189 results on '"Hiroshi Ikenoue"'
Search Results
2. Size Effects of Poly-Si Formed by Laser Annealing With Periodic Intensity Distribution on the TFT Characteristics
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Akira Mizutani, Fuminobu Hamano, Daisuke Nakamura, Tetsuya Goto, Siti Rahmah Aid, and Hiroshi Ikenoue
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Low temperature polycrystalline Si (LTPS) ,thin-film-transistor (TFT) ,excimer laser annealing (ELA) ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 - Abstract
Currently, low-temperature polycrystalline silicon (LTPS) thin-film transistors (TFTs), which are characterized by high mobility of electrons, are fabricated by excimer laser annealing. High mobility in low-temperature polycrystalline silicon is achieved by controlling the grain size to approximately 300 nm. However, with future potential growth of active-matrix organic light-emitting diodes in terms of their increasing use as backlight in active matrix micro-LEDs, even higher mobility is required. One of the methods to improve mobility is to produce grains of sizes above 300 nm. However, as far as we know, there are no reports of investigating the dependence between the device characteristics and the grain size of above 300 nm. In this study, we examine the possibility of controlling the grain size above approximately 350 nm by laser annealing with an intensity distribution and investigate the grain size dependence of the TFT characteristics. We show that the grain size can be controlled approximately in the range of 1–2.5 $\mu \text{m}$ , and mobility of 248±28 cm2 V−1s−1 is achieved at a grain size of 2.5 $\mu \text{m}$ . Furthermore, we compare the device characteristics of the step-and-repeat and scan annealing and verify that the device characteristics do not deteriorate even during scan annealing. The study confirms that it is technically possible to produce LTPS with grain sizes controlled in the range of 1–2.5 $\mu \text{m}$ for customizing device characteristics.
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- 2021
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3. Fabrication of CMOS Invertors in Si Thin-Film-Transistors by Laser Doping Using a Chemical Solution Coating
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Kaname Imokawa, Takayuki Kurashige, Akira Suwa, Daisuke Nakamura, Taizoh Sadoh, Tetsuya Goto, and Hiroshi Ikenoue
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Low temperature poly Si (LTPS) ,thin-film-transistor (TFT) ,excimer laser annealing (ELA) ,laser doping ,chemical solution coating ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 - Abstract
We demonstrated that p- and n-type activation layers can be formed in Si films by laser doping with H3PO4 solution and Al2O3 sol coating. The phosphorus and aluminum concentrations at the laser doped region were found to be over 1019 cm-3 in Si films. In addition, generations of the activation carriers for n- and p-type layers were confirmed by Hall effects measurement. In this study, the characteristic of CMOS invertors fabricated by laser doping are presented.
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- 2020
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4. Low-temperature
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Kenta Moto, Takayuki Sugino, Ryo Matsumura, Hiroshi Ikenoue, Masanobu Miyao, and Taizoh Sadoh
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Physics ,QC1-999 - Abstract
Low temperature (8%) on insulating substrates is essential to realize next generation flexible electronics. To achieve this, a growth method of high quality GeSn films on insulating substrates by combination of laser irradiation and subsequent thermal annealing is developed. Here, the laser fluence is chosen as weak, which is below the critical fluence for crystallization of GeSn. It is clarified that for samples irradiated with weak laser fluence, complete crystallization of GeSn films is achieved by subsequent thermal annealing at ∼170 oC without incubation time. In addition, the quality of GeSn films obtained by this method is higher compared with conventional growth techniques such as melting growth by pulsed laser annealing or solid-phase crystallization (SPC) without pre-laser irradiation. Substitutional Sn concentrations in the grown layers estimated by Raman spectroscopy measurements are 8-10%, which far exceed thermal equilibrium solid-solubility of Sn in Ge (∼2%). These phenomena are explained by generation of a limited number of nuclei by weak laser irradiation and lateral SPC by subsequent thermal annealing. This method will facilitate realization of next-generation high performance devices on flexible insulating substrates.
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- 2017
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5. Formation of Low Resistance Contacts to p-type 4H-SiC using Al-Film Source Laser Doping.
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Kento Okamoto, Toshifumi Kikuchi, Akihiro Ikeda, Hiroshi Ikenoue, and Tanemasa Asano
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- 2019
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6. Painless thyroiditis mimicking relapse of hyperthyroidism during or after potassium iodide or thionamide therapy for Graves’ disease resulting in remission
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Ken Okamura, Kaori Sato, Megumi Fujikawa, Sachiko Bandai, Hiroshi Ikenoue, and Takanari Kitazono
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Endocrinology ,Endocrinology, Diabetes and Metabolism - Abstract
The diagnosis of painless thyroiditis (PT) during antithyroid drug (ATD) treatment of Graves' disease (GD) is difficult. We evaluated the thyroidal radioactive iodine uptake (RAIU) in 100 patients with relapsed thyrotoxicosis during or after careful ATD treatment. The RAIU was5%/5 h in 35 patients (35%) (Group A - PT), 5%-15%/5 h in 6 patients (6%) (Group B - indefinite) and15%/5 h in 59 patients (59%) (Group C - relapsed GD [rGD]). TSH receptor antibody (TBII) was positive in 4 (11.4%), 3 (50.0%) and 39 (only 66.1%) patients in Groups A, B and C, respectively. In Group A, the serum fT
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- 2023
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7. Excimer laser doping for the fabrication of 4H-SiC power devices
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Yoshiaki Kakimoto, Keita Katayama, Takuma Yasunami, Tetsuya Goto, Daisuke Nakamura, and Hiroshi Ikenoue
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- 2023
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8. Nanosecond time-resolved two-dimensional temperature estimation of nanosecond laser-irradiated silicon
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Reiji Koike, Toshifumi Kikuchi, Keita Katayama, Yoshiaki Kakimoto, Daisuke Nakamura, and Hiroshi Ikenoue
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- 2023
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9. Iodide-sensitive Graves’ hyperthyroidism and the strategy for resistant or escaped patients during potassium iodide treatment
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Ken Okamura, Kaori Sato, Megumi Fujikawa, Sachiko Bandai, Hiroshi Ikenoue, and Takanari Kitazono
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Iodine Radioisotopes ,Methimazole ,Endocrinology ,Antithyroid Agents ,Hypothyroidism ,Endocrinology, Diabetes and Metabolism ,Potassium Iodide ,Humans ,Thyrotropin ,Thyroid Neoplasms ,Iodides ,Hyperthyroidism ,Graves Disease - Abstract
The effectiveness of potassium iodide (KI) (100 mg/day) was evaluated in 504 untreated patients with Graves' hyperthyroidism (GD). Initial response to KI within 180 days, the effect of additional methylmercaptoimidazole (MMI) or radioactive iodine (RI) in resistant or escaped patients, and long-term prognosis were evaluated. Serum fT
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- 2022
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10. Simultaneous laser doping and annealing to form lateral p–n junction diode structure on silicon carbide films
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Nilesh J. Vasa, Hiroshi Ikenoue, H. G. Prashantha Kumar, M. S. Ramachandra Rao, Tiju Thomas, Sree Harsha Choutapalli, Daisuke Nakamura, and Emmanuel Paneerselvam
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010302 applied physics ,Materials science ,Annealing (metallurgy) ,business.industry ,Doping ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Laser ,01 natural sciences ,Pulsed laser deposition ,Carbide ,law.invention ,chemistry.chemical_compound ,chemistry ,law ,0103 physical sciences ,Silicon carbide ,Optoelectronics ,Thin film ,0210 nano-technology ,business ,p–n junction - Abstract
Laser-assisted doping of intrinsic silicon carbide (SiC) films deposited on Si (100) substrates by pulsed laser deposition (PLD) method and its influence on simultaneous annealing of the thin film is studied. PLD grown intrinsic SiC films are transformed to p-type SiC and n-type SiC, using laser-assisted doping in aqueous aluminum chloride and phosphoric solutions, respectively. Simultaneous doping and annealing of the SiC film are observed during laser-assisted doping. By precisely positioning the selectively doped region, lateral p–n diodes are formed on the SiC films without using any mask. Electric characteristics confirmed the formation of a lateral p–n diode structure. Numerical analysis of temperature distribution along the depth of the SiC films explains the mechanism of simultaneous doping and annealing during the laser treatment.
