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In this paper an approach for analysing the potential for implementation of different technology pathways for the European pulp and paper industry (PPI) is presented. The approach is based on detailed technical research and aggregates the knowledge from previous studies to incorporate the whole European PPI. Thus, the potential for different technology pathways can be estimated on a European level whilst still considering important characteristics of individual mills. The usefulness of the approach was exemplified by applying it to a case study of the potential for introduction of carbon capture and storage (CCS) within the European PPI. The results from the case study show that for the European PPI, CCS has an up-hill road in order to be a viable, large scale alternative for reduction of CO2 emissions. If CCS is to be introduced in large scale within the European PPI, large biomass-based point sources of CO2 emissions need to be included when planning for CCS infrastructure and also the infrastructure needs to be built out for clusters emitting <20 MtCO2/yr. [ABSTRACT FROM AUTHOR]

Many studies anticipate that carbon capture and sequestration (CCS) will be essential to decarbonizing the U.S. economy. However, prior work has not estimated the time required to develop, approve, and implement a geologic sequestration site in the United States. We generate such an estimate by identifying six clearance points that must be passed before a sequestration site can become operational. For each clearance point (CP), we elicit expert judgments of the time required in the form of probability distributions and then use stochastic simulation to combine and sum the results. We find that, on average, there is a 90% chance that the time required lies between 5.5 and 9.6 y, with an upper bound of 12 y. Even using the most optimistic expert judgements, the lower bound on time is 2.7 y, and the upper bound is 8.3 y. Using the most pessimistic judgements, the lower bound is 3.5 y and the upper bound is 19.2 y. These estimates suggest that strategies must be found to safely accelerate the process. We conclude the paper by discussing seven potential strategies. [ABSTRACT FROM AUTHOR]

This paper is written in response to the paper "How green is blue hydrogen?" by R. W. Howarth and M. Z. Jacobson. It aims at highlighting and discussing the method and assumptions of that paper, and thereby providing a more balanced perspective on blue hydrogen, which is in line with current best available practices and future plant specifications aiming at low CO2 emissions. More specifically, in this paper, we show that: (i) the simplified method that Howarth and Jacobson used to compute the energy balance of blue hydrogen plants leads to significant overestimation of CO2 emissions and natural gas (NG) consumption and (ii) the assumed methane leakage rate is at the high end of the estimated emissions from current NG production in the United States and cannot be considered representative of all‐NG and blue hydrogen value chains globally. By starting from the detailed and rigorously calculated mass and energy balances of two blue hydrogen plants in the literature, we show the impact that methane leakage rate has on the equivalent CO2 emissions of blue hydrogen. On the basis of our analysis, we show that it is possible for blue hydrogen to have significantly lower equivalent CO2 emissions than the direct use of NG, provided that hydrogen production processes and CO2 capture technologies are implemented that ensure a high CO2 capture rate, preferably above 90%, and a low‐emission NG supply chain. [ABSTRACT FROM AUTHOR]

In order to achieve greenhouse gas neutrality, hydrogen generated from renewable sources will play an important role. Additionally, as underlined in the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC), new technologies to remove greenhouse gases from the atmosphere are required on a large scale. A novel concept for hydrogen production with net negative emissions referred to as HyBECCS (Hydrogen Bioenergy with Carbon Capture and Storage) combines these two purposes in one technological approach. The HyBECCS concept combines biohydrogen production from biomass with the capture and storage of biogenic carbon dioxide. Various technology combinations of HyBECCS processes are possible, whose ecological effects and economic viability need to be analyzed in order to provide a basis for comparison and decision‐making. This paper presents fundamentals for the techno‐economic and environmental evaluation of HyBECCS approaches. Transferable frameworks on system boundaries as well as emission, cost, and revenue streams are defined and specifics for the application of existing assessment methods are elaborated. In addition, peculiarities concerning the HyBECCS approach with respect to political regulatory measures and interrelationships between economics and ecology are outlined. Based on these considerations, two key performance indicators (KPIs) are established, referred to as levelized cost of carbon‐negative hydrogen (LCCNH) and of negative emissions (LCNE). Both KPIs allow deciding whether a specific HyBECCS project is economically viable and allows its comparison with different hydrogen, energy provision, or negative emission technologies (NETs). Carbon‐negative hydrogen production referred to as HyBECCS (Hydrogen Bioenergy with Carbon Capture and Storage) combines hydrogen production from biomass with the capture and storage of biogenic carbon dioxide. Various technology combinations of HyBECCS processes are possible, whose ecological effects and economic viability need to be analysed. This paper presents fundamentals for the techno‐economic and environmental evaluation of HyBECCS approaches. Transferable frameworks on system boundaries as well as emission, cost and revenue streams are defined and specifics for the application of existing assessment methods are elaborated. [ABSTRACT FROM AUTHOR]

Carbon Capture Utilization and Storage (CCUS) is a set of technologies aimed at capturing carbon dioxide (CO2) emissions from point-source emitters to either store permanently or use as a feedstock to produce chemicals and fuels. In this paper, the potential benefits of CCUS integration into the energy supply sector are evaluated from a Life Cycle Assessment (LCA) perspective by comparing two different routes for the CO2 captured from a natural gas combined cycle (NGCC). Both the complete storage of the captured CO2 and its partial utilization to produce dimethyl ether are investigated. Moreover, the assessment is performed considering the region-specific features of two of the largest CO2 emitters in Europe, namely Italy and Poland. Results shows that the complete storage of the captured CO2 reduces Global Warming Potential (GWP) by ~89% in Italy and ~97%, in Poland. On the other hand, the partial utilization of CO2 to produce dimethyl ether leads to a decrease of ~58% in Italy and ~68% in Poland with respect to a comparable reference entailing conventional dimethyl ether production. A series of environmental trade-offs was determined, with all the investigated categories apart from GWP showing an increase, mainly connected with the higher energy requirements of CCUS processes. These outcomes highlight the need for a holistic-oriented approach in the design of novel implemented configurations to avoid burden shifts throughout the value chain. [ABSTRACT FROM AUTHOR]

