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Partial discharges (PDs) are believed to be one of the key factors accelerating high voltage (HV) equipment ageing. The chemical by-products of PDs actively contribute to the modification of insulations surface quality, especially in air medium due to the diversity of its constituents. Although nonthermal plasmas in air have been widely studied, their adaptation to HV systems is still highly complex and prone to controversies. In this work, a typical simulation of a fault leading to PD in air, through a Dielectric Barrier Discharge (DBD) point-to-plane configuration, is performed in order to measure ozone (O 3 ), nitrogen oxide (NO) and dioxide (NO 2 ) by-products gases. The evolution of these species regarding PD duration, PD power and humidity is analyzed. Ozone production rate and dynamics are found to predominate over NO 2 and NO ones. The effect of humidity on gases evolution is found to be indirect, as it mainly affects PD power.

Partial discharges characterization on ceramic substrates and dielectric liquids under high temperature up to $350^{\circ}\mathrm{C}$ is investigated. Aluminum nitride (AlN) and alumina (Al 2 O 3 substrates, and a high temperature non-polar dibenzyltoluene (DBT) liquid are used. Several complementary measurements are also done in a synthetic ester liquid. PD measurements on AlN substrates embedded in DBT show a good behavior up to $300^{\circ}\mathrm{C}$, and up to $350^{\circ}\mathrm{C}$ with Alumina. This shows that high temperature insulating liquid may constitute a good alternative to silicone gels for the encapsulation of power electronics circuits at high temperature and high voltage. The comparison between PD characteristics in the liquid alone and with substrates show that PDs mostly occur within the ceramic material at temperatures up to $300^{\circ}\mathrm{C}$.

International audience; Breakdown measurements are carried out in liquids under point-sphere and pointplane electrode geometries, over a large range of gap distances up to 35 cm. Non-polar hydrocarbon liquids with different chemical structures are studied: saturated, aromatic, polyaromatic, mineral oils, and ester. Two high voltage impulse shapes are used: the standard lightning impulse (LI), and a specific “step” impulse (ST). Step impulses are favorable to interpret breakdown measurements since the applied voltage remains constant while prebreakdown streamers propagate. Conversely, with lightning impulse and long gaps the propagation of streamers with a low propagation velocity (a few km/s) is quenched due to the rapidly decaying voltage. In this case, breakdown can result only from the propagation of faster streamers, which appear in very different conditions according to the liquid nature. The results obtained allow us to interpret the large variations of breakdown voltage observed in large gaps, when either the high voltage impulse shape or the liquid nature is changed. These results also help to define proper conditions for testing and comparing liquids. Testing with lightning impulse in short gaps, such as in standard tests, does not provides data relevant for very high voltage applications.

An experimental study of discharges in air at atmospheric pressure under impulse voltage, creeping on insulating solid surface is presented. The objective is to get a better understanding of creeping discharge by studying streamer initiation and propagation, and by looking at the influence of the nature of the insulating solid. Several solid materials, of different chemical natures and permittivity are investigated. Pre-breakdown streamers are investigated by high speed visualization and transient current measurements. In the presence of insulating solids such as epoxy resin, PPA/glass fibers and polycarbonate, surface streamers appear during the voltage rise, and the time delay to appearance is correspondingly rather short. With two materials of polyolefin and fluorine modified polyolefin families, characterized by lower permittivity, the first creeping streamer appears at the maximum voltage after a much longer statistical time delay, very close to that obtained in air without solid.

This paper deals with physical processes involved during streamer inception in liquid cyclohexane under impulse voltage. In point-plane geometry, the inception of streamers is detected with a high temporal resolution (about 1 ns) by measurement of charge, visualization, and detection of phase change by scattered laser light. These techniques allow us to obtain precise measurements of the inception delay time, versus applied voltage and hydrostatic pressure. Measurements carried out in positive and negative polarity with a fast impulse voltage (20 ns risetime) show a large difference. In positive polarity, a minimum "formative time" close to 45 ns is observed, while negative streamers can appear almost immediately at high voltage. The hypothesis of cavitation induced by the EHD motion is considered to explain positive streamer inception.

