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Graphene has great potential for use in infrared (IR) nanodevices. At these length scales, nanoscale features, and their interaction with light, can be expected to play a significant role in device performance. Bubbles in van der Waals heterostructures are one such feature, which have recently attracted considerable attention, thanks to their ability to modify the optoelectronic properties of two-dimensional (2D) materials through strain. Here, we use scattering-type scanning near-field optical microscopy (sSNOM) to measure the nanoscale IR response from a network of variously shaped bubbles in hexagonal boron nitride (hBN)-encapsulated graphene. We show that within individual bubbles there are distinct domains with strongly enhanced IR absorption. The IR domain boundaries coincide with ridges in the bubbles, which leads us to attribute them to nanoscale strain domains. We further validate the strain distribution in the graphene by means of confocal Raman microscopy and vector decomposition analysis. This shows intricate and varied strain configurations, in which bubbles of different shape induce more bi- or uniaxial strain configurations. This reveals pathways toward future strain-based graphene IR devices.

Infrared radiation thermometry, which derives temperature of an object from the intensity of emitted radiation, suffers from diffraction-limited insufficient spatial resolution. This limit is overcome by introducing a terahertz near-field technique to locally probe fluctuating electromagnetic (EM) evanescent fields. We report here nanoscale hot electron temperature distribution directly mapped with a newly developed near-field technique, called scanning noise microscope (SNoiM). Nanoscale lattice temperature distribution in the same sample was also mapped with a commercially available contact-type scanning thermal microscope (SThM). By comparison, subtle but essential difference has been found between the distributions of the lattice temperature and the electron temperature, leading to detailed understanding of the hot electron kinetics along with the phonon-relaxation process.

Noise and decoherence due to spurious two-level systems located at material interfaces are long-standing issues for solid-state quantum devices. Efforts to mitigate the effects of two-level systems have been hampered by a lack of knowledge about their chemical and physical nature. Here, by combining dielectric loss, frequency noise and on-chip electron spin resonance measurements in superconducting resonators, we demonstrate that desorption of surface spins is accompanied by an almost tenfold reduction in the charge-induced frequency noise in the resonators. These measurements provide experimental evidence that simultaneously reveals the chemical signatures of adsorbed magnetic moments and highlights their role in generating charge noise in solid-state quantum devices., The performance of solid-state quantum devices is often affected by low-frequency noise that appears to arise from the presence of two-level defects. Here the authors show that surface spins that cause magnetic noise are an origin of dielectric noise in superconducting resonators.

One of the aspirations of quantum metrology is to deliver primary standards directly to end-users thereby significantly shortening the traceability chains and enabling more accurate products. Epitaxial graphene grown on silicon carbide (epigraphene) is known to be a viable candidate for a primary realisation of a quantum Hall resistance standard, surpassing conventional semiconductor two-dimensional electron gases, such as those based on GaAs, in terms of performance at higher temperatures and lower magnetic fields. The bottleneck in the realisation of a turn-key quantum resistance standard requiring minimum user intervention has so far been the need to fine-tune the carrier density in this material to fit the constraints imposed by a simple cryo-magnetic system. Previously demonstrated methods, such as via photo-chemistry or corona discharge, require application prior to every cool-down as well as specialist knowledge and equipment. To this end we perform metrological evaluation of epigraphene with carrier density tuned by a recently reported permanent molecular doping technique. Measurements at two National Metrology Institutes confirm accurate resistance quantisation below 5 n Omega Omega(-1). Furthermore, samples show no significant drift in carrier concentration and performance on multiple thermal cycles over three years. This development paves the way for dissemination of primary resistance standards based on epigraphene. Funding Agencies|Swedish-Korean Basic Research Cooperative Program of the NRF [NRF-2017R1A2A1A18070721]; Swedish Foundation for Strategic Research (SSF) [IS14-0053, GMT14-0077, RMA15-0024]; Swedish Research Council (VR); VINNOVA; Knut and Alice Wallenberg Foundation; Chalmers Area of Advance NANO; UK Department of Business, Energy and Industrial Strategy (BEIS); European Unions Horizon 2020 research and innovation programme [785219]