Capillary trapping of gas in porous media is important for many processes such as oil recovery and gas geo-sequestration. Foam can mitigate gravity override and viscous fingering of gas by reducing its relative permeability through gas trapping. However, there are limited studies dedicated to understanding how foam assists in gas trapping, the best mode of foam injection for trapping, and its application in geo-sequestration. This paper uses an initial–residual saturation analysis to investigate foam-assisted capillary trapping during the surfactant alternating gas (SAG) injection process in saline aquifers. More specifically, we studied the effects of pore geometric properties, in situ generated foam, and surfactant concentration on gas trapping efficiency and final residual gas saturation, Sgr. First, NMR surface relaxometry measurements were carried out on the rock samples to indicate the mean pore sizes of the rocks. A series of core flooding tests, equipped with resistivity measurements, were then conducted using single-cycle gas injection followed by water injection, water alternating gas (WAG), and SAG injection methods to identify which mode of injection results in the most trapped gas. The results showed that the SAG method had a better sweep efficiency and trapped more gas than other methods. The initial–residual (IR) gas saturation relationships from SAG data measured from several rock samples were then analyzed using Land's trapping model. Gas trapping efficiency (indicated by Land's coefficient, C) and residual gas were also found to increase in rocks with large average pore sizes and with increasing surfactant concentration. However, increasing the surfactant concentration above a certain limit did not cause further improvement in the trapping coefficient but only increased the Sgr. The results also showed that high values of surfactant concentrations might cause a slight reduction in the foam's apparent viscosity, which then reduces the initial gas saturation, and consequently, Sgr. Finally, a linear relationship between the Sgr and the measured log mean of surface relaxation times (T2LM) was obtained, and two correlations were proposed. Therefore, the NMR measurements can be considered a reliable prediction method for Sgr in porous media. [ABSTRACT FROM AUTHOR]

The successful and fast development and deployment of renewable energy and greenhouse gas reduction technologies is a continuing and structural challenge. The deployment of these technologies is slowed down and sometimes even stalled due to societal challenges like public resistance, lack of appropriate policy and regulations, unsolid business cases and uncertainty concerning the impact on the environment. In this paper we elaborate on societal aspects that influence technology development and deployment and introduce the societal embeddedness level (SEL) framework. Building upon the technology readiness level (TRL), the SEL framework enables the assessment of the current level of societal embeddedness of energy technologies in order to identify the societal aspects which need to be taken into account to accelerate deployment of energy technologies. The SEL framework takes into account four societal dimensions (impact on the environment, stakeholder involvement, policy and regulations, and market and financial resources) and four stages of technology development (exploration, development, demonstration and deployment) that are linked to the TRL. The SEL framework has been elaborated for CCS technologies and is being applied to the monitoring of geological CO2 storage by the ACT II project DigiMon (Digital Monitoring of CO2 storage projects). DigiMon is an ACT second call project, funded by the national funding agencies in the period September 2019–August 2022. [ABSTRACT FROM AUTHOR]

This paper explores the potential role of bioenergy coupled to carbon dioxide (CO2) capture and storage (BECCS) in long-term global scenarios. We first validate past insights regarding the potential use of BECCS in achieving climate goals based on results from 11 integrated assessment models (IAMs) that participated in the 33rd study of the Stanford Energy Modeling Forum (EMF-33). As found in previous studies, our results consistently project large-scale cost-effective BECCS deployment. However, we also find a strong synergistic nexus between CCS and biomass, with bioenergy the preferred fuel for CCS as the climate constraint increases. Specifically, the share of bioenergy that is coupled to CCS technologies increases since CCS effectively enhances the emissions mitigation capacity of bioenergy. For the models that include BECCS technologies across multiple sectors, there is significant deployment in conjunction with liquid fuel or hydrogen production to decarbonize the transportation sector. Using a wide set of scenarios, we find carbon removal to be crucial to achieving goals consistent with 1.5 °C warming. However, we find earlier BECCS deployment but not necessarily greater use in the long-term since ultimately deployment is limited by economic competition with other carbon-free technologies, especially in the electricity sector, by land-use competition (especially with food) affecting biomass feedstock availability and price, and by carbon storage limitations. The extent of BECCS deployment varies based on model assumptions, with BECCS deployment competitive in some models below carbon prices of 100 US$/tCO2. Without carbon removal, 2 °C is infeasible in some models, while those that solve find similar levels of bioenergy use but substantially greater mitigation costs. Overall, the paper provides needed transparency regarding BECCS' role, and results highlight a strong nexus between bioenergy and CCS, and a large reliance on not-yet-commercial BECCS technologies for achieving climate goals. [ABSTRACT FROM AUTHOR]