This paper presents an experimental study of the influence of pulsed electrical discharges of low energy (3 to 10 J) on the extraction of polyphenols from grape seeds. To obtain a better understanding, three basic phenomena involved in the whole discharge process are studied separately: pulsed electric field (PEF), pre-breakdown phase (streamer), and breakdown phase (arc). The polyphenol extraction is much more efficient with arcs, compared to streamers and PEF. Therefore, during the discharge process, the enhancement of polyphenol extraction can be mainly ascribed to the final arc phase. The total energy per unit mass CWp required to extract 5000 mg GAE/100 g DM with the arc (CWp = 16 kJ/kg) is 27 times lower compared to streamers alone, and 47 times lower compared to PEF. An optical study shows that the mechanical effects of arcs (shock waves, expanding cavity, and strong turbulence) are much more pronounced compared to streamers. These mechanical effects are responsible for the fragmentation of grape seeds, and strongly promote the release of polyphenols. Other parameters such as the test cell shape and the inter-electrode distance also show that the polyphenol extraction is further enhanced when grape seeds are in close proximity with the breakdown arc. In optimized conditions, the extraction efficiency with low energy discharges can be significantly higher than previous measurements with high energy discharges. Industrial relevance This paper presents relevant information for the design of generating electrical discharges treatment. The study also addresses a specific case of use of by-products and shows the effectiveness of such technology.

International audience; Surface resistivity of solid insulators is usuallydetermined by measuring the current induced when an electricfield tangential to the surface is applied. This classical methodcan become questionable when the electric field is raised. In fact,a current may also flow above the interface through the humidgas, in addition to currents flowing at the interface and below theinterface within the solid bulk. This paper presents anexperimental study of the variation of the surface resistivityversus electric field and relative humidity RH of the surroundinggas. The results show that in dry gas (RH < 1%) and for anelectric field up 8 kV/mm, the surface gets no specific propertiescompared to the volume. However, in humid gas (1% < RH

In gas-insulated systems, the presence of solid insulators used to hold conductors at high voltage induces the presence of triple interfaces where the metal, solid insulator and gas are in contact. These regions, usually named “triple junction”, constitute weak points for the insulation, mainly due to the mismatch between permittivities of solid and gas, which induces an enhancement of the electric field. If the design of these regions is not carried out with great care, partial discharges (PDs) may appear and accelerate the ageing of the insulator. This paper deals with an experimental study of PDs in a “triple junction” electrode configuration, carried out with sensitive electrical and optical PD measurements. Experiments are done in two pure gases, nitrogen and SF6. Two discharge regimes can be observed: very small discharges (

In this paper, we present the results of electrical breakdown experiments performed in a contact gap ranging from 100nm to 10µm under air and nitrogen environment. The electrodes arrangement corresponds to a point-plane system and consists in a probe tip with a radius of curvature of 20µm and a perfectly flat electrode. A high precision piezoelectric actuator provides to the system a static resolution of ±30nm allowing to investigate submicrometer contact gaps. Numerous experiments have been performed at those distances (

The dielectric properties of two grades of bi-oriented isotactic polypropylene were studied with a variety of techniques: breakdown field measurements, dielectric spectroscopy, thermally stimulated depolarization currents (Is), and direct-current (dc) conduction I values. Standard polypropylene (STPP) and high-crystallinity polypropylene (HCPP) films were investigated. Measurements were carried out over a wide temperature range (2150C/1125C). The breakdown fields in both materials showed a very small difference. On the other hand, the dielectric losses and dc conduction I values were significantly lower in HCPP. Both materials showed a decrease in the dielectric loss versus temperature in the range 20–90C; this is favorable for application in alternating-current power capacitors. The analysis of the dc I value allowed us to find evidence of two main conduction mechanisms: (1) below 80C in both materials, a hopping mechanism due to the motion of electrons occurred in the amorphous phase, and (2) above 80C, ionic conduction occurred in HCPP, and hopping conduction occurred in STPP.