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- 2021
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11. Laser-Induced Phosphorus-Doped Conductive Layer Formation on Single-Crystal Diamond Surfaces
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Abdelrahman Zkria, Hiroshi Ikenoue, Shinya Ohmagari, Yū Ki Katamune, Eslam Abubakr, and Tsuyoshi Yoshitake
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Materials science ,business.industry ,Doping ,Physics::Optics ,Diamond ,engineering.material ,Nanosecond ,Laser ,law.invention ,Monocrystalline silicon ,Condensed Matter::Materials Science ,law ,Electrical resistivity and conductivity ,engineering ,Optoelectronics ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,Physics::Atomic Physics ,business ,Ohmic contact ,Layer (electronics) - Abstract
A laser-induced doping method was employed to incorporate phosphorus into an insulating monocrystalline diamond at ambient temperature and pressure conditions. Pulsed laser beams with nanosecond duration (20 ns) were irradiated on the diamond substrate immersed in a phosphoric acid liquid, in turns, and a thin conductive layer was formed on its surface. Phosphorus incorporation in the depth range of 40-50 nm below the irradiated surface was confirmed by secondary ion mass spectroscopy (SIMS). Electrically, the irradiated areas exhibited ohmic contacts even with tungsten prober heads at room temperature, where the electrical resistivity of irradiated areas was greatly decreased compared to the original surface. The temperature dependence of the electrical conductivity implies that the surface layer is semiconducting with activation energies ranging between 0.2 eV and 54 meV depending on irradiation conditions. Since after laser treatment no carbon or graphitic phases other than diamond is found (the D and G Raman peaks are barely observed), the incorporation of phosphorus is the main origin of the enhanced conductivity. It was demonstrated that the proposed technique is applicable to diamond as a new ex situ doping method for introducing impurities into a solid in a precise and well-controlled manner, especially with electronic technology targeting of smaller devices and shallower junctions.
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- 2020
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12. P‐11: High Performance All‐Solution Processed InZnO Thin‐Film Transistors via Photo‐Functionalization at Varying Fluence and Annealing Environment
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Hiroshi Ikenoue, Juan Paolo Bermundo, Dianne C. Corsino, Yasuaki Ishikawa, Yukiharu Uraoka, and Mami N. Fujif
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Materials science ,business.industry ,Thin-film transistor ,Annealing (metallurgy) ,Optoelectronics ,Surface modification ,business ,Fluence ,Solution processed - Published
- 2020
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13. Evaluation of Temperature at SiC Surface During Pulsed Excimer Laser Irradiation
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Shogo Mutoh, Akihiro Ikeda, Hiroshi Ikenoue, and Tanemasa Asano
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- 2021
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14. Laser doping mechanism of 4H-SiC by KrF excimer laser irradiation using SiNx thin films
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Takuma Yasunami, Daisuke Nakamura, Keita Katayama, Yoshiaki Kakimoto, Toshifumi Kikuchi, and Hiroshi Ikenoue
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General Engineering ,General Physics and Astronomy - Abstract
In this study, nitrogen is doped into 4H-SiC by irradiating 4H-SiC with a SiNx thin film and a KrF excimer laser. The doping depth profile, crystal structure, electrical properties, and surface roughness results are analyzed to evaluate the excimer-laser doping mechanism. High-concentration doping is possible at a fluence of 2.5 J cm−2 and 10 shots, while maintaining the 4H-SiC crystal structure via solid-phase diffusion. However, changes in the 4H-SiC crystalline state are observed upon liquid-phase diffusion at a fluence of ≥2.8 J cm−2. At a fluence of 2.5 J cm−2 and 100 shots, nitrogen can be deeply diffused via solid-phase diffusion; however, an amorphous layer is formed on the surface and there is an increase in contact resistance.
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- 2023
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15. Impact of Cyber-Physical Systems on Research and Development of Semiconductor Devices
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Hiroshi Ikenoue, Keita Katayama, Yoshiaki Kakimoto, Toshifumi Kikuchi, and Daisuke Nakamura
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General Medicine - Published
- 2022
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16. Electrical Characteristics of LTPS-TFTs Fabricated by ELA with Laser Intensity Distributions Controlled by Dot Array Masks
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Toru Okatsugi, Keita Katayama, Yoshiaki Kakimoto, Daisuke Nakamura, Tetsuya Goto, and Hiroshi Ikenoue
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General Medicine - Published
- 2022
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17. Fabrication of CMOS Invertors in Si Thin-Film-Transistors by Laser Doping Using a Chemical Solution Coating
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Tetsuya Goto, Akira Suwa, Takayuki Kurashige, Kaname Imokawa, Hiroshi Ikenoue, Taizoh Sadoh, and Daisuke Nakamura
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Fabrication ,Materials science ,chemistry.chemical_element ,engineering.material ,thin-film-transistor (TFT) ,law.invention ,Coating ,law ,Aluminium ,laser doping ,Electrical and Electronic Engineering ,business.industry ,excimer laser annealing (ELA) ,Phosphorus ,Low temperature poly Si (LTPS) ,Doping ,chemical solution coating ,Laser ,Electronic, Optical and Magnetic Materials ,chemistry ,CMOS ,Thin-film transistor ,engineering ,Optoelectronics ,lcsh:Electrical engineering. Electronics. Nuclear engineering ,business ,lcsh:TK1-9971 ,Biotechnology - Abstract
We demonstrated that p- and n-type activation layers can be formed in Si films by laser doping with H3PO4 solution and Al2O3 sol coating. The phosphorus and aluminum concentrations at the laser doped region were found to be over 1019 cm-3 in Si films. In addition, generations of the activation carriers for n- and p-type layers were confirmed by Hall effects measurement. In this study, the characteristic of CMOS invertors fabricated by laser doping are presented.
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- 2020
18. High-Concentration, Low-Temperature, and Low-Cost Excimer Laser Doping for 4H-SiC Power Device Fabrication
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Kento Okamoto, Tanemasa Asano, Toshifumi Kikuchi, Daisuke Nakamura, Akihiro Ikeda, Hiroshi Ikenoue, and Kaname Imokawa
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High concentration ,Materials science ,Fabrication ,Excimer laser ,business.industry ,Mechanical Engineering ,medicine.medical_treatment ,Doping ,Condensed Matter Physics ,Power (physics) ,Mechanics of Materials ,medicine ,Optoelectronics ,General Materials Science ,business ,p–n diode - Abstract
We developed a novel KrF excimer laser doping system for 4H-SiC power devices, and demonstrated laser doping of 4H-SiC with Al thin film deposited on the surface. As seen from the results of the Al depth profile, high concentration implantation (~ 1021 cm-3 at the surface) of Al was achieved by laser ablation of the Al thin film. A high, built-in-potential (~3.5 V) of the pn junction diode was clearly seen in the I-V curve. In addition, the contact resistivity of the deposited Al/Ti electrodes on the surface was 1.9 × 10−4 Ωcm2 by TLM (Transmission Line Model). It was confirmed that a high concentration of Al doping and low contact resistivity were achieved by the KrF excimer laser doping system.
