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We introduce and study conformal field theories specified by W −algebras commuting with certain set of screening charges. These CFT’s possess perturbations which define integrable QFT’s. We establish that these QFT’s have local and non-local Integrals of Motion and admit the perturbation theory in the weak coupling region. We construct factorized scattering theory which is consistent with non-local Integrals of Motion and perturbation theory. In the strong coupling limit the S−matrix of this QFT tends to the scattering matrix of the O(N) sigma model. The perturbation theory, Bethe ansatz technique, renormalization group approach and methods of conformal field theory are applied to show, that the constructed QFT’s are dual to integrable deformation of O(N) sigma-models.

Since the emergence of graphene, we have seen several proposals for the realization of Landau lasers tunable over the terahertz frequency range. The hope was that the non-equidistance of the Landau levels from Dirac fermions would suppress the harmful non-radiative Auger recombination. Unfortunately, even with this non-equidistance an unfavorable non-radiative process persists in Landau-quantized graphene, and so far no cyclotron emission from Dirac fermions has been reported. One way to eliminate this last non-radiative process is to sufficiently modify the dispersion of the Landau levels by opening a small gap in the linear band structure. A proven example of such gapped graphene-like materials are HgTe quantum wells close to the topological phase transition. In this work, we experimentally demonstrate Landau emission from Dirac fermions in such HgTe quantum wells, where the emission is tunable by both the magnetic field and the carrier concentration. Consequently, these results represent an advance in the realization of terahertz Landau lasers tunable by magnetic field and gate-voltage., Main text with the figures of the published version

We revisit the Riemann-Hilbert problem determined by Donaldson-Thomas invariants for the resolved conifold and for other small crepant resolutions. While this problem can be recast as a system of TBA-type equations in the conformal limit, solutions are ill-defined due to divergences in the sum over infinite trajectories in the spectrum of D2-D0-brane bound states. We explore various prescriptions to make the sum well-defined, show that one of them reproduces the existing solution in the literature, and identify an alternative solution which is better behaved in a certain limit. Furthermore, we show that a suitable asymptotic expansion of the $\tau$ function reproduces the genus expansion of the topological string partition function for any small crepant resolution. As a by-product, we conjecture new integral representations for the triple sine function, similar to Woronowicz' integral representation for Faddeev's quantum dilogarithm., Comment: 25+14 pages; added proof for integral representation of the double sine function and a similar conjecture for the triple sine; version accepted for publication in Annales Henri Poincar\'e

Primary Sjögren’s syndrome (pSS) is an autoimmune disease with frequent neurological involvement. Memory complaints are common, but their precise patterns remain unclear. We wanted to characterize patterns of neurocognitive profiles in pSS patients with cognitive complaints. Only pSS patients with memory complaints were included, prospectively. Cognitive profiles were compiled through a comprehensive cognitive evaluation by neuropsychologists. Evaluations of anxiety, depression, fatigue, sleep disorders and quality of life were performed for testing their interactions with cognitive profiles. All 32 pSS patients showed at least borderline cognitive impairment, and 17 (53%) exhibited a pathological cognitive profile: a hippocampal profile (37%), a dysexecutive profile (22%), and an instrumental profile (16%) (possible overlap). Regarding the secondary objectives: 37% of patients were depressed, and 48% exhibited a mild-to-severe anxiety trait. Sleep disorders were frequent (excessive daytime sleepiness (55%), high risk for sleep apnea (45%), and insomnia (77%)). Cognitive impairments could not be explained alone by anxiety, depression or sleep disorders. Fatigue level was strongly associated with sleep disorders. Our study highlights that cognitive complaints in pSS patients are supported by measurable cognitive impairments, apart from frequently associated disorders such as depression, anxiety or sleep troubles. Sleep disorders should be screened.

As a glass-forming liquid is cooled, the dynamics of its constituent particles changes from being liquid-like to more solid-like. The solidity of the resulting glassy material is believed to be due to a cage-formation process, whereby the motion of individual particles is increasingly constrained by neighbouring particles. This process begins at the temperature (or particle density) at which the glass-forming liquid first shows signs of glassy dynamics; however, the details of how the cages form remain unclear1–4. Here we study cage formation at the particle level in a two-dimensional colloidal suspension (a glass-forming liquid). We use focused lasers to perturb the suspension at the particle level and monitor the nonlinear dynamic response of the system using video microscopy. All observables that we consider respond non-monotonically as a function of the particle density, peaking at the density at which glassy dynamics is first observed. We identify this maximum response as being due to cage formation, quantified by the appearance of domains in which particles move in a cooperative manner. As the particle density increases further, these local domains become increasingly rigid and dominate the macroscale particle dynamics. This microscale rheological deformation approach demonstrates that cage formation in glass-forming liquids is directly related to the merging of such domains, and reveals the first step in the transformation of liquids to glassy materials1,5. The onset of rigidity in a two-dimensional colloidal glass-forming system is identified by the formation and merging of locally rigid domains in which particles move in a cooperative manner.