Streamers initiated in point-plane electrode geometry under impulse voltage are studied. Characterization up to 30 kV in both polarities shows two streamer types. In negative polarity, only slow `bush-like' streamers with a velocity of about 100 m s-1 are observed. In positive polarity, both `bush-like' and filamentary streamers appear. Positive `bush-like' streamers have similar velocity as in negative polarity, whereas filamentary streamers have a propagation velocity up to 30 km s-1. This high velocity is correlated to large transient current and light emission. Spectroscopic study of the light emitted by filaments shows mainly the second positive system of nitrogen. This system allows us to estimate the gas temperature inside a filament by making a comparison with a numerically simulated spectrum. A temperature close to 500 K is found. Dilution of hydrogen gas in liquid nitrogen allows us to determine also the electron density by Stark broadening of the Balmer Hα line. An electron density of about 1.1018 cm-3 is found.

International audience

International audience

This paper presents an experimental study of streamer initiation in liquid cyclohexane. The aim is to compare specific features of streamer initiation in positive and negative polarity. Experiments are carried out in point-plane geometry under impulse voltage. A new differential charge measurement system is presented. It allows to obtain a high detection sensitivity under impulse voltage (below 0.1 pC). The investigations presented consider the influence of applied voltage, impulse rise time, hydrostatic pressure. As previously observed under DC voltage, negative streamer initiation is due to an avalanche in the liquid phase, and is not affected by pressure, up to 10 MPa. In contrast, the mechanisms leading to positive streamer initiation are not clearly established. In this polarity, an increase of streamer initiation voltage is observed when the pressure is raised.

This paper presents an experimental study on the influence of an aromatic additive (pyrene) on the propagation of positive filamentary streamers and breakdown in liquid cyclohexane. Experiments are carried out in point-plane gaps up to 5 cm over a wide voltage range. With pyrene, the propagation is facilitated, and thus the breakdown voltage is lowered in point-plane geometry. Streamers also become very branched, and a much larger number of filaments propagate than in pure cyclohexane. Correlated to this, a large increase of the inception voltage of fast streamers (acceleration voltage) is observed at high voltage. This fact can be explained by macroscopic electrostatic properties of streamers, which depend on their geometrical structure. When more and more filaments propagate at high voltage they shield each other, which in turn limits their tip field (and thus velocity) at a nearly constant value over a large voltage range. The propagation velocity is thus not only determined by microscopic processes at the filament heads. Consequently, it does not always constitute an adequate parameter to directly appreciate and compare microscopic propagation processes. A discussion about streamer mechanisms is also presented.

This paper presents an experimental study of positive streamer propagation in mineral oil, in large point-plane gaps under impulse voltage. A systematic investigation was done concerning the influence of gap distance (/spl les/35 cm), and voltage from streamer inception up to large overvoltages. The measurements presented concern breakdown voltage measurements, time to breakdown, visualization of streamers (streak and still photographs), electrical measurements (transient current, charge), light emission intensity. Streamers are characterized and then classified into different modes (2nd, 3rd and 4th modes) according to their propagation velocities up to more than 100 km/s. According to the applied voltage, transitions between modes are observed, and correlations are established between charge, shape, and streamer velocity. The physical mechanisms as well as practical consequences are then discussed.

This paper presents an experimental study of Partial Discharges and light emission with ceramic substrates embedded in silicone oil, under ac and square high voltage. Two types of ceramic materials used in power electronics modules are considered: Aluminum Nitrite (AlN) and Alumina (Al2O3). With AlN, a large light emission due to the electroluminescence of the ceramics occurs during the negative dV/dt. This phenomenon is not observed with Al2O3. With Al2O3 and silicon oil, the light emitted is only due to PDs, and recording under square voltage wave shows that PDs are more numerous and/or more intense compared to ac. Square voltage is more relevant to actual working conditions within power electronics modules than ac.

Dark current measurements in pressurized gases at high electric field are performed in a coaxial electrode geometry. Three main parameters are investigated: the influence of electrode surface roughness, the nature and pressure of gas, the presence of water. Currents are measured in both negative and positive polarities. A large influence of electrode surface roughness and of the gas water content is observed. Most of results suggest that charge injection from the electrode constitute the basic mechanism of high field conduction through pressurized gases, and this mechanism is considerably enhanced when water is present.

