51. Engineered CoS/Ni3S2 Heterointerface Catalysts Grown Directly on Carbon Paper as an Efficient Electrocatalyst for Urea Oxidation
- Author
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Saba A. Aladeemy, Prabhakarn Arunachalam, Abdullah M. Al-Mayouf, P. N. Sudha, A. Rekha, A. Vidhya, J. Hemapriya, Srinivasan Latha, P. Supriya Prasad, S. Pavithra, Raja Arunadevi, and Salah T. Hameed
- Subjects
electrodeposition ,heterojunction ,nickel-based chalcogenide electrocatalysts ,UORs ,Chemical technology ,TP1-1185 ,Chemistry ,QD1-999 - Abstract
Developing highly efficient and stable electrocatalysts for urea electro-oxidation reactions (UORs) will improve wastewater treatment and energy conversion. A low-cost cobalt sulfide-anchored nickel sulfide electrode (CoS/Ni3S2@CP) was synthesized by electrodeposition in DMSO solutions and found to be highly effective and long-lasting. The morphology and composition of catalyst surfaces were examined using comprehensive physicochemical and electrochemical characterization. Specifically, CoS/Ni3S2@CP electrodes require a potential of 1.52 volts for a 50 mA/cm2 current, confirming CoS in the heterointerface CoS/Ni3S2@CP catalyst. Further, the optimized CoS/Ni3S2@CP catalyst shows a decrease of 100 mV in the onset potential (1.32 VRHE) for UORs compared to bare Ni3S2@CP catalysts (1.42 VRHE), demonstrating much greater performance of UORs. As compared to Ni3S2@CP, CoS/Ni3S2@CP exhibits twofold greater UOR efficiency as a result of a larger electroactive surface area. The results obtained indicate that the synthetic CoS/Ni3S2@CP catalyst may be a favorable electrode material for managing urea-rich wastewater and generating H2.
- Published
- 2024
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