We systematically compare the active and the passive methods for infrared scattering-type scanning near-field optical microscopy (s-SNOM). The active SNOM makes use of IR lasers or incoherent thermal emitters to illuminate a sample, whereas the passive method directly measures extremely weak fluctuating electromagnetic evanescent fields spontaneously generated at the sample surface without any external illumination. For this reason, our specific version of the passive SNOM is called a scanning noise microscope (SNoiM). In thermal equilibrium, the two methods are shown to be similar, both mapping the nanoscale variation of the complex dielectric constant of the sample. We demonstrate that a significant difference between the two methods emerges when the sample is driven out of thermal equilibrium, viz., the active SNOM is insensitive whereas the SNoiM is extremely sensitive to the electron temperature in locally heated nanoregions.

The discovery 8 years ago of the quantum Hall effect (QHE) in graphene sparked an immediate interest in the metrological community. Here was a material which was completely different from commonly used semiconductor systems and which seemed to have some uniques properties which could make it ideally suited for high-precision resistance metrology. However, measuring the QHE in graphene turned out to be not so simple as first thought. In particular the small size of exfoliated graphene samples made precision measurements difficult. This dramatically changed with the development of large-area graphene grown on SiC and in this short review paper we discuss the journey from first observation to the highest-ever precision comparison of the QHE.

We report the response of sub-micron epitaxial graphene Hall devices to localized and inhomogeneous magnetic field produced by an MFM tip. We analyze the magneto-transport properties of epitaxial graphene and report the independent contribution of magnetic and electric fields in the measured transverse voltage maps with respect to the lateral and vertical position of the tip. A finite element model has also been developed to support the experimental results.

An on-chip electron spin resonance technique is applied to reveal the nature and origin of surface spins on Al2O3. We measure a spin density of 2.2×1017 spins/m2, attributed to physisorbed atomic hydrogen and S=1/2 electron spin states on the surface. This is direct evidence for the nature of spins responsible for flux noise in quantum circuits, which has been an issue of interest for several decades. Our findings open up a new approach to the identification and controlled reduction of paramagnetic sources of noise and decoherence in superconducting quantum devices.

Interfacing rare-earth-doped crystals with superconducting circuit architectures provides an attractive platform for quantum memory and transducer devices. Here, we present the detailed characterization of such a hybrid system: a locally implanted rare-earth Gd3+ in Al2O3 spin system coupled to a superconducting microresonator. We investigate the properties of the implanted spin system through angular-dependent microresonator electron spin resonance (micro-ESR) spectroscopy. We find, despite the high-energy near-surface implantation, the resulting micro-ESR spectra to be in excellent agreement with the modeled Hamiltonian, supporting the integration of dopant ions into their relevant lattice sites while maintaining crystalline symmetries. Furthermore, we observe clear contributions from individual microwave field components of our microresonator, emphasizing the need for controllable local implantation.

Weak localization in graphene is studied as a function of carrier density in the range from 1 x 10(11) cm(-2) to 1.43 x 10(13) cm(-2) using devices produced by epitaxial growth onto SiC and CVD growth on thin metal film. The magnetic field dependent weak localization is found to be well fitted by theory, which is then used to analyze the dependence of the scattering lengths L-phi, L-i, and L-* on carrier density. We find no significant carrier dependence for L-phi, a weak decrease for L-i with increasing carrier density just beyond a large standard error, and a n(-1/4) dependence for L-*. We demonstrate that currents as low as 0.01 nA are required in smaller devices to avoid hot-electron artifacts in measurements of the quantum corrections to conductivity. DOI: 10.1103/PhysRevB.86.235441 Funding Agencies|UK EPSRC||Swedish Research Council||Foundation for Strategic Research||UK National Measurement Office||EU FP7 STREP ConceptGraphene

We have demonstrated quantum Hall resistance measurements with metrological accuracy in a relatively easy to use and compact cryogen-free system operating at a temperature of around 3.8 K and magnetic field below 5 T. This advance in technology is due to the unique properties of epitaxial graphene on silicon carbide (SiC) which lifts the stringent requirements for quantum hall effect seen in conventional semiconductors. This paper presents the processes involved in fabrication and characterization of metrologically viable epitaxial graphene samples.