Whenever available, refined BPS indices provide considerably more information on the spectrum of BPS states than their unrefined version. Extending earlier work on the modularity of generalized Donaldson-Thomas invariants counting D4-D2-D0 brane bound states in type IIA strings on a Calabi-Yau threefold $\mathfrak{Y}$, we construct the modular completion of generating functions of refined BPS indices supported on a divisor class. Although for compact $\mathfrak{Y}$ the refined indices are not protected, switching on the refinement considerably simplifies the construction of the modular completion. Furthermore, it leads to a non-commutative analogue of the TBA equations, which suggests a quantization of the moduli space consistent with S-duality. In contrast, for a local CY threefold given by the total space of the canonical bundle over a complex surface $S$, refined BPS indices are well-defined, and equal to Vafa-Witten invariants of $S$. Our construction provides a modular completion of the generating function of these refined invariants for arbitrary rank. In cases where all reducible components of the divisor class are collinear (which occurs e.g. when $b_2(\mathfrak{Y})=1$, or in the local case), we show that the holomorphic anomaly equation satisfied by the completed generating function truncates at quadratic order. In the local case, it agrees with an earlier proposal by Minahan et al for unrefined invariants, and extends it to the refined level using the afore-mentioned non-commutative structure. Finally, we show that these general predictions reproduce known results for $U(2)$ and $U(3)$ Vafa-Witten theory on $\mathbb{P}^2$, and make them explicit for $U(4)$., Comment: 34+24 pages, 6 figures; misprints fixed

International audience; Photobiomodulation (PBM) has been shown to improve cell proliferation and cell migration. Many cell types have been investigated, with most studies using deep penetrating red light irradiation. Considering the interest of surface biostimulation of oral mesenchymal cells after surgical wound, the present study aimed to assess green light irradiation effects on Dental Pulp Stem Cells’ (DPSC) proliferation and migration. To understand the mechanisms underlying these effects, we investigated cytoskeleton organization and subsequent cell shape and stiffness. A 532-nm wavelength Nd:YAG laser (30 mW) was applied between 30 and 600 s on DPSC in vitro. Cell proliferation was analyzed at 24, 48, and 72 h after irradiation, by cell counting and enzymatic activity quantification (paranitrophenylphosphate phosphatase (pNPP) test). A wound healing assay was used to study cell migration after irradiation. Effects of PBM on cytoskeleton organization and cell shape were assessed by actin filaments staining. Elasticity changes after irradiation were quantified in terms of Young’s modulus measured using Atomic Force Microscopy (AFM) force spectroscopy. Green light significantly improved DPSC proliferation with a maximal effect obtained after 300-s irradiation (energy fluence 5 J/cm2). This irradiation had a significant impact on cell migration, improving wound healing after 24 h. These results were concomitant with a decrease of cells’ Young’s modulus after irradiation. This cell softening was explained by actin cytoskeleton reorganization, with diminution of cell circularity and more abundant pseudopodia. This study highlights the interest of green laser PMB for the proliferation and migration of mesenchymal stem cells, with encouraging results for clinical application, especially for surgical wound healing procedures.

Within the context of top-down holography, we study a one-parameter family of regular background solutions of maximal gauged supergravity in seven dimensions, dimensionally reduced on a 2-torus. The dual, four-dimensional confining field theory realises the global (spontaneous as well as explicit) symmetry breaking pattern SO(5)->SO(4). We compute the complete mass spectrum for the fluctuations of the 128 bosonic degrees of freedom of the five-dimensional gravity theory, which correspond to scalar, pseudoscalar, vector, axial-vector, and tensor bound states of the dual field theory, and includes particles with exotic SO(4) quantum numbers. We confirm the existence of tachyonic instabilities near the boundaries of the parameter space. We discuss the interplay between explicit and spontaneous symmetry breaking. The SO(5)/SO(4) coset might provide a first step towards the realisation of a calculable framework and ultraviolet completion of minimal composite Higgs models, if the four pseudo-Nambu-Goldstone bosons are identified with the real components of the Higgs doublet in the standard model (SM), and a subgroup of SO(4) with the SU(2)xU(1) SM gauge group. We exhibit an example with an additional localised boundary term that mimics the effect of a weakly-coupled external sector., Version accepted for publication

We raise the question whether a simple model for traffic, generic but based on microscopic rules, can provide an additional angle for interpreting flow through a road system. Using the totally simple exclusion process (TASEP) on a road segment with ramps, we show that measuring the flow directly at the road junctions may be a useful setup. We show that the presence of junctions affects the characterisation of traffic, suggesting that interpretations in terms of a 2-phase or a 3-phase description may be complementary, rather than contradictory. We furthermore argue that hysteresis-like features can appear in a system with junctions, which is intriguing as the TASEP dynamics as such do not lead to hysteresis. We discuss our findings in the light of boundary-driven phase transitions.