Simple Summary: With the growing population of cancer survivors, survivorship management has become central for both medical professionals and patients. This entails, among other factors, empowering survivors with the necessary knowledge about their medical history and their risk for late effects, because informed patients make better lifestyle and health choices. Although a lack of information and low satisfaction with information received are fairly well-documented phenomena among childhood cancer survivors, less is known about survivors of young adult cancer and populations of long-term survivors no longer engaged in follow-up care. This paper aims to fill this gap by investigating information provision in childhood, adolescent and young adult cancer survivors. Background: Knowledge of medical history and late effects is central in modern survivorship management, especially for long-term childhood, adolescent and young adult cancer survivors' (CAYACS) with long life expectancy rates and high risks of late effects. Identifying information and knowledge gaps is, therefore, important. As part of the population-based NOR-CAYACS study, we investigated the following: (1) written information received about their disease and treatment, and any information about late effects; (2) satisfaction with this information and associated factors; (3) knowledge about late effects and factors associated with low knowledge of specific late effects. Material and methods: A questionnaire-based survey (Nor-CAYACS) was mailed to 5361 CAYACS (childhood cancers, breast and colorectal cancer, acute lymphatic leukemia, non-Hodgkin lymphoma and malignant melanoma) identified by the Cancer Registry of Norway (CRN). Of these, 2018 answered questions about disease and late effects information and knowledge. Exposure variables were extracted from the questionnaire and CRN. Unfortunately, it was not possible to stratify by treatment in the analyses. We ran descriptive statistics for comparisons and logistic regressions to identify factors associated with outcomes of interest. Results: Overall, 50% to 60% of survivors reported not having received written information about their disease and treatment, or any information about late effects. There was a large variation in reported knowledge across 17 late effects. Lower levels of knowledge were associated with male sex, lower education and poorer health literacy in multivariable regression models. Conclusions: Knowledge of cancer history and risks of late effects is essential for effective self-management, yet significant information and knowledge gaps were reported in this population-based sample of long-term CAYACS. Systematic approaches to making (up-to-date) information available to long-term survivors are needed to ensure that information does not get lost in medical and life transitions. [ABSTRACT FROM AUTHOR]

This study summarizes the OASIS (Overburden Analysis and Seal Integrity Study for CO 2 Sequestration in the North Sea) project that focuses on assessing the containment risks associated with the geological carbon sequestration (CCS) of the Northern Lights project. CCS is viewed as one of the most effective solutions for reducing carbon emissions, as it captures carbon dioxide from point sources and permanently stores it in suitable geological formations. However, injecting CO 2 into the subsurface may have mechanical consequences, including fault reactivation, top seal fracturing, surface heave, etc. This study proposes an interdisciplinary workflow to characterize the caprock, faults, and overburden associated with CCS projects in the Horda Platform area, to improve injection-induced containment risk assessment. Our findings show that the proposed workflows and tools effectively characterize stress-related mechanical hazards. However, due to the complex nature of rocks, it is challenging to evaluate the top seal integrity using a single method. Therefore, the proposed interdisciplinary approach is more effective for any fluid injection site's characterization, given the complex nature of the subsurface and its behavior under injection-induced stress changes. This research paper adds knowledge about the top seal integrity assessment and the reliability of injected CO 2 , making CCS projects more reliable and safer. Although this study focuses on the northern North Sea, the proposed methods are equally applicable globally to characterize subsurface CO 2 storage sites. Apart from CCS projects, these research results can benefit other subsurface injection projects, such as water injection for reservoir management, wastewater injection for disposal, hydrogen storage, and hydraulic fracturing for unconventional hydrocarbon resources. • Brittleness indices property can reflect the rock integrity. • Seismic inverted properties resolve the data limitation issues within the overburden intervals. • An analytical structural reliability model can help evaluate the top sealing risks quickly. • Overburden interval rock properties must be realistic in any 3D field-scale geological models. • An interdisciplinary workflow is required for subsurface CCS site characterization. [ABSTRACT FROM AUTHOR]

Considerable efforts are made in order to reduce the power sector's carbon footprint. Paired with a realization that thermal power plants are likely to play a significant role during the transitional period towards a 100% sustainable energy system, carbon capture and storage (CCS) retrofit is becoming a growingly important consideration for a number of power plant operators. This paper analyzes the possibility of retrofitting a coal-fired power plant based in Croatia. A techno-economic model of the proposed unit is built setting up key elements of the technological solution and determining their capital and operational costs. Both a sensitivity analysis and a market analysis are conducted in order to best evaluate the feasibility of the CCS retrofit project. Particularities of South East Europe power sectors are considered utilizing an optimization software. Special consideration is given to the influence of the EU emission trading scheme (ETS) on CCS projects. Further research focuses on the main factors influencing the potential implementation of CCS. Key recommendations that might aid CCS deployment are outlined signaling stronger government support, stable regulatory framework, and market incentives as crucial factors able to foster CCS development. Considering the project in the study, analyses showed that, although technically feasible, CCS retrofit is currently not a financially viable option. Without a stable regulatory framework able to guarantee an adequate supporting scheme, the project is not market competitive. It is important to note that the economic gap of CCS retrofit has been considerably reduced during the past years. [ABSTRACT FROM AUTHOR]

Summary: Coal is the most abundant energy source, and around 40% of the world's electricity is produced by coal combustion. The emission generated through it put a constraint on power production by coal combustion. There is a need to reduce the emissions generated through it to utilize the enormous energy of coal for power production. Detailed understanding of various aspects of coal combustion is required to reduce the emissions from coal‐fired furnaces. The aim of present paper is to review various aspects of pulverized coal combustion such as oxy‐fuel combustion, co‐combustion of coal and biomass, emissions from pulverized coal furnaces, ash formation and deposition, and carbon capture and sequestration (CCS) technologies to outline the progress made in these aspects. Both experimental and numerical aspects are included in this review. This review also discusses the thermodynamic aspects of the combustion process. Furthermore, the effect of various submodels such as devolatilization models, char combustion models, radiation models, and turbulent models on the process of pulverized coal combustion has been investigated in this paper. [ABSTRACT FROM AUTHOR]

Abstract Carbon capture and storage (CCS) is now known to be an effective way to reduce greenhouse gas emissions especially CO 2 to the atmosphere. Amino acid salt (AAS) solutions are regarded as promising CO 2 absorbents compared to traditional amine solutions, as they are environmentally being with lower evaporation as well as fewer degradation issues. This paper is intended to review recent developments in CO 2 capture using AASs. The thermodynamics and kinetics of CO 2 and different AASs are illustrated in detail. We will also discuss the blended solutions containing AASs in terms of applications and absorption or regeneration performance. Additionally, we will present specific directions for future research on CO 2 -AAS systems. This paper could provide a guideline for effective carbon capture by new absorbents. Highlights • A comprehensive review of amino acid salts fundamentals is introduced. • Detailed thermodynamics and kinetics between CO 2 and various amino acid salts are discussed. • The developments of CO 2 capture by amino acid salts in the fields of biogas upgrading, natural gas and flue gas purification are illustrated. [ABSTRACT FROM AUTHOR]