We demonstrate quantum Hall resistance measurements with metrological accuracy in a small cryogen-free system operating at a temperature of around 3.8 K and magnetic fields below 5 T. We use this system to investigate the optimisation of graphene/SiC devices for maximum breakdown current. In addition we report the first characterisation of a cryogen-free cryogenic current comparator which enables entirely cryogen-free primary resistance metrology.

Here we review the concepts and technologies, in particular photochemical gating, which contributed to the recent progress in quantum Hall resistance metrology based on large scale epitaxial graphene on silicon carbide.

A novel heterostructure based on epitaxial graphene grown on silicon carbide combined with two polymers is demonstrated, with a neutral spacer and a photoactive layer that provides potent electron acceptors under UV light exposure. UV exposure of this heterostructure enables control of the electrical parameters of graphene in a non-invasive, non-volatile, and reversible way.

The quantum Hall effect allows the international standard for resistance to be defined in terms of the electron charge and Planck's constant alone. The effect comprises the quantization of the Hall resistance in two-dimensional electron systems in rational fractions of R(K) = h/e(2) = 25,812.807557(18) Omega, the resistance quantum. Despite 30 years of research into the quantum Hall effect, the level of precision necessary for metrology--a few parts per billion--has been achieved only in silicon and iii-v heterostructure devices. Graphene should, in principle, be an ideal material for a quantum resistance standard, because it is inherently two-dimensional and its discrete electron energy levels in a magnetic field (the Landau levels) are widely spaced. However, the precisions demonstrated so far have been lower than one part per million. Here, we report a quantum Hall resistance quantization accuracy of three parts per billion in monolayer epitaxial graphene at 300 mK, four orders of magnitude better than previously reported. Moreover, by demonstrating the structural integrity and uniformity of graphene over hundreds of micrometres, as well as reproducible mobility and carrier concentrations across a half-centimetre wafer, these results boost the prospects of using epitaxial graphene in applications beyond quantum metrology.

We examine the application of Josephson radiation emitters to spectral calibration of single-photon-resolving detectors. Josephson junctions are patterned in a YBCO film on a bicrystal sapphire substrate and are voltage controlled to generate radiation in the frequency range of 0.05-1 THz. The detector used in this work consists of a gate-defined quantum-dot photon-to-charge transducer coupled to a single-electron transistor. Both the emitter and the detector are equipped with a matching on-chip wide-band antenna. The combination of a tuneable emitter and detector allows us to determine the efficacy of the YBCO emitter and also to analyze the elementary processes involved in the detection.

Experimental evidence from both spin-valve and quantum transport measurements points towards unexpectedly fast spin relaxation in graphene. We report magnetotransport studies of epitaxial graphene on SiC in a vector magnetic field showing that spin relaxation, detected using weak-localization analysis, is suppressed by an in-plane magnetic field B-parallel to, and thereby proving that it is caused at least in part by spinful scatterers. A nonmonotonic dependence of the effective decoherence rate on B-parallel to reveals the intricate role of the scatterers spin dynamics in forming the interference correction to the conductivity, an effect that has gone unnoticed in earlier weak localization studies. Funding Agencies|NSERC; CFI; Quantum Matter Institute (QMI); EC Graphene Flagship [CNECT-ICT-604391]; European Metrology Research Program (EMRP) project GraphOhm; ERC Synergy Grant Hetero2D; Deutsche Forschungsgemeinschaft [GRK 1621]; Linnaeus Centre for Quantum Engineering; Swedish Research Council; Knut and Alice Wallenberg Foundation; Swedish Foundation for Strategic Research (SSF); Chalmers Area of Advance NANO

We demonstrate quantum Hall resistance measurements with metrological accuracy in a small cryogen-free system operating at a temperature of around 3.8K and magnetic fields below 5T. Operating this system requires little experimental knowledge or laboratory infrastructure, thereby greatly advancing the proliferation of primary quantum standards for precision electrical metrology. This significant advance in technology has come about as a result of the unique properties of epitaxial graphene on SiC., 15 pages, 9 figures

We report on depairing critical currents in submicron YBa2Cu3O7−δ microbridges. A small-angle bicrystal grain boundary junction is used as a tool to study the entrance of vortices induced by a transport current and their influence on the I–V curves. The interplay between the depairing and the vortex motion determines a crossover in the temperature dependence of the critical current. The high entrance field of vortices in very narrow superconducting channels creates the possibility of carrying a critical current close to the depairing limit determined by the S–S′–S nature of the small-angle grain boundary junction.

