice‐matched conditions. The measured photoresponse covers the spectral range 1.7–4.2 μm with an external quantum efficiency of 65% without antireflective coating. The typical zero‐bias resistance area product is in excess of 109 Ω cm2. The typical leakage current desity is less than 10−9 A/cm2 for 100 mV reverse bias. All parameters were measured at 77 K.

Device‐quality Hg1−xCdxTe (0.26

High‐performance backside‐illuminated photodiodes have been fabricated for the first time from InAs1−xSbx‐InAs heterostructures prepared by liquid‐phase‐epitaxy technique. The peak wavelength can be tuned compositionally from 3.1 to over 7.0 μm at 77 K. The half‐width of the spectral responses as narrow as 1760 A (at 4.0 μm) have been achieved. Internal quantum efficiencies of 90% and zero‐bias‐resistance–area products of 2×107 Ω cm2 have been obtained at 77 K.

Infrared photodiodes fabricated with HgCdTe epilayers grown on GaAs substrates by molecular beam epitaxy (MBE) are reported here for the first time. Growth was carried out on the (211)B orientation of GaAs, and the as‐grown epilayer (x=0.24) was p type. The n‐p junction was formed by Be ion implantation, the resistance‐area product (R0 A) at zero bias was 1.4×103 Ω cm2 , the wavelength cutoff was 8.0 μm, and the quantum efficiency was 22%; all were measured at 77 K. We show that in the diffusion regime diodes fabricated with MBE HgCdTe/GaAs have comparable R0 A product values to those made with HgCdTe grown by bulk techniques. This result discloses new possibilities for advanced monolithic HgCdTe devices based on GaAs integrated circuit technology.

Low‐capacitance (< 10 pF) Pb1−xSnxTe photodiodes operating near 77 °K (areas 1.7 × 10−4 cm2) have been obtained via liquid‐phase epitaxial growth of low‐carrier‐concentration material (low 1014 cm−3 to high 1015 cm−3). Response to a mode‐locked 1.06‐μm Nd:YAG laser with the devices terminated in 50 Ω indicated a frequency response to 400 MHz. With a 14‐Ω load and by exciting a photocurrent with radiation from a CO2 laser, the shot noise rolloff point was found to be 1200 MHz. Optimum parameters have not yet been achieved, as evidenced by the increase in frequency response with increase in reverse bias; these results represent only a lower limit to this material's capability.

This is the final report of the first phase of a program whose objective is the development of a long wave infrared (LWIR) HgCdTe material technology based on heteroepitaxial growth on low cost substrates and to advance this technology to device processing and ultimately focal plane array demonstration. A matrix of five growth techniques and three base substrates (GaAs, Ge and Si) were used to identify the most promising approach. Three epitaxial vapor growth techniques, Laser Assisted Deposition and Annealing (LADA), Molecular Beam Epitaxy (MBE) and Organo-Metallic Vapor Phase Epitaxy (OMVPE) were used to grow epitaxial layers of CdTe on the base substrates. Single crystalline layers of CdTe with near-bulk qualities were obtained on all three base substrates (GaAs, Ge, Si) by all three CdTe vapor growth techniques (LADA, MBE, OM-VPE). OM-VPE growth CdTe on GaAs had the highest crystallinity as determined by x-ray double crystal diffraction. The growth of an additional CdTe layer by Liquid Phase Epitaxy (LPE) improved by the crystallinity of the vapor growth CdTe, but often resulted in higher impurity levels of base substrate elements in the epitaxial CdTe layer due to slight chemical attack of the base substrate during the CdTe LPE cycle. LPE and Isothermal VPE (ISO-VPE) were used for the epitaxial growth of the active HgCdTe layer. Originator furnished keywords include: HgCdTe, Mercury Cadmium Telluride, CdTe, Cadmium Telluride, ISO-VPE, LPE, LADA, MBE, OMVPE, GaAs, Ge, si, PACE-2 Alternative Substrates.

We have achieved multiple‐layer liquid epitaxial growth of Pb1−xSnx Te from Pb–Sn solution. Hall‐effect and capacitance measurements determine carrier concentrations to be as low as 3 × 1015 cm−3 at 77 °K. Interference microscopy reveals that deviations from planarity of the grown surface are less than 1 μm over an area of 1 mm2.

Light atom species, such as Li, Mg, B, Be, Cl, F and Al implanted in bulk and epitaxial HgCdTe of compositions from 3 to 12 µm cut-off yielded n/p junctions. The nature of these junctions has not previously been understood. Implantation of light atoms has been observed to induce n-type electrically active defects which propagate deep into the material during the implantation process. The experiments, performed on an epitaxial wafer of ∼5 µm cut-off wavelength, showed an electron profile of the implanted layer 3 to 4 times deeper than the mean projected range determined by SIMS measurements. The results are in good agreement with the graded junction profile determined from C-V measurement, and have junction depths of 2–3 µm determined from EBIC measurements. It has been concluded that the junction formation mechanism in HgCdTe is determined primarily by radiation induced mobile defects.