This work reports on the relationship between structure and dielectric properties of biaxially oriented polypropylene. The morphology of semi-crystalline bioriented isotactic polypropylene (BOiPP) films is investigated using Wide Angle X-ray Diffraction (WAXD) and Polarized Optical Microscopy (POM). A β-orthorhombic structure, with a crystallinity ratio of about 46%, and a “Crater” morphology of the β-form is identified. Dielectric properties are measured by Broadband Dielectric Spectroscopy (BDS) over a wide temperature range (-150°C to 125°C). Since the dissipation factor of the PP is very low, special care was taken to obtain valid data. Two main relaxation processes are observed: a α-relaxation peak associated to the glass transition temperature (Tg) at low frequency and temperature about -7°C, and a broad β*-relaxation at high frequency at about -60°C, attributed to CH orientation. The variation of the dissipation factor versus sample thickness (from 3.8 μm to 11.8 μm) is correlated and explained by the increase of crystallinity ratio at larger thicknesses.

In Insulated gate Bipolar Transistor (IGBT) modules, ceramic substrates are used as insulation between semiconductor chips and the ground potential. The substrate, semiconductor chips and connections are covered with silicone gel to prevent partial discharges (PDs) from occurring. In this work, partial discharges are investigated on laboratory samples made of metalized substrates embedded in silicone gel and various liquids. Substrates are made of aluminum nitride (AlN), alumina (Al2O3), or glass/epoxy composite. The objective is to determine the actual origin of PDs, by changing the nature of encapsulating material and substrate. The various liquids used are first characterized using a point-plane geometry. Experiments show that a rather large discrepancy on the PD behavior can be due to the ceramic substrate itself. "Good" and "bad" substrates can be identified on the basis of PD measurements. The influence of the sample preparation (degassing procedure) is also evidenced. The main conclusion obtained in this paper shows that partial discharges do not occur within the encapsulating material, contrary to most previous hypotheses, but within pores existing in sintered ceramic materials. Changing the substrate nature has a large influence on PD behavior, whereas a modification of the encapsulating material has almost no effect.

This paper presents a study of the dynamics of positive streamer filaments in pentane using an optical method described in the text for pressures up to 9 MPa. It is observed that filaments expand and collapse, in a similar way to cavitation bubbles. Good agreement with the Rayleigh model shows that the dynamics of filaments is determined by liquid inertia. The influence of electric forces (electrostatic pressure) on the dynamics is found to be negligible. An evaluation of the energies involved shows that filaments are mainly composed of vapour, whose pressure varies with time and space and is on average higher than the hydrostatic pressure. Vaporization results mainly from energy dissipated at the filament extremity, which may be compared to a propagating point heat source of about 10 W power. At low pressure, a significant influence of energy dissipation within the filament, attributed to the transient current flowing during propagation, is also observed. At high pressure and/or high voltage, the stopping of the streamer is due to collapse of the gaseous filaments.

In this first part, the gaseous nature of filamentary positive streamers is demonstrated by the influence of hydrostatic pressure on their propagation in cyclohexane and pentane up to 7 MPa. At a fixed voltage, when the pressure is increased, the propagation velocity is found to be constant whereas the stopping length of streamers is greatly reduced. Correlated to this effect, the duration of transient currents and light emission signals is reduced. These effects are discussed in terms of the hypothesis that the conductivity of the streamer results from a gas discharge mechanism occurring within the filaments. These results constitute the experimental basis on which a study of the filament dynamics has been developed (part II).

We examine the breakdown and prebreakdown behavior of two insulating liquids: benzyl-toluene and mineral oil in a nonuniform electric field at large distances (up to 20 cm) under a positive impulse voltage. We evaluate and compare the breakdown strengths of both liquids in these conditions as a function of interelectrode distance via Weibull type plots, a method commonly used when dealing with insulating gases and solids. The comparative behaviors of the liquids change greatly when the cumulative probability of breakdown is decreased from 100%. The second part of this study concerns streamer stopping lengths and the corresponding current and light emission signals. >