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- 2019
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19. Increasing Laser-Doping Depth of Al in 4H-SiC by Using Expanded-Pulse Excimer Laser
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Tanemasa Asano, Akihiro Ikeda, Hiroshi Ikenoue, and Takashi Shimokawa
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010302 applied physics ,Materials science ,Excimer laser ,business.industry ,Mechanical Engineering ,medicine.medical_treatment ,Doping ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Laser ,01 natural sciences ,Pulse (physics) ,law.invention ,Mechanics of Materials ,law ,0103 physical sciences ,medicine ,Optoelectronics ,General Materials Science ,0210 nano-technology ,business - Abstract
Al doping into 4H-SiC performed by irradiating pulse-width-expanded excimer laser to an Al film deposited on the 4H-SiC surface is investigated. An optical pulse stretcher was constructed to produce the laser pulse whose peak intensity was reduced as half as that of the original pulse and pulse width was expanded from 55 ns to 100 ns. The irradiation of the expanded pulses is found to reduce the ablation of the materials from the surface and enable irradiation of multiple shots. As the result, doping depth of Al is significantly increased. The multiple shots of the expanded pulses is also fund to decrease the sensitivity to spatial non-uniformity of laser intensity and increase the uniformity of doped region.
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- 2019
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20. 30‐3: High Performance All Solution Processed Oxide Thin‐Film Transistor via Photo‐induced Semiconductor‐to‐Conductor Transformation of a‐InZnO
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Juan Paolo Bermundo, Dianne C. Corsino, Chaiyanan Kulchaisit, Aimi Syairah, Hiroshi Ikenoue, Yasuaki Ishikawa, Mami N. Fujii, and Yukiharu Uraoka
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Materials science ,Excimer laser ,business.industry ,medicine.medical_treatment ,Oxide thin-film transistor ,Conductor ,Solution processed ,Transformation (function) ,Semiconductor ,Thin-film transistor ,medicine ,Optoelectronics ,business ,Transparent conducting film - Published
- 2019
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21. Formation of low resistivity layers on singlecrystalline diamond by excimer laser irradiation
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Abdelrahman Zkria, Shinya Ohmagari, Yūki Katamune, Tsuyoshi Yoshitake, Eslam Abubakr, Hiroshi Ikenoue, and Kaname Imokawa
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Materials science ,medicine.medical_treatment ,Analytical chemistry ,chemistry.chemical_element ,Cathodoluminescence ,02 engineering and technology ,engineering.material ,010402 general chemistry ,01 natural sciences ,Materials Chemistry ,medicine ,Electrical and Electronic Engineering ,Boron ,Ohmic contact ,Excimer laser ,Dopant ,Mechanical Engineering ,Doping ,Diamond ,General Chemistry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Amorphous carbon ,chemistry ,engineering ,0210 nano-technology - Abstract
A singlecrystalline diamond (100)(Ib) plate immersed in 2% boric acid was irradiated by 193-nm ArF excimer laser beams for the formation of conductive layers on the surface of an insulating diamond substrate. From current-voltage measurements of the irradiated areas, it was confirmed that semiconducting layers with high conductivities are formed on the diamond surface. It was possible to form ohmic contacts by directly touching tungsten probes with the layer surface. Since Raman spectra exhibited only peaks due to diamond and no peaks due to amorphous carbon, the drastically enhanced conductivity is not attributed to amorphous carbon formation but due to the incorporation of boron atoms into the diamond subsurface from the dopant acid. Secondary ion mass spectrometric depth profile showed the incorporation of boron atoms up to 40 nm depths from the surface. From cathodoluminescence measurements at low temperatures, it was difficult to detect clear peaks for the substitutional incorporation of boron atoms into diamond lattices, which could be attributed to the small thickness of the doped layer for detection. The proposed technique is a new potential method for shallow doping and formation of conductive layers on singlecrystalline diamond surfaces.
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- 2019
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22. Laser Assisted Doping of Silicon Carbide Thin Films Grown by Pulsed Laser Deposition
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M. S. Ramachandra Rao, Mitsuhiro Higashihata, Daisuke Nakamura, Hiroshi Ikenoue, Emmanuel Paneerselvam, Vinoth Kumar Lakshmi Narayanan, and Nilesh J. Vasa
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Materials science ,Infrared spectroscopy ,02 engineering and technology ,Substrate (electronics) ,01 natural sciences ,Pulsed laser deposition ,chemistry.chemical_compound ,symbols.namesake ,X-ray photoelectron spectroscopy ,0103 physical sciences ,Materials Chemistry ,Silicon carbide ,Electrical and Electronic Engineering ,Thin film ,010302 applied physics ,business.industry ,Doping ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,chemistry ,symbols ,Optoelectronics ,0210 nano-technology ,business ,Raman scattering - Abstract
Cubic silicon carbide (3C-SiC) films were grown by pulsed laser deposition (PLD) on magnesium oxide [MgO (100)] substrates at a substrate temperature of 800°C. Besides, p-type SiC was prepared by laser assisted doping of Al in the PLD grown intrinsic SiC film. The SiC phases, in the grown thin films, were confirmed by x-ray diffraction (XRD), Si–C bond structure is identified by Fourier-transform infrared spectroscopy spectrum analysis. Measurements based on the XRD and Raman scattering techniques confirmed improvement in crystallization of 3C-SiC thin films with the laser assisted doping. The studies on I–V characteristics by two probe technique, elemental analysis by energy dispersion spectrum, binding energy by x-ray photoelectron spectroscopy and carrier concentration by Hall effect, ensured Al doping in SiC thin film. From the UV–visible NIR spectroscopic analysis, the optical bandgap of the PLD grown 3C-SiC was obtained. Numerical analysis of temperature and carrier concentration distribution is simulated to understand the mechanism of laser assisted doping.
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- 2019
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23. Fabrication of nanoparticles of oxide materials by UV pulsed laser ablation in gas phase
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Hiroshi Ikenoue, Keita Katayama, Reiji Koike, Mitsuhiro Higashihata, Daisuke Nakamura, and Rio Suzuki
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chemistry.chemical_compound ,Fabrication ,Laser ablation ,Materials science ,chemistry ,Nanoporous ,Oxide ,Nanoparticle ,Nanotechnology ,Particle size ,Dielectric ,Pulsed laser deposition - Abstract
SiO2 nanoporous films has been attracting attention as low-k dielectric constant insulating films. We have succeeded in SiO2 nanoparticles with a particle size of a few nm and depositing a nanoporous film by pulsed laser deposition with controlling the ambient gas pressure. However, the details of the formation process of SiO2 nanoparticles have not been clarified. In this study, we visualized the time-resolved nanoparticle distribution in the gas phase by laser imaging technique to clarify the nanoparticle formation process and to be helpful for optimizing the growth condition of the low-k nanoporous film.
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- 2021
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24. Formation of twisted Au microstructures by optical vortex pulse irradiation
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Mitsuhiro Higashihata, Hiroshi Ikenoue, Tsubasa Fujimoto, Daisuke Nakamura, and Miki Kawamoto
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Materials science ,business.industry ,Physics::Optics ,Microstructure ,Laser ,law.invention ,Pulse (physics) ,Optics ,law ,Torque ,Optical radiation ,Thin film ,business ,Optical vortex ,Beam (structure) - Abstract
The formation of a twisted Au microstructure was demonstrated by irradiating the Au thin film with a focused optical vortex laser pulse. The theoretically calculated torque generated by optical radiation force of optical vortex was confirmed to be consistent with the twist direction of the experimental results. The microstructures formed by changing the focal position were experimentally investigated. Through simulations, it was shown that the spherical wave of the focused beam may affect the distribution of the optical radiation force at the defocus positions.