Most proposed realizations of a high temperature superconductor (HTS) qubit require the use of very small Josephson junctions. The properties of bicrystal junctions are especially interesting since they make it possible to implement several types of flux qubits in a relatively simple way. We have developed a technique that allows us to produce high quality sub-micrometer junctions in a reproducible way using bicrystal technology. We have successfully fabricated and characterized a large number of YBCO junctions and SQUIDs with bridge width as small as 0.2 micrometer on 0/spl deg/-3/spl deg/, 0/spl deg/-40/spl deg/ and 0/spl deg/-45/spl deg/ bicrystal STO substrates. The properties of these junctions have been extensively examined at temperatures down to 20 mK. The effects of external magnetic fields on these structures have been investigated. Figures of merit for the proposed qubits were also extracted from these measurements.

Epitaxial graphene on silicon carbide is a promising material for the next generation of quantum Hall resistance standards. Single Hall bars made of graphene have already surpassed their state-of-the-art GaAs based counterparts as an R-K/2 (RK = h/e(2)) standard, showing at least the same precision and higher breakdown current density. Compared to single devices, quantum Hall arrays using parallel or series connection of multiple Hall bars can offer resistance values spanning several orders of magnitude and (in case of parallel connection) significantly larger measurement currents, but impose strict requirements on uniformity of the material. To evaluate the quality of the available material, we have fabricated arrays of 100 Hall bars connected in parallel on epitaxial graphene. One out of four devices has shown quantized resistance that matched the correct value of R-K/200 within the measurement precision of 10(-4) at magnetic fields between 7 and 9 T. The defective behaviour of other arrays is attributed mainly to non-uniform doping. This result confirms the acceptable quality of epitaxial graphene, pointing towards the feasibility of well above 90% yield of working Hall bars. Funding Agencies|EU FP7 STREP ConceptGraphene; EMRP project GraphOhm; Graphene Flagship [CNECT-ICT-604391]; Swedish Foundation for Strategic Research (SSF); Linnaeus Centre for Quantum Engineering; Knut and Allice Wallenberg Foundation; Chalmers AoA Nano; EURAMET; European Union

We report a study of disorder effects on epitaxial graphene in the vicinity of the Dirac point by magnetotransport. Hall effect measurements show that the carrier density increases quadratically with temperature, in good agreement with theoretical predictions which take into account intrinsic thermal excitation combined with electron-hole puddles induced by charged impurities. We deduce disorder strengths in the range 10.2-31.2 meV, depending on the sample treatment. We investigate the scattering mechanisms and estimate the impurity density to be 3.0-9.1x10(10) cm(-2) for our samples. A scattering asymmetry for electrons and holes is observed and is consistent with theoretical calculations for graphene on SiC substrates. We also show that the minimum conductivity increases with increasing disorder strength, in good agreement with quantum-mechanical numerical calculations. Funding Agencies|U.K. EPSRC; NMS, E.U. Graphene Flagship [CNECT-ICT-604391]; EMRP Graph Ohm; Swedish Foundation for Strategic Research (SSF); Linnaeus Centre for Quantum Engineering; Knut and Alice Wallenberg Foundation; Chalmers AoA Nano; China Scholarship Council

We discuss the properties of sub-micron YBa2Cu3O7−δ step-edge Josephson junctions and their application in micro-SQUIDs. We suggest a design of a micro-SQUID sensor for the scanning SQUID microscopy. Two methods of coupling the modulation and feedback signals to the sensor are described. Influence of a superconducting sample on the sensor parameters is analyzed for the two configurations.

Magnetophysiology is the use of a superconducting quantum interference device (SQUID) based instrument to detect neuromagnetic fields evoked by electrical stimulation of brain tissue slices. In this paper we show that a SQUID based on high temperature superconductors (HTSs) would have considerable advantages over a low Tc device in this application. We construct a model of electrical activity in a hippocampal brain slice, which enables the neuromagnetic field to be determined as a function of position and distance from the tissue. We then describe the design of HTS SQUID systems for magnetophysiology and the two styles of system we are developing. Finally we use our model to show that an existing HTS SQUID magnetometer would give a superior signal to noise ratio compared to a low Tc system for the hippocampal brain slice preparation at least.