The targets of limiting global warming levels below 2°C or even 1.5°C set by Paris Agreement heavily rely on bioenergy with carbon capture and storage (BECCS), which can remove carbon dioxide in the atmosphere and achieve net zero greenhouse gas (GHG) emission. Biomass and coal co‐firing with CCS is one of BECCS technologies, as well as a pathway to achieve low carbon transformation and upgrading through retrofitting coal power plants. However, few studies have considered co‐firing ratio of biomass to coal based on each specific coal power plant's characteristic information such as location, installed capacity, resources allocation, and logistic transportation. Therefore, there is a need to understand whether it is worth retrofitting any individual coal power plant for the benefit of GHG emission reduction. It is also important to understand which power plant is suitable for retrofit and the associated co‐firing ratio. In order to fulfill this gap, this paper develops a framework to solve these questions, which mainly include three steps. First, biomass resources are assessed at 1 km spatial resolution with the help of the Geography Information Science method. Second, by setting biomass collection points and linear program model, resource allocation and supply chain for each power plants are complete. Third, is by assessing the life‐cycle emission for each power plant. In this study, Hubei Province in China is taken as the research area and study case. The main conclusions are as follows: (a) biomass co‐firing ratio for each CCS coal power plant to achieve carbon neutral is between 40% and 50%; (b) lower co‐firing ratio sometimes may obtain better carbon emission reduction benefits; (c) even the same installed capacity power plants should consider differentiated retrofit strategy according to their own characteristic. Based on the results and analysis above, retrofit suggestions for each power plant are made in the discussion. [ABSTRACT FROM AUTHOR]

• The risk of injectivity loss during CCS operations observed in lab scale is also applicable to field scale. • Several mechanisms can impact the injectivity, due to the potential of reducing permeability, especially in cases with lower permeability reservoirs. • Non-Darcy effect showed no impact on well injectivity for a wide range of injection rates. • Negligible effect of the trapped gas trapped on the CO 2 injectivity. This paper aims to review the main mechanisms identified in the lab scale that impact CO 2 injectivity during CCS projects in saline aquifers and evaluate their relevance in field scale through numerical models. They may include water vaporization, salt precipitation in the dry-out zone, mineral dissolution, which can result in fines migration in porous media, CO 2 hydrate formation, and effects of non-Darcy flow. All those mechanisms are observed from lab experiments and significantly impact reservoir petrophysical properties such as porosity and permeability and consequently on injectivity in field operations. This study includes these mechanisms in numerical models to quantify their impacts on the CO 2 injectivity well index in synthetic and real field cases. In addition, a sensitivity analysis was performed for a range of brine compositions of seawater and higher salinities. This analysis shows an additional injectivity reduction as the salinity increases due to the halite scale, in agreement with the lab data from the literature. Another dependence evaluated in this study is when the ratio between capillary and viscous forces is decreased, reducing the injectivity. Additionally, when mineral reaction dissolution is considered in our modeling, it is possible to observe two occurring competitive phenomena, where the mineral dissolution can compensate for part of the injectivity loss due to salt deposition in the dry-out zone. That is especially relevant when the reservoir rock matrix is rich in reactive minerals, such as calcite and dolomite. However, mineral dissolution may lead to fines, and the risk of fines migration can lower the injectivity by at least 10% within five years of CO 2 injection, according to our results. The mineral dissolution is also considered in these calculations, and the loss in injectivity is the net result of dissolution and fines migration. The gain in porosity–permeability as the results of mineral dissolution was modeled using the Kozeny-Carman equation. The results show the importance of considering the uncertainty of injectivity loss in CCS projects, where the amount of CO 2 captured for storage must be injected often with no other alternatives, highlighting the need to provide flexibility in project planning to deal with such risks. [ABSTRACT FROM AUTHOR]

This paper presents the results of chemical looping combustion (CLC) research. Nowadays, CLC is one of the best prospective combustion technologies, because it enables the production of a concentrated carbon dioxide (CO 2 ) stream, following water condensation, without any energy penalty for its separation. The objective of this work was to study chemical looping reaction performance with the application of novel perovskite-type oxygen carriers (OCs). Sr(Fe 1-x Cu x )O 3-δ family members were tested for hydrogen combustion for power generation purposes. Sr(Fe 1-x Cu x )O 3-δ , which is a perovskite-type oxide, was prepared using the calcination method, where x = 0, 0.1 and 0.33. Reactivity tests were performed using a thermogravimetric analyser (TGA, Netzsch STA 409 PG Luxx) under isothermal conditions in multiple reduction–oxidation cycles. Both the temperature (600–800 °C) and number of redox cycles (five cycles) effects on the reaction performance of recently developed OC samples were evaluated in the study. TGA data were used for the assessment of the oxygen transport capacity value, redox reaction rates and stability. Sr(Fe 1-x Cu x )O 3-δ showed an excellent stable chemical looping performance. The changing of oxygen content (3.8–4.86 wt%) occurred within approximately 2 min, with the chemical properties of the material maintained during the cycling combustion tests. In addition, new SrFeO 3-δ OCs, doped with copper (Cu) perovskite-type materials, were analysed using multiple methods: X-ray powder diffraction (XRD); scanning electron microscopy (SEM); surface area by Brunauer–Emmett–Teller (BET) method; and melting behaviour study. In terms of physical properties, the new OCs can resist both high CLC process temperatures and mechanical forces, which are essentially useful. The analysis showed that Sr(Fe 1-x Cu x )O 3-δ carriers performed at extremely high melting temperatures (>1280 °C). Results of crushing strength testing showed that developed materials had a pronounced mechanical resistivity with a crushing strength higher than 1 N and will perform well in fluidized beds (4.31–6.23 N). In this paper, it was demonstrated that known mixed oxygen-ionic and electronic conducting membrane materials such as Sr(Fe 1-x Cu x )O 3-δ might also be applied as oxygen carriers. Overall results demonstrated Fe-Cu-based perovskites might be successfully used as OCs in the chemical looping combustion process. [ABSTRACT FROM AUTHOR]

