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The clinical management of elderly patients with heart failure (HF) is not firmly established. Decision-making should be individualized depending on the biological deterioration of each patient, from aggressive management to a palliative approach. Frailty can serve as the basis for this comprehensive individualized management. Our objective was to evaluate the importance of the main clinical problems, as well as the events that required the use of health resources, based the degree of frailty, in elderly patients with HF.Retrospective observational cohort study. Frailty was defined according to the deficit accumulation construct. A total of 546 patients hospitalized for acute HF were included. The median age (Q1-Q3) was 82 (78-86) years. A total of 454 patients (83%) showed some degree of frailty: 221 (48.7%) mild, 207 (45.6%) moderate and 26 (5.7%) advanced. There was a significant tendency towards polypharmacy from no to severe frailty. Hospital events were recorded for 4 (1-6) patients with mild frailty, 4 (2-6) patients with moderate frailty and 2 ((1-4) patients with advanced frailty (p = 0.045). A total of 204 patients (37.4%) died during follow-up. The median time to death was 11.4 (4-16.8), 6.7 (3.3-11.6), 6.5 (3.4-12.2) and 4.1 (0.8-7.7) months for patients with no, mild, moderate, or advanced frailty, respectively (p = 0.006).Frailty due to deficit accumulation is a good predictor of clinical problems and events that require the use of health resources; therefore, it can serve as a basis for the management of HF in the elderly.

A method for the determination of N distribution in dilute nitride GaAsSbN superlattices (SLs) by using different STEM imaging settings is proposed. The method combines the simultaneous acquisition under Low Angle (LA-) and High Angle (HA-) Annular Dark Field (ADF) conditions by exploiting two different dedicated angle intervals. On one hand, HAADF technique gives information that principally depends on the atomic number (Sb sensitive) and on the other hand, N atoms produce high static atomic displacements affecting the image intensity especially under LAADF conditions. However, the simultaneous presence of Sb and N supposes an important handicap to differentiate both elements. N distribution maps could be obtained from suitable normalization and the separation of the intensity ratios in regions with/without Sb. Semi-quantitative maps are also available by combination of the results from high-resolution X-ray diffraction and energy dispersive X-Ray spectroscopy techniques. Type-I (GaAsSbN/GaAs) and type-II (GaAsSb/GaAsN) SL structures are evaluated using the proposed methodology. Differences in the N distribution between both samples such as inhomogeneities and cluster formation are discussed. Specifically, we have found a greater number of N-rich regions in type-I structure as compared to their type-II counterparts, which could have an influence on the optical response of each design.

GaAsSbN alloys is recognized as an effective candidate to incorporate in multijunction solar cell applications due to its advantages of being grown lattice-matched to GaAs and its capability to achieve bandgap around 1.0 eV. Recently, the use of superlattice (SL) structures that permit type–II (GaAsSb/GaAsN) and type-I (GaAsSbN/GaAs) alignments showed a strongly heightened luminescence and a significant EQE compared to their thicker quaternary bulk counterparts. In this work, the correlation between the compositional distribution and its optical properties in both SL structures before and after RTA treatment is analyzed. Firstly, while N is confined following the nominal design, Sb presents a strong segregation to the upper layers achieving similar compositional profiles along the growth direction even after the RTA. However, the SL type-II approach presents a higher interface quality and a much lower trend to cluster formation than SL type-I. Secondly, RTA gives place to an improvement of the interface roughness, together to a decrease of the area associated to clusters in both structures. The blueshift and the improvement of the PL intensity induced by annealing in both samples is more correlated to the decomposition of nitrogen pairs to isolated substitutional nitrogen than to the dissolution of Sb inhomogeneities. A different distribution of new substitutional N atoms around Sb clusters could explain the differences in the PL improvement of both SLs during the annealing. SL type-II approach is the best design to minimize cluster formation and to obtain more abrupt interfaces and mainly describe the optical enhancement compared to SL type-I structures.