© 2014 IEEE. We present the phase space defined by the quantum Hall effect breakdown in polymer gated epitaxial graphene on SiC (SiC/G) as a function of temperature, current, carrier density, and magnetic field. At 2 K, breakdown currents (Ic) almost 2 orders of magnitude greater than in GaAs devices are observed. We use this knowledge to explore the potential of using graphene as a high temperature (> 2 K) and low magnetic field (< 5 T) quantum resistance standard.

A new joint research project (JRP) integrating metrology institutes and universities from nine countries is aimed at realization of a new generation of standards for quantum resistance metrology. The project exploits graphene's properties to simplify operation of standards without compromising the unprecedented precision delivered by semiconductor quantum Hall devices. Higher operating temperatures (above 4.2 K, and up to 8 K) and together with lower magnetic fields (below 5 T, and potentially down to 2 T) will lead to a significantly improved and cost-saving dissemination of intrinsically referenced resistance standards to all end-users relying on electrical measurements.

Using local scanning electrical techniques we study edge effects in side-gated Hall nanodevices made of epitaxial graphene. We demonstrate that lithographically defined edges of the graphene channel exhibit hole conduction within the narrow band of ~60-125 nm width, whereas the bulk of the material is electron doped. The effect is the most pronounced when the influence of atmospheric contamination is minimal. We also show that the electronic properties at the edges can be precisely tuned from hole to electron conduction by using moderate strength electrical fields created by side-gates. However, the central part of the channel remains relatively unaffected by the side-gates and retains the bulk properties of graphene., Comment: 4 Figures, 1 Table

Submicron step-edge Josephson junctions in YBa2Cu3O7−δ (YBCO) thin films were fabricated and studied. All measured junctions fall into three categories: low critical current resistively shunted Josephson junctions, intrinsic Josephson junctions, and quasiparticle tunnel junctions. The transport in the junctions is correlated with the microstructure of YBCO films grown on the step edge. We argue that the properties of conventional step-edge junctions can be understood as a superposition of those types.

We present a design of a scanning SQUID microscope (SSM) operating in a temperature range between about 5 K (2 K with pumping) and 100 K.

We demonstrate reversible carrier density control across the Dirac point (Delta n similar to 10(13) cm(-2)) in epitaxial graphene on SiC (SiC/G) via high electrostatic potential gating with ions produced by corona discharge. The method is attractive for applications where graphene with a fixed carrier density is needed, such as quantum metrology, and more generally as a simple method of gating 2DEGs formed at semiconductor interfaces and in topological insulators. Funding Agencies|Graphene Flagship [CNECT-ICT-604391]; Swedish Foundation for Strategic Research (SSF); Linnaeus Centre for Quantum Engineering; Knut and Allice Wallenberg Foundation; Chalmers AoA Nano; NMS (UK); EMRP project GraphOhm; EMRP within EURAMET; European Union

Energy relaxation of hot Dirac fermions in bilayer epitaxial graphene is experimentally investigated by magnetotransport measurements on Shubnikov-de Haas oscillations and weak localization. The hot-electron energy loss rate is found to follow the predicted Bloch-Gr\"uneisen power-law behaviour of $T^4$ at carrier temperatures from 1.4 K up to $\sim$100 K, due to electron-acoustic phonon interactions with a deformation potential coupling constant of 22 eV. A carrier density dependence $n_e^{-1.5}$ in the scaling of the $T^4$ power law is observed in bilayer graphene, in contrast to the $n_e^{-0.5}$ dependence in monolayer graphene, leading to a crossover in the energy loss rate as a function of carrier density between these two systems. The electron-phonon relaxation time in bilayer graphene is also shown to be strongly carrier density dependent, while it remains constant for a wide range of carrier densities in monolayer graphene. Our results and comparisons between the bilayer and monolayer exhibit a more comprehensive picture of hot carrier dynamics in graphene systems., Comment: 9 pages, 8 figures

Tl-2212 thin films were grown ex situ in a two step process on a variety of substrates, including ones with artificially introduced high angle steps. Grain boundary weak links were formed on LaAlO/sub 3/ substrates with steps and on bicrystal substrates and were employed in dc SQUIDs. The white noise level of the SQUIDs was 50/spl mu//spl Phi//sub 0///spl radic/(Hz) at 77 K. A 12.5 GHz HEMT oscillator stabilized with a Tl-2212 resonator gave 8-10 dB lower phase noise than using a gold resonator.