Traditional technologies of carbon capture and storage (CCS) are being focused on capturing CO 2 in large-scale demonstrations, which has been proved to result in the high cost and energy penalty. Meanwhile, typical innovative measures, commonly defined as the second generation CCS technologies, elude conventional ones by integrating with solar energy and thus contributing to a more energy-efficient conversion of CO 2 . However, few reviews pay attention to thermodynamic processes and parameters of these novel technologies, and there is a lack of systematic evaluation and comparison among them. This paper firstly presents a guided tour on the state-of-art of typical and innovative CCS technologies integrated with solar energy. An overview on thermodynamic processes, including chemical reactions, operating conditions and efficiency indexes of five typical technologies is presented so that the current development level can be clarified. Since the high energy requirement and related operating cost are the main barriers to the application of existing CCS technologies, the minimum work and second-law efficiency are applied as the main indicators in the second part of this paper which relates to performance evaluation. In addition, the performance windows for innovative technologies are illustrated for the comparison of technological maturity. The results show that energy requirement of innovative CCS technologies from the flue gas is avg. 100–200 kJ/mol CO 2 and the second-law efficiency of them is only 5–12%. Therefore, the maturity and popularity of these novel technologies are still relatively low. But the well-integrated systems and diversified output of these technologies can benefit existing energy infrastructures in a long period. [ABSTRACT FROM AUTHOR]

Engineering efforts to handle contemporary energy supply challenges and mitigate pollutant emission lead towards more complicated systems. Power plants are supplementing with additional processing units, alternative production modes and higher level of automation. Wind and solar sources, biomass combustion, gasification, carbon capture and storage (CCS), and cogeneration have appeared as important players in the energy systems. The increasing complexity comprises a risk that the systems become less manageable and less stable than currently. Traditional steady-state engineering methods cannot fully address these challenges that are inherently dynamic in their nature. Dynamic process simulation appears as important tool to the systems design and optimisation tasks. A large variety of dynamic process modelling and simulation approaches has been presented recent years. This paper presents a brief review of methods and simulation packages that are generally applied for studying energy systems' transient behaviour. A CCS capable power plant is presented as an example of utilizing dynamic process simulation for virtual evaluation of a novel electricity production concept. The modelling was performed using two simulators Apros and Aspen Plus Dynamics, which were linked together for dynamic simulating the full chain of cryogenic oxygen distillation, oxy combustion, turbine islands and carbon dioxide purification and liquefaction operations. • Dynamic simulations for design and optimisation of contemporary energy systems have been reviewed. • A case study for evaluating oxy combustion CFB boiler cycle with carbon capturing is presented. • Co-simulation with two dynamic process simulation software: Apros and Aspen Plus Dynamics were shown. • Flexibility aspects of oxy combustion power plant are discussed. [ABSTRACT FROM AUTHOR]

The LNG market connects numerous export and import markets, and the global LNG trade has been growing steadily. Despite the availability of multiple alternatives, only a small fraction of this global cryogenic potential is currently utilized, and a negligible number of regasification terminals are equipped with cold energy recovery systems. This paper explores various options for recovering cold energy from LNG regasification processes including electricity production, refrigeration, cryogenic separation processes, CO 2 capture and liquefaction. The present study examines the industrial recovery options, proposing both conventional and innovative process schemes and analysing them in terms of their thermodynamic modelling and feasibility. Nine case studies were selected and simulated using Aspen Hysys software, considering material and energy balances. Specific energy consumptions are calculated, and an exergetic comparison methodology is adopted to provide a unified approach capable to embrace heterogeneous systems utilizing mechanical/electrical energy, thermal energy, and "chemical energy". The temperature profiles are examined, and sensitivity analyses are performed on key parameters. The integration of direct cooling and condensation brings high exergy efficiency of above 40% and economic advantages due to the absence of an external refrigeration cycle. Coupling regasification with CO 2 liquefaction reduces specific energy consumption by 53% compared to the conventional process. Similarly, in the case of an ethylene production plant, energy consumption is reduced by 95%. Simulations for electricity generation using an ORC cycle with LNG as the cold source achieve around 25% exergy efficiency, but the LCOE (Levelized Cost of Electricity) is attractive, ranging from 0.07 to 0.09 €/kWh. Integration with an Air Separation Unit (ASU) for cryogenic distillation leads to a 41% decrease in specific energy consumption. Further integration with Allam and cascade ORC cycles has been simulated. Globally, air separation shows exergy efficiencies of 37–38%, which is higher than the average 25% obtained from conventional thermodynamic cycles with low-temperature hot sources. Regarding cryogenic CO 2 capture, it exhibits lower specific energy consumption compared to traditional processes. The exergy efficiency is high at 22%, and the LCOP (Levelized Cost of CO2 Production) of 55 €/ton is attractive for carbon capture processes that can be coupled with regasification units and NG utilization (a.e. for hydrogen and electricity production). [ABSTRACT FROM AUTHOR]