The practical realization of epitaxial quantum dot (QD) nanocrystals led before long to impressive experimental advances in optoelectronic devices, as well as to the emergence of new technological fields. However, the necessary capping process is well-known to hinder a precise control of the QD morphology and therefore of the possible electronic structure required for certain applications. A straightforward approach is shown to tune the structural and optical properties of InAs/GaAs QDs without the need for any capping material different from GaAs or annealing process. The mere adjust of the capping rate allows controlling kinetically the QD dissolution process induced by the surface In-Ga intermixing taking place during overgrowth, determining the final metastable structure. While low capping rates make QDs evolve into more thermodynamically favorable quantum ring structures, increasing capping rates help preserve the QD height and shape, simultaneously improving the luminescence properties. Indeed, a linear relationship between capping rate and QD height is found, resulting in a complete preservation of the original QD geometry for rates above ∼2.0 ML s−1. In addition, the inhibition of In diffusion from the QDs top to the areas in between them yields thinner WLs, what could improve the performance of several QD-based optoelectronic devices.

GaAsSbN dilute nitrides are potential candidates for integration in high-performance multi-junction solar cells due to the bandgap tunability in the 1.0–1.15 eV range and the possibility to match the lattice constant to the GaAs substrates. Recently, the use of GaAsSb/GaAsN superlattices (SLs) has been shown as an effective way to enhance photovoltaic efficiency as compared to the quaternary counterparts. Here we apply a combination of HR-XRD and cross-sectional (S)TEM techniques together with theoretical calculations to analyse the compositional distribution in GaAsSb/GaAsN SLs with different periodicity. The measurements of compositional profiles indicate that Sb is strongly segregated into the GaAsN layers while N remains confined where it is deposited. We demonstrate that the Sb profiles run as a shark-fin waveform that can be precisely described with a one-dimensional model where segregation of the supplied Sb is promoted by a three-layer fluid exchange mechanism. Moreover, the role played by the periodicity in the effectiveness of the Sb incorporation adds a new level of complexity. The modelling of Sb segregation in the GaAsSb/GaAsN SLs system could be used to carry out more precise pseudopotential calculations on the band structure in order to understand and predict their electrical and optical behaviour.

InAs/GaAs QDs are being investigated in the field of solar cells (SCs) with the aim of achieving high SC performances. In order to control the band offsets and the accumulated strain, the application of capping layers (CLs) made of GaAs-based alloys is becoming a common approach that shows promising advantages for SC applications. However, up to now there are very few statistically reliable studies of their impact on the QD morphologies. Our work by TEM techniques over more than a hundred of InAs QDs has evaluated a broad range of CL materials and structures with Sb and/or N with a singular accuracy. Our outcomes showed that the Sb could play antagonistic roles regarding the QD decomposition depending on the growth conditions. Unlike it occurs at common growth rates (1 ML/s), at high growth rates of 2 ML/s the Sb does not protect the QDs, but even intensifies their erosion. On the other side, N provides the best results in terms of maintaining the original shape of the QDs. In the case of a simultaneous presence of Sb and N, a synergetic effect in the erosion strength is observed. Nevertheless, avoiding the concomitance presence of N and Sb on the growth front by growing a short-period GaAsSb/GaAsN superlattice CLs moderates this behavior. The results are discussed in terms of processes such as surfactant, intermixing, segregation, bond strength or strain-enhanced diffusion that could operate during the capping process. The strong modifications on the QD–CL morphology, that we show are expected to have a significant impact on QD SC performance, cannot be disregarded.

In this work, two different strategies to preserve InAs/GaAs QDs against decomposition during the capping process have been compared structurally and optically. They are based on: (i) the control of the growth parameters of the capping layer (CL), such as growth rate, and (ii) the nature of the CL, such as the use of GaAsSb strain-reducing layers (SRL). For this, we have statistically determined the average size, composition and areal density in sample populations of dozens of QDs as well as the wetting layer features. Faster growth rates and the presence of Sb in the CL results in an increase of both average QD height as well as the In content but the thorough comparison among all the samples allowed us to draw the following important inferences. i) QD volume is a better parameter than QD height to assess QD decomposition and PL redshift; ii) higher QD volumes are not always linked to higher In contents and iii) a reduction in the QD density is observed in both strategies related to the increase of the average volume. The results are discussed in terms of the mechanisms that might operate during the capping process, such as surface coverage, intermixing or segregation.