In this paper we review the recent extraordinary progress in the development of a new quantum standard for resistance based on graphene. We discuss the unique properties of this material system relating to resistance metrology and discuss results of the recent highest-ever precision direct comparison of the Hall resistance between graphene and traditional GaAs. We mainly focus our review on graphene expitaxially grown on SiC, a system which so far resulted in the best results. We also brie y discuss progress in the two other graphene material systems, exfoliated graphene and chemical vapour deposition graphene, and make a critical comparison with SiC graphene. Finally we discuss other possible applications of graphene in metrology., arXiv admin note: substantial text overlap with arXiv:1202.2985

Energy loss rates for hot carriers in graphene have been measured using graphene produced by epitaxial growth on SiC, exfoliation, and chemical vapor deposition (CVD). It is shown that the temperature dependence of the energy loss rates measured with high-field damped Shubnikov-de Haas oscillations and the temperature dependence of the weak localization peak close to zero field correlate well, with the high-field measurements understating the energy loss rates by similar to 40% compared to the low-field results. The energy loss rates for all graphene samples follow a universal scaling of T-e(4) at low temperatures and depend weakly on carrier density proportional to n(-1/2), evidence for enhancement of the energy loss rate due to disorder in CVD samples. Funding Agencies|UK EPSRC||Swedish Research Council||Foundation for Strategic Research||UK National Measurement Office||EU

We compare the three most commonly used scanning probe techniques to obtain a reliable value of the work function in graphene domains of different thickness. The surface potential (SP) of graphene is directly measured in Hall bar geometry via a combination of electrical functional microscopy and spectroscopy techniques, which enables calibrated work function measurements of graphene domains in ambient conditions with values Φ1LG ~4.55 ± 0.02 eV and Φ2LG ~ 4.44 ± 0.02 eV for single- and bi-layer, respectively. We demonstrate that frequency-modulated Kelvin probe force microscopy (FM-KPFM) provides more accurate measurement of the SP than amplitude-modulated (AM)-KPFM. The discrepancy between experimental results obtained by different techniques is discussed. In addition, we use FM-KPFM for contactless measurements of the specific components of the device resistance. We show a strong non-Ohmic behavior of the electrode-graphene contact resistance and extract the graphene channel resistivity. Funding Agencies|NMS under the IRD Graphene Project (NPL)||EU FP7 Project ConceptGraphene

We report on the present status of our high-T/sub c/ SQUID based system for measurements of room temperature samples. The main application of the system is magnetic recordings of signals in nerve tissue, i.e., magnetophysiology. We have fabricated four slotted SQUID sensors of two different designs. The best SQUID sensor shows an intrinsic white noise of 8.2 /spl mu//spl Phi//sub 0//Hz/sup 1/2/ and a corresponding magnetic field noise of 4.5 pT/Hz/sup 1/2/ at 77 K.

Hall sensors with the width range from 0.5 to 20.0 mu m have been fabricated out of a monolayer graphene epitaxially grown on SiC. The sensors have been studied at room temperature using transport and noise spectrum measurements. The minimum detectable field of a typical 10-mu m graphene sensor is approximate to 2.5 mu T/root Hz, making them comparable with state of the art semiconductor devices of the same size and carrier concentration and superior to devices made of CVD graphene. Relatively high resistance significantly restricts performance of the smallest 500-nm devices. Carrier mobility is strongly size dependent, signifying importance of both intrinsic and extrinsic factors in the optimization of the device performance. Funding Agencies|EU|JRP IND 11

The half-integer quantum Hall effect in epitaxial graphene is compared with high precision to the well known integer effect in a GaAs/AlGaAs heterostructure. We find no difference between the quantised resistance values within the relative standard uncertainty of our measurement of $8.7\times 10^{-11}$. The result places new tighter limits on any possible correction terms to the simple relation $R_{\rm K}=h/e^2$, and also demonstrates that epitaxial graphene samples are suitable for application as electrical resistance standards of the highest metrological quality. We discuss the characterisation of the graphene sample used in this experiment and present the details of the cryogenic current comparator bridge and associated uncertainty budget.

