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Purpose: To investigate the effect of adhesive type and long-term aging on the shear bond strength (SBS) between silicabased ceramics and composite cement (CC). Materials and Methods: Lithium-silicate (LS), feldspathic (FD) and polymer-infiltrated ceramic (PIC) blocks were sectioned (10 x 12 x 2 mm) and divided into 24 groups considering the factors: "ceramics" (LS, FD, and PIC), "adhesive" (Ctrl: without adhesive; 2SC: 2-step conventional; 3SC: 3-step conventional; 1SU: 1-step universal), and "aging" (non-aged or aged [A]). After the surface treatments, CC cylinders (n = 15, ɸ=2mm; height = 2mm) were made and half of the samples were subjected to thermocycling (10,000) and stored in water at 37°C for 18months. The samples were submitted to SBS testing (100 kgf, 1mm/min) and failure analysis. Extra samples were prepared for microscopic analysis of the adhesive interface. SBS (MPa) data was analyzed by 3-way ANOVA and Tukey's test (5%). Weibull analysis was performed on the SBS data. Results: All factors and interactions were significant for SBS (p<0.05). Before aging, there was no significant difference between the tested groups and the respective control groups. After aging, the LS_1SU (22.18±7.74) and LS_2SC (17.32±5.86) groups exhibited significantly lower SBS than did the LS_Ctrl (30.30±6.11). Only the LS_1SU group showed a significant decrease in SBS after aging vs without aging. The LS_1SU (12.20) group showed the highest Weibull modulus, which was significantly higher than LS_2SC_A (2.82) and LS_1SU_A (3.15) groups. Conclusion: No type of adhesive applied after silane benefitted the long-term adhesion of silica-based ceramics to CC in comparison to the groups without adhesive. [ABSTRACT FROM AUTHOR]

Polylactic acid (PLA) composites reinforced with 10 wt% of flax (FF) or bamboo (BF) fibers were prepared via an internal mixer and/or twin-screw extrusion. Alkali pretreated fibers were soaked in silane to improve adhesion between fibers and matrix. 0.8 wt% of Joncryl™, a grafted copolymer acting as PLA chain extender, was also used alone or in combination with silane treatment of fibers to improve interfacial adhesion. The influence of silane treatment and/or Joncryl on the composite materials on mechanical, thermal and thermomechanical properties of materials processed through injection molding was investigated. Improved adhesion of the fibers to the matrix was shown using a scanning electron microscope. Fourier Transform Infrared Spectroscopy indicated that chemical bonds were formed between the silane coupling agent and fibers. X-ray Photo-electron Spectroscopy confirmed that fibers and silane derivatives were effectively coupled. XPS also highlighted that silane coupling agent reacted in higher amounts on bamboo than flax fibers, probably due to a higher amount of lignin in the case of bamboo fibers. Thermogravimetric analyses indicated that silane-treated flax and bamboo increased the thermal stability of the corresponding composites (PLA-SFF and PLA-SFB) compared to non-treated fiber composites. The incorporation of Joncryl alone entailed a degradation of the thermal stability of the corresponding composites (PLAJ-FF and PLAJ-FB) but enhanced the PLA/fibers interfacial adhesion. The combination of Joncryl and silane treatment resulted in strong improvements of thermal stability and interfacial adhesion for the PLAJ-SFF and PLAJ-SBF composites. Increase in tensile moduli and decrease in tensile strengths with the incorporation of the pristine fibers were noted. For silane-treated fibers, the tensile modulus and the strength of the corresponding composites were improved when adding Joncryl alone or in combination with silane. From also rheological and molar weight measurements, it could be concluded that Joncryl acts both as PLA chain extender and coupling agent. [ABSTRACT FROM AUTHOR]

The purpose of the work is to present issues related to the influence of surface treatment on the strength of adhesive joints of C45 steel sheets by grinding based on experimental research. These issues were related to determining the impact of the gradation and type of abrasive material on the strength of adhesive joints of the steel sheets. The grinding was carried out manually using an angle grinder with a disc diameter of 125 mm and a rotational speed of 11.060 min-1, using abrasive materials with grains made of: ceramics, zirconium and electro-corundum with a gradation of P40, and sandpaper with grains made of electro-corundum with various grain sizes with three gradations P40, P220, P400 (according to European FEPA standards). To make the adhesive joints of steel sheets, the epoxy adhesive was used, which contains an epoxy resin based on bisphenol A and a triethyleneteramine curing agent. A profilographometer from Hommel - Etamic was used to determine selected 2D and 3D surface roughness parameters, and the strength tests of the steel sheets adhesive joints were performed on a ZWICK/ROELL Z150 testing machine. The analysis of the tests showed a significant impact of the surface treatment method on the attained shear strength of the steel sheets adhesive joints. Comparing the samples prepared with electrocorundum of the variable gradation, the tests exhibited that the samples prepared with P40 paper had the highest roughness, while samples prepared with P400 paper had the highest shear strength. Roughness analysis indicated that in the comparison group of samples prepared with abrasives of the various abrasive materials, ceramics showed the highest roughness parameters and the shear strength of the adhesive joints after this treatment. [ABSTRACT FROM AUTHOR]

Boron nitride (hBN) serves as an outstanding high‐performance polymer organic filler. However, its hexagonal crystal structure renders it chemically inert, thus limiting its applications. This study proposes the modification of hBN using economical amine and anhydride curing agents to reduce aggregation and enhance the heat conduction of epoxy resin. Specifically, the DETA curing agent and methyl tetrahydrophthalic anhydride (MTHPA) curing agent were grafted onto the hBN surface via ball milling and eco‐friendly water scrubbing processes. Subsequently, the modified functionalized BNNS were uniformly dispersed in epoxy resin via a wet process to form composite materials. Results indicate that both modified fillers maintain good dispersion at the epoxy interface. Compared to epoxy resin, the heat conduction of the EP/MTHPA‐BNNS composite material with 10 vol% loading increased by 212%. The EP/DETA‐BNNS composite exhibited a relative thermal conductivity enhancement of 191%. Moreover, both of materials demonstrated significantly improved thermal stability, with slightly reduced breakdown strength. Mechanical property testing revealed a maximum increase of 187.5% in fracture elongation. Highlights: Comprehensive study on curing agent modified hBNHigh dispersion of BNNS after wet ball millingModified BNNS improves composite interface propertiesThe thermal conductivity increases twice under 10 wt% BNNS loadingComposite materials with outstanding electrical insulation and high fracture elongation [ABSTRACT FROM AUTHOR]