The implementation of GaAs0.8Sb0.2 as CL to obtain type-II strain-coupled InAs MQD structures has been examined and compared to similar structures without Sb or without strain coupling. First, it has been demonstrated that capping with GaAsSb prevents the formation of In-rich agglomerations that hampered the QD formation as it has been observed in the sample without Sb. Instead, it promotes the vertical alignment (VA) of almost all QDs with a high density of QD columns. Second, there is a preferential Sb accumulation over the dots together with an undulation of the growth front, contrary to the observed in the uncoupled structure. In case of a deficient covering of GaAsSb, as occurs for giant QDs, In-rich agglomerations may develop. Each VAQD column consists of a sequence of alternating quantum blocks of pyramid-shaped In(Ga)As separated by GaAsSb blocks that rest over them. These Sb-rich blocks are not homogeneous accumulating around the pyramidal apex like a collar. Between the columns, there is an impoverishment of In and Sb compared to the uncoupled sample. These columns can behave as self-aligned nanowires with type II band alignment between self-assembled InAs and GaAsSb quantum blocks that opens new opportunities for novel devices.

The unavoidable presence of the wetting layer (WL) in Stranski-Krastanov quantum dots (QD) has typically a negative impact on the performance of QD solar cells. In this work, a simple method to engineer the WL of InAs/GaAs QD solar cells is investigated. In particular, we show that covering the QDs at high GaAs capping rates reduces In-Ga intermixing and, therefore, In redistribution from the QDs to the WL. This results not only in larger QDs, but also in thinner WLs, with larger quantum confinement energies and reduced potential barriers for electrons and holes. Carrier trapping by the WLs and subsequent recombination is therefore reduced, resulting in larger photocurrent values of the QD solar cells under short circuit conditions.

We demonstrate type-II GaAsSb/GaAsN superlattices as a suitable candidate to form a lattice-matched 1.01.15 eV subcell that could significantly improve the performance of multi-junction solar cells. The spatial separation of N and Sb allows better lattice-matching control, composition homogeneity, crystal quality and interface abruptness. Moreover, the type-II band alignment provides effective bandgap and radiative lifetime tunability through the period thickness. For the impact of period thickness on transport, quantum-kinetic simulations support the experimental finding of efficient carrier extraction at thicknesses up to 6 nm. All this leads to single-junction solar cells with improved efficiency under monochromatic illumination over the equivalent bulk devices.

The impact of using thin GaAs(Sb)(N) capping layers (CLs) on InAs/GaAs quantum dots (QDs) is investigated for their application in solar cell devices. We demonstrate the ability to combine strain-balancing techniques with band engineering approaches through the application of such CLs. Extended photoresponse is attainable by means of an independent tunability of the electron and hole confinements in the QD. Moreover, the CL acts itself as a quantum well (QW), providing an additional photoresponse, so that the devices work as hybrid QD–QW solar cells. The use of a GaAsSb CL is particularly beneficial, providing devices with efficiencies under AM1.5 conditions 20% higher than standard GaAs-capped QDs. This is mainly due to a significant increase in photocurrent beyond the GaAs bandgap, leading to an enhanced short-circuit current density ( J sc ). The addition of N to the CLs, however, produces a strong reduction in J sc . This is found to be related to carrier collection problems, namely, hindered electron extraction and retrapping in the CLs. Nevertheless, the application of reverse biases induces a release of the trapped carriers assisted by a sequential tunneling mechanism. In the case of GaAsN CLs, this leads to a complete carrier collection and reveals an even higher QD–QW-related photocurrent than when using a GaAsSb CL. The hindered carrier collection is stronger in the case of the quaternary CLs, likely due to the faster recombination rates in the type-I GaAsSbN/GaAs QW structure as compared to the type-II ternary counterparts. Nevertheless, alternative approaches, such as the use of a thinner CL or a short-period superlattice CL, lead to significant improvements, demonstrating a great potential for the quaternary CLs under a proper device design.