This paper explores the adsorption behaviour of geomaterials in the framework of CO 2 sequestration in shallow level coal seams. Manometric adsorption experiments were carried out on two anthracite coal samples, two rock samples from East Irish Sea, MX80-bentonite, Speswhite kaolinite, dry, wet and biofilm-laden (Bascillus mojavensis -laden) sand at subcritical pressure range (up to 6.4 MPa) of isothermal condition at 298.15 K. The experiments were aimed to investigate the influence of the biogeological conditions of coal and caprock constitutions on CO 2 adsorption. At lower pressures, the moisture had an influence on the CO 2 adsorption on coal resulted in reduced adsorption capacity. At elevated pressures, the volume expulsion behaviour and coal-water interaction had an influence on the adsorption capacities of moist coal sample and resulted in comparable adsorption capacities to dry sample. The disparity in the adsorption capacities between the wet powdered and wet intact core samples showed that the results obtained with powder samples may not reflect the field conditions. Wet conditions and Bascillus mojavensis bacteria influenced the adsorption capacity of sand and showed CO 2 chemisorption capacity. The desorption isotherm pattern of wet and biofilm sand showed that the CO 2 was continuously adsorbed independent of the gas phase pressure. Among the clay minerals, bentonite had greater affinity towards CO 2. Despite the fact that the adsorption capacity of the cap rock is smaller than that of the coal samples, the experimental investigation with constituents of the cap rock provides insights into the effect of biogeological conditions of coal and rock sample constituents on CO 2 storage in coal seams. [ABSTRACT FROM AUTHOR]

CO 2 carriers are considered as a solution for CO 2 transport as a part of Carbon Capture and Storage. CO 2 carriers' design is similar to that of commercial liquefied gas carriers and core technology of liquefied gas carriers is to handle boil-off gas during voyages. This paper introduced newly developed CO 2 boil-off gas re-liquefaction processes making use of cold LNG fuel and investigated economic feasibility of newly developed processes by comparison with a conventional boil-off gas re-liquefaction process. New processes enabled considerable main equipment costs saving and additional fuel cost saving for re-liquefying boil-off gas. Simulation study results showed total amount of boil-off gas in a LNG fueled CO 2 carrier could be re-liquefied by LNG fuel consumed during the voyage and comparative cost assessment results demonstrated those newly developed processes could be applied into a LNG fueled CO 2 carrier with insignificant additional cost. The finding of this paper confirms those newly introduced processes are technically and commercially feasible at present and will contribute to growing the potential market of LNG as a marine fuel as well as commercializing CCS technology by providing more cost-effective solution for CO 2 shipping. [ABSTRACT FROM AUTHOR]

This paper investigates various alternatives for the application of CCS at a cement plant which is one of the focus site for CCS deployment in Norway. A matrix consisting of nine CCS alternative chains is analysed in order to quantify cost reduction potentials across the CCS value chain based on an in-house techno-economic assessment methodology and tool called iCCS. In particular, the paper quantifies the strong cost reduction potential of second generation capture technologies and transport technology selection. CO 2 EOR is also identified to have a strong potential to reduce the overall CCS cost, however the cost benefits are strongly dependent on the oil value and the considered EOR injection period. The impact of the inclusion of CO 2 capture and conditioning in the cost of cement shows that public financial support will be required to ensure that the plant remain competitive under current cement market price. Finally, comparison of the full-scale capture versus part-scale capture shows, in this case, that the economies of scale are nearly compensated by the additional steam cost, therefore limiting the interest for full-scale implementation. However, joint deployment with the two other CCS potential sites in Norway (Yara and Klemenstrud) may bring more synergies. [ABSTRACT FROM AUTHOR]

Abstract Integrating solar-thermal energy into the power plant with post-combustion carbon capture and storage can reduce the energy penalty derived from solvent regeneration. However, few metrics exist to evaluate the trade-off associated with technic, economic and ecological perspectives for different integration schemes of the three subsystems, namely the solar field, power plant and carbon capture system. This paper analysis five configurations of coal-fired power plant with and without solar field as well as CCS technology based on the resilience concept. Still at the budding stage, the status of resilience definitions and evaluation methods related to energy system is reviewed. The resilience level for five configurations of coal-fired power plant both with and without solar-field, together with the CCS system is measured, which takes into consideration five critical characteristics towards resilience: fossil fuel depletion potential (CADP), global warming potential (GWP), levelized cost of energy (LCOE), solar to electricity fraction and spare capacity. Results indicate that among all the configurations, the solar-assisted power generation CCS power plant with 90% capture rate shows the highest resilience level. However, the scheme which utilizes solar energy to assisted solvent regeneration, shows limited advantage in terms of resilience level due to high CADP and LCOE. Highlights • Resilience concept and evaluation studies concerning energy systems are reviewed. • A resilience index measure is proposed for solar-assisted CCS energy systems. • Five resilience indicators are covered. • The solar hybrid CCS power plant shows the highest resilience level [ABSTRACT FROM AUTHOR]

Abstract Gas chimneys are geological features that are associated with seal bypass systems. Knowledge of the capacity of the seal is important for the evaluation of the petroleum systems and Carbon Capture and Storage (CCS) studies. The seal is breached when the capillary pressure threshold is exceeded by the underlying buoyancy pressure. The chaotic seismic character that is generally associated with the gas chimneys has been studied previously to evaluate the origin and geometry of the chimneys. Seismic attributes have also been used to determine the character of the gas chimneys and the potential association of hydrocarbon fields. However, it is important to evaluate the sealing potential of the cap rock in the vicinity of the gas chimney. This paper demonstrates that the chimney can be used as a calibration point and, with the use of seismic attributes, variations of sealing capacity can be evaluated. Out of many existing seismic attributes, understanding the shale structure is crucial to narrow the search criteria for the right class of attributes. Using the most useful stream of seismic attributes, the average sealing potential of the Lakes Entrance Formation is estimated. The sealing capacity map across the field is then shown to help evaluate the prospectivity of the area of study and may upgrade subsequent play fairway maps. Highlights • Sealing potential of the Lakes Entrance Formation was investigated. • Applications of seismic attributes to predict sealing potential were tested. • Seismic Anisotropy and attributes show consistent results in predicting the sealing capacity. • The gas chimney was used as a calibration point for the seal failure. • All relevant attributes were used to set a prediction process for sealing potential. [ABSTRACT FROM AUTHOR]