The aim of this investigation was to evaluate the effect of etching protocols on bond strength, surface roughness, and mechanical properties of a zirconia-reinforced lithium silicate (ZLS) CAD/CAM-ceramic. In total, 100 bars (ISO 6872), 75 plaques, and 25 cubes were cut from ZLS blocks(Vita Suprinity®). The surfaces were standardized, crystallized and divided into five groups: 1. control (no/treatment-C), 2. 5%-Hydrofluoric-acid (HF)/20 s (HF5%20s), 3.HF5%60s, 4.HF10%20s, and 5.HF10%60s. Flexural strength (FS) (three-point bending test, 1 mm/min), roughness (Pa), and micro-shear bond-strength (µSBS) tests were performed. The data were statistically analyzed with one-way ANOVA, Tukey's test (p ˂ 0.05) and Weibull (FS data). C showed higher Pa (1.176 ± 0.370 µm) than HF10%60s (0.627 ± 0.236 µm) and all other groups. Groups C and 20 s showed the most irregular surface patterns. The FS results were not influenced by etching protocols, while the Weibull modulus was, with the 5%HF groups being the most reliable (m: 5.63/6.70), while C and HF10%60s (m: 2.78/2.73) were the least reliable. All fractures originated from surface defects on the treated side of specimens. The 5%HF groups showed higher µSBS (20 s: 21.35 ± 4.70 MPa; 60 s: 23.50 ± 4.27 MPa) than the 10%HF groups (20 s: 14.51 ± 2.47 MPa; 60 s: 16.54 ± 3.12 MPa) and C (6.46 ± 2.71 MPa). The most prevalent failure pattern was "mixed" for etched groups, and "adhesive" for C. Etching protocols affect the evaluated properties by roughening materials' surface and, in some cases, regularizing surface defects. The best overall outcomes were achieved when applying 5%HF. [ABSTRACT FROM AUTHOR]

Thermoplastic composites are gaining widespread application in aerospace and other industries due to their superior durability, excellent damage resistance, and recyclability compared to thermosetting materials. This study aims to enhance the lap shear strength (LSS) of resistance-welded GF/PP (glass fiber-reinforced polypropylene) thermoplastic composites by modifying stainless steel mesh (SSM) heating elements using a silane coupling agent. The influence of oxidation temperature, solvent properties, and solution pH on the LSS of the welded joints was systematically evaluated. Furthermore, scanning electron microscopy (SEM) was utilized to investigate the SSM surface and assess improvements in interfacial adhesion. The findings indicate that surface treatment promotes increased resin infiltration into the SSM, thereby enhancing the LSS of the resistance-welded joints. Treatment under optimal conditions (500 °C, ethanol solvent, and pH 11) improved LSS by 27.2% compared to untreated joints. [ABSTRACT FROM AUTHOR]

The purpose of this study was to investigate the effect of silane treatment of a resin-coated resin-based composite (RBC) base material on its microtensile bond strength (μTBS) to a computer aided-design/computer-aided manufacturing (CAD/CAM) ceramic restorative material. RBC blocks (4 mm × 7 mm × 10 mm) were prepared, and the adherend surfaces were prepared as follows: no resin coating + no silane treatment (Group I), no resin coating + silane treatment (Group II), resin coating only (Group III), and resin coating + silane treatment (Group IV). The resin coating was applied with Clearfil SE Bond and flowable RBC to the adherend surface. Each treated sample was bonded to a ceramic block using Panavia V5. After storage in 37 °C water for 1 week, microspecimens were fabricated, and the μTBS was tested. The failure mode of each specimen was determined using stereomicroscopy and scanning electron microscopy. The µTBS of Group II (20.2 ± 4.0 MPa) was not significantly different from that of Group I (17.6 ± 5.9 MPa) (p > 0.05), and the µTBS of Group I was significantly smaller than that of Group III (21.3 ± 7.2 MPa) (p < 0.05). The µTBS of Group IV (24.9 ± 3.8 MPa) was significantly greater than that of Group III (p < 0.05). Our findings indicate that silane treatment of the resin-coated surface can enhance the µTBS. Silane treatment of RBC base material was not effective when prepared without resin coating. [ABSTRACT FROM AUTHOR]

Self adhesion is a simple and effective bonding technique that can be used to produce environmentally friendly and green straw-based fiberboard (CLS) through deep eutectic-like solvent (DES) treatment. This article mainly introduces the use of DES composed of choline chloride and oxalic acid. DES is diluted with deionized water and straw is immersed in it, and finally dried into pretreated fiber raw materials. Fiber boards are prepared by adjusting the hot pressing parameters and the preset moisture content of straw itself for hot pressing solidification. The aim of this study was to investigate the effects of different processing parameters (hot pressing temperature and straw moisture content) on the microstructure, physical properties, and mechanical properties of CLS. Straw-based fiberboard heated at 180 ° C exhibited the best mechanical and water resistance performance. The fiberboard reached its highest mechanical performance at a moisture content of 50%. The bending performance of fiberboard produced at 180 °C reached 13.5 MPa, and compared with the board manufactured at 120 °C, the bending strength, tensile strength, and internal bonding strength increased by 320%, 224%, and 280%, respectively. [ABSTRACT FROM AUTHOR]

This article presents a comprehensive review of the advancements in the use of Date Palm Fiber (DPF) reinforced composites, highlighting their mechanical, thermal, and morphological properties and the enhancements achieved through various modification techniques. Date palm fibers, a sustainable and biodegradable resource, have garnered significant interest due to their potential in reducing environmental impact across several key industries, including building and construction, automotive, and packaging. The review discusses the effects of hybrid approaches and physical and chemical treatments on the mechanical properties of DPF composites, demonstrating improvements in tensile strength, elasticity, and flexural strength through optimized fiber‐matrix bonding and reduced moisture absorption. Thermal behavior analyses through Thermogravimetric Analysis (TGA), Dynamic Mechanical Analysis (DMA), and thermal conductivity underscore the composites' suitability for applications requiring high thermal stability and conductivity for insulation applications. Morphological studies reveal that surface‐treated fibers integrate more effectively with various polymeric matrices, leading to enhanced composite performance. The practical applications of DPF composites are explored, emphasizing their role in promoting sustainable manufacturing practices. Challenges such as scalability, cost‐efficiency, and performance consistency are addressed, alongside future perspectives that suggest a promising direction for further research and technological development in the field of natural fiber composites. This review aims to solidify the foundation for ongoing advancements and increase the adoption of DPF composites in commercial applications. [ABSTRACT FROM AUTHOR]