Trabajo presentado en el SPIE Octo: Physics, Simulation, and Photonic Engineering of Photovoltaic Devices VII, celebrado en San Francisco (California, Estado Unidos), del 27 de enero al 1 de febrero de 2018, Dilute nitride GaAsSbN is an ideal candidate to form the 1-1.15 eV lattice-matched sub-cell that would significantly enhance the performance of 3- and 4-junction solar cells. However, growth problems inherent to this quaternary alloy lead typically to a poor crystal quality that limits its applicability. Better compositional control and crystal quality have been recently reported by growing the material as a GaAsSb/GaAsN superlattice, because of the spatial separation of Sb and N that avoid miscibility problems. Moreover, these structures provide bandgap tunability trough period thickness. Here we study the performance of lattice-matched 1.15 eV GaAsSb/GaAsN type-II superlattice p-i-n junction solar cells with different period thickness and compare them with the bulk and GaAsSbN/GaAs type-I superlattice counterparts. We demonstrate carrier lifetime tunability through the period thickness in the type-II structures. However, the long carrier lifetimes achievable with periods thicker than 12 nm are incompatible with a high carrier extraction efficiency under short-circuit conditions. Only superlattices with thinner periods and short carrier lifetimes show good solar cell performance. Quantum kinetic calculations based on the non-equilibrium Green’s function (NEGF) formalism predict a change in transport regime from direct tunneling extraction to sequential tunneling with sizable thermionic emission components when passing from 6 nm to 12 nm period length, which for low carrier lifetime results in a decrease of extraction efficiency by more than 30%., J. M. Ulloa acknowledges funding from the Spanish MINECO through project MAT2016-77491-C2-1-R and D. Fuertes Marrón from Comunidad de Madrid (S2013/MAE-2780). U. Aeberhard, D. Fuertes Marrón and J.M. Ulloa acknowledge EU COST Action MP1406 “Multiscale in modelling and validation for solarphotovoltaics (MultiscaleSolar)”.

A procedure to quantitatively analyse the relationship between the wetting layer (WL) and the quantum dots (QDs) as a whole in a statistical way is proposed. As we will show in the manuscript, it allows determining, not only the proportion of deposited InAs held in the WL, but also the average In content inside the QDs. First, the amount of InAs deposited is measured for calibration in three different WL structures without QDs by two methodologies: strain mappings in high-resolution transmission electron microscopy images and compositional mappings with ChemiSTEM x-ray energy spectrometry. The area under the average profiles obtained by both methodologies emerges as the best parameter to quantify the amount of InAs in the WL, in agreement with high-resolution x-ray diffraction results. Second, the effect of three different GaAs capping layer (CL) growth rates on the decomposition of the QDs is evaluated. The CL growth rate has a strong influence on the QD volume as well as the WL characteristics. Slower CL growth rates produce an In enrichment of the WL if compared to faster ones, together with a diminution of the QD height. In addition, assuming that the QD density does not change with the different CL growth rates, an estimation of the average In content inside the QDs is given. The high Ga/In intermixing during the decomposition of buried QDs does not only trigger a reduction of the QD height, but above all, a higher impoverishment of the In content inside the QDs, therefore modifying the two most important parameters that determine the optical properties of these structures.

As promising candidates for solar cell and photodetection applications in the range 1.0–1.16 eV, the growth of dilute nitride GaAsSbN alloys lattice matched to GaAs is studied. With this aim, we have taken advantage of the temperature gradient in the molecular beam epitaxy reactor to analyse the impact of temperature on the incorporation of Sb and N species according to the wafer radial composition gradients. The results from the combination of X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopies (EDS) show an opposite rate of incorporation between N and Sb as we move away from the centre of the wafer. A competitive behaviour between Sb and N in order to occupy the group-V position is observed that depends on the growth rate and the substrate temperature. The optical properties obtained by photoluminescence are discussed in the frame of the double-band anticrossing model. The growth conditions define two sets of different parameters for the energy level and the coupling interaction potential of N, which must be taken into account in the search for the optimum compositions 1–1.15-eV photonic applications.