International audience; Few studies addressed the evolution of brain activity before and after brain tumor resection. Using a fMRI naming task, we evaluated possible underlying plasticity phenomena. Thirty-two patients with left low-grade gliomas (16 women; age = 38.6 ± 8.31 years) and 19 healthy controls (7 women; age = 42.4 ± 12.1) were included in the study. An overt picture-naming task (DO80) was performed pre and post (3 months) surgery, as well as within the MRI in a covert manner. Exams included an injected 3DT1, a T2FLAIR, a DTI and a GE-EPI (task) sequence. Activations maps were compared with picture naming score, FA and MD maps were estimated, a VLSM analysis was performed on tumor masks, and disconnectome maps were reconstructed. Pre-surgery, the left parahippocampal gyrus (LPH) was inversely associated with task performance. Increased pre-post surgery left lingual gyrus (LLG) activity was found related to decreased picture naming performance. The evolution of left lingual gyrus (LLG) activity was negatively associated with the evolution of picture naming performance. In controls, the LPH was functionally connected to the right precentral gyrus (RPCG) and slightly to the LLG. This was not clearly retrieved in the patient group. Preoperatively, the LLG was connected to the left planum temporale and to the right lingual gyrus. The same result was found for controls. Postoperatively, the LLG was only connected to the RPCG. No association was found between evolution of FA/MD and evolution of picture naming performance. There is not one unique pattern of pre- and postoperative plasticity concerning picture-naming performance in DLGG patients.

In the continuity of our previous paper arXiv:1509.05516, we define three new algebras, $A_{n}(a,b,c)$, $B_{n}$ and $C_{n}$, that are close to the braid algebra. They allow to build solutions to the braided Yang-Baxter equation with spectral parameters. The construction is based on a baxterisation procedure, similar to the one used in the context of Hecke or BMW algebras. The $A_{n}(a,b,c)$ algebra depends on three arbitrary parameters, and when the parameter $a$ is set to zero, we recover the algebra $M_{n}(b,c)$ already introduced elsewhere for purpose of baxterisation. The Hecke algebra (and its baxterisation) can be recovered from a coset of the $A_{n}(0,0,c)$ algebra. The algebra $A_{n}(0,b,-b^2)$ is a coset of the braid algebra. The two other algebras $B_{n}$ and $C_{n}$ do not possess any parameter, and can be also viewed as a coset of the braid algebra., Comment: 9 pages

We numerically study the relaxation dynamics and associated criticality of non-Brownian frictionless spheres below jamming in spatial dimensions $d=2$, $3$, $4$, and $8$, and in the mean-field Mari-Kurchan model. We discover non-trivial finite-size and volume fraction dependences of the relaxation time associated to the relaxation of unjammed packings. In particular, the relaxation time is shown to diverge logarithmically with system size at any density below jamming, and no critical exponent can characterise its behaviour approaching jamming. In mean-field, the relaxation time is instead well-defined: it diverges at jamming with a critical exponent that we determine numerically and differs from an earlier mean-field prediction. We rationalise the finite $d$ logarithmic divergence using an extreme-value statistics argument in which the relaxation time is dominated by the most connected region of the system. The same argument shows that the earlier proposition that relaxation dynamics and shear viscosity are directly related breaks down in large systems. The shear viscosity of non-Brownian packings is well-defined in all $d$ in the thermodynamic limit, but large finite-size effects plague its measurement close to jamming., Comment: 11 pages, 8 figures

When a microparticle is trapped at a fluid interface, particle's electrical charge and weight combine to deform the interface. Such deformation is expected to affect the particle diffusion via hydrodynamics boundary conditions. Using available models of particle-induced electrostatic deformation of the interface and particle dynamics at the interface, we are able to analytically predict particle diffusion coefficient values in a large range of particle's contact angle and size. This might offer a solid background of numerical values to compare with for future experimental studies in the field of particle diffusion at a fluid interface.

International audience; A novel and simple method for the measurement of cloud point temperatures of solutions is presented. Cloud point determination , which is currently used to establish the phase diagrams of protein solutions, is indicative of proteins interactions and constitutes a useful tool for food products engineering. We describe a novel experimental setup that allows screening of a large number of physical-chemical conditions in one measurement and the determination of cloud point temperatures both above and below ambient temperature. We use a simple method to avoid solvent evaporation and condensation, so that the setup can be used for solutions prepared with a volatile solvent. We present the operating parameter range and the precision of the measurement. The optical properties of the system are calibrated with solutions of known transmittance, and the determination of cloud point temperatures is validated on a standard non-ionic surfactant solution. Finally, we demonstrate the efficiency of the method by determining the phase diagram of a wheat protein extract, soluble in a water/ethanol mixture. Complemented with differential scanning calorimetry measurements, the liquid-liquid phase transition can be determined up to a protein concentration of 250 g/L, a range inaccessible with conventional methods for this protein extract.