The increasing environmental concerns and stringent regulations targeting emissions and energy efficiency necessitate innovative material solutions that not only comply with these standards but also enhance performance and sustainability. This study investigates the potential of heterojunction bilayer composites comprising stainless steel (SUS) and polyamide 66 (PA66), aiming to improve fuel efficiency and reduce harmful emissions by achieving lightweight materials. Joining a polymer to SUS is challenging due to the differing physical and chemical properties of each material. To address this, various surface treatment techniques such as blasting, plasma, annealing, and etching were systematically studied to determine their effects on the microstructural, chemical, and mechanical properties of the SUS surface, thereby identifying mechanisms that improve adhesion. Chemical etching using HNO3/HCl and CuSO4/HCl increased surface roughness and mechanical properties, but these properties decreased after annealing. In contrast, K3Fe(CN)6/NaOH treatment increased the lap shear strength after annealing. Blasting increased surface roughness and toughness with increasing spray pressure and further enhanced these properties after annealing. Contact angle measurements indicated that the hydrophilicity of the SUS surface improved with surface treatment and further improved due to microstructure formation after annealing. This study demonstrates that customized surface treatments can significantly enhance the interfacial adhesion and mechanical properties of SUS/polymer heterojunction bilayer composites, and further research is recommended to explore the long-term stability and durability of these treatments under various environmental conditions. [ABSTRACT FROM AUTHOR]

This study aimed to use a carboxybetaine methacrylate (CBMA) copolymer solution to surface treat 3D printed clear aligners at different fabrication stages, to impart antifouling properties, and assess the surface treatment at various fabrication stages' impact on physico-mechanical characteristics. Surface treatments using a blend of 2-hydroxyethyl methacrylate (HEMA) and CBMA, termed CCS, were performed at various stages of 3D printed clear aligner fabrication. Experimental groups, CB1, CB2, and CB3, were determined by the stage of surface treatment during post-processing. CB1, CB2, and CB3 received treatment before post-curing, after post-curing, and after post-processing, respectively. Untreated samples served as controls. Physical and mechanical properties were assessed through tensile testing, Fourier-transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and UV-Vis spectroscopy. The surface was further characterized through scanning electron microscopy and contact angle measurements. The cytotoxicity was assessed with 7-day elution and agar diffusion assays. Lastly, bacterial biofilm resistance was evaluated using confocal laser scanning microscopy. Crystal violet assay was performed using Streptococcus mutans. Surface treatment during CB1 stage exerted the most significantly unfavorable influence on properties of the 3D printed aligner resin. CB2 samples showed the maximum preservation of translucency even after 7-day aging. CB2 and CB3 phases showed enhanced hydrophilicity of sample surfaces with reduced adhesion of multispecies biofilm and S. mutans. Application of CCS surface treatment immediately after post-curing (CB2) can enhance the biofilm resistance of 3D printed clear aligners while maintaining high fidelity to optical translucency and constituent mechanical properties. [ABSTRACT FROM AUTHOR]

The main objective of this study is to investigate the effect of curing temperature on the mechanical properties of hemp fiber reinforced polymer (HFRP) composites. In this study, hemp fiber was considered as a reinforcement and epoxy resin with hardener as a matrix. The mercerization process was used to remove contaminants from the fiber surface. The overall volumetric fraction used was 40% fiber and 60% matrix. One composite sample was cured at open temperature (27 ± 3 °C) for 15 days and others at elevated temperatures such as 80, 120 and 160 °C for various durations such as 1, 2, and 3 h (h). Different mechanical tests were performed under ASTM standards to examine the mechanical performance of HFRP composites. The tensile and compressive properties such as Young's modulus, tensile and compressive strengths are higher in the specimens cured at 120 °C for 3-h. The flexural strength and stiffness are maximum in the composites cured at 80 °C for 3-h. The maximum interlaminar shear strength representing the composite's resistance to delamination is observed at 120 °C for 3-h curing condition. The Fourier transform infrared (FTIR) study identifies that the chemical treatment has reduced the impurities present on the fiber surface. Scanning electron microscopic (SEM) studies indicate better fiber/matrix adhesion in specimens cured at elevated temperatures than those cured at open temperature. Finally, this study emphasizes that curing at elevated temperature (120 °C for 3-h) improves the mechanical performance of the NFRP composites. [ABSTRACT FROM AUTHOR]

Utilizing recycled concrete aggregate (RCA) is a countermeasure to address the scarcity of landfills and the depletion of natural aggregates. Surface modification techniques have been proposed and implemented to improve the properties of RCA; however, to our best knowledge, few investigations on improving RCA under various pozzolanic slurry concentrations and extended soaking durations have been done. This study comprehensively assessed the properties and microstructure of low-strength RCA treated with cement–fly ash slurry with different concentrations and soaking durations. The purposes of this study were not only to provide the optimal slurry concentration and treatment duration but also to explore the enhancement mechanism of RCA under various treatment conditions. The RCA from concrete with a low-strength grade of 20 MPa was soaked in cement–fly ash slurry at low and high concentrations (i.e., 30% and 70% by mass of RCA, respectively) for 24 and 72 h. The physical and mechanical properties of RCA before and after treatment were evaluated through water absorption and crushing value measurements, respectively. Additionally, the pore structure, Ca(OH)2 contents, surface morphology, and phase compositions of RCAs were evaluated through a mercury intrusion porosimetry test, thermal gravimetric differential thermal analysis (TG-DTA), scanning electron microscopy, and X-ray diffraction (XRD) analyses, respectively. The water absorption of treated RCA reduced by 9.2%–37.9%, whereas the crushing value decreased by 8.6%–26.9% compared with the untreated RCA. The TG-DTA results indicated a 22.3%–43.8% increase in the Ca(OH)2 content of treated RCA. The XRD analysis depicted a higher ettringite (AFt) peak in all treated RCA samples compared with the untreated sample. For both concentrations, with a 24 h treatment, the slurry infiltration effect was clearly observable, whereas the 72 h treatment resulted in the formation of a pozzolanic coating layer on the RCA surface. In conclusion, the optimal slurry concentration and soaking duration were 70% and 72 h, respectively. [ABSTRACT FROM AUTHOR]

The construction sector is one of the main sources of pollution, due to high energy consumption and the toxic substances generated during the processing and use of traditional materials. The production of cement, steel, and other conventional materials impacts both ecosystems and human health, increasing the demand for ecological and biodegradable alternatives. In this paper, we analyze the properties of panels made from a combination of plant fibers and castor oil resin, analyzing the viability of their use as construction material. For the research, orthogonal fabrics made with waste plant fibers supplied by a company that deals with the manufacture of furniture and craft products were used. These fabrics were made with strips of plant fibers of the Calamus rotang, Bambusa vulgaris, Heteropsis flexuosa, and Salix viminalis species. To improve their compatibility with the castor oil resin, a cold argon plasma treatment was applied. The effect of the treatment on the properties of the fibers and the panels was analyzed. The density, water absorption capacity, and swelling percentage were evaluated. Tensile, compression, static bending, and linear buckling tests were carried out. The study found that panels made with treated fiber fabrics exhibited a reduction of approximately 10% in absorption capacity and up to 35% in swelling percentage values. Panels made with Bambusa vulgaris fabrics exhibited the highest strength and stiffness values. Numerical models were constructed using commercial finite element software. When comparing the numerical results with the experimental ones, differences of less than 15% were seen, demonstrating that the models allow adequately predicting the analyzed properties. On comparing the values obtained with the characteristic values of oriented strand board, the results suggest that panels made with unconventional materials could replace commercial panels traditionally made with wood-based fibers and particles and other composite materials in several applications in the construction industry. [ABSTRACT FROM AUTHOR]

