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Photomechanical effects in polymeric materials and composites transduce light into mechanical work. The ability to control the intensity, polarization, placement, and duration of light irradiation is a distinctive and potentially useful tool to tailor the location, magnitude, and directionality of photogenerated mechanical work. Unfortunately, the work generated from photoresponsive materials is often slow and yields very small power densities, which diminish their potential use in applications. Here, we investigate photoinitiated snap-through in bistable arches formed from samples composed of azobenzene-functionalized polymers (both amorphous polyimides and liquid crystal polymer networks) and report orders-of-magnitude enhancement in actuation rates (approaching 10(2) mm/s) and powers (as much as 1 kW/m(3)). The contactless, ultra-fast actuation is observed at irradiation intensities <<100 mW/cm(2). Due to the bistability and symmetry of the snap-through, reversible and bidirectional actuation is demonstrated. A model is developed to elucidate the underlying mechanics of the snap-through, specifically focusing on isolating the role of sample geometry, mechanical properties of the materials, and photomechanical strain. Using light to trigger contactless, ultrafast actuation in an otherwise passive structure is a potentially versatile tool to use in mechanical design at the micro-, meso-, and millimeter scales as actuators, as well as switches that can be triggered from large standoff distances, impulse generators for microvehicles, microfluidic valves and mixers in laboratory-on-chip devices, and adaptive optical elements.

ABSTRACT: Liquid crystals are widely employed as stimuli‐responsive materials. Liquid crystallinity can be retained in polymeric form. Photoinduced mechanical effects in liquid crystalline polymer networks and elastomers have been a topic of considerable recent research. This review details the historical underpinnings and recent advances in the synthesis and the corresponding photomechanical response of these materials. In nearly all cases, the conversion of light into mechanical work has employed azobenzene as either a guest additive or covalently attached to the network. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 695–705 [ABSTRACT FROM AUTHOR]

All-optical deformation and recovery of complex topographical features is demonstrated within elastic sheets composed of main-chain type azobenzene-functionalized liquid crystalline elastomers (azo-LCEs). The azo-LCEs are synthesized via an orthogonal, two-step reaction between commercially available LC monomers and n-butylamine. By employing surface alignment, the local orientation of the nematic director is spatially complex ('blueprinted'). Exposing the blueprinted LCE films to light as an actinic stimulus generates a photomechanical response which yields reversible shape changes between 2D and 3D shapes. The deformation of azo-LCEs strongly depends on the azobenzene concentration as well as the network structure (i.e., crosslink density). Blueprinting complex director profiles within azo-LCEs yield reconfigurable elastic sheets that can be addressed both remotely and selectively which may have benefit in a variety of applications in aerospace, medicine, and optics. [ABSTRACT FROM AUTHOR]

Photomechanical effects in polymeric materials and composites transduce light into mechanical work. The ability to control the intensity, polarization, placement, and duration of light irradiation is a distinctive and potentially useful tool to tailor the location, magnitude, and directionality of photogenerated mechanical work. Unfortunately, the work generated from photoresponsive materials is often slow and yields very small power densities, which diminish their potential use in applications. Here, we investigate photo-initiated snap-through in bistable arches formed from samples composed of azobenzene-functionalized polymers (both amorphous polyimides and liquid crystal polymer networks) and report orders-of-magnitude enhancement in actuation rates (approaching 102 mm/s) and powers (as much as 1 kW/m3). The contactiess, ultra-fast actuation is observed at irradiation intensities <<100 mW/cm2. Due to the bistability and symmetry of the snap-through, reversible and bidirectional actuation is demonstrated. A model is developed to elucidate the underlying mechanics of the snap-through, specifically focusing on isolating the role of sample geometry, mechanical properties of the materials, and photomechanical strain. Using light to trigger contactless, ultrafast actuation in an otherwise passive structure is a potentially versatile tool to use in mechanical design at the micro-, meso-, and millimeter scales as actuators, as well as switches that can be triggered from large standoff distances, impulse generators for microvehicles, microfluidic valves and mixers in laboratory-on-chip devices, and adaptive optical elements. [ABSTRACT FROM AUTHOR]