In this work we investigate the effect of rapid thermal annealing (RTA) on the performance of solar cells consisting of different GaAsSbN-based structures and correlate the device results with modifications of the optical and structural properties of the alloy. In particular, bulk layers grown at different growth rates and type-II GaAsSb/GaAsN superlattices with different period thickness are analyzed. We find evidences of material quality improvement after the annealing process such as a reduction of N-related radiative defects and Sb clusters. These RTA-induced changes lead to a notable enhancement of the open circuit voltage (VOC), which results in values of the bandgap-voltage offset (WOC = EG/q-VOC) comparable to that of a non-optimized reference GaAs solar cell with the same device structure (WOC ∼0.63 eV). The decrease in WOC after annealing shows a correlation with the reduced radiative recombination at low energy N-related sub-bandgap states. These results suggest that radiative recombination in a broad band of deep defect states is a source of VOC degradation in GaAsSbN solar cells.

Using a thin capping layer to engineer the structural and optical properties of InAs/GaAs quantum dots (QDs) has become common practice in the last decade. Traditionally, the main parameter considered has been the strain in the QD/capping layer system. With the advent of more exotic alloys, it has become clear that other mechanisms significantly alter the QD size and shape as well. Larger bond strengths, surfactants, and phase separation are known to act on QD properties but are far from being fully understood. In this study, we investigate at the atomic scale the influence of these effects on the morphology of capped QDs with cross-sectional scanning tunneling microscopy. A broad range of capping materials (InGaAs, GaAsSb, GaAsN, InGaAsN, and GaAsSbN) are compared. The QD morphology is related to photoluminescence characteristics.

The effect of the capping process on the morphology of InAs/GaAs quantum dots (QDs) by using different GaAs-based capping layers (CLs), ranging from strain reduction layers to strain compensating layers, has been studied by transmission microscopic techniques. For this, we have measured simultaneously the height and diameter in buried and uncapped QDs covering populations of hundreds of QDs that are statistically reliable. First, the uncapped QD population evolves in all cases from a pyramidal shape into a more homogenous distribution of buried QDs with a spherical-dome shape, despite the different mechanisms implicated in the QD capping. Second, the shape of the buried QDs depends only on the final QD size, where the radius of curvature is function of the base diameter independently of the CL composition and growth conditions. An asymmetric evolution of the QDs' morphology takes place, in which the QD height and base diameter are modified in the amount required to adopt a similar stable shape characterized by a averaged aspect ratio of 0.21. Our results contradict the traditional model of QD material redistribution from the apex to the base and point to a different universal behavior of the overgrowth processes in self-organized InAs QDs.

This work reports on the benefits from using thin GaAsSb capping layers (CLs) on InAs/GaAs quantum dot (QD) solar cells. The application of such CLs allows the tunability of the QD ground state, switching the QD-CL band alignment from type I to type II for high Sb contents and extending the photoresponse beyond 1.5 µm. Two different structures with ~10% and ~20% Sb contents in the CL (type-I and type-II band alignments, respectively) are explored, leading to efficiency improvements over a reference InAs/GaAs QD solar cell of 20% and 10%, respectively. In general, a significant increase in short-circuit current density (Jsc) is observed, partially due to the extended photocurrent spectrum and the additional contribution of the CL itself. Particularly, for a moderate Sb content, an improved carrier collection efficiency is also found to be a main reason for the Jsc increase. Calculations from an 8×8 k·p method suggest the attribution of such an improvement to longer carrier lifetimes in the wetting layer-CL structure due to the transition to a type-II band alignment. Open-circuit voltages (Voc) exceeding that of a reference QD solar cell are demonstrated under light concentration using GaAsSb CLs, which proves that the Voc is not limited by the low bandgap CLs. Moreover, the highest value is obtained for the high Sb content type-II structure, despite the higher accumulation of strain and the lower effective bandgap. Indeed, the faster Voc increase with light power found in the latter case leads to an Voc even larger than the effective bandgap., We acknowledge the Spanish MICINN-MINECO for funding through project MAT2013-47102-C2-2-R. JMLL and IA acknowledge the financial support of the Comunidad Autónoma de Madrid (Grant S2013/MAE-2780), TEC2015-64189-C3-2-R (MINECO/FEDER) and MINECO (Grant AIC-B_2011-0806).