The present study focuses on the fabrication and characterization of cerium oxide (CeO2)-doped yttria-stabilized zirconia (YSZ) composite particles, aiming to enhance the durability of thermal barrier coatings (TBCs) in high-temperature applications such as gas turbines and aircraft engines. The incorporation of CeO2 into the YSZ matrix was motivated by the need to address the limitations of YSZ coatings, particularly their phase transformation and thermal degradation at temperatures exceeding 1300 °C. The synthesis of a composite with a core–shell structure, where CeO2 is doped into YSZ particles, was pursued to improve the thermal stability and reduce the thermal conductivity of the material. The fabrication process involved surface treatment of YSZ particles with HCl and NH4OH to enhance their dispersion characteristics, followed by the adsorption of CeO2 nanoparticles precipitated from Ce precursors. The study revealed a reduction in the average particle size and improved the dispersion stability of the surface-treated YSZ. Notably, base-treated YSZ exhibited increased CeO2 adsorption due to the strong interaction between Ce ions and surface hydroxyl groups. The successful formation of the YSZ@CeO2 core–shell structure was confirmed through XRD, HR-TEM, and SAED analyses. The study suggest that base-treated YSZ@CeO2 composites have the potential to extend the operating life and improve the performance of TBCs under extreme temperature conditions, which may contribute to the development of more resilient thermal barrier systems. [ABSTRACT FROM AUTHOR]

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The renewable nature and exceptional strength-to-weight ratio of bamboo have led to numerous studies on incorporating bamboo fiber (BF) in composite fabrication. The mechanochemical BF extraction process used to produce high-quality micron fibers still faces limitations such as low percentage (%) yield and hydrophilicity. Moreover, the bead formation during BF extraction reduces the % yield and complicates the fiber separation process. This study introduces an innovative method for extracting BF with fewer fiber beads to improve the % yield. The process parameters were optimised using the response surface method (RSM) having a face-centred central composite design (FCCD). The optimal fiber extraction conditions were 80.61 min of boiling with 15% NaOH concentration and stirring at 1800 rpm. The most influencing parameter was identified using analysis of variance (ANOVA) and parametric analysis. Diisopropanolamine (DIPA) was used to graft amine functional groups on BF's surface to increase their hydrophobicity, whose confirmation was obtained using water retention value (WRV) analysis. Fourier-transform infrared spectroscopy (FTIR) validates the surface modification of BF. The crystallinity of BF appeared to be minimally affected by the DIPA modification, as confirmed by the X-ray diffraction (XRD) analysis. Field-emission scanning electron microscopy (FESEM) analysis of BF and DIPA-modified BF reveals well-separated fibers with minimal cellulose surface peeling after surface treatment. Thermogravimetric (TG) and differential thermogravimetric (DTG) analyses were also accomplished to validate the improved thermal stability of BF by amine-based treatment. [ABSTRACT FROM AUTHOR]

Aluminum and its alloys are essential in construction due to their lightweight nature and recyclability. To enhance durability, protection against corrosion is vital, with cataphoretic painting being particularly effective. This study evaluated the damage rate of cataphoresis coatings on AW 1050 H24 aluminum, focusing on the impact of different degreasing solutions. By analyzing temperature, concentration, and deposition time, the study found that concentrations above 5.25 % degrade surface quality due to aluminum dissolution, while temperatures between 37 °C and 50 °C are optimal. At higher temperatures, shorter deposition times improve quality, whereas longer times lead to defects. [ABSTRACT FROM AUTHOR]

The chemical modification of carbon fiber surface often uses toxic reagents and harsh reaction conditions, while the preparation process of metal‐phenol networks (MPNs) is simple, rapid, non‐toxic and harmless, which provides a direction for alleviating environmental problems. In this study, tannic acid (TA) was coordinated with Fe3+ to form MPNs, which was coated on the surface of carbon fibers through π‐π interaction. The results indicated that oxygen functionalities on the surface of the MPN coating can facilitate better adhesion between the carbon fiber and the epoxy resin, when the molar ratio of TA to Fe3+ is 1:3 and the pH is 4, the interlaminar shear strength (ILSS) performance of the composite material reaches its optimal level. In addition, a green and non‐destructive method is provided for the surface modification of carbon fiber, which can effectively optimize the interfacial properties of carbon fiber reinforced polymer (CFRP) composites. [ABSTRACT FROM AUTHOR]

Atmospheric plasma jets generated from air or nitrogen using commercial sources with relatively high energy densities are commonly used for industrial applications related to surface treatments, especially to increase the wettability of polymers or to deposit thin films. The heat fluxes to which the substrates are subjected are typically in the order of 100–300 W/cm2, depending on the treatment conditions. The temperature rise in the treated polymer substrates can have critical consequences, such as a change in the surface crystallinity or even the surface degradation of the materials. In this work, we report the phase transitions of two semicrystalline industrial-grade polymer resins reinforced with glass fibers, namely polyphenylene sulfide (PPS) and polyphthalamide (PPA), subjected to plasma treatments, as well as the modeling of the associated heat transfer phenomena using COMSOL Multiphysics. Depending on the treatment time, the surface of PPS becomes more amorphous, while PPA becomes more crystalline. These results show that the thermal history of the materials must be considered when implementing surface engineering by this type of plasma discharge. [ABSTRACT FROM AUTHOR]

This research looked at how the properties of an epoxy-based biocomposite changed when a cellulose-free veldt grape (Cissus quadrangularis) fiber (VGF) and Ziziphus jujuba seed (ZJS) micro powder were added. The primary goal of this study was to reveal how cellulose-free plant fiber influences on the load-bearing and time-dependent behavior of a polymer matrix composite. The fiber was treated with 0.5, 1, and 2 N NaOH solution as three stands and subsequently treated using aminosilane. The composites were made using a hand layup process and tested. It is noted that the subsequent alkali treatment on fiber and silane treatment improved the mechanical properties by up to 59%. A highest tensile strength of 148 MPa was noted for composite with "A3" designation. Similarly, the fatigue life counts also improved from 974 to 36,471 counts when 30 vol.% of VGF addition with 1 vol.% of particle. Similar findings were found in SEM pictures of fractured composites, which showed strongly reacted phases of fiber. However, the addition of cellulose-free fiber slightly increased the water uptake behavior, but is acceptable in range. The results of this characterization study showed that epoxy with surface-modified VGF and ZJS composites might be employed in a variety of industrial applications to reduce weight and high-performance activities. [ABSTRACT FROM AUTHOR]