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- 2021
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25. Estimation of the mobility of low temperature polycrystalline silicon thin film transistors through deep learning
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Daisuke Nakamura, Hiroshi Ikenoue, Akira Mizutani, Keita Katayama, Tetsuya Goto, and Fuminobu Hamano
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Materials science ,Microscope ,Excimer laser ,business.industry ,medicine.medical_treatment ,Low-temperature polycrystalline silicon ,Substrate (electronics) ,engineering.material ,law.invention ,Polycrystalline silicon ,Optical microscope ,law ,Thin-film transistor ,engineering ,medicine ,Surface roughness ,Optoelectronics ,business - Abstract
The crystallization of a-Si leads to alterations in the morphology of Si film such as surface color and surface roughness as a result of excimer laser annealing (ELA). These surface changes correlate with the characteristics of polysilicon films. The quality of crystallized poly Si has been evaluated by Non-destructive optical inspection methods. This study aims to use deep learning to estimate the quantitative relationship between the microscope images of a low-temperature polycrystalline silicon (LTPS) film and the mobility of an LTPS thin film transistor (TFT). This method would make it possible to measure the mobility from the images captured after annealing and improve the crystallization by in situ feedback. An a-Si substrate with a film thickness of 100 nm was polycrystallized by employing a KrF (wavelength of 248 nm) excimer laser, after which an optical microscope image of the substrate was captured. By changing the laser fluence and the number of shots (44 conditions N=10), LTPS films of various surface morphology were fabricated. We fabricated 440 transistors using these LTPS channels (channel size L = 20 μm, W = 30 μm) and measured their mobilities. Then, we performed deep learning with these sets of annealed optical microscope images and the corresponding mobilities. The mobility was estimated with an accuracy of ±12.8 cm2 V-1 s-1. Further improvement of the prediction accuracy (
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- 2021
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26. Silicon twisted cone structure produced by optical vortex pulse with structure evaluation by radiation hydrodynamic simulation
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Takeshi Higashiguchi, Daisuke Nakamura, Hiroki Oshima, Hiroshi Ikenoue, Miki Kawamoto, Atsushi Sunahara, Ryohei Tasaki, Mitsuhiro Higashihata, and Toshitaka Wakayama
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Materials science ,Silicon ,chemistry.chemical_element ,Physics::Optics ,02 engineering and technology ,01 natural sciences ,Article ,law.invention ,Optics ,law ,0103 physical sciences ,Irradiation ,Laser power scaling ,010302 applied physics ,Laser material processing ,Multidisciplinary ,business.industry ,Plasma ,Laser-produced plasmas ,021001 nanoscience & nanotechnology ,Laser ,Pulse (physics) ,chemistry ,Electromagnetic shielding ,0210 nano-technology ,business ,Optical vortex - Abstract
We demonstrate a radiation hydrodynamic simulation of optical vortex pulse-ablated microcone structures on silicon (Si) substrates. Doughnut-shaped craters were formed by single pulse irradiation on the Si substrate, and a twisted cone structure with a height of 3.5 µm was created at the center of the irradiation spot by the circularly polarized optical vortex pulse. A two-dimensional (2-D) radiation hydrodynamic simulation reproduced the cone structure well with a height of 3 µm. The central part of the incident laser power was lowered from the initial profile due to plasma shielding over the laser pulse duration for an inverted double-well laser profile. The acute tip shape of the silicon surface can survive over the laser irradiation period.
- Published
- 2020
27. Preliminary Study on Laser Annealed NP Junction in Phosphorus Implanted Germanium
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Siti Rahmah Aid, Anthony Centeno, Nur Nadhirah Mohd Rashid, Hiroshi Ikenoue, and Nur Farhana Arissa Jonny
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Materials science ,Equivalent series resistance ,Excimer laser ,Silicon ,Dopant ,business.industry ,Annealing (metallurgy) ,medicine.medical_treatment ,chemistry.chemical_element ,020207 software engineering ,Germanium ,02 engineering and technology ,Dopant Activation ,Ion implantation ,chemistry ,020204 information systems ,0202 electrical engineering, electronic engineering, information engineering ,medicine ,Optoelectronics ,business - Abstract
One option in enhancing metal-oxide-semiconductor transistor devices is by replacing silicon with high-mobility material of germanium. However, fabrication of Ge np junction faces low dopant activation problem due to the interaction between dopant and defect that was originated from ion implantation, during thermal annealing process results in dopant deactivation. Eventually, series resistance of np junction between source and drain regions will increase and affect the device drive current. Therefore, minimizing junction resistance remains an important issue to be solved. In this work, ultrafast/high temperature excimer laser of KrF was adopted for post-implantation annealing process in order to achieve high activation level. Laser energy fluences and shot numbers were varied between 100–2000 mJ/cm2 and 1–1000 shots, respectively to investigate the influence of laser parameter to the np junction resistance value, surface morphology and recrystallization. It is found that resistance lower than 300 Ω can be obtained when annealing the substrate between 500–1000 mJ/cm2 with shot number up to two. Taking into consideration on the morphological and structural analyses leads to the conclusion that an optimum parameter for LTA in the sample implanted with phosphorus at higher energy/dose concentration of 40 keV/6.0×1014 cm−2 is 700 mJ/cm2, with shot number of two.
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- 2020
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28. Long-Term Antithyroid Drug Treatment: Trends in Serum TSH and TSH Receptor Antibody Changes in Patients with Graves’ Disease
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Hiroshi Ikenoue, Megumi Fujikawa, Sachiko Bandai, Takanari Kitazono, Ken Okamura, and Kaori Sato
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endocrine system ,medicine.medical_specialty ,endocrine system diseases ,business.industry ,Endocrinology, Diabetes and Metabolism ,Graves' disease ,Thyroid ,030209 endocrinology & metabolism ,Trab ,medicine.disease ,Gastroenterology ,03 medical and health sciences ,Drug treatment ,0302 clinical medicine ,Pharmacotherapy ,medicine.anatomical_structure ,Internal medicine ,TSH receptor antibody ,medicine ,Euthyroid ,030212 general & internal medicine ,business ,hormones, hormone substitutes, and hormone antagonists ,Hormone - Abstract
Objectives: Trends in serum thyroid-stimulating hormone (TSH) and TSH receptor antibody (TRAb) changes during antithyroid drug treatment, and long-term prognosis were evaluated in Graves’ hyperthyroidism (GD). Methods: In 609 GD patients initially treated with 15 mg of methyl-mercapto imidazole (MMI), the changes in serum TRAb and long-term prognosis were compared in the TSH-normalized group (A) and the TSH-suppressed group (B and C) during the initial 180 days of treatment. Results: Early responses to MMI during 180 days of treatment were as follows: 48 cases (7.9%) became hypothyroid with elevated TSH (A1), and 188 cases (30.9%) became euthyroid with normal TSH (A2). Among patients with continuously suppressed TSH, the free T4 (fT4) level was low in 31 cases (5.1%) (B1-inappropriately suppressed TSH), fT4 and fT3 were normal in 185 cases (30.4%) (B2), fT4 was normal, but fT3 remained high in 84 cases (13.8%) (B3), and fT4 remained high in 73 cases (12.0%) (C-refractory). Serum TRAb became negative after < 5 years then remained negative in 25% - 51% of the cases (smooth type), became negative after < 5 years then became positive again in 30% - 43% of the cases (fluctuating type), and remained positive after > 5 years in 10% - 42% of the cases (smoldering type). In total, remission occurred after 6.2 (3.0 - 10.4) years of treatment in 42%, possible remission on a small maintenance dosage of antithyroid drug occurred in 13%, and spontaneous hypothyroidism occurred in 4.4% of the cases. The smoldering type was more frequent in the B1 and C groups than in others, and remission was less frequent. The difference in the long-term prognosis depending on the early response to MMI disappeared after excluding the ablated patients. Without ablation, remission or spontaneous hypothyroidism could be expected in 60% - 75% of patients after tenacious treatment for > 10 years. Conclusions: Prolonged suppression of serum TSH may suggest active TRAb activity during treatment, and continuous TRAb positivity for more than 5 years suggests persistent GD activity.