This paper presents an experimental study of the initiation of positive streamers under step voltage in point-plane geometry, in a number of hydrocarbon liquids. The experimental conditions (point tip radius, pulse risetime, gap length) were strictly controlled in order to take valid measurements of the initiation fields and threshold propagation voltages of streamers. Transient currents associated with the initiation of positive streamers were recorded down to the /spl mu/A range with a sensitive differential measurement technique. The different current shapes obtained in the liquids studied are presented. The measured inception fields of positive streamers and propagation thresholds of filamentary streamers are discussed according to the properties of the liquids (ionization potentials and mobility of charge carriers). >

This paper presents an experimental study of the propagation of prebreakdown phenomena in transformer oil, in large point-plane gaps (5 to 20 cm), in positive polarity under step and ac voltages. The prebreakdown phenomena are characterized via the simultaneous recordings of transient currents, charges, photocurrents, and high-speed photographs of the emitted light. In these experimental conditions, prebreakdown phenomena in oil are basically composed of weakly luminous branched filaments, most of the time not connected to the point electrode, and propagating continuously. Bright luminous fast discharges reilluminate periodically the main branch of the propagating discharge from the point electrode to the extremity of these weakly luminous filaments. Below the breakdown voltage, streamers stop at an average length which increases linearly with the voltage. Above a critical length, they cannot stop any more and lead to breakdown. The main propagation velocity remains constant throughout the propagation. These observations, which present a number of similarities with leader phenomena in gases, are then discussed. >

Aluminium nitrite (AlN) or alumina (Al 2 O 3 ) substrates are widely used in power electronics modules, due to their ability to provide both electrical insulation, and heat conduction properties. A silicon gel usually covers the substrate, semiconductor chips, and bondings to prevent partial discharges (PD) from occurring within the module. However, at high voltage PDs can be observed in high electric field regions, mainly at the sharp edges of copper tracks on the substrate. In this study, we try to determine the origin of these PDs. Phase resolved PD recordings (PRPD) and optical visualization at very high sensitivity are carried out on substrates embedded in gel or insulating liquids. PD features are very different from those obtained in needle-plane geometry in gel or liquid, and do not depend on the nature of the liquid or gel. The main conclusion is that PDs recorded with substrates originate from the ceramic material itself, due to the presence of numerous μm-sized pores in sintered materials.

This paper presents an experimental study of the inception of positive streamers in point-to-plane geometry under pulsed voltage. The different pre-breakdown events (slow and filamentary streamers) are characterized via sensitive transient current recordings, obtained using a new differential measurement technique described in the text. The roles of the tip radius, voltage pulse rise time, gap distance and hydrostatic pressure are systematically investigated in two liquids, cyclohexane and pentane. We found two parameters to characterize inception of both streamer types in a liquid: a unique initiation field for slow and filamentary streamers (depending slightly on the point tip radius of curvature); and a threshold propagation voltage for filamentary streamers (depending on the gap distance). There is also a critical point-tip radius above which no slow streamers are observed. It is shown that the initiation field and the propagation threshold can be accurately determined only in very specific conditions, namely below the critical point-tip radius and with fast rise time voltage impulses (about 10 ns). The presence of a gaseous phase in the initiation process is identified via the influence of hydrostatic pressure. Finally, the significance of the critical point-tip radius and that of the propagation voltage of filamentary streamers are discussed by comparison between the streamer and a conducting filament.

Pulsed high-voltage discharges induce simultaneously several physical processes (UV light, shock waves) and chemical processes (active species and radicals such as °OH, °H, °O, °HO 2 , H 2 O 2 , O 3 , etc.), able to degrade harmful organic compounds in wastewater. This paper aims to compare various discharge types (either in the solution volume, or in the gas phase in close proximity to the liquid surface), based on the measurement of their energetic efficiency. This is done by correlating electrical measurements (injected energy) with chemical measurements (pollutant degradation), with various pollutants and catalysers. Pulsed corona discharges in the gas above the liquid appears to be the most effective process in terms of mol pollutant degraded per joule of electrical energy, and also the most simple to implement.