Highlights The mechanical properties of carbon fiber (CF) reinforced thermoplastic polymer composites are primarily governed by the interphase between CFs and matrix. However, the inherent inertness of CF surfaces combined with the high viscosity and processing temperatures of thermoplastic resin often result in relatively weak interfacial bonding. This study aims to enhance the interfacial adhesion of carbon fiber reinforced polyamide 6 composites to improve their mechanical properties. CFs were de‐sized and oxidized, followed by re‐sizing with silanized carbon nanotubes. Fracture morphology and composition analysis of the fibers were conducted, and the fibers were subsequently incorporated into composites for mechanical testing. Results revealed a 20.0% increase in tensile strength, a 25.11% increase in flexural strength, and a 24.88% increase in interlaminar shear strength for the resized‐carbon fiber reinforced polyamide 6 composites compared to the pristine‐carbon fiber reinforced polyamide composites. The cross‐sectional morphology of the modified composites exhibited a zig‐zag fracture pattern. Dynamic mechanical analysis indicated that the modified fibers required higher activation energy for the free movement of the polyamide 6 molecular chain. These findings suggest that surface treatment enhances the interfacial adhesive between CF and resin, thereby significantly improving the mechanical properties of carbon fiber reinforced polyamide 6 composites. An efficient and reliable carbon fiber surface treatment method is proposed. Surface modification improves surface chemical activity of carbon fibers. Composites show substantial improvements in mechanical properties. Interfacial performance enhancement mechanism of composite was revealed. [ABSTRACT FROM AUTHOR]

Purpose: Bioceramic coatings have been shown to promote bone repair, which aids in the early integration of implants. This study aimed to evaluate the influence of air abrasion with a bioceramic abrasive on the surface characteristics of different implant materials and surfaces. The dissolution of the applied treatment from the surfaces over 3 weeks was also assessed. Materials and Methods: Discs of three alloys used for dental implants were studied and compared: two types of commercially pure titanium (CpTi)/ (CpTi SLActive) and titanium‐zirconia (TiZr). The tested surfaces were: CpTi control (CpC), sandblasted (SB), sandblasted and acid‐etched (SBE), and CpTi SLActive®, (TiZr) Roxolid®. Three discs from each group underwent air abrasion with apatite bioceramic powders, 95% hydroxyapatite (HA)/5% calcium oxide (CaO), and 90% hydroxyapatite (HA)/10% calcium oxide (CaO). The treated discs were surface characterized by optical profilometry to obtain surface roughness, scanning electron microscopy (SEM), and energy dispersive X‐ray spectroscopy (EDS) to compare element weight percentages of titanium, calcium, and phosphate. Dissolution was assessed using inductively coupled plasma optic emission spectrometry (ICP‐OES). Results: Bioceramic powders were deposited on all tested surfaces leading to changes in surface characteristics. The only statistically significant differences between the material groups for surface roughness were found with 95% HA/5% CaO powder in the Sp and Rp parameters (p = 0.03 and 0.04, respectively). There were no significant differences in the Ca and P wt% between all groups and powders 95% HA/5% CaO and 90% HA/10% CaO (p = 0.14, 0.18, and p = 0.15, 0.12, respectively). A non‐uniform dispersion of the treatment on the surface layer was visible on all treated surfaces. The bioceramic powder continued to dissolute from the tested surfaces for 3 weeks. Conclusion: Bioceramic abrasion modifies implant surface characteristics, although the change in surface characteristics resulting from such treatment was not influenced by the implant material or surface treatment. Air abrasion with hydroxyapatite and calcium oxide bioceramics leaves powder deposits on the treated implant surfaces that could potentially influence the healing of implants affected by peri‐implantitis. [ABSTRACT FROM AUTHOR]

The iron (Fe) specimens selected as the substrate metal for this study were surface-treated using fluorine gas, and their wettability with liquid sodium (Na) was evaluated using the sliding angle. Additionally, the surface morphology and binding state were analyzed, and the applicability of wettability control with liquid sodium by fluorination was discussed using the analysis results. Fluorination formed a fluoride layer comprising FeF2 and FeF3 bonds on the iron surface. The composition of the fluoride layer varied, depending on the treatment conditions. The surface of the specimen that contains a lot of FeF3 bonds had a small sliding angle for the liquid sodium droplet and was harder to wet than the untreated specimen. In contrast, the surface of the specimen that contains a lot of FeF2 bonds had a large sliding angle for the liquid sodium droplet and was easier to wet than the untreated specimen. These results indicate that fluorination is an effective surface modification technique that can be applied to control the wettability of iron with liquid sodium. [ABSTRACT FROM AUTHOR]

This research investigates using Polyether ether ketone (PEEK) in dental prosthetics, focusing on enhancing the mechanical properties, adhesion capabilities, and environmental sustainability through AI-driven data analysis and advanced surface treatments. The objectives include improving PEEK's adhesion to dental types of cement, assessing its biocompatibility, and evaluating its environmental impact compared to traditional materials. The methodologies employed involve surface treatments such as plasma treatment and chemical etching, mechanical testing under ASTM standards, biocompatibility assessments, and lifecycle analysis. AI models predict and optimize mechanical properties based on extensive data. Significant findings indicate that surface-treated PEEK exhibits superior adhesion properties, maintaining robust mechanical integrity with no cytotoxic effects and supporting its use in direct contact with human tissues. Lifecycle analysis suggests PEEK offers a reduced environmental footprint due to lower energy-intensive production processes and recyclability. AI-driven analysis further enhances the material's performance prediction and optimization, ensuring better clinical outcomes. The study concludes that with improved surface treatments and AI optimization, PEEK is a promising alternative to conventional dental materials, combining enhanced performance with environmental sustainability, paving the way for broader acceptance in dental applications. [ABSTRACT FROM AUTHOR]

The vacuum‐ultraviolet‐photoionization chamber was constructed to allow controlled ion generation and well‐defined surface treatment with these ions at atmospheric pressure. It utilizes atmospheric helium plasma as a photon source and separates the ion generation from the plasma by an aerodynamic window. The ions are guided to the grounded substrate by a weak electric field, while the diffusive transport of neutrals is reduced by a helium gas flow along the substrate. Ionic species and the absolute ion flux were determined in the substrate region. Ion‐based thin film deposition using a C2H2 ${{\rm{C}}}_{2}{{\rm{H}}}_{2}$ precursor was investigated as a model process. The proposed system enables future investigation of e.g. the isolated interaction of ions with biological substrates. [ABSTRACT FROM AUTHOR]