We present experimental details on the carrier density dependent breakdown current in epitaxial graphene grown on SiC. We show that in this system even at very low carrier densities and moderate temperatures it is still possible to have a breakdown current large enough for metrologically accurate quantum Hall resistance measurements. This work paves the way for a simple bench top/turnkey quantum resistance standard. © 2012 IEEE.

Josephson junctions and superconducting quantum interference devices (SQUIDs) were made by depositing thin films of YBa2Cu3O7 on bicrystal substrates of Y‐ZrO2 and SrTiO3. The critical current density of the junctions at 77 K could be adjusted from 100 to 106 A/cm2 by selecting bicrystals with misorientation angles θ from 45° to 0°. Current‐voltage curves from junctions with θ≳22° followed the resistively shunted junction model with noise rounding close to the transition temperature. The response of the critical current to magnetic fields was Fraunhofer‐like and the width (w) dependence was 1/w2 due to flux focusing effects. Shapiro steps under microwave radiation were observed. SQUIDs based on these junctions had energy resolutions at 77 K down to 8.6×10−30 J/Hz and a 10 Hz flux noise level down to 1.5×10−9 Φ20/Hz at 85 K. A SQUID of the Ketchen design with a flux focusing washer had a magnetic field sensitivity of 15 pT/√Hz at 77 K. The temperature dependence of the voltage modulation depth close to TC ...

Submicron YBa2Cu3Ox/PrBa2Cu2.6Ga0.4Ox/YBa2Cu3Ox ramp-type Josephson junctions were fabricated and tested. The submicron bridges in the top electrode were patterned by e-beam lithography and Ar ion milling through an amorphous carbon (a-C) mask. Junctions with width ranging from 0.2 to 8 μm and oriented along different crystal directions of YBa2Cu3Ox have been produced. Current–voltage characteristics show a behavior consistent with the resistively shunted junction model with small excess current. Junction critical current densities of about 10 kA/cm2 and characteristic voltages up to 6 mV were measured at 4.2 K for the submicron junctions. Junctions along different crystal orientations showed different characteristics suggesting an influence from the d-wave order parameter.

We explore the robust quantization of the Hall resistance in epitaxial graphene grown on Si-terminated SiC. Uniquely to this system, the dominance of quantum over classical capacitance in the charge transfer between the substrate and graphene is such that Landau levels (in particular, the one at exactly zero energy) remain completely filled over an extraordinarily broad range of magnetic fields. One important implication of this pinning of the filling factor is that the system can sustain a very high nondissipative current. This makes epitaxial graphene ideally suited for quantum resistance metrology, and we have achieved a precision of 3 parts in 1010 in the Hall resistance-quantization measurements. Original Publication:T J B M Janssen, A Tzalenchuk, Rositsa Yakimova, S Kubatkin, S Lara-Avila, S Kopylov and V I Falko, Anomalously strong pinning of the filling factor nu=2 in epitaxial graphene, 2011, PHYSICAL REVIEW B, (83), 23, 233402.http://dx.doi.org/10.1103/PhysRevB.83.233402Copyright: American Physical Societyhttp://www.aps.org/

The microstructure of an artificial grain boundary in an YBa 2 Cu 3 O 7-σ (YBCO) thin film grown on a (100)(110), [001]-tilt yttria-stabilized-zirconia (YSZ) bicrystal substrate has been studied using transmission electron microscopy (TEM). The orientation relationship between the YBCO film and the YSZ substrate was [001] YBCO ‖[001] YSZ and [110] YBCO ‖[100] YSZ for each half of the bicrystal film. However, the exact boundary geometry of the bicrystal substrate was not transferred to the film. The substrate boundary was straight while the film boundary was wavy. In several cases there was bending of the lattice confined within a distance of a few basal-plane lattice spacings from the boundary plane and microfaceting. No intergranular secondary phase was observed but about 25% of the boundary was covered by c -axis-tilted YBCO grains and a -axis-oriented grains, both of which were typically adjacent to CuO grains or surrounded by a thin Cu-rich amorphous layer.