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- 2020
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29. The long-term follow-up of patients with thionamide-treated Graves’ hyperthyroidism
- Author
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Kaori Sato, Sachiko Bandai, Hiroshi Ikenoue, Ken Okamura, Takanari Kitazono, and Megumi Fujikawa
- Subjects
Adult ,Male ,endocrine system ,medicine.medical_specialty ,Poor prognosis ,Goiter ,endocrine system diseases ,Graves hyperthyroidism ,Long term follow up ,Endocrinology, Diabetes and Metabolism ,Graves' disease ,030209 endocrinology & metabolism ,Gastroenterology ,Young Adult ,03 medical and health sciences ,0302 clinical medicine ,Endocrinology ,Antithyroid Agents ,Interquartile range ,Internal medicine ,Humans ,Medicine ,Retrospective Studies ,business.industry ,Thyroid ,Clinical course ,Middle Aged ,Prognosis ,medicine.disease ,Graves Disease ,Treatment Outcome ,medicine.anatomical_structure ,030220 oncology & carcinogenesis ,Female ,business ,Follow-Up Studies - Abstract
Since there have been few reports on the long-term prognosis of Graves' hyperthyroidism, the prognosis of 549 Graves' hyperthyroidism patients initially treated with thionamide and followed for >8 (range: 8.6-36.4) years was studied, evaluating the change in the TSH binding inhibitor immunoglobulin activity (TBII). The distribution of the time required for the first disappearance of TBII was normal after logarithmic conversion, and the mean ± 2 SD was 1.5 (0.3-8.1) years. TBII became negative once within 5 years in 78.9% of patients. However, TBII re-elevation was observed in 47.8% of this group (fluctuating type). Remission was observed in 88.9% of the non-fluctuating type (smooth remission) and 37.2% of the fluctuating type patients. TBII remained positive for >5 years in 21.1% (smoldering type) of patients, with remission observed in only 19.8% of patients. Final remission was observed in 301 (54.8%) patients; the median time to remission was 6.8 (interquartile range: 4.0-10.9) years. A longer time until normalization of TBII and higher final thyroid weight were associated with a poor prognosis. Spontaneous hypothyroidism was observed in 6.0% of patients, independent of the TBII change. Our findings suggest that remission of Graves' hyperthyroidism mostly occurred after 4-11 years treatment. While predicting the prognosis before therapy was difficult, the clinical course may suggest a better prognosis if TBII disappears within five years without TBII fluctuation or enlargement of the goiter. Patients may safely wait more than five years to undergo ablative therapy if they hope to avoid permanent hypothyroidism.
- Published
- 2019
- Full Text
- View/download PDF
30. Laser-induced novel ohmic contact formation for effective charge collection in diamond detectors
- Author
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Eslam Abubakr, Shinya Ohmagari, Abdelrahman Zkria, Hiroshi Ikenoue, and Tsuyoshi Yoshitake
- Subjects
Mechanics of Materials ,Mechanical Engineering ,General Materials Science ,Condensed Matter Physics - Published
- 2022
- Full Text
- View/download PDF
31. LTPS Thin-Film Transistors Fabricated Using New Selective Laser Annealing System
- Author
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Shigetoshi Sugawa, Kaori Saito, Masami Takimoto, Michinobu Mizumura, Hiroshi Ikenoue, Makoto Hatanaka, Tetsuya Goto, Gotoh Jun, and Fuminobu Imaizumi
- Subjects
010302 applied physics ,Materials science ,Silicon ,Annealing (metallurgy) ,business.industry ,Transistor ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Laser ,01 natural sciences ,Grain size ,Electronic, Optical and Magnetic Materials ,law.invention ,Laser annealing ,chemistry ,law ,Thin-film transistor ,0103 physical sciences ,Optoelectronics ,Electrical and Electronic Engineering ,0210 nano-technology ,business ,Excimer laser annealing - Abstract
Selective laser annealing system was developed to realize fabrications of low-temperature poly-Si thin-film transistors (TFTs) even for large substrate, while the conventional excimer laser annealing system has the limitation in substrate size due to the difficulty in obtaining uniform beam line. In this paper, this new system was applied to fabricate poly-Si TFTs, using two laser exposure methods such as the static exposure and the scan exposure. Grain size increased as the laser energy density increased, and TFTs with the field-effect mobility larger than 100 cm2V−1s−1 with the ON– OFF ratio of drain current of approximately 106 could be obtained. Furthermore, for the scan exposure, periodic grain structure was observed resulting from the lateral solidification. In this condition, variations of electrical properties of TFT could be reduced compared to the case of the static exposure.
- Published
- 2018
- Full Text
- View/download PDF
32. Influence of pulse frequency on synthesis of nano and submicrometer spherical particles by pulsed laser melting in liquid
- Author
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Shota Sakaki, Takeshi Tsuji, Hiroshi Ikenoue, Naoto Koshizaki, and Yoshie Ishikawa
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Materials science ,Fabrication ,Analytical chemistry ,Evaporation ,General Physics and Astronomy ,Nanoparticle ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,law.invention ,Suspension (chemistry) ,Submicrometer particles ,law ,Nano ,Zinc oxide ,Irradiation ,Colloids ,Composite material ,Pulsed laser melting ,Nanoparticles ,Surfaces and Interfaces ,General Chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Laser ,0104 chemical sciences ,Surfaces, Coatings and Films ,Particle ,0210 nano-technology - Abstract
Submicrometer spherical particles (SMSPs) are reported to be fabricated by pulsed laser irradiation with a frequency of 10 or 30 Hz onto raw nanoparticles dispersed in liquid. Here, the effect of the pulse frequency on particles obtained by laser irradiation onto the suspension in a vessel, especially at higher pulse frequencies up to 800 Hz, is investigated. At 200 Hz or lower, SMSPs of similar size can be fabricated, as at 10 or 30 Hz, by the same number of pulses. This indicates that the time required for particle fabrication can be greatly reduced and production efficiency can be improved using a high-frequency laser. In contrast, at 400 Hz or above, nanospherical particles (NSPs) are formed in addition to SMSPs, and the mass fraction of SMSPs is drastically decreased. This result suggests that consecutive laser pulse irradiation induces heat accumulation in particles and suspensions, resulting in a temperature increase and partial evaporation of the particles at 400 Hz or above. From the temperature increase of the suspension, the local temperature of the liquid surrounding the particles is believed to be increased by heat dissipation from the heated particles. Calculations suggest that an increase in the local liquid temperature would cause further heating of the particles.
- Published
- 2018
33. Increased doping depth of Al in wet-chemical laser doping of 4H-SiC by expanding laser pulse
- Author
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Hiroshi Ikenoue, Rikuho Sumina, Akihiro Ikeda, Daichi Marui, and Tanemasa Asano
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Materials science ,medicine.medical_treatment ,02 engineering and technology ,01 natural sciences ,Fluence ,law.invention ,Pulsed laser deposition ,Optics ,law ,0103 physical sciences ,medicine ,General Materials Science ,010302 applied physics ,Dye laser ,Excimer laser ,business.industry ,Mechanical Engineering ,Doping ,Injection seeder ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Chemical laser ,Laser ,Mechanics of Materials ,0210 nano-technology ,business - Abstract
Al is doped into 4H-SiC by irradiating pulsed KrF excimer laser to 4H-SiC immersed in AlCl3 aqueous solution. Impact on doping depth of the use of expanded laser-pulse width is investigated. Expanded laser pulse is produced by splitting and recombining the laser beam with mirrors. The laser pulse width was expanded from its original width of 55–100 ns, while the peak power of the expanded pulse is as half as that of the original pulse under the same laser fluence. Multiple shots of the expanded laser pulses increased the doping depth at the Al concentration of 1×1016 /cm3 to 100 nm from 30 nm of the single shot of the original short, high-peak power laser. The increased doping depth could be due to enhanced diffusion by extra vacancies generated by the repeated laser irradiations. Due to the smaller laser peak power, the expanded pulse laser can suppress damage generation under multiple laser shots and, as a result, leakage current of the pn junction diode is kept low.