Aluminium nitrite (AlN) or alumina (Al 2 O 3 ) substrates are widely used in power electronics modules, due to their ability to provide both electrical insulation, and heat conduction properties. A gel layer usually covers the substrate, semiconductor chips, and bondings to prevent partial discharges (PD) from occurring within the module. However, at high voltage PDs can be observed in high electric field regions, mainly at the sharp edges of copper tracks on the substrate. In this study, we try to determine the origin of these PDs. Phase resolved PD recordings (PRPD) and optical visualisation at very high sensitivity are carried out on substrates embedded in gel or insulating liquids. PD features are very different from those obtained in needle-plane geometry in gel or liquid. The main conclusion is that PDs of low amplitudes probably originate from the ceramic itself, due to the presence of numerous µm-sized pores in sintered materials.

Gassing phenomena under an AC voltage in various dielectrics liquids subjected to partial discharges produced in different gases are discussed. The roles of the numerous experimental parameters which affect the results have been studied using a uniform field test cell. It is shown first that from the classical PD equivalent circuit, a more refined analysis permits a good description of the influence of parameters such as gas and solid thickness as well as the amplitude and frequency of the applied voltage on gas volume variations, and discharge characteristics. This allows one to get suitable measurement of the charge and energies involved in the gaseous discharges, from which one can deduce the energy required to absorb (or to create) a gas molecule. This gassing energy, which is independent of the experimental parameters, is characteristic of each gas/liquid pair and constitutes a valuable quantitative evaluation of the gassing properties. >

Trifluoroiodomethane CF 3 I has been recently considered as a potential alternative to SF 6 , thanks to its high electronegativity and extremely low environmental effect. However, due to its high boiling point, CF 3 I should be mixed with other gases such as N 2 or CO 2 in order to avoid the liquefaction at low temperature. In this paper, we present breakdown measurements carried out in CF3I and CF 3 I-N 2 gas mixtures, under dc voltage, and with a pressure-distance product (p.d) up to 5 mmbar. Pure CF3I has a higher breakdown voltage (V b ) than SF 6 . However, the favourable synergistic effect observed in SF 6 gas mixtures with N 2 , at low SF 6 content, is not observed in CF 3 I gas mixtures. In CF 3 I-N 2 mixtures, the dc breakdown voltage increases proportionally to the CF 3 I content. As a consequence, breakdown voltages for mixtures containing up to 50% CF 3 I are lower than with SF 6 at the same ratio. These results are in good agreement with calculated values using breakdown model and reduced critical field strength (E/N) crit reported by others authors. In CF3I, the appearance of solid by-products (particles) generated by breakdown is also observed. The nature of these particles is tentatively attributed to the formation of iodine. In our sphere-sphere geometry, the accumulation of such solid particles leads to a measurable conductivity.

In gas insulated switchgears (GIS), high voltage electrodes are supported by solid insulators. A "triple junction" (TJ) exists at the interface between metal, insulating solid, and gas. This area constitutes a preferential zone were partial discharges (PDs) can appear. A further degradation of insulation performance can occur if solid particles accumulate at that place. This paper presents experiments carried out to obtain a quantitative account of the influence of a metallic particle located close to a triple junction area, both in dry air and SF6. PDs are detected and measured by conventional electrical measurements, and observed optically with a high-sensitivity intensified camera. Measurements under AC voltage show the influence of the particle on PD inception and flash-over voltage, in comparison with the same geometry without particle. In SF6, the particle induces a large decrease of PD inception and breakdown voltages, which become nearly independent of the gas pressure.

International audience; In this study, the efficiency of different types of pulsed electrical discharges for the removal of organic pollutants from wastewater has been determined. Three discharge types, either in the water volume or in close proximity to the water surface are studied. The production of hydrogen peroxide in pure water, and the degradation of two typical pollutants (4-chlorophenol and 4-nitrophenol) is measured together with the amount of electrical energy dissipated in discharges. It is shown that the energy yield for the degradation of organic pollutants, expressed in terms of degraded moles per Joule, strongly depends on the discharge type. The highest efficiency is obtained with pulsed corona discharges in humid air above the water surface. A lower efficiency is found with spark discharges in water, and the less efficient process is constituted by streamer discharges in water. The influence of ferrous ions added to solutions is also very different according to the discharge type. This helps to get a better understanding of the degradation processes involved with the different discharge types.

