Search

Applications of Raman spectroscopy in monitoring the concentration of solvents in various distillation and solvent exchange steps in chemical synthesis are discussed. Two case studies from early-phase active pharmaceutical ingredient (API) process development, one each from the distillation and the solvent exchange operations, are presented. The results are compared to respective conventional techniques. Sampling, measuring, and building models using appropriate chemometric tools are described in detail. A list of 70 different pairs of commonly used solvents and reactants, where Raman spectroscopy models could be successfully developed and employed, is provided with the corresponding range of quantitation. The advantages of Raman spectroscopy, such as rapid and nondestructive analysis, suitability for process analytical technology (PAT)-based applications for real-time monitoring, and ease of automation, are highlighted over traditional approaches. Some practical challenges of the technique towards its implementation are also discussed.

A modified synthetic route to BMS-978587 was developed featuring a chemoselective nitro reduction and a stereospecific Suzuki coupling as the key bond formation steps. A systematic evaluation of the reaction conditions led to the identification of a robust catalyst/ligand/base combination to reproducibly effect the Suzuki reaction on large scale. The modified route avoided several challenges with the original synthesis and furnished the API in high overall yield and purity without recourse to chromatography.

We demonstrate a tool which can function as an interface between VLSI designers and process-technology engineers throughout the Design-Technology Co-optimization (DTCO) process. This tool uses a Monte Carlo algorithm on the output of lithography simulations to model the frequency of fail mechanisms on wafer. Fail mechanisms are defined according to process integration flow: by Boolean operations and measurements between original and derived shapes. Another feature of this design rule optimization methodology is the use of a Markov-Chain-based algorithm to perform a sensitivity analysis, the output of which may be used by process engineers to target key process-induced variabilities for improvement. This tool is used to analyze multiple Middle-Of-Line fail mechanisms in a 10nm inverter design and identify key process assumptions that will most strongly affect the yield of the structures. This tool and the underlying algorithm are also shown to be scalable to arbitrarily complex geometries in three dimensions. Such a characteristic which is becoming more important with the introduction of novel patterning technologies and more complex 3-D on-wafer structures.

We discuss the transition to Ti based silicides for source-drain (SD) contacts for 3D FinFET devices starting from the 14nm node & beyond. Reductions in n-FET & p-FET contact resistances are reported with the optimization of metallization process & dopant concentrations. The optimization of SiGe epitaxy and addition of a thin interfacial NiPt(10%) are found to significantly improve p-FET contact performance.

A highly optimized silicon-on-insulator FinFET technology is utilized for the IBM processor designs in the 14-nm node. This process technology has a number of unique elements that enable these prod...

We present a fully integrated 14nm CMOS technology featuring finFET architecture on an SOI substrate for a diverse set of SoC applications including HP server microprocessors and LP ASICs. This SOI finFET architecture is integrated with a 4th generation deep trench embedded DRAM to provide an ultra-dense (0.0174um2) memory solution for industry leading ‘scale-out’ processor design. A broad range of Vts is enabled on chip through a unique dual workfunction process applied to both NFETs and PFETs. This enables simultaneous optimization of both lowVt (HP) and HiVt (LP) devices without reliance on problematic approaches like heavy doping or Lgate modulation to create Vt differentiation. The SOI finFET's excellent subthreshold behavior allows gate length scaling to the sub 20nm regime and superior low Vdd operation. This leads to a substantial (>35%) performance gain for Vdd ∼0.8V compared to the HP 22nm planar predecessor technology. At the same time, the exceptional FE/BE reliability enables high Vdd (>1.1V) operation essential to the high single thread performance for processors intended for ‘scale-up’ enterprise systems. A hierarchical BEOL with 15 levels of copper interconnect delivers both high performance wire-ability as well as effective power supply and clock distribution for very large >600mm2 SoCs.

In this paper, we present a 10nm CMOS platform technology for low power and high performance applications with the tightest contacted poly pitch (CPP) of 64nm and metallization pitch of 48nm ever reported in the FinFET technology on both bulk and SOI substrates. A 0.053um2 SRAM bit-cell is reported with a corresponding Static Noise Margin (SNM) of 140mV at 0.75V. Intensive multi-patterning technology and various self-aligned processes have been developed with 193i lithography to overcome optical patterning limits. Multi-workfunction (MWF) gate stack has been enabled to provide Vt tunability without the variability degradation induced by Random Dopant Fluctuation (RDF) from channel dopants.

A 10nm logic platform technology is presented for low power and high performance application with the tightest contacted poly pitch (CPP) of 64nm and metallization pitch of 48nm ever reported in the FinFET technology on both bulk and SOI substrate. A 0.053um 2 SRAM bit-cell is reported with a corresponding Static Noise Margin (SNM) of 140mV at 0.75V. Intensive multi-patterning technology and various self-aligned processes have been developed with 193i lithography to overcome optical patterning limit. Multi-workfunction (WF) gate stack has been enabled to provide Vt tunability without the variability degradation induced by channel dopants.

We compare the intrinsic reliability of the dielectric stack of a high performance bulk planar 20nm replacement gate technology to the reliability of high performance bulk planar 28 nm gate first high-k metal gate (HKMG) technology, developed within the IBM Alliance. Comparable N/PFET TDDB and comparable/improved NFET PBTI are shown to be achievable for similar Tinv. The choice to not include channel silicon germanium as a PFET performance element in the 20nm technology impact NBTI, driving a potential tradeoff between NBTI and PBTI. The complexity of integrating such performance elements while accounting for reliability/performance tradeoffs demands their selection during technology definition with due consideration to realistic product usage conditions.