- Published
- 2017
- Full Text
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34. Pulse-Width Dependence of the Cooling Effect on Sub-Micrometer ZnO Spherical Particle Formation by Pulsed-Laser Melting in a Liquid
- Author
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Shota Sakaki, Hiroshi Ikenoue, Takeshi Tsuji, Naoto Koshizaki, and Yoshie Ishikawa
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Phase transition ,Materials science ,Thermodynamics ,Nanoparticle ,02 engineering and technology ,Nanosecond ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Laser ,01 natural sciences ,Molecular physics ,Atomic and Molecular Physics, and Optics ,0104 chemical sciences ,law.invention ,Pulse (physics) ,Colloid ,law ,Particle ,Physics::Atomic Physics ,Irradiation ,Physical and Theoretical Chemistry ,0210 nano-technology - Abstract
Sub-micrometer spherical particles can be synthesized by irradiating particles in a liquid with a pulsed laser (pulse width: 10 ns). In this method, all of the laser energy is supposed to be spent on particle heating because nanosecond heating is far faster than particle cooling. To study the cooling effect, sub-micrometer spherical particles are fabricated by using a pulsed laser with longer pulse widths (50 and 70 ns). From the increase in the laser-fluence threshold for sub-micrometer spherical particle formation with increasing pulse width, it is concluded that the particles dissipate heat to the surrounding liquid, even during several tens of nanoseconds of heating. A particle heating-cooling model considering the cooling effect is developed to estimate the particle temperature during laser irradiation. This model suggests that the liquid surrounding the particles evaporates, and the generated vapor films suppress heat dissipation from the particles, resulting in efficient heating and melting of the particles in the liquid. In the case of small particle sizes and large pulse widths, the particles dissipate heat to the liquid without forming such vapor films.
- Published
- 2017
35. Surface flattening of poly-Si thin films by laser annealing and electrical properties of LTPS-TFTs
- Author
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Fuminobu Hamano, Daisuke Nakamura, Akira Mizutani, Tetsuya Goto, Kaname Imokawa, and Hiroshi Ikenoue
- Subjects
Materials science ,business.industry ,Laser ,Flattening ,law.invention ,Laser annealing ,Thin-film transistor ,law ,Optoelectronics ,Irradiation ,Thin film ,Crystallization ,business ,Excimer laser annealing - Abstract
Low-temperature poly-Si (LTPS) thin films formed by excimer laser annealing (ELA) are used as the channel material for thin film transistors (TFTs), which have an application as switching devices in flat panel displays. It is well known that one of the major problems in TFT manufacturing is the prominent ridges that form on LTPS thin films after ELA due to volume expansion by crystallization, which in turn induces gate leakage current in the TFTs. In this presentation, we report on the use of additional laser irradiation to reduce the height of the ridges and resulting changes in the electrical properties of LTPS-TFTs.
- Published
- 2020
- Full Text
- View/download PDF
36. Fabrication of multicomponent semiconductor microspheres by laser ablation in air (Conference Presentation)
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Hiroki Oshima, Yuichiro Wakiyama, M. S. Ramachandra Rao, Daisuke Nakamura, Nilesh J. Vasa, Mitsuhiro Higashihata, and Hiroshi Ikenoue
- Subjects
Fabrication ,Laser ablation ,Materials science ,business.industry ,Physics::Medical Physics ,Doping ,technology, industry, and agriculture ,Physics::Optics ,equipment and supplies ,Microsphere ,Condensed Matter::Soft Condensed Matter ,Surface tension ,Condensed Matter::Materials Science ,Semiconductor ,parasitic diseases ,Optoelectronics ,Whispering-gallery wave ,business ,Spherical shape - Abstract
We have demonstrated the fabrication of semiconductor microspherical crystals such as ZnO and Si microspheres by a simple laser ablation technique. In addition, doped and alloyed microspheres have achieved by this technique. The fabrication mechanism of the spherical crystals is based on instantaneous heating of target material, formation of spherical shape by surface tension of liquid-state material, and rapid freezing with keeping the spherical shape. In this study, the technique is expanded to other various materials, and microspheres consisting of multicomponent semiconductor such as Sr3Sn2O7 was successfully fabricated. This technique is a candidate for fabrication of functional microspherical crystals.
- Published
- 2019
- Full Text
- View/download PDF
37. Formation of nanoporous SiO2 films with super-low dielectric constant by F2 laser deposition
- Author
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Toshifumi Kikuchi, Daisuke Nakamura, Ryota Miyano, Kaname Imokawa, and Hiroshi Ikenoue
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Laser ablation ,Materials science ,Nanoporous ,business.industry ,Dielectric ,Partial pressure ,RC time constant ,Laser ,law.invention ,Pulsed laser deposition ,law ,Optoelectronics ,Vacuum chamber ,business - Abstract
Ultra-large scale integrated circuits (ULSIs) have been continually scaled down according to Moore’s law. This can improve their power consumption and operation frequency but not the RC delay of their interconnections; to this end, super low dielectric constant films are required. We propose a novel method to fabricate porous SiO2 films with a super low dielectric constant by F2 laser deposition. In this method, a quartz target is evaporated by F2 laser ablation in vacuum-chamber-controlled Ar partial pressure. The evaporated SiO2 molecules are agglomerated in the vacuum, and the size of the SiO2 nanoparticles are controlled by the Ar partial pressure. Porous SiO2 films are formed on a Si-receiving substrate, which is placed in front of the quartz target. The pulse duration of the F2 laser was approximately 20 ns, and the repetition rate of laser shots was 100 Hz. The base pressure of the vacuum chamber was 5 × 10−3 Pa. Then, Ar gas was introduced into the vacuum chamber through a mass flow controller to control the Ar partial pressure. The dominant size of the SiO2 nanoparticles decreased from 1.5–2.0 nm to 1.0–1.5 nm with the Ar partial pressure decreasing from 20 Pa to 4.5 Pa. In addition, the relative dielectric constant k of the porous SiO2 film formed at an Ar partial pressure of 4.5 Pa was 2.8, which is lower than that of thermal SiO2 (k = 4.0). In addition, the leakage current of the nanoporous SiO2 film was almost equal to that of the thermal SiO2 film. From these results, we conclude that nanoporous SiO2 films with a super low dielectric constant can be formed by F2 laser deposition.