Purpose: To investigate the effects of different surface treatments and thicknesses on the color, transparency, and surface roughness of ultra-transparent zirconia. Methods: A total of 120 Katana ultra-translucent multi-layered zirconia specimens were divided into 12 groups according to the thickness (0.3, 0.5, and 0.7 mm) and surface treatment (control, airborne particle abrasion [APA], lithium disilicate coating, and glaze on). Color difference (ΔE00) and relative translucency parameter (RTP00) were calculated using a digital spectrophotometer. The surface roughness (Ra, Rq, Sa, and Sq) was measured using a non-contact profile scanner. The surface morphologies and microstructures of the samples were observed using a tungsten filament scanning electron microscope. Statistical analyses were performed by one-way and two-way analysis of variance (ANOVA) followed by post hoc multiple comparisons and Pearson’s correlation (α = 0.05). Results: The results showed that the surface treatment, ceramic thickness, and their interactions had significant effects on ΔE00 and RTP00 (p < 0.001). The surface treatment significantly altered the micromorphology and increased the surface roughness of the ceramic samples. APA exhibited the lowest transparency, largest color difference, and highest surface roughness. Zirconia with 0.3 mm and 0.7 mm thicknesses showed strong negative correlations between Sa and RTP00. Conclusions: The three internal surface treatments significantly altered the surface roughness, color difference, and transparency of ultra-transparent zirconia. As the thickness increased, the influence of the inner surface treatment on the color difference and transparency of zirconia decreased. Clinical implications: For new zirconia internal surface treatment technologies, in addition to considering the enhancement effect on the bonding properties, the potential effects on the color and translucency of high-transparency zirconia should also be considered. Appropriately increasing the thickness of zirconia restorations helps minimize the effect of surface treatment on the optical properties. [ABSTRACT FROM AUTHOR]

Coatings play a crucial role in minimizing eddy current loss in soft magnetic composites (SMCs). The powder atomic layer deposition (PALD) technique was utilized to coat Fe–Ni–Mo soft magnetic powder in this study. The Al 2 O 3 coating fabricated via PALD enhanced corrosion resistance and reduced core loss in SMCs. Additional deposition cycles increased the resistivity of the Fe–Ni–Mo powder and the corrosion resistance of the Fe–Ni–Mo SMCs, indicating that the density and integrity of the amorphous Al 2 O 3 coating were enhanced. Thinner coatings (20 cycles) exhibited anodic passivation in corrosion, which was attributed to insufficient density. Nevertheless, an excessively thick coating (100 cycles) resulted in a decrease in effective permeability and an increase in hysteresis loss. The fabricated Fe–Ni–Mo SMCs (50 cycles) demonstrated a core loss of 603.1 mW/cm3 at 100 kHz/100 mT, coupled with an effective permeability of 108.5 and a Q value of 97.8 at 100 kHz. [ABSTRACT FROM AUTHOR]

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Copyright of Electromachining & Mould is the property of Electromachining & Mould Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

In this study, we investigated reducing the VUV irradiation dose required for modification of a silicone hard coat in plastic glazing for automobile windows by utilizing xenon excimer lamps. We assessed the effects of heating temperature on the surface composition and surface hardness in the modification of the hard coat using Fourier transform infrared spectroscopy and nanoindentation, respectively. We revealed that the higher the heating temperature during VUV irradiation, the greater the degree of modification and hardness of the surface layer at the same VUV irradiation dose, indicating that heating accelerates the modification and reduces the necessary VUV irradiation dose. [ABSTRACT FROM AUTHOR]

The current study evaluates the effect of morpholine on saliva-contaminated acrylic resin repaired with light-cured resin composites. Sixty rods of self-curing acrylic resin were fabricated and assigned into four groups of fifteen specimens and surface-treated with saliva, phosphoric acid (PH), morpholine (MR), liquid MMA monomer, and a universal adhesive agent (UA, Singlebond Universal) based on the following techniques: group 1, saliva; group 2, saliva + PH + MMA + UA; group 3, saliva + MMA + UA; and group 4, saliva + MR + MMA + UA. An Ultradent model was placed at the center of the specimen, and then the resin composite was pressed and light-cured for 20 s. A mechanical testing device was used to evaluate the samples' shear bond strength (SBS) scores. The debonded specimen areas were inspected under a stereomicroscope to identify their failure mechanisms. The data were assessed by employing the one-way ANOVA approach, and the significance level (p < 0.05) was established with Tukey's test. The greatest SBS scores for group 2 (30.46 ± 2.26 MPa) and group 4 (32.10 ± 2.72 MPa) did not differ statistically significantly from one another. The lowest SBS recorded for group 1 was 1.38 ± 0.87 MPa. All of the fractured samples in group 1 had an adhesive failure profile. Groups 2 and 4 had the greatest percentages of cohesive failures. This study concluded that applying phosphoric acid and morpholine to sandblasted self-curing acrylic resin contaminated with saliva before MMA and universal adhesive agents are applied is the most efficient protocol for stimulating SBS when it is repaired with light-cured resin composites. [ABSTRACT FROM AUTHOR]

Woven fabric structures facilitate the mechanical interlacement of textile yarns for increased strength, which leads to more balanced mechanical properties in a composite. This study worked on epoxy matrix composites reinforced with surface-modified cotton fabrics of different woven structures. The composites were fabricated using the resin vacuum bagging technique and mechanically characterized for tensile, three-point bending, and impact properties. Surface modification was conducted by alkali treatment using a 6% concentration of sodium hydroxide (NaOH). The interfacial adhesion of the various fabric structures and epoxy matrix was examined using a scanning electron microscope (SEM). The results obtained show that surface-treated composites yielded improved mechanical properties than untreated composites, with improvements of up to 14.4%, 36.2%, and 26.7% for impact, flexural, and tensile strengths, respectively. The different woven structures also significantly affected the mechanical performance of the composite. The composites of plain, herringbone, and twill woven structures presented better mechanical properties compared to the other woven composite structures in that order. The plain-woven composite structure, respectively, had the maximum impact, flexural, and tensile strengths of 80.03 KJ/mm2, 38.6 MPa, and 43.7 MPa. This was closely followed by the herringbone and twill-woven composite structures. SEM results revealed complete impregnation of fibers and a strong interfacial relationship between the thermoset matrix and the treated cotton fabrics in the composite laminate structures produced via the vacuum bagging technique. In conclusion, the study indicated that different weave structures and fiber surface treatments, as well as the vacuum bagging technique used, are of significant importance in enhancing the overall mechanical performance of woven fabric composites. [ABSTRACT FROM AUTHOR]

The purpose of the work is to present issues related to the influence of surface treatment on the strength of adhesive joints of C45 steel sheets by grinding based on experimental research. These issues were related to determining the impact of the gradation and type of abrasive material on the strength of adhesive joints of the steel sheets. The grinding was carried out manually using an angle grinder with a disc diameter of 125 mm and a rotational speed of 11,060 min-1, using abrasive materials with grains made of: ceramics, zirconium and electro-corundum with a gradation of P40, and sandpaper with grains made of electro-corundum with various grain sizes with three gradations P40, P220, P400 (according to European FEPA standards). To make the adhesive joints of steel sheets, the epoxy adhesive was used, which contains an epoxy resin based on bisphenol A and a triethyleneteramine curing agent. A profilographometer from Hommel - Etamic was used to determine selected 2D and 3D surface roughness parameters, and the strength tests of the steel sheets adhesive joints were performed on a ZWICK/ROELL Z150 testing machine. The analysis of the tests showed a significant impact of the surface treatment method on the attained shear strength of the steel sheets adhesive joints. Comparing the samples prepared with electrocorundum of the variable gradation, the tests exhibited that the samples prepared with P40 paper had the highest roughness, while samples prepared with P400 paper had the highest shear strength. Roughness analysis indicated that in the comparison group of samples prepared with abrasives of the various abrasive materials, ceramics showed the highest roughness parameters and the shear strength of the adhesive joints after this treatment.