We present a detailed study of ρ xx and ρ xy measured on a large high-quality epitaxially grown graphene sample. We have investigated the bias current, temperature, and magnetic field dependence and demonstrate quantization better than 1 part in 108. This level of accuracy easily satisfies all the usual criteria for reliable traceability based on the quantum Hall effect.

One of the promising ways to perform single-photon counting of terahertz radiation consists in sensitive probing of plasma excitation in the electron gas upon photon absorption. We demonstrate the ultimate sensor operating on this principle. It is assembled from a GaAs/AlGaAs quantum dot, electron reservoir and superconducting single-electron transistor. The quantum dot is isolated from the surrounding electron reservoir in such a way that when the excited plasma wave decays, an electron could tunnel off the dot to the reservoir. The resulting charge polarization of the dot is detected with the single-electron transistor. Such a system forms an easy-to-use sensor enabling single-photon counting in a very obscure wavelength region.

We investigate Ti/Au contacts to monolayer epitaxial graphene on SiC (0001) for applications in quantum resistance metrology. Using three-terminal measurements in the quantum Hall regime we observed variations in contact resistances ranging from a minimal value of 0.6 Omega up to 11 k Omega. We identify a major source of high-resistance contacts to be due bilayer graphene interruptions to the quantum Hall current, whilst discarding the effects of interface cleanliness and contact geometry for our fabricated devices. Moreover, we experimentally demonstrate methods to improve the reproducibility of low resistance contacts (less than 10 Omega) suitable for high precision quantum resistance metrology. Funding Agencies|Graphene Flagship [CNECT-ICT-604391]; Swedish Foundation for Strategic Research (SSF); Linnaeus Centre for Quantum Engineering; Knut and Alice Wallenberg Foundation; Chalmers AoA Nano; Swedish-Korean Basic Research Cooperative Program of the NRF [2014R1A2A1A1 2067266]; EMRP project GraphOhm; EMRP within EURAMET; EMRP within European Union

We report measurements of the flux hysteresis curves and trapped flux distribution in an YBa2Cu3O7 r.f. SQUID containing two closely spaced grain boundary Josephson junctions in parallel. Broadening of the flux distribution from T = 15 K to 30 K is followed by a bifurcation at T = 35 K which corresponds to a degenerate ground state. Above T ~ 40 K the bifurcation disappears, the flux distribution narrows significantly and small secondary loops appear in the hysteresis curves. This behaviour can be modelled qualitatively if we assume a temperature dependent second harmonic term in the current-phase relationship of the junctions., 10 pages, 7 figures

In this paper we examine the state-of-the-art patterning techniques for fabrication of ultrasmall bicrystal Josephson junctions in YBa 2 Cu 3 O x . We determine the dependence of junction parameters critical current, characteristic voltage I c R n , and capacitance-on its size. Using the values of the Josephson and the Coulomb energies extracted from experiment, we analyze the dynamics of the junction in zero-bias quantum regime. Finally, we discuss the relevance of parameters, obtained from transport measurements, for the decohfrence time in the system.

The predominant d-wave pairing symmetry in high temperature superconductors allows for a variety of current-phase relations in Josephson junctions, which is to a certain degree fabrication controlled. In this letter we report on direct experimental observations of the effects of a non-sinusoidal current-phase dependence in YBCO dc-SQUIDs, which agree with the theoretical description of the system., Comment: 4 pages, 4 ps figures, to apprear in Phys. Rev. Lett

We report low noise operation of YBa2Cu3O7 SQUIDs superconducting quantum interference devices using Josephson junctions grown on bicrystal substrates of (Y)ZrO2. Energy sensitivities measured at 10 Hz (Se=4.5×10−29 J/Hz) were to our knowledge lower than previously reported for a YBa2Cu3O7 SQUID with practical loop size (∼40 μm). The 1/f part of the voltage noise reached a maximum at 85 K where the noise spectrum was essentially white. The 1/f noise increased both at lower temperatures due to increased critical current fluctuations (∼Ibias2.2) and at higher temperatures, where the flux noise from the film produces a peak below Tc(=89 K).