- Published
- 2019
- Full Text
- View/download PDF
38. Low-temperature, high-concentration laser doping of 4H-SiC for low contact resistance
- Author
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Daisuke Nakamura, Akihiro Ikeda, Kaname Imokawa, Hiroshi Ikenoue, Toshifumi Kikuchi, and Tanemasa Asano
- Subjects
Laser ablation ,Materials science ,Dopant ,Excimer laser ,medicine.medical_treatment ,Contact resistance ,Doping ,Analytical chemistry ,medicine ,Substrate (electronics) ,Chemical vapor deposition ,Sputter deposition - Abstract
We propose low-temperature and high-concentration doping of 4H-silicon carbide (4H-SiC)(0001) by KrF excimer laser irradiation of source films on a 4H-SiC substrate, in which a dopant atom is included. In n-type doping, a SiN x film with a thickness of 100 nm was deposited on an n-type 4H-SiC(0001) substrate by chemical vapor deposition. A gas supply nozzle for ambient environment control was installed to prevent oxidation of the SiC surface. High-concentration nitrogen doping (~1 × 10 21 /cm 3 at the surface) was achieved by laser ablation of the SiN x film. Al/Ti electrodes were formed on the doped area at a room temperature, and a contact resistance of 2.2 × 10 -5 Ω・cm 2 was obtained, which is sufficiently small for the backside contact resistance of Schottky barrier diodes. In p-type doping, an Al film with a thickness of 240 nm was deposited on a 4H-SiC substrate by sputtering deposition. After laser irradiation of the Al film in ambient Ar, high-concentration Al doping (~1 × 10 21 /cm 3 at the surface) was achieved. Al/Ti electrodes were formed on the doped area at a low temperature of 600 °C, and a contact resistance 1.9 × 10 -4 Ω・cm 2 was obtained. We conclude that low-temperature and high-concentration doping of 4H-SiC for low contact resistance can be achieved by laser ablation of the source films on the 4H-SiC substrate.
- Published
- 2019
- Full Text
- View/download PDF
39. Synthesis of GeSn particles with high substitutional Sn concentration by low-pressure pulsed-laser-deposition
- Author
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Kaname Imokawa, Teppei Nakashima, Toshifumi Kikuchi, Hiroshi Ikenoue, and Daisuke Nakamura
- Subjects
Materials science ,business.industry ,Optoelectronics ,business ,Pulsed laser deposition - Published
- 2019
- Full Text
- View/download PDF
40. Low-temperature and low-cost excimer laser doping for poly-Si thin-film transistor fabrication
- Author
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Kaname Imokawa, Taizoh Sadoh, Daisuke Nakamura, Akira Suwa, Hiroshi Ikenoue, Tetsuya Goto, and Nozomu Tanaka
- Subjects
Fabrication ,Materials science ,Excimer laser ,business.industry ,medicine.medical_treatment ,Transistor ,Doping ,engineering.material ,Laser ,law.invention ,Coating ,Thin-film transistor ,law ,medicine ,engineering ,Optoelectronics ,Thin film ,business - Abstract
The electrical properties of poly-Si thin films doped using KrF excimer laser irradiation with a phosphoric-acid coating were investigated. After laser doping, the mobility, carrier concentration, activation ratio, and contact resistivity of the poly-Si were found to be 61 cm2 /Vs, 1.5×1018 cm-3 , 18.1 %, and 8.5 × 10−5 Ω⋅cm2 , respectively. Additionally, the operation of a bottom gate transistor fabricated using laser doping was realized and is described herein.
- Published
- 2019
- Full Text
- View/download PDF
41. Corrigendum: Impact of Mg-level on lattice-relaxation in p-AlGaN hole source layer (HSL) and attempting excimer laser annealing on p-AlGaN HSL of UVB emitters (2021 Nanotechnology 32 055702)
- Author
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Juan Paolo Bermundo, Sachie Fujikawa, Hideki Hirayama, Noritoshi Maeda, Yukio Kashima, Masafumi Jo, Yasuaki Ishikawa, Eriko Matsuura, Hiroshi Ikenoue, and M. Ajmal Khan
- Subjects
Lattice (module) ,Materials science ,Condensed matter physics ,Mechanics of Materials ,Mechanical Engineering ,Relaxation (physics) ,General Materials Science ,Bioengineering ,General Chemistry ,Electrical and Electronic Engineering ,Layer (electronics) ,Excimer laser annealing - Published
- 2021
- Full Text
- View/download PDF
42. Observation of SiO2 Nanoparticle Formation via UV Pulsed Laser Ablation in a Background Gas.
- Author
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Reiji Koike, Rio Suzuki, Keita Katayama, Mitsuhiro Higashihata, Hiroshi Ikenoue, and Daisuke Nakamura
- Subjects
LASER ablation ,ULTRAVIOLET lasers ,PULSED lasers ,LASER pulses ,PULSED laser deposition ,SPATIAL distribution (Quantum optics) ,GAS distribution - Abstract
SiO2 nanoporous films have recently gained significant popularity as low-k dielectric constant insulating films. In this study, we demonstrated the fabrication of a low-k SiO2 nanoporous film consisting of SiO2 nanoparticles by pulsed laser deposition. However, to optimize the growth conditions of nanoporous films, it is important to understand the spatial and size distribution of nanoparticles produced by laser ablation. Here, we visualized laser-ablated SiO2 nanoparticles using a two-dimensional laser scattering imaging technique and investigated the influence of gas species and pressure on the spatial distribution of the nanoparticles in the gas phase. After the decay of the plasma emission within several microseconds, a spherical-shaped scattering image depicting the spatial distribution of SiO2 nanoparticles was obtained from a delay time of approximately 10 ms. In Ar gas, the sphericalshaped distribution of SiO2 nanoparticles changed to an ellipsoidal shape with increasing pressure, whereas in O2 gas, it changed a mushroom-like shape. These results show that the gas species and pressure are dominant parameters affecting the spatial distribution of nanoparticle formation. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
43. Fabrication of P-, Sb-, and Mg-Doped ZnO Spherical Microcrystals by Laser Ablation in Air
- Author
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Shuhei Takao, Tatsuya Ikebuchi, Mitsuhiro Higashihata, Daisuke Nakamura, Hiroshi Ikenoue, Takeshi Ueyama, Fumiaki Nagasaki, Yuki Fujiwara, Tatsuo Okada, and Toshinobu Tanaka
- Subjects
Fabrication ,Laser ablation ,Materials science ,Doping ,Nanotechnology ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Industrial and Manufacturing Engineering ,0104 chemical sciences ,Electrical and Electronic Engineering ,0210 nano-technology ,Instrumentation - Published
- 2016
- Full Text
- View/download PDF
44. Al Doping from Laser Irradiated Al Film Deposited on 4H-SiC
- Author
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Akihiro Ikeda, Hiroshi Ikenoue, Tanemasa Asano, and Rikuho Sumina
- Subjects
010302 applied physics ,Materials science ,Excimer laser ,Orders of magnitude (temperature) ,Mechanical Engineering ,medicine.medical_treatment ,Doping ,Analytical chemistry ,02 engineering and technology ,Plasma ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Laser ,01 natural sciences ,law.invention ,Mechanics of Materials ,law ,0103 physical sciences ,medicine ,General Materials Science ,Irradiation ,0210 nano-technology ,p–n junction ,p–n diode - Abstract
Al doping of 4H-SiC with high surface concentration and deep depth profile is found to be realized by irradiating single-pulse excimer laser to an Al film deposited on the surface. Optical emission spectra suggest that high-temperature molten Al is produced behind the laser-generated high-density Al plasma and Al is diffused from the molten Al into 4H-SiC. The Al doping depth reaches to ~200 nm by irradiating a single laser pulse. A pn junction diode fabricated by the doping with the molten Al shows on/off ratio over 10 orders of magnitude.