This paper presents an experimental study of streamer inception in a silicone gel. Many parameters are able to influence the inception of discharges in a gel: voltage wave shape, electrode geometry, temperature, etc. In this work, streamer inception is studied in various conditions of electrode shapes (from sharp points up to quasi-uniform field), voltage (ac, dc, impulse voltage) and temperature. Streamer inception is detected by the measurement of breakdown voltages in selected conditions. The results obtained show that streamer inception field varies when the electrode shape is changed, in a similar way as in liquids: the inception field decreases when the electrode surface increases. On the other hand, temperature and voltage wave shape have almost no influence on the inception field. Results are discussed in comparison with data already obtained in liquids in similar conditions.

A study of transient currents associated with the propagation of filamentary positive streamers in liquids is presented. Experimental measurements of currents in several selected liquids were analyzed with a simple model in which the channel is compared to a cylindrical conducting filament. Good agreement was found between theory and experiment, which indicates a rather high conductivity of the streamer filaments. An estimation of the charge carrier mobility in the filament was obtained, and it is concluded that the high current densities recorded are likely carried by electrons moving in a gaseous phase. The propagation of positive filaments in liquids is found to be similar to that of leaders in electronegative gases. >

This paper presents an experimental study of pre-breakdown discharges in water (usually called ldquostreamersrdquo) and transient breakdown arcs (called ldquosparksrdquo) generated by high voltage pulses, in relation with their potential application to degrade organic molecules for depollution purposes. An experimental set-up is described using semiconductor high voltage switches to produce high voltage pulses. In a point-plane gap, depending on the high voltage pulse duration, either streamers alone or streamers followed by a transient breakdown arc can be produced. Electrical measurements provide data correlated to streamer and spark processes: current, charge, power, and dissipated energy. Coupled to these electrical measurements, the degradation of 4-chlorophenol and 4-nitrophenol molecules is studied by HPLC measurements. It is reported that the energy yield for the degradation of these products is higher when sparks are used instead of streamers.

The purpose of this work is to evaluate the chemical stability of a bio-degradable insulating oil composed by a mixture of esters based on rape-seed oil. The measurements are done in comparison with a commercial mineral oil. Both oils are subjected to accelerated ageing conditions at 120degC under air (open beaker method). Dielectric properties (dissipation factor, permittivity, conductivity, AC breakdown voltage) and chemical parameters (acidity, water content) are monitored during the ageing process. In the rape-seed based oil, ageing has a negligible influence on the breakdown voltage, whereas conductivity and acid content show a large increase.

Silicone gels are widely used to encapsulate power electronics modules. The objective of this paper is to study the partial discharge (PD) mechanism in a silicone gel, using electrical measurements and fast visualization. Experiments are carried out in a pointplane geometry, using either impulse voltage or ac. Under impulse voltage, the visualization shows that the first discharges recorded in a new sample are due to the initiation and propagation of "streamers", with features close to those previously reported in viscous liquids. Under ac, a stable PD regime rapidly establishes: a streamer creates a cavity with a long lifetime, and PDs occur in this cavity during the subsequent ac waves. Since slow streamers develop during long times (some ms), classical PD measurements do not provide an adequate evaluation of the actual discharge magnitude: very small PDs (1 pC) are recorded, whereas large cavities with a total charge in excess of 10 pC are actually present in the gel. When PDs are repeated permanent degradations of the gel rapidly occur, showing the limited self-healing capabilities of silicone gels.

This paper presents an experimental study of pre-breakdown discharges in water (usually called 'corona' or 'streamer') used to degrade organic molecules for depollution purposes. Streamers in water are generated by high voltage pulses of short duration in order to minimize energy losses by Joule heating. Measurements of the electrical energy used to develop streamers can be taken only when losses due to the electrical conduction in the test cell becomes negligible, i.e. at high voltage. Coupled to electrical measurements, the formation of hydrogen peroxide and the degradation of organic compounds such as 4-chlorophenol and 4-nitrophenol is studied. Chemical effects are correlated with the amount of electrical energy released, which depends mainly on conductivity and applied voltage. On the other hand, the chemical yield of these processes, expressed in terms of mole/joule is independent of voltage and conductivity.

