1. Anomalous transport and thermoelectric performances of CuAgSe compounds
- Author
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Hong, A. J., Li, L., Zhu, H. X., Zhou, X. H., He, Q. Y., Liu, W. S., Yan, Z. B., Liu, J. M., and Ren, Z. F.
- Subjects
Condensed Matter - Materials Science - Abstract
The copper silver selenide has two phases: the low-temperature semimetal phase ({\alpha}-CuAgSe) and high-temperature phonon-glass superionic phase (\b{eta}-CuAgSe). In this work, the electric transport and thermoelectric properties of the two phases are investigated. It is revealed that the \b{eta}-CuAgSe is a p-type semiconductor and exhibits low thermal conductivity while the {\alpha}-CuAgSe shows metallic conduction with dominant n-type carriers and low electrical resistivity. The thermoelectric figure of merit zT of the polycrystalline \b{eta}-CuAgSe at 623 K is ~0.95, suggesting that superionic CuAgSe can be a promising thermoelectric candidate in the intermediate temperature range., Comment: 14 pages, 6 figures
- Published
- 2015