Prior examinations have reported that polymer stabilisation of azobenzene-based cholesteric liquid crystal (CLC) mixtures can reduce the time necessary for complete colour restoration in the dark from three days to as few as five minutes. This work extends upon these prior examinations by exploring and elucidating the role of crosslinker concentration and monomer polarity on the colour restoration of a representative CLC mixture composed of a high HTP bis(azo) binapthanyl chiral dopant (QL76) mixed into the cyanobiphenyl nematic liquid crystal host MDA-00-1444. The impact of these variables was unexpectedly convoluted. In all the formulations examined here, polymer stabilisation dramatically reduces the time for complete colour restoration of the starting reflection notch. In mixtures based on nonpolar liquid crystal monomers, increasing the crosslinker concentration reduces the time necessary for complete colour restoration. However, the dependence on crosslinker concentration reverses in mixtures composed from polar liquid crystal monomers in which increasing the crosslinker concentration serves to increase the time necessary for complete colour restoration. [ABSTRACT FROM AUTHOR]

The potential for wireless transduction of input lightenergy into mechanical outputs has led to a reinvigorated pursuitof photomechanical effects in polymeric materials and composites.We report here on factors influencing the photochemical mechanism(and thus the mechanical output) in monodomain azobenzene-functionalizedliquid crystal polymer networks. Through systematic examination ofa representative material with both mechanics and spectroscopic characterizationthe prevalence of the trans–cis and trans–cis–transmechanisms is elucidated. Furthermore, the role of light intensityin generating heat (photothermal effects) is also reported. [ABSTRACT FROM AUTHOR]

Light can wirelessly direct functional responses in photoresponsive polymeric materials and composites. The intensity, phase, and polarization of light can be spatially modulated into complex patterns with holography (intensity or polarization) or masking (intensity or phase). Deriving from these foundational properties of light, photoresponsive macromolecular systems exhibit exceeding potential to yield rapid and highly engineered macroscopic as well as spatially selectable mechanically adaptive responses useful as soft actuators or topographical surfaces in aerospace, automotive, and biomedical applications. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012 [ABSTRACT FROM AUTHOR]

The photoinduced topographical deformation of azobenzene‐functionalized liquid crystalline elastomers is reported by T.J. White and co‐workers on page 5819. The authors report on the use of UV light irradiation to transform originally flat sheets into topographical surfaces. The photoinduced shape transformation and relaxation is shown to strongly depend on the azobenzene concentration as well as the network structure. [ABSTRACT FROM AUTHOR]

Photoresponsive polymers convert a light stimulus inputinto amechanical output (work). Photoinduced conformational changes, suchas within azobenzene, dictate molecular-level distortions that summateinto a macroscopic strain, which often manifests as a shape changeor motion. The transduction of the molecular-level response to a macroscaleeffect is regulated by mesoscopic features, such as chain packing,free volume, and local molecular orderfactors which dependon chemical composition as well as the process history ofthe material. Herein, we demonstrate the ability to widelytailor the photomechanical response of a photoresponsive polymer bymanipulating the energy state of the glass, rather than formulatingnew chemical compositions. Physical aging increases the density ofthe glass, reduces local free volume, and thus reduces the minimain local conformation space, thereby strongly influencing the azobenzenephotochemistry (trans–cis–trans isomerization). Thesubsequent change in the energy landscape of the system reduces thefraction of azobenzene able to undergo reconfiguration as well asincreases the probability that those photoinduced conformations willrelax back to the initial local environment. The result is a tuningof the magnitude of macroscopic strain and the ability to shift fromshape fixing to shape recovery, respectively. [ABSTRACT FROM AUTHOR]