In order to increase the knowledge of the processes involved during the degradation of insulating silicone gels under ac stress, recordings of the activity of partial discharges (PD) are performed. Silicone gels are commonly used for the insulation and packaging of high voltage semiconductors such as IGBT modules. We worked on a commercially available dielectric silicone gel. Electrical and optical apparatus allows the measurement of PD's and their location, either on actual power module substrates, or in a point-plane gap. The temperature dependence of PD inception voltage is moderate, while the number of PD's and their charge steeply increases versus temperature. We show that the formation of cavities constitutes the main factor responsible for the degradation under ac conditions. The actual self-healing capabilities of silicone gels are also studied and discussed.

This paper presents an experimental study of the influence of vapor bubbles on breakdown in liquid nitrogen. Vapor bubbles are initiated by creating a small hot spot at the surface of an electrode. The behavior of vapor bubbles is first investigated by visualization, versus power dissipated by the heater, pressure and electric field. When breakdown occurs in the presence of bubbles, it is due to formation of either a vapor bridge between the electrodes (at low pressure), or a vapor layer on the hot spot (at high pressure). The results are discussed in comparison with gas breakdown fields obtained from the Paschen's law.

This paper presents streamer charge measurements carried out in liquid cyclohexane, and calculations of the electric field acting on the streamer. The time resolved measurement of streamer charge is made with a differential system that allows to subtract the electrode charge in order to obtain the streamer charge under impulse voltage with a high sensitivity (below 1pC). Measurements are carried out in a point plane gap versus applied voltage and hydrostatic pressure, and concern slow subsonic streamers observed in positive polarity. With the charge data obtained, and with the measured streamer size, numerical calculations of the electric field within the gaseous streamer and outside the streamer are done. This allows to calculate the voltage drop existing within the streamer, and also to determine the intensity of the electrostatic pressure acting at the gas/liquid interface.

A real-time optical detection method combined with high-speed current measurement and visualization was used to investigate bubble generation and growth in purified cyclohexane. The generation of gaseous bubbles in the high field region present on a sharp tip appears to be a consequence of the detected current pulse. An analysis of the influence of the energy input together with that of the hydrostatic pressure shows that vaporization of the liquid is the most probable mechanism of bubble generation. The energy input is achieved in a very short time (a few nanoseconds). As the bubble grows, the pressure and temperature decrease in the bubble down to steady-state boiling conditions; the bubble size is then maximal, and as the temperature decreases further to the ambient value, the vapour condenses and the bubble disappears. >

An experimental study of the initiation of positive streamers under step voltage in a variety of hydrocarbon liquids is presented. The experimental conditions (point tip radius, pulse risetime, and gap length) required for obtaining valuable measurements of the initiation fields and threshold propagation voltages of streamers are defined. The results obtained are discussed with reference to the known properties of the liquids (ionization potentials and breakdown strength).

The authors present a study of the dynamics of positive streamer filaments in pentane, for hydrostatic pressures above 1MPa. They describe an experimental setup allowing the simultaneous visualization of the channels, together with the electrooptical time-resolved measurement of their diameter. The dynamics of the expansion and collapse is fairly well described by Rayleigh theory, showing that the filaments are gaseous channels. It is shown that the stopping of filamentary streamers at high pressure is determined by the collapse of the channel. The behavior of the filaments may be described by considering their extremities as moving point sources of energy.

This paper presents a summary of the introductory lecture to be presented at the 1996 ICDL on the particular problem of prebreakdown phenomena in long liquid gaps (centimeters to decimeters). The specific topics developed concern the characterisation of the propagation of positive discharges in mineral oil, including a description of the various propagation modes, together with the study and modelling of their gaseous nature and electrical properties.

In this study we examine breakdown and prebreakdown phenomena in asymmetric geometry (point to plane) at large gap distances (up to 20 cm) under positive voltage steps (up to 500 kV) in liquids of distinct chemical families: saturated, aromatic and polyaromatic. Signal analysis shows that the currents are not continuous but are made up of bursts with different waiting times between them. The duration and number of these bursts vary according to the general chemical composition of the liquid. For example, there are numerous short bursts in mineral oil and a few long bursts in the aromatic liquids. The polyaromatic has a behaviour which retains features of both. >