In rhythmical movement performance, our brain has to sustain movement while correcting for biological noise-induced variability. Here, we explored the functional anatomy of brain networks during voluntary rhythmical elbow flexion/extension using kinematic movement regressors in fMRI analysis to verify the interest of method to address motor control in a neurological population. We found the expected systematic activation of the primary sensorimotor network that is suggested to generate the rhythmical movement. By adding the kinematic regressors to the model, we demonstrated the potential involvement of cerebellar-frontal circuits as a function of the irregularity of the variability of the movement and the primary sensory cortex in relation to the trajectory length during task execution. We suggested that different functional brain networks were related to two different aspects of rhythmical performance: rhythmicity and error control. Concerning the latter, the partitioning between more automatic control involving cerebellar-frontal circuits versus less automatic control involving the sensory cortex seemed thereby crucial for optimal performance. Our results highlight the potential of using co-registered fine-grained kinematics and fMRI measures to interpret functional MRI activations and to potentially unmask the organisation of neural correlates during motor control.

Hybrid supercapacitors with nickel hydroxide electrode are widely used as modern power sources for electrovehicles, ignition of different electric engines, etc. Nickel hydroxide for supercapacitor use must satisfy special features which are quite different from those requested for battery application. The aim of this work is to improve the promising two-stage high-temperature method by altering hydrolysis condition (hot and cold) in order to obtain Ni(OH)2 with improved electrochemical activity. Ni(OH)2 samples have been investigated by PXRD, TG, DSC, SEM, TEM, cyclic voltammogramm, and galvanostatic charge-discharge cycling. It has been established from PXRD, TG, and DSC analyses that material obtained by hydrolysis at high temperature is a highly crystalline β-Ni(OH)2 characterized by high thermal stability. Materials prepared by cold hydrolysis are a highly defective βbc-Ni(OH)2, with 6.3 % water content and a lower thermal stability. It has been shown that samples prepared by hot hydrolysis have a high redox reversibility and electrochemical cycling stability, but a lower electrochemical capacity. This suggests that the electrochemical processes are localized in the thin layer at the particle surface. Cyclic voltammograms of samples prepared by cold hydrolysis exhibit gradual activation of the active material, anyhow resulting in higher capacity. By means of the galvanostatic charge-discharge curves at different current densities, the specific capacities of the samples have been calculated. The sample prepared by cold hydrolysis has higher specific capacities than the sample prepared by hot hydrolysis.

The physical behavior of glass-forming liquids presents complex features of both dynamic and thermodynamic nature. Some studies indicate the presence of thermodynamic anomalies and of crossovers in the dynamic properties, but their origin and degree of universality is difficult to assess. Moreover, conventional simulations are barely able to cover the range of temperatures at which these crossovers usually occur. To address these issues, we simulate the Kob-Andersen Lennard-Jones mixture using efficient protocols based on multi-CPU and multi-GPU parallel tempering. Our setup enables us to probe the thermodynamics and dynamics of the liquid at equilibrium well below the critical temperature of mode-coupling theory, $T_{\rm MCT} = 0.435$. We find that below $T=0.4$ the analysis is hampered by partial crystallization of the metastable liquid, which nucleates extended regions populated by large particles arranged in an fcc structure. By filtering out crystalline samples, we reveal that the specific heat grows in a regular manner down to $T=0.38$. Possible thermodynamic anomalies suggested by previous studies can thus occur only in a region of the phase diagram where the system is highly metastable. Using the equilibrium configurations obtained from the parallel tempering simulations, we perform molecular dynamics and Monte Carlo simulations to probe the equilibrium dynamics down to $T=0.4$. A temperature-derivative analysis of the relaxation time and diffusion data allows us to assess different dynamic scenarios around $T_{\rm MCT}$. Hints of a dynamic crossover come from analysis of the four-point dynamic susceptibility. Finally, we discuss possible future numerical strategies to clarify the nature of crossover phenomena in glass-forming liquids., 12 pages, 9 figures, contribution to the special issue "Advances in Computational Methods for Soft Matter Systems". Data relevant to this work are available at https://doi.org/10.5281/zenodo.1227830

The quantum Hall effect provides a universal standard for electrical resistance that is theoretically based on only the Planck constant h and the electron charge e. Currently, this standard is implemented in GaAs/AlGaAs, but graphene's electronic properties have given hope for a more practical device. Here, we demonstrate that the experimental conditions necessary for the operation of devices made of high-quality graphene grown by chemical vapour deposition on silicon carbide can be extended and significantly relaxed compared with those for state-of-the-art GaAs/AlGaAs devices. In particular, the Hall resistance can be accurately quantized to within 1 × 10−9 over a 10 T wide range of magnetic flux density, down to 3.5 T, at a temperature of up to 10 K or with a current of up to 0.5 mA. This experimental simplification highlights the great potential of graphene in the development of user-friendly and versatile quantum standards that are compatible with broader industrial uses beyond those in national metrology institutes. Furthermore, the measured agreement of the quantized Hall resistance in graphene and GaAs/AlGaAs, with an ultimate uncertainty of 8.2 × 10−11, supports the universality of the quantum Hall effect. This also provides evidence of the relation of the quantized Hall resistance with h and e, which is crucial for the new Systeme International d'unites to be based on fixing such fundamental constants of nature. Large-area graphene devices synthesized by chemical vapour deposition are used to develop electrical resistance standards, based on the quantum Hall effect, with state-of-the-art accuracy and under an extended range of experimental conditions of magnetic field, temperature and current.