Abstract This study focused on sustainable and novel development of concrete through treated and untreated plastic waste aggregates. In this study, the surface of Elec-waste coarse aggregates was treated with sulfuric acid, marble dust coating, silica fume coating, and alkaline bleach. Elec-waste aggregates were used in concrete by replacing natural coarse aggregates in amounts of 10%, 20%, and 30%. The 10%, 20%, and 30% Elec-waste replacement ratios resulted in the compressive strength reduction of 8.97%, 27.99%, and 42.01%, respectively. The same percentage of Elec-waste aggregates reduced the splitting tensile strength by 21.77%, 35.89%, and 47.89%, respectively. However, the slump was observed to increase by 41.4%, 52.1%, and 68.8%, respectively. All the considered treatments enhanced the performance of Elec-waste aggregate concrete (E-WAC). Overall, the best improvement in the performance of E-WAC was imparted by silica fume coating, irrespective of the quantity of Elec-waste aggregates. The present study proposed an expression to estimate the reduction of the compressive strength of E-WAC. It was demonstrated that the equation by JCI-08 predicted splitting tensile strength of E-WAC close to experimental results.

This study focuses on enhancing the surface characteristics of Ti–6Al–4V alloy fabricated through laser powder bed fusion (LPBF), a prominent additive manufacturing technique. The primary objective is to assess the impact of post-processing surface treatments on the surface roughness, microstructure, and mechanical properties of LPBF Ti–6Al–4V. As-built specimens with fully dense structures underwent sandblasting (SB), chemical etching (CE), and a combination of sandblasting and chemical etching (SB + CE). The investigation reveals significant variation in the surface morphology of as-built samples, primarily influenced by factors such as spattered particles, powder adhesion, and the stair-step effect. In the as-built condition, the down-skin exhibited the highest particle adhesion, covering 11.9 % of the surface. Sandblasting proved particularly effective in removing adhered particles, reducing surface roughness to 5.1 μm from an initial value of 17.8 μm for the down-skin surface. Furthermore, combining sandblasting and chemical etching was more effective than chemical etching alone in achieving uniform surface profiles. Tensile testing indicated that while the ultimate tensile strength remained unchanged, the strain at break significantly improved from 4.8 % to 11.5 %, representing a noticeable increase in ductility in post-processed samples compared to as-built conditions. These findings underscore the influence of post-processing treatments in mitigating surface roughness and enhancing ductility without compromising mechanical strength.

This systematic review evaluated the effect of different hydrofluoric acid (HF) etching regimens and a self-etch ceramic primer (SECP) on the flexural strength (FS) and fatigue failure load (FFL) of glass-ceramic materials.The identification of relevant studies was conducted by two authors in five databases: PubMED, Scopus, Web Of Science, LILACS and Virtual Health Library (BVS) until July 2022 with no year limit. The analysis was conducted in RevMan 5.4.1 Software (Cochrane Collaboration) using Random effect model at 5 %. The risk of bias of the included studies were assessed. From the 5349 articles identified, 34 were included for quantitative analysis. Meta-analysis showed that for predominantly glassy ceramics, etching with HF 5 % had no significant impact on FS, however, HF acid etching with concentrations greater than 5 % negatively impacted FS. For lithium disilicate glass-ceramics (LDGC) HF acid etching, negatively influenced FS, while increasing the FFL. HF etching negatively affected FS of hybrid ceramics. The self-etch ceramic primer and HF acid etching showed a similar impact on FFL and FS. This meta-analysis indicates that the impact of SECP and HF acid etching on the mechanical behavior of glass ceramics is material-dependent.

This review examined the efficacy of surface treatments and adhesive monomers for enhancing zirconia-resin bond strength. A comprehensive literature search in PubMed, Embase, Web of Science, Scopus, and the Cochrane Library yielded relevant in vitro studies. Employing pairwise and Bayesian network meta-analyses, 77 articles meeting inclusion criteria were analyzed. Gas plasma was found to be ineffective, while treatments including air abrasion, silica coating, laser, selective infiltration etching, hot etching showed varied effectiveness. Air abrasion with finer particles (25–53 µm) showed higher immediate bond strength than larger particles (110–150 µm), with no significant difference post-aging. The Rocatec silica coating system outperformed the CoJet system in both immediate and long-term bond strength. Adhesives containing 10-methacryloyloxydecyl dihydrogen phosphate (10-MDP) were superior to other acidic monomers. The application of 2-hydroxyethyl methacrylate and silane did not improve bonding performance. Notably, 91.2 % of bonds weakened after aging, but this effect was less pronounced with air abrasion or silica coating. The findings highlight the effectiveness of air abrasion, silica coating, selective infiltration etching, hot etching, and laser treatment in improving bond strength, with 10-MDP in bonding agents enhancing zirconia bonding efficacy.

A study on the effect of bond coating (BC) surface modifications prior to ceramic deposition is presented. Grit blasting and polishing were used to modify the BC surface finish. Thermal barrier coating (TBC) systems were made of a commercial yttria-stabilized zirconia (YSZ) deposited by electron beam physical vapor deposition on a β-(Ni,Pt)Al-coated Ni-based single crystal superalloy. Surface roughness measurements and scanning electron microscopy observations, before and after thermal cycling at 1100 °C, were performed to investigate the influence of the initial surface treatment on the YSZ/BC interface morphology and top coat spallation resistance. Surface states enhancing TBC spallation resistance have been found. In particular, it is shown that rumpling can be avoided even in the presence of phase transformations in the BC, by grinding samples with P600 SiC paper or by applying an "heavy" grit blasting leading to a thinner BC. [ABSTRACT FROM AUTHOR]

This study research focuses on optimising adhesion through surface treatments on 7075-T6 aluminium alloy substrates using a chromium-free protocol. The treatment involves acetone degreasing, NaOH etching, and sulphuric acid-based solution etching. Wettability analysis and scanning electron microscopy were used to characterise the treated surfaces, highlighting the effectiveness of the proposed protocol. The proposed etching protocol was then applied to aluminium alloy substrates, and fracture surfaces corresponding to each treatment were compared. Mechanical testing, specifically double cantilever beam (DCB) experiments, assesses the fracture energy of bonded assemblies in mode I. The results demonstrate that the sulphuric acid-based treatment significantly improves the surface characteristics, leading to enhanced adhesion and optimal fracture energy in bonded aluminium assemblies. [ABSTRACT FROM AUTHOR]