Super-resolution (SR) software-based techniques aim at generating a final image by combining several noisy frames with lower resolution from the same scene. A comparative study on high-resolution high-angle annular dark field images of InAs/GaAs QDs has been carried out in order to evaluate the performance of the SR technique. The obtained SR images present enhanced resolution and higher signal-to-noise (SNR) ratio and sharpness regarding the experimental images. In addition, SR is also applied in the field of strain analysis using digital image processing applications such as geometrical phase analysis and peak pairs analysis. The precision of the strain mappings can be improved when SR methodologies are applied to experimental images.

In this manuscript we carry out a comparative analysis of p-i-n junction solar cells based on 10 stacks of InAs/GaAs quantum dots (QDs) capped with GaAs(Sb)(N) capping layers (CLs). The application of such CLs allows to significantly extend the photoresponse beyond 1.3 μm. Moreover, a strong photocurrent from the CLs is observed so that the devices work as QD-quantum well solar cells. The GaAsSb CL leads to the best results, providing a strong sub-band-gap contribution, which is higher than that in a sample containing standard GaAs-capped QDs, despite giving rise to the highest accumulated strain. The use of a GaAsN CL reduces the photocurrent originating from GaAs, pointing to electron retrapping and hindered extraction and/or the introduction of point defects as possible reasons for this. Nevertheless, the addition of N helps to balance the accumulated strain, necessary to stack a higher number of QD layers. In addition, the possibility to independently tune the hole and electron confinements by the simultaneous presence of Sb and N in the CL is also confirmed for 10 stacked QD layers. This not only allows to further extend the QD ground state and, therefore, the photoresponse, but also offers the possibility to design an optimized structure facilitating carrier extraction from the QDs. Nevertheless, carrier losses seem to be stronger under the simultaneous presence of N and Sb in the CL.

An extensive study on molecular beam epitaxy growth conditions of quaternary GaAsSbN as a capping layer (CL) for InAs/GaAs quantum dots (QD) was carried out. In particular, CL thickness, growth temperature, and growth rate were optimized. Problems related to the simultaneous presence of Sb and N, responsible for a significant degradation of photoluminescence (PL), are thereby solved allowing the achievement of room-temperature (RT) emission. A particularly strong improvement on the PL is obtained when the growth rate of the CL is increased. This is likely due to an improvement in the structural quality of the quaternary alloy that resulted from reduced strain and composition inhomogeneities. Nevertheless, a significant reduction of Sb and N incorporation was found when the growth rate was increased. Indeed, the incorporation of N is intrinsically limited to a maximum value of approximately 1.6% when the growth rate is at 2.0 ML s−1. Therefore, achieving RT emission and extending it somewhat beyond 1.3 μm were possible by means of a compromise among the growth conditions. This opens the possibility of exploiting the versatility on band structure engineering offered by this QD-CL structure in devices working at RT. PACS 81.15.Hi (molecular beam epitaxy); 78.55.Cr (III-V semiconductors); 73.21.La (quantum dots)

The influence of indium doping on morphology, structural, and luminescence properties of gallium oxide micro- and nanostructures is reported. Indium-doped gallium oxide micro- and nanostructures have been grown by thermal oxidation of metallic gallium in the presence of indium oxide. The dominant morphologies are beltlike structures, which in many cases are twisted leading to springlike structures, showing that In diffusion in Ga2O3 influences the microstructure shapes. High-resolution transmission electron microscopy has revealed the presence of twins in the belts, and energy-dispersive X-ray spectroscopy in the scanning electron microscopy (SEM) has detected a segregation of indium impurities at the edges of planar structures. These results suggest that indium plays a major role in the observed morphologies and support the assumption of a layer by layer model as growth mechanism. An additional assessment of indium influence on the defect structure has been performed by cathodoluminescence in the SEM, X-ray photoelectron microscopy, and spatially resolved Raman spectroscopy.