Subcritical crack growth and crack closure are analysed using the double cleavage drilled compression method, in two calcium phosphate-based glasses. The measurements of the crack velocity as a function of temperature, from ambient to 250 °C, are reported for two different relative humidity levels. Studied glasses present unusual trends characterized by a non-gradual shift of V–K I curves versus temperature. Moreover, when the load is released and crack closes, expulsion of a “liquid-like” phase is observed forming droplets along the crack path. These droplets are only formed at certain temperatures, but both under high and low water humidity. They evolve towards residues when temperature is decreased.

International audience; A thorough understanding of the mechanisms and factors involved in the dynamics of organic carbon in soils is required to identify and enhance natural sinks for greenhouse gases. Some tropical soils, such as Andosols, have 3-6 fold higher concentrations of organic carbon than other kinds of soils containing classical clays. In the tropics, toxic pesticides permanently pollute soils and contaminate crops, water resources, and ecosystems. However, not all soils are equal in terms of pesticide contamination or in their ability to transfer pollution to the ecosystem. Andosols are generally more polluted than the other kinds of soils but, surprisingly, they retain and trap more pesticides, thereby reducing the transfer of pesticides to ecosystems, water resources, and crops. Andosols thus have interesting environmental properties in terms of soil carbon sequestration and pesticide retention. Andosols contain a nano porous clay (allophane) with unique structures and physical properties compared to more common clays; these are large pore volume, specific surface area, and a tortuous and fractal porous arrangement. The purpose of this mini review is to discuss the importance of the allophane fractal microstructure for carbon sequestration and pesticide trapping in the soil. We suggest that the tortuous microstructure (which resembles a labyrinths) of allophane aggregates and the associated low accessibility partly explain the poor availability of soil organic matter and of any pesticides trapped in andosols.

Some recent results on the rotational dynamics of polymers are reviewed and extended. We focus here on the relaxation of a polymer, either flexible or semiflexible, initially wrapped around a rigid rod. We also study the steady polymer rotation generated by a constant torque on the rod. The interplay of frictional and entropic forces leads to a complex dynamical behavior characterized by non-trivial universal exponents. The results are based on extensive simulations of polymers undergoing Rouse dynamics and on an analytical approach using force balance and scaling arguments. The analytical results are in general in good agreement with the simulations, showing how a simplified approach can correctly capture the complex dynamical behavior of rotating polymers., Comment: 13 pages; 7 figures; proceedings of the International Workshop on "Brownian Motion in Confined Geometries", Max Planck Institute for the Physics of Complex Systems in Dresden from 17 - 21 March 2014; to appear in EPJ-ST

We consider minimal dark matter scenarios featuring momentum-dependent couplings of the dark sector to the Standard Model. We derive constraints from existing LHC searches in the monojet channel, estimate the future LHC sensitivity for an integrated luminosity of 300 fb$^{-1}$, and compare with models exhibiting conventional momentum-independent interactions with the dark sector. In addition to being well motivated by (composite) pseudo-Goldstone dark matter scenarios, momentum-dependent couplings are interesting as they weaken direct detection constraints. For a specific dark matter mass, the LHC turns out to be sensitive to smaller signal cross-sections in the momentum-dependent case, by virtue of the harder jet transverse-momentum distribution., 23 pages, 4 figures

International audience; Despite a better understanding of their anatomy, the functional role of frontal pathways, i.e., the fronto-striatal tract (FST) and frontal aslant tract (FAT), remains obscure. We studied 19 patients who underwent awake surgery for a frontal glioma (14 left, 5 right) by performing intraoperative electrical mapping of both fascicles during motor and language tasks. Furthermore, we evaluated the relationship between these tracts and the eventual onset of transient postoperative disorders. We also performed post-surgical tract-specific measurements on probabilistic tractography. All patients but one experienced intraoperative inhibition of movement and/or speech during subcortical electrostimulation. On postoperative tractography, the subcortical distribution of stimulated sites corresponded to the spatial course of the FST and/or FAT. Furthermore, we found a significant correlation between postoperative worsening and distances between these tracts and resection cavity. A resection close to the (right or left) FST was correlated with transitory motor initiation disorders (p = 0.026), while a resection close to the left FAT was associated with transient speech initiation disorders (p = 0.003). Moreover, the measurements of average distances between resection cavity and left FAT showed a positive correlation with verbal fluency in both semantic (p = 0.019) and phonemic scores (p = 0.017), while average distances between surgical cavity and left FST showed a positive correlation with verbal fluency scores in both semantic (p = 0.0003) and phonemic modalities (p = 0.037). We suggest that FST and FAT would cooperatively play a role in self-initiated movement and speech, as a part of "negative motor network" involving the pre-supplementary motor area, left inferior frontal gyrus and caudate nucleus.

