1. Excellent dielectric response and microwave absorption in magnetic field-induced magnetic ordered structures.
- Author
-
Xiu, Zheng, Pan, Fei, Yao, Kai, Jiang, Haojie, Wang, Xiao, Li, Lixin, Wang, Jingli, Ma, Xiaona, Yang, Yang, and Lu, Wei
- Subjects
ELECTROMAGNETIC wave absorption ,METAL fibers ,MAGNETIC structure ,IMPEDANCE matching ,MAGNETIC materials - Abstract
• Centimeter-level Co long fibers (Co-lf) consistently exhibited higher permittivity than Co particles and Co short fibers due to the enhancement of the effective EM coupling. • A template method is applied to fabricate Co 2 P with inheritance morphology to further confirm the influence of anisotropic structure on the dielectric and microwave absorption performance. • A well-designed phosphorylation process introduces a heterogeneous interface that enriches the type of electromagnetic wave loss while improving the impedance matching to further enhance the EMA properties. Weak interactions prevent the magnetic particles from achieving excellent electromagnetic wave absorption (EMA) at a low filler loading (FL). The construction of one-dimensional magnetic metal fibers (1D-MMFs) contributes to the formation of an electromagnetic (EM) coupling network, enhancing EM properties at a low FL. However, precisely controlling the length of 1D-MMFs to regulate permittivity at low FL poses a challenge. Herein, a novel magnetic field-assisted growth strategy was used to fabricate Co-based fibers with adjustable permittivity and aspect ratios. With a variety of FL changes, centimeter-level Co long fibers (Co-lf) consistently exhibited higher permittivity than Co particles and Co short fibers due to the enhancement of the effective EM coupling. The Co-lf exhibits excellent EMA performance (–54.85 dB, 5.8 GHz) at 10 wt.% FL. Meanwhile, heterogeneous interfaces were introduced to increase the interfacial polarization through a fine phosphorylation design, resulting in elevated EMA performances (–51.50 dB, 6.6 GHz) at 10 wt.% FL for Co 2 P/Co long fibers. This study improves the orderliness of the particle arrangement by regulating the length of 1D-MMFs, which affects the behavior of electrons inside the fibers, providing a new perspective for improving the EMA properties of magnetic materials at a low FL. Significant improvements in dielectric response and electromagnetic absorption performance of ordered magnetic structures fabricated by magnetic field-induced growth [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2025
- Full Text
- View/download PDF