The transboundary transportation of carbon dioxide (CO2) gives rise to international legal issues not faced in other standalone carbon capture and storage (CCS) projects or domestic projects. While the European Union CCS Directive establishes a framework for CCS, it does not address specifically the issue of transboundary transportation. This will require participating Member States to agree a statutory framework for CO2 transport, which addresses issues at the international, national and local levels of law. This paper considers several key issues for developing and resolving legal issues around ownership and risk for CO2 transportation, an area with limited research literature to date. The legal challenges are examined using a ‘pilot’ project to explore and highlight specific examples. The research draws from a series of CCS industry stakeholder meetings and analysis was developed through interdisciplinary perspectives. In addition, the potential partnership arrangements are explored from a law and policy perspective with an examination of the key issues for these partnerships for Member States. Finally, this research presents a timeline for a legal strategy on resolving the issues for risk and ownership for CO2 transport. [ABSTRACT FROM AUTHOR]

The carbon capture by adsorption (CCA) is regarded as an available engineering technology because of its low energy-consumption, easy to control, and possible integration with renewable energy. The recent advances in CCA research comprises mainly about the performance improvement of adsorbents, design and optimization of engineering process. However, considering the time-consuming and intensive funding required for experimental investigation, the numerical simulation has been widely applied in CCA. In numerical simulation field of CCA, the adsorption process is commonly simplified into mathematical models group comprised of adsorption kinetics model, the adsorption equilibrium model, pressure drop model and heat transfer model. However, few studies’ focus is to provide a detailed review of the research methodology of mathematical modeling in CCA simulation. This paper presents a pathway map on CCA mathematical modeling through literature review and case study. An overview of model screening and modeling method of CCA is provided in the review part. This part also provides a short guided tour on how to combine the fundamental models about heat and mass transfer together to form a model group for various application scenarios in CCA. Then the pathway map on CCA modeling, which is summarized based on the review, is applied to a case study. In this part, the adsorption of CO 2 /N 2 mixtures on activated carbon under the conditions of high temperature and low pressure is numerically investigated based on the established models. The performance indicators comprise gas temperature, mole fraction, and adsorbate amount of the fixed bed, are applied in the evaluation performance of CCA. Based on the proposed methodology, the CCA modeling demonstrates a more fluent design process relative to the real physical scenario, with a possible access to further optimization. Particularly, the simulation results showed that the optimized dimensionless velocity for the highest utilization efficiency of the fixed bed can be obtained and thus is proposed as 1.2–1.4 for the most suitable feed velocity to fit different size of fixed bed and different types of adsorbents for the engineering design. [ABSTRACT FROM AUTHOR]

With regard to the climate policy that has been adopted, the implementation of the carbon capture and storage and carbon capture and utilization technologies seems to be the unavoidable solution to reduce emissions from the energy sector. As most Polish energy is derived from coal, the government has taken steps to reduce CO emissions by initiating a strategic research program-'Advanced technologies for energy generation: Development of a technology for highly efficient zero-emission coal-fired power units integrated with CO capture.' This paper presents the results of an investigation of a process for continuous removal of CO from the gas stream on a laboratory unit. This study was conducted at the Institute for Chemical Processing of Coal in Zabrze, Poland. The purpose of the tests that were conducted was to establish the effect of the sorption column load on CO recovery and on the process regeneration heat duty. In the second part of the paper, a simple comparison of three amine solvents is presented as a part of the solvent selection process for further pilot plant tests. [ABSTRACT FROM AUTHOR]

Paper presents parametric evaluation of a modified design of a conceptual micro-combined heat and power unit (micro-CHP) with solid oxide fuel cells. The system incorporates oxygen transport membranes to supply high purity oxygen for post-combustion of lean fuel leaving the SOFC stack. The concentrations of CO 2 in the flue gases leaving the system, approaches 99% (on dry gas basis). High temperature oxygen transport membranes, made of perovskite materials, enable oxygen permeation rate exceeding 6 Nml/(cm 2 min). The oxygen permeation is strongly related to the ratio of oxygen partial pressures at the retentate and permeate sides. Results of a parametric evaluation of the system, including the analysis of effects of membrane characteristics on the electrical efficiency, are presented and discussed. Oxygen transport membranes require high pressure at the feed site, therefore an increase of auxiliary power consumption should be expected to achieve high oxygen flow through the membrane. Electrical penalty in range 6–12%-point was observed, in comparison with a conventional micro-CHP system without oxy-combustion. These numbers are often quoted for large power systems operating in a CCS-ready mode with state-of-the-art oxygen separation methods such as pressure swing adsorption (PSA). Electrical efficiency of the system discussed in this paper was evaluated and effects of oxygen permeation rate on the electrical efficiency were analyzed. [ABSTRACT FROM AUTHOR]

Abstract: Black liquor gasification (BLG) is being developed as an alternative technology for energy and chemical recovery in kraft pulp mills. This study compares BLG – with downstream production of DME (dimethyl ether) or electricity – with recovery boiler-based pulping biorefinery concepts for different types of mills. The comparison is based on profitability as well as CO2 emissions, using different future energy market scenarios. The possibility for carbon capture and storage (CCS) is considered. The results show that, if commercialised, BLG with DME production could be profitable for both market pulp mills and integrated pulp and paper mills in all energy market scenarios considered. Recovery boiler-based biorefinery concepts including extraction of lignin or solid biomass gasification with DME production could also be profitable for market and integrated mills, respectively. If the mill is located close to an infrastructure for CO2 collection and transportation, CCS significantly improves profitability in scenarios with a high CO2 emissions charge, for both combustion- and gasification-based systems. Concepts that include CCS generally show a large potential for reduction of global CO2 emissions. Few of the concepts without CCS achieve a significant reduction of CO2 emissions, especially for integrated mills. [Copyright &y& Elsevier]