In this paper, we present a high performance planar 20nm CMOS bulk technology for low power mobile (LPM) computing applications featuring an advanced high-k metal gate (HKMG) process, strain engineering, 64nm metal pitch & ULK dielectrics. Compared with 28nm low power technology, it offers 0.55X density scaling and enables significant frequency improvement at lower standby power. Device drive current up to 2X 28nm at equivalent leakage is achieved through co-optimization of HKMG process and strain engineering. A fully functional, high-density (0.081um2 bit-cell) SRAM is reported with a corresponding Static Noise Margin (SNM) of 160mV at 0.9V. An advanced patterning and metallization scheme based on ULK dielectrics enables high density wiring with competitive R-C.

Replacement metal gate (RMG) process requires gate fill with low resistance materials on top of work function tuning metals. Conventional titanium (Ti)-aluminum (Al) based RMG metal fill scheme for low resistance gate formation becomes challenging with further gate length scaling for 20nm node and beyond. In this work, we have demonstrated competitive low resistance gate formation at smaller than 25nm L gate using a novel cobalt (Co)-aluminum based metal fill scheme for extreme gate length scaling. Challenges in CMP for the implementation as well as assessment on resistance and device characteristics of this new low resistance fill scheme are also discussed.

This letter reports on 1.5-V single work-function W/WN/n/sup +/-poly gate CMOS transistors for high-performance stand-alone dynamic random access memory (DRAM) and low-cost low-leakage embedded DRAM applications. At V/sub dd/ Of 1.5-V and 25/spl deg/C, drive currents of 634 /spl mu/A//spl mu/m for 90-nm L/sub gate/ NMOS and 208 /spl mu/A-/spl mu/m for 110-nm L/sub gate/ buried-channel PMOS are achieved at 25 pA//spl mu/m off-state leakage. Device performance of this single work function technology is comparable to published low leakage 1.5-V dual work-function technologies and 25% better than previously reported 1.8-V single work-function technology. Data illustrating hot-carrier immunity of these devices under high electric fields is also presented. Scalability of single work-function CMOS device design for the 90-nm DRAM generation is demonstrated.

CMOS devices with high-k/metal gate stacks have been fabricated using a gate-first process flow and conventional stressors at gate lengths of 25 nm, highlighting the scalability of this approach for high performance SOI CMOS technology. AC drive currents of 1630muA/mum and 1190muA/mum have been demonstrated in 45 nm ground-rules at 1V and 200nA/mum off current for nFETs and pFETs, at a Tinv of 14 and 15 respectively. The drive currents were achieved using a simplified high-k/metal gate integration scheme with embedded SiGe and dual stress liners (DSL) and without utilizing additional stress enhancers. Devices have been fabricated with Tinv's down to 12 and 10.5 demonstrating the scalability of this approach for 32 nm and beyond.

In this paper we present enhancements in transistor performance and manufacturability of a high performance 65nm node SOI transistor by the combination of reduced RTA temperature and laser spike anneal (LTRTA+LSA) achieved through simultaneous optimization of offset spacer and extension/halo. DC NFET drive current is increased by 10% to a value of 1120 muA/mum (1220muA/mum if 9% NFET SOI self-heating effect included) at 200nA/mum off-state current and VDD of 1.0V. PMOS drive current is enhanced by 5% to a value of 575muA/mum (60OmuA/mum if 5% PFET SOI self-heating effect included) which is less than enhancement observed in the NFET due to the differing amount of enhancement of capacitive inversion thickness (TINV) at short channel. With respect to circuit and product performance, this device provides a 5% delay improvement for a product-like ring-oscillator (RO) and results in an improved cross-die statistical distribution of RO delay time. The minimum stable SRAM operating voltage (Vmin) is also significantly improved, indicating that control of the overlap capacitance (Cov) may play a significant role in determining SRAM Vmin. For the first time, we report that the NFET Tinv reduction by LSA is substantially larger at shorter channel lengths which explains the large NFET drive current enhancements obtained by LSA

A high performance 65 nm SOI CMOS technology is presented featuring 35 nm gate length, 1.05 nm gate oxide, performance enhancement from dual stress nitride liners (DSL), and 10 wiring levels with low-k dielectric offered in the first 8 levels. DSL enhancement is shown to scale well to 65 nm with larger enhancement seen than at 90 nm design rules. A high performance 0.65/spl mu/m/sup 2/ SRAM cell is also presented. SOI allows the SRAM cell to use Metal 1 instead of Metal 2 for bit-line wiring, which lowers the capacitance and improves access times. A functional dual-core microprocessor test chip containing 76Mb SRAM cache and key execution units has been fabricated.

In this paper we discuss the use of area enhancement techniques to increase capacitance while minimizing node leakage in 0.11 /spl mu/m deep trench capacitors. The thinning of conventional SiN/SiO/sub 2/ dielectric is discussed and its effectiveness for future generations assessed. Other capacitance enhancement schemes examined rely on independently enhancing the capacitor surface area while retaining the critical dimensions of the trench top with a protective SiN film. Area enhancement schemes reviewed include bottling of non-rotated and rotated wafers-(100) notch-aligned, and hemispherical-grained silicon deposition. We have demonstrated these capacitance enhancement techniques on 0.11 /spl mu/m ground rules, and have achieved more than 55% capacitance enhancement while still maintaining less than 1 fA/cell leakage. We also report reliable operational lifetimes on capacitance enhanced structures. The scalability of these area enhancement techniques is examined.

In this paper, we present the implementation of W/WN/poly gates in a 135 nm sub-8F2 vertical cell DRAM technology with dual gate oxide planar support transistors. Key features include low sheet resistance wordlines, high performance peripheral logic circuitry and a scalable memory cell array. A process flow detailing the decoupling of the array and support regions of the DRAM to achieve planar support transistors with L/sub eff/(nFET)