International audience; Purpose Polymers typically have intrinsic thermal conductivity much lower than other materials. Enhancement of this property may be obtained by the addition of conductive fillers. Nanofillers are preferred to traditional ones, due to their low percolation threshold resulting from their high aspect ratio. Beyond these considerations, it is imperative that the development of such new fillers takes place in a safe and sustainable manner. A conventional life cycle assessment (LCA) has been conducted on epoxy-based composites, filled with graphite nanoplatelets (GnP). In particular, this study focuses on energy requirements for the production of such composites, in order to stress environmental hot spots and primary energy of GnP production process (nano-wastes and nanoparticles emissions are not included). Methods A cradle-to-grave approach has been employed for this assessment, in an attributional modeling perspective. The data for the LCA have been gathered from both laboratory data and bibliographic references. A technical LCA software package, SimaPro (SimaPro 7.3), which contains Ecoinvent (2010) life cycle inventory (LCI) database, has been used for the life cycle impact assessment (LCIA), studying 13 midpoint indicators. Sensitivity and uncertainty analyses have also been performed. Results and discussion One kilogram of GnP filler requires 1,879 MJ of primary energy while the preparation of 1 kg of epoxy composite loaded with 0.058 kg of GnP 303 MJ. Besides energy consumption in the filler preparation, it is shown that the thermoset matrix material has also a nonnegligible impact on the life cycle despite the use of GnP: the primary energy required to make epoxy resin is 187 MJ, i.e., 62 % of the total energy to make 1 kg of composite. Conclusions Raw material extraction and filler and resin preparation phase exhibit the highest environmental impact while the composite production is negligible. Thermosetting resin remains the highest primary energy demand when used as matrix for GnP fillers. The result of the sensitivity analysis carried out on the electricity mix used during the GnP and the composite production processes does not affect the conclusions.

We report a new ORganically MOdified SILicates (ORMOSILs) stable sol based on vinyl ether function which can be deposited as a layer and structured by mean of UV radiation through a mask or by direct laser writing. Silica matrix is synthesized by sol–gel process and organic network is formed by photopolymerization. One of the potential applications is the fabrication of integrated optical circuits. [2-(3,4 epoxycyclohexyl ethyltrimethoxysilane)] has already used for the fabrication of such devices and to develop microstructures on an organic substrate by cationic polymerization. Obtained results show some weakness such as an important contribution of OH and aliphatic CH groups to the attenuation at 1550 nm wavelength and low conversion rate of organic polymerization involving poor mechanical properties. This work treats on the design of a new generation of hybrid materials with a very high reactivity and low amount of groups involved in the attenuation. We have chosen vinyl ether function as reactive organic part for her highest polymerization rate via cationic way. The new synthesized molecule is 4-vinylether phenyltriethoxysilane. Sol–gel kinetic reactions were monitored by liquid 29Si-NMR spectroscopy. In order to obtain the highest reactive multifunctional oligomers and the lowest OH groups, hydrolysis and polycondensation reactions were followed as a function of time, temperature and pH of the water involved in the hydrolysis conditions. Finally, we show the feasibility to microstructure films deposited with this sol.

Deep ultra-violet semiconductor lasers have numerous applications for optical storage and biochemistry. Many strategies based on nitride heterostructures and adapted substrates have been investigated to develop efficient active layers in this spectral range, starting with AlGaN quantum wells on AlN substrates and more recently sapphire and SiC substrates. Here we report an efficient and simple solution relying on binary GaN/AlN quantum wells grown on a thin AlN buffer layer on a silicon substrate. This active region is embedded in microdisk photonic resonators of high quality factors and allows the demonstration of a deep ultra-violet microlaser operating at 275 nm at room temperature under optical pumping, with a spontaneous emission coupling factor β = (4 ± 2) 10−4. The ability of the active layer to be released from the silicon substrate and to be grown on silicon-on-insulator substrates opens the way to future developments of nitride nanophotonic platforms on silicon.

We have studied 4 He confined in a 95% porosity silica aerogel in the vicinity of the bulk liquid gas critical point. Both thermodynamic measurements and light scattering experiments were performed to probe the effect of a quenched disorder on the liquid gas transition, in relation with the Random Field Ising Model (RFIM). We find that the hysteresis between condensation and evaporation present at lower temperatures disappears at a temperature T ch between 25 and 30 mK below the critical point. Slow relaxations are observed for temperatures slightly below T ch , indicating that some energy barriers, but not all, can be overcome. Above T ch , no density step is observed along the (reversible) isotherms, showing that the critical behavior of the equilibrium phase transition in presence of disorder, if it exists, is shifted to smaller temperatures, where it cannot be observed due to the impossibility to reach equilibrium. Above T ch , light scattering exhibits a weak maximum close to the pressure where the isotherm slope is maximal. This behavior can be accounted for by a simple model incorporating the compression of 4 He close to the silica strands., Comment: 6 pages