Background: Osseointegration depends on primary stability, and further, implant surface modifications may improve secondary stability. This randomized clinical trial evaluates whether adding a fluoride solution enhances the implant stability. Materials and Methods: Stability of dental implants with two different types of surface treatments was compared utilizing resonance frequency analysis (RFA). Twelve patients were recruited: eight females and four males with an average age of 58.3 years and they received either double acid etched implants (control: Porus Implant, Sistema Conexão) and double acid etched implants containing fluoride on their surfaces (test: Porus Nano Implant, Sistema Conexão). Each patient received one implant from the test category and another implant from the control category, resulting in 24 implants in this study. RFA, utilizing Osstell was used to assess the implant stability, immediately after the placement of implant and 15, 30 and 45 days post-implant placement. Results: At the initial time, there was no difference between the test and control groups regarding the ISQ. However, after 15, 30, and 45 days, ISQ values for the test group were significantly higher than the control group. When using implants without fluoride addition, it was observed that after 15 days, the ISQ values were lower than those found at the initial time, but after 30 days, values matched the initial. Concerning the test group results, the ISQ values from T0 (immediately after implant placement) to T3 (45 days after implant placement) always increased from every period of evaluation. Conclusions: It was concluded that double acid etched implants with surfaces containing fluoride solution increases the implant stability quotient, compared to implants with fluoride-free double acid etched surfaces.

Due to the need to develop methods that optimize the surface properties of lightweight alloys such as aluminum, titanium, and magnesium and align with contemporary requirements of the 21st century, such as enhanced environmental and sanitary efficiency, the plasma electrolytic oxidation (PEO) process stands out as a comprehensive solution. This process can develop oxide coatings on the mentioned alloys, which exhibit superior physical and chemical properties compared with conventional methods. Since 2010, research in this area has been conducted with real-world applications. Recent studies have adopted experimental design approaches to optimize parameters to reduce operational costs and make the technology more accessible. The present study conducted a comparative analysis between treatments performed by conventional methods and by plasma processes, highlighting the most promising results.

The iron (Fe) specimens selected as the substrate metal for this study were surface-treated using fluorine gas, and their wettability with liquid sodium (Na) was evaluated using the sliding angle. Additionally, the surface morphology and binding state were analyzed, and the applicability of wettability control with liquid sodium by fluorination was discussed using the analysis results. Fluorination formed a fluoride layer comprising FeF2 and FeF3 bonds on the iron surface. The composition of the fluoride layer varied, depending on the treatment conditions. The surface of the specimen that contains a lot of FeF3 bonds had a small sliding angle for the liquid sodium droplet and was harder to wet than the untreated specimen. In contrast, the surface of the specimen that contains a lot of FeF2 bonds had a large sliding angle for the liquid sodium droplet and was easier to wet than the untreated specimen. These results indicate that fluorination is an effective surface modification technique that can be applied to control the wettability of iron with liquid sodium.

Abstract This study involves the preparation of polymer composites using untreated and treated chicken feather, leather, and cow hair fiber in combination with unsaturated polyester resin (UPR) and analyzing the effect of gamma radiation on tensile properties. These fibers were incorporated into the resin matrix at various weight percentages (2%, 5%, 7%, 10%, 12%, and 15%). Additionally, the nanoparticle ZnO was added in the composites as filler to improve the mechanical properties. The composites that utilized treated chicken feather fibers yielded superior results in comparison to those that relied on untreated fibers. Prepared composites outperformed neat composites when inorganic components were added as filler to UPR. Composite materials’ mechanical properties, particularly their tensile strength and modulus, can be improved by combining cow hair feather and chicken feather mixed fibers with ZnO filler and gamma radiation modification, according to this study. The morphological and spectroscopic analysis provides supporting evidence for the mechanical strength between the fibers and the resin. Ionizing gamma radiation modification of the fiber resulted in superior tensile characteristics. The optimized composites of animal fibers were then subjected to gamma radiation of variable dose of 0, 2.5, 5 and 7.5 kGy. The tensile properties were found to be the maximum at 5 kGy. Scanning electron microscopy was used to investigate the structural changes caused by the incorporation of animal fibers (chicken feather and cow hair) and ZnO. Composite material and UPR functional group identification were achieved by means of Fourier Transform Infrared Spectroscopy (FTIR).

Abstract Existing ice particle jet surface treatment technology is prone to ice particle adhesion during application, significantly affecting surface treatment efficiency. Based on the basic structure of the jet pump, the ice particle air jet surface treatment technology is proposed for the instant preparation and utilization of ice particles, solving the problem of ice particle adhesion and clogging. To achieve efficient utilization of ice particles and high-speed jetting, an integrated jet structure for ice particle ejection and acceleration was developed. The influence of the working nozzle position (L d), expansion ratio (n), and acceleration nozzle diameter ratio (D n) length-to-diameter ratio (L n) on the ice particle ejection and acceleration was systematically studied. The structural parameters of the ejector were determined using the impact kinetic energy of ice particles as the comprehensive evaluation index, and the surface treatment test was conducted to verify the results. The study shows that under 2 MPa air pressure, the ejector nozzle parameters of n = 1.5, D n = 4.0, L d = 4, and L n = 0 mm can effectively eject and accelerate the ice particles. The aluminum alloy plate depainting test obtained a larger paint removal radius and resulted in a smoother aluminum alloy plate surface, reducing the surface roughness from 3.194 ± 0.489 μm to 1.156 ± 0.136 μm. The immediate preparation and utilization of ice particles solved the problems of adhesion and storage in the engineering application of ice particle air jet technology, providing a feasible technical method in the field of material surface treatment.

The purpose of this study was to investigate the effect of the reflector, surface treatment, and length of scintillation crystals on the performance of a time-of-flight and depth-of-interaction (TOF-DOI) PET detector with a dual-ended readout and to determine the best reflector and surface treatment. Various types of crystal arrays with three different reflectors (ESR, BaSO4, and Toray), three different lateral surface treatments (all-polished (AP), all-roughened (AR), and partially roughened (PR, three sides polished, and one side roughened)), and two different lengths (20 and 15 mm) were fabricated. The highest light collection efficiency and best energy resolution were achieved using a crystal with a diffuse reflector (BaSO4 for AP and Toray for AR). In contrast, the best coincidence timing resolution (CTR) was achieved using an AR crystal with a specular reflector (ESR). The best DOI resolution was achieved using an AR crystal with BaSO4. Moreover, the results measured with the 20 mm long crystals were similar to those measured with the 15 mm long crystals. Therefore, we concluded that the dual-ended readout PET detector employing the crystal with AR lateral surface treatment and ESR was a good candidate for TOF-DOI PET because it provided excellent CTR and adequate DOI resolution.