- Published
- 2016
- Full Text
- View/download PDF
45. 30-4: Characterization of Si Thin Films Doped by Wet-Chemical Laser Processing
- Author
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Daisuke Nakamura, Taizoh Sadoh, Nozomu Tanaka, Akira Suwa, and Hiroshi Ikenoue
- Subjects
010302 applied physics ,Materials science ,Doping ,Analytical chemistry ,02 engineering and technology ,Dopant Activation ,021001 nanoscience & nanotechnology ,Chemical laser ,Laser ,01 natural sciences ,law.invention ,Characterization (materials science) ,law ,Electrical resistivity and conductivity ,0103 physical sciences ,Thin film ,0210 nano-technology ,Laser processing - Abstract
In this paper, we report on the characterization of Si thin films doped by wet-chemical laser processing. Using this method, implantation and dopant activation can be performed simultaneously. After laser doping, the mobility, carrier concentration, and resistivity of the films were 74 cm2/V·s, 5.5 × 1017 cm−3, and 0.15 Ω·cm, respectively.
- Published
- 2017
- Full Text
- View/download PDF
46. Impact of Mg level on lattice relaxation in a p-AlGaN hole source layer and attempting excimer laser annealing on p-AlGaN HSL of UVB emitters
- Author
-
Sachie Fujikawa, M. Ajmal Khan, Hiroshi Ikenoue, Yukio Kashima, Juan Paolo Bermundo, Hideki Hirayama, Masafumi Jo, Yasuaki Ishikawa, Noritoshi Maeda, and Eriko Matsuura
- Subjects
Electron mobility ,Photoluminescence ,Materials science ,Analytical chemistry ,Bioengineering ,02 engineering and technology ,010402 general chemistry ,medicine.disease_cause ,01 natural sciences ,law.invention ,Crystallinity ,Impurity ,law ,Electrical resistivity and conductivity ,medicine ,General Materials Science ,Electrical and Electronic Engineering ,Diode ,Mechanical Engineering ,General Chemistry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Mechanics of Materials ,0210 nano-technology ,Ultraviolet ,Light-emitting diode - Abstract
Mg-doped p-type semiconducting aluminium-gallium-nitride hole source layer (p-AlGaN HSL) materials are quite promising as a source of hole ‘p’ carriers for the ultraviolet-B (UVB) light-emitting diodes (LEDs) and laser diodes (LDs). However, the p-AlGaN HSL has a central issue of low hole injection due to poor activation of Mg atoms, and the presence of unwanted impurity contamination and the existence of a localized coherent state. Therefore, first the impact of the Mg level on the crystallinity, Al composition and relaxation conditions in the p-AlGaN HSL were studied. An increasing trend in the lattice-relaxation ratios with increasing Mg concentrations in the p-AlGaN HSL were observed. Ultimately, a 40%–60% relaxed and 1.4 μm thick p-AlGaN HSL structure with total threading dislocation densities (total-TDDs) of approximately ∼8–9 × 108 cm−2 was achieved, which almost matches our previous design of a 4 μm thick and 50% relaxed n-AlGaN electron source layer (ESL) with total-TDDs of approximately ∼7–8 × 108 cm−2. Subsequently, structurally a symmetric p–n junction for UVB emitters was accomplished. Finally, the influence of excimer laser annealing (ELA) on the activation of Mg concentration and on suppression of unwanted impurities as well as on the annihilation of the localized energy state in the p-AlGaN HSL were thoroughly investigated. ELA treatment suggested a reduced Ga–N bonding ratio and increased Ga–O, as well as Ga–Ga bonding ratios in the p-AlGaN HSL. After ELA treatment the localized coherent state was suppressed and, ultimately, the photoluminescence emission efficiency as well as conductivity were drastically improved in the p-AlGaN HSL. By using lightly polarized p-AlGaN HSL assisted by ELA treatment, quite low resistivity in p-type AlGaN HSL at room temperature (hole concentration is ∼2.6 × 1016 cm−3, the hole mobility is ∼9.6 cm2 V1 s−1 and the resistivity is ∼24.39 Ω. cm) were reported. ELA treatment has great potential for localized activation of p-AlGaN HSL as well as n- and p-electrodes on n-AlGaN and p-AlGaN contact layers during the flip-chip (FC) process in low operating UVB emitters, including UVB lasers.
- Published
- 2020
- Full Text
- View/download PDF
47. Excimer Laser Doping of LTPS Thin Films for Printable Device Fabrication
- Author
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Akira Suwa, Hiroshi Ikenoue, D. Nakamura, N. Tanaka, Taizoh Sadoh, and Kaname Imokawa
- Subjects
Materials science ,Fabrication ,Excimer laser ,business.industry ,medicine.medical_treatment ,Doping ,medicine ,Optoelectronics ,Thin film ,business - Published
- 2018
- Full Text
- View/download PDF
48. Characterization of Excimer-Laser Doping of a Poly-Si Thin Film with a Phosphoric-Acid Coating for Thin-Film-Transistor Fabrication
- Author
-
Hiroshi Ikenoue, Akira Suwa, Daisuke Nakamura, Taizoh Sadoh, Tetsuya Goto, Nozomu Tanaka, and Kaname Imokawa
- Subjects
Materials science ,Excimer laser ,business.industry ,medicine.medical_treatment ,Doping ,engineering.material ,Dopant Activation ,Laser ,law.invention ,Coating ,Thin-film transistor ,law ,engineering ,medicine ,Optoelectronics ,Thin film ,Crystallization ,business - Abstract
We characterize poly-Si thin films doped by KrF excimer laser irradiation with a phosphoric-acid coating. In this method, implantation and dopant activation can be performed simultaneously without damage of the poly-Si crystallization. After the laser doping, the mobility, carrier concentration, activation ratio, and resistivity of poly-Si were 61 cm2/Vs, 1.5×1018 cm−3, 14.6 %, and 0.08 Ω.cm, respectively.
- Published
- 2018
- Full Text
- View/download PDF
49. Instantaneous Semiconductor-to-Conductor Transformation of a Transparent Oxide Semiconductor a-InGaZnO at 45 °C
- Author
-
Yasuaki Ishikawa, Juan Paolo Bermundo, Yukiharu Uraoka, Hiroshi Ikenoue, and Mami N. Fujii
- Subjects
010302 applied physics ,Materials science ,Fabrication ,business.industry ,Emphasis (telecommunications) ,02 engineering and technology ,Substrate (electronics) ,Conductivity ,021001 nanoscience & nanotechnology ,01 natural sciences ,Conductor ,Semiconductor ,0103 physical sciences ,Hardware_INTEGRATEDCIRCUITS ,Optoelectronics ,General Materials Science ,Irradiation ,0210 nano-technology ,business ,Transparent conducting film - Abstract
The emphasis on ubiquitous technology means that future technological applications will depend heavily on transparent conducting materials. To facilitate truly ubiquitous applications, transparent conductors should be fabricated at low temperatures (
- Published
- 2018
50. Simple fabrication of semiconductor microspheres by laser ablation in air (Conference Presentation)
- Author
-
Mitsuhiro Hiashihata, Daisuke Nakamura, Hiroshi Ikenoue, Hiroki Oshima, Yuichiro Wakiyama, Sho Kawagoe, Ryohei Tasaki, and Nilesh J. Vasa
- Subjects
Laser ablation ,Fabrication ,Materials science ,Silicon ,business.industry ,Alloy ,technology, industry, and agriculture ,chemistry.chemical_element ,engineering.material ,equipment and supplies ,Semiconductor ,chemistry ,engineering ,Optoelectronics ,Whispering-gallery wave ,business ,Optical vortex ,Lasing threshold - Abstract
We have succeeded in synthesizing zinc oxide (ZnO) microspherical crystals and Silicon microspheres by a simple laser ablation technique in air, and demonstrated whispering-gallery-mode (WGM) lasing from optically-pumped ZnO microsphere. ZnO/MgO alloy microspheres were also successfully fabricated, and blue-shift of WGM lasing wavelength was achieved. Recently, size-controlled and on-demand fabrication of semiconductor microspheres by introducing of an optical vortex beam.
- Published
- 2018
- Full Text
- View/download PDF
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