International audience

Spin noise spectroscopy is an optical technique which can probe spin resonances non-perturbatively. First applied to atomic vapours, it revealed detailed information about nuclear magnetism and the hyperfine interaction. In solids, this approach has been limited to carriers in semiconductor heterostructures. Here we show that atomic-like spin fluctuations of Mn ions diluted in CdTe (bulk and quantum wells) can be detected through the Kerr rotation associated to excitonic transitions. Zeeman transitions within and between hyperfine multiplets are clearly observed in zero and small magnetic fields and reveal the local symmetry because of crystal field and strain. The linewidths of these resonances are close to the dipolar limit. The sensitivity is high enough to open the way towards the detection of a few spins in systems where the decoherence due to nuclear spins can be suppressed by isotopic enrichment, and towards spin resonance microscopy with important applications in biology and materials science., Coupling an atomic vapour to the polarization of light has enabled the creation of spin squeezed and entangled atomic states. Here, the authors realize a solid-state approach by adapting spin noise spectroscopy to probe the spin of manganese ions in cadmium telluride.

The nitrogen-vacancy (NV) color center in diamond is an atom-like system in the solid-state which specific spin properties can be efficiently used as a sensitive magnetic sensor. An external magnetic field induces Zeeman shifts of the NV center levels which can be measured using Optically Detected Magnetic Resonance (ODMR). In this work, we exploit the ODMR signal of an ensemble of NV centers in order to quantitatively map the vectorial structure of a magnetic field produced by a sample close to the surface of a CVD diamond hosting a thin layer of NV centers. The reconstruction of the magnetic field is based on a maximum-likelihood technique which exploits the response of the four intrinsic orientations of the NV center inside the diamond lattice. The sensitivity associated to a 1 {\mu}m^2 area of the doped layer, equivalent to a sensor consisting of approximately 10^4 NV centers, is of the order of 2 {\mu}T/sqrt{Hz}. The spatial resolution of the imaging device is 400 nm, limited by the numerical aperture of the optical microscope which is used to collect the photoluminescence of the NV layer. The versatility of the sensor is illustrated by the accurate reconstruction of the magnetic field created by a DC current inside a copper wire deposited on the diamond sample., Comment: 11 pages, 5 figures, figure 4 added, results unchanged

International audience; We use dynamic light scattering to investigate the effects of charge polydispersity and chargeresidence time on the dynamics of a micellar system. While in the corresponding uncharged system onlyone exponential relaxation is observed, two relaxation modes are seen when charging the micelles byadding charged co-surfactant molecules with a long residence time. We attribute the existence of thesetwo relaxation modes to the combined effect of size polydispersity and charge polydispersity, i.e. frozenfluctuations of the number of charges per micelle. Further support to this scenario is provided by controlexperiments on a similar charged system, but where the charge residence time is short compared to thetime scales probed by dynamic light scattering. Here, charge polydispersity is effectively suppressed dueto the rapid exchange of charged molecules between micelles and only one single relaxation mode is seen,thereby demonstrating the key role of frozen charge fluctuations in the complex dynamics of our micellarsystem.

The shape and interactions between model microemulsion droplets (R = 8.2 nm, polydispersity 20%) either decorated with hydrophilic-hydrophobic diblock (PEO-m: C12H25-(EO)n, MPEO = 5.2 kg/mol), or with telechelic triblock copolymers (PEO-2m: C12H25-(EO)2n-C12H25 , MPEO = 10.4 kg/mol) have been studied by small angle neutron scattering (SANS). The results as a function of droplet and copolymer concentration have been compared to the reference case of the bare microemulsion. Using Porod representations, the average bare droplet size was found to be independent of microemulsion concentration in the range studied here, up to some 13%v. Upon addition of copolymer (from r=0 to 30 hydrophobic stickers per droplet), the average droplet radius was unaffected. The interactions between bare and decorated droplets have been analyzed using the structure factor S(q), at first in a model-free way based on its low-q limit S(q→0). This analysis provides clear evidence on the concentration-dependent repulsive or attractive nature of the contributions to the pair droplet-droplet pair potential of the copolymers. Model pair potentials describing the steric repulsions and attractions by copolymer bridging are used to describe the low-q behavior of the structure factor based on an integral equation approach, giving a quantitative estimate of the range and amplitude of the potentials. Moreover, they provide an explanation for the observed transient clustering in terms of a shallow minimum of the total potential.

International audience; Droplets and bubbles coated by a protective armour of particles find numerous applications in encapsulation, stabilization of emulsions and foams, and flotation techniques. Here we study the role of a body force, such as in flotation, as a means of continuous encapsulation by particles. We use dense particles, which self-assemble into rafts, at oil-water interfaces. We show that these rafts can be spontaneously or controllably destabilized into armoured oil-in- water droplets, which highlights a possible role for common granular materials in environ- mental remediation. We further present a method for continuous production and discuss the generalization of our approach towards colloidal scales.