Changing the growth rate during the heteroepitaxial capping of InAs/GaAs quantum dots (QDs) with a 5 nm-thick GaAsSbN capping layer (CL) strongly modifies the QD structural and optical properties. A size and shape transition from taller pyramids to flatter lens-shaped QDs is observed when the CL growth rate is decreased from 1.5 to 0.5 ML/s. This indicates that the QD dissolution processes taking place during capping can be controlled to some extent by the GaAsSbN CL growth rate, with high growth rates allowing a complete preservation of the QDs. However, the dissolution processes are shown to have a leveling effect on the QD height, giving rise to a narrower size distribution for lower growth rates. Contrary to what could be expected, these effects are opposite to the strong blue-shift and improvement of the photoluminescence (PL) observed for higher growth rates. Nevertheless, the PL results can be understood in terms of the strong impact of the growth rate on the Sb and N incorporation into the CL, which results in lower Sb and N contents at higher growth rates. Besides the QD-CL band offsets and QD strain, the different CL composition alters the band alignment of the system, which can be transformed to type-II at low growth rates. These results show the key role of the alloyed CL growth parameters on the resulting QD properties and demonstrate an intricate correlation between the PL spectra and the sample morphology in complex QD-CL structures.

The application of a GaAsSb/GaAsN short-period superlattice capping layer (CL) on InAs/GaAs quantum dots (QDs) is shown to be an option for providing improved luminescence properties to this system. Separating both GaAsSb and GaAsN ternaries during the growth in 2 monolayer-thick phases solves the GaAsSbN immiscibility-related problems. Strong fluctuations in the CL composition and strain field as well as in the QD size distribution are significantly reduced, and a more regular CL interface is also obtained. Room-temperature (RT) photoluminescence (PL) is obtained for overall N contents as high as 3%, yielding PL peak wavelengths beyond 1.4 μm in samples with a type-II band alignment. High external quantum efficiency electroluminescence and photocurrent from the QD ground state are also demonstrated at RT in a single QD-layer p-i-n device. Thus, it becomes possible to combine and transfer the complementary benefits of Sb- and N-containing GaAs alloys to InAs QD-based optoelectronics.

To know the influence of upper gastrointestinal bleeding in diagnostic methods of H. pylori infection.We prospectively studied patients with peptic ulcers: 55 with upper gastrointestinal bleeding and 62 without upper gastrointestinal bleeding. We analysed the results of culture, urease test, Gram, histology and serological test IgG and IgA in both groups. H. pylori infection was determined by a positive culture or positive urease test and histology.Patients with upper gastrointestinal bleeding were older, but there were not statistical differences in sex, H. pylori prevalence infection or duodenal or gastric ulcers between patients with and without upper gastrointestinal bleeding. 78% having H. pylori infection. The urease test had a false negative rate in patients with upper gastrointestinal bleeding of 22% but only 3% in patients without upper gastrointestinal bleeding (p0.05). The culture, histology and Gram had higher false negative rate in upper gastrointestinal bleeding group than in non upper gastrointestinal bleeding group but without statistical significance. All patients with false negative urease test had antral culture positive.Urease test has a high false negative rate when is studied in patients with peptic ulcers and upper gastrointestinal bleeding. Caution should be made if urease test was used alone for diagnosis in patients with upper gastrointestinal bleeding. Urease test and culture together could be a good diagnostic method.

Type I and type II band alignment InAs/GaAs quantum dot laser diodes (LD) are demonstrated using a 5-nm-thick GaAsSb capping layer with moderate or high Sb contents. The threshold current density, external differential quantum efficiency, and characteristic temperature substantially improve when Sb is used in the capping layer. Nevertheless, in the type II LD, lasing arises from type I-like excited states with much shorter lasing wavelengths than expected. This is likely related to the observed inhibition of the ground state transition in the spontaneous emission, which would also reduce the radiative current and, therefore, the threshold current.