International audience; Porous silicon microcavity (PSiMc) structures were used to immobilize photosynthetic reaction center (RC) purified from the purple bacterium Rhodobacter sphaeroides R-26. Two different binding methods were compared by specular reflectance measurements. Structural characterization of PSiMc was performed by Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). The activity of the immobilized RC was checked by measuring the visible absorption spectra of the externally added electron donor, mammalian cytochrome c. PSi/RC complex was found to oxidize the cytochrome c after every saturating Xe flash, indicating the accessibility of specific surface binding sites on the immobilized RC, for the external electron donor. This new type of bio-nanomaterial is considered as an excellent model for new generation applications of silicon based electronics and biological redox systems.

We show that the dark matter (DM) could be a light composite scalar $\eta$, emerging from a TeV-scale strongly-coupled sector as a pseudo Nambu-Goldstone boson (pNGB). Such state arises naturally in scenarios where the Higgs is also a composite pNGB, as in $O(6)/O(5)$ models, which are particularly predictive, since the low-energy interactions of $\eta$ are determined by symmetry considerations. We identify the region of parameters where $\eta$ has the required DM relic density, satisfying at the same time the constraints from Higgs searches at the LHC, as well as DM direct searches. Compositeness, in addition to justify the lightness of the scalars, can enhance the DM scattering rates and lead to an excellent discovery prospect for the near future. For a Higgs mass $m_h\simeq 125$ GeV and a pNGB characteristic scale $f \lesssim 1$ TeV, we find that the DM mass is either $m_\eta \simeq 50-70$ GeV, with DM annihilations driven by the Higgs resonance, or in the range 100-500 GeV, where the DM derivative interaction with the Higgs becomes dominant. In the former case the invisible Higgs decay to two DM particles could weaken the LHC Higgs signal., Comment: 19 pages + appendices, 16 figures. v2: minor changes. v3: version published in JHEP

The concept of THz detection based on excitation of plasma waves in two-dimensional electron gas in Si FETs is one of the most attractive ones, as it makes possible the development of the large-scale integrated devices based on a conventional microelectronic technology including on-chip antennas and readout devices integration. In this work we report on investigations of Terahertz detectors based on low-cost silicon technology field effect transistors. We show that detectors, consisting of a coupling antenna and a n-MOS field effect transistor as rectifying element, are efficient for THz detection and imaging. We demonstrate that in the atmospheric window around 300 GHz, these detectors can achieve a record noise equivalent power below 10 pW/Hz0.5 and a responsivity above 90 kV/W once integrated with on-chip amplifier. We show also that they can be used in a very wide frequency range: from ∼0.2 THz up to 1.1 THz. THz detection by Si FETs pave the way towards high sensitivity silicon technology based focal plane arrays for THz imaging.

Micro-Raman and micro-transmission imaging experiments have been done on epitaxial graphene grown on the C- and Si-faces of on-axis 6H-SiC substrates. On the C-face it is shown that the SiC sublimation process results in the growth of long and isolated graphene ribbons (up to 600 μm) that are strain-relaxed and lightly p-type doped. In this case, combining the results of micro-Raman spectroscopy with micro-transmission measurements, we were able to ascertain that uniform monolayer ribbons were grown and found also Bernal stacked and misoriented bilayer ribbons. On the Si-face, the situation is completely different. A full graphene coverage of the SiC surface is achieved but anisotropic growth still occurs, because of the step-bunched SiC surface reconstruction. While in the middle of reconstructed terraces thin graphene stacks (up to 5 layers) are grown, thicker graphene stripes appear at step edges. In both the cases, the strong interaction between the graphene layers and the underlying SiC substrate induces a high compressive thermal strain and n-type doping., We greatly acknowledge for partial support the EC through the RTN "ManSiC" Project (Grant MRTN-CT-2006-035735) and the French ANR through the Graph-SiC Project (Grant No. ANR-07-Blanc-0161). Finally, one of us (N.C.) acknowledges the Spanish Government for a Grant "Juan de la Cierva 2006" during his stay in Barcelona

Background Most dental implant systems are presently made of two pieces: the implant itself and the abutment. The connection tightness between those two pieces is a key point to prevent bacterial proliferation, tissue inflammation and bone loss. The leak has been previously estimated by microbial, color tracer and endotoxin percolation. Methods A new nitrogen flow technique was developed for implant-abutment connection leakage measurement, adapted from a recent, sensitive, reproducible and quantitative method used to assess endodontic sealing. Results The results show very significant differences between various sealing and screwing conditions. The remaining flow was lower after key screwing compared to hand screwing (p = 0.03) and remained different from the negative test (p = 0.0004). The method reproducibility was very good, with a coefficient of variation of 1.29%. Conclusions Therefore, the presented new gas flow method appears to be a simple and robust method to compare different implant systems. It allows successive measures without disconnecting the abutment from the implant and should in particular be used to assess the behavior of the connection before and after mechanical stress.