• A novel decarbonization concept applied to offshore natural gas wells benefiting CCUS technology. • A comprehensive CFD model considers real gas EOS and the behaviours of gas, droplets, liquid film. • Compatible with pure CO 2 and CH 4 -CO 2 models to study condensation and separation characteristics. • The maximum CO 2 condensation amount under high pressure and low temperature is 10.33 ton/h. • The maximum CO 2 capture capacity is 4.43 ton/h with high heterogeneous droplet mass concentration. Carbon capture, utilisation and storage (CCUS) is of unique significance for building a green and resilient energy system, and it is also a key solution to tackle the climate challenge. The concept of supersonic decarburization, a joint product of non-equilibrium condensation and swirling separation, can contribute to CCUS technology in a clean way. In this paper, a numerical model is established and validated to investigate the complex physical phenomena of supersonic decarbonization in a high-pressure environment based on the real gas equation of state. The model is compatible with the pure CO 2 model and CH 4 -CO 2 model. Through the simulation of the supersonic nozzle and supersonic separator, the condensation and separation performance of supersonic decarbonization technology was evaluated. For the condensation performance of carbon dioxide, the results show that higher pressure makes it much easier to achieve the condensation process. When the pressure is supercritical, the decrease of inlet temperature or the increase of inlet mole fraction of CO 2 leads to a higher liquid fraction. For separation performance, when the mass concentration of inlet heterogeneous droplets increases from 0.1 kg/m3 to 7.5 kg/m3, the carbon separation amount increases from 3.33 ton/h to 4.43 ton/h, while the exergy loss of condensed CO 2 drops from 436.57 kJ/kg to 329.56 kJ/kg. It demonstrates that the decarburization process is easier, and exergy required for condensation decreases when the concentration of the foreign core is larger. This new concept is beneficial to CCUS technology and can be applied to carbon capture in offshore natural gas processing. [ABSTRACT FROM AUTHOR]

The two major pathways for energy utilization from biomass are conversion to a liquid fuel (i.e., biofuels) or conversion to electricity (i.e., biopower). In the United States (US), biomass policy has focused on biofuels. However, this paper will investigate three options for biopower: low co-firing (co-firing scenarios refer to combusting a given percentage of biomass with coal) (5%-10% biomass), medium co-firing (15%-20% biomass), and dedicated biomass firing (100% biomass). We analyze the economic and greenhouse gas (GHG) emissions impact of each of these options, with and without CO2 capture and storage (CCS). Our analysis shows that in the absence of land use change emissions, all biomass co-combustion scenarios result in a decrease in GHG emissions over coal generation alone. The two biggest barriers to biopower are concerns about carbon neutrality of biomass fuels and the high cost compared to today's electricity prices. This paper recommends two policy actions. First, the need to define sustainability criteria and initiate a certification process so that biomass providers have a fixed set of guidelines to determine whether their feedstocks qualify as renewable energy sources. Second, the need for a consistent, predictable policy that provides the economic incentives to make biopower economically attractive. [ABSTRACT FROM AUTHOR]

This paper discusses the economic impacts of climate change, including those on ecosystems, and whether a new backstop technology should be used under conditions of strict temperature targets. Using the dynamic integrated climate-economy (DICE) model, we developed a new model to calculate the optimal path by considering new backstop technologies, such as CO 2 capture and storage (CCS). We identify the effects of parameter changes based on the resulting differences in CO 2 leakage and sites, and we analyse the feasibility of CCS. In addition, we focus on ocean acidification and consider the impact on economic activity. As a result, when CCS is assumed to carry a risk of CO 2 leakage and acidification is considered to result in a decrease in utility, we find that CCS can only delay the effects of climate change, but its use is necessary to achieve strict targets, such as a 1.5 °C limit. This observation suggests that if the target temperature is too tight, we might end up employing a technology that sacrifices the ecosystem too greatly. [ABSTRACT FROM AUTHOR]

In this paper, a novel carbon capture and utilization process is proposed. It is based on using a fraction of the captured carbon dioxide to produce sodium bicarbonate, a widely used product in the chemical and food industries. The process couples the Dry Carbonate process for carbon dioxide capture with sodium bicarbonate production. Raw material is trona or sodium sesquicarbonate dehydrate, which is a relatively abundant mineral composed by approximately 46% sodium carbonate and 35% sodium bicarbonate by weight. In the process, trona is firstly converted into sodium carbonate in a fluidized bed reactor operated at 180–200 °C and 1 bar. Heat required in the fluidized bed reactor for decomposing trona can be supplied by renewable sources such as low/medium temperature solar energy or biomass. A fraction of the sodium carbonate generated is recirculated for carbon dioxide capture by means of the dry carbonate process. The rest is converted to sodium bicarbonate in a carbonating tower through the reaction with carbon dioxide and water. After separation of sodium bicarbonate and other salts from water, the sodium bicarbonate produced is suitable for direct sale. The use of renewable sources for supplying the energy required at the sorbent regenerator and for trona decomposition yields a near-zero carbon dioxide emissions global system. As case of study, carbon dioxide capture coupled to sodium bicarbonate production has been analysed for a 15 MW el coal fired power plant. Heat required in the carbon capture process penalizes the global system efficiency by a 10.2%, which is reduced just to the electricity parasitic consumption for solids transport and carbon dioxide compression (∼3%) if renewable energy sources are integrated. From an economic perspective, the penalty in electricity consumption is fully compensated by the new by-product sales. Taking into account the reduction of electricity sales and current prices of trona and sodium bicarbonate a return of investment is obtained in the range between 3 and 8.7 years with an internal rate of return over 12%. These values improve the current forecast of any other carbon capture and storage process up to date, which suggests a high interest of the proposed conceptual integration specially for regions where trona is widely available. [ABSTRACT FROM AUTHOR]

Partition (or distribution) coefficients determine the relative equilibrium concentrations of chemical constituents (or chemical tracers) in each of the phases of a multi-phase system under dilute conditions. The various fluid phases in a reservoir have differing transport properties (e.g. varying relative permeability) and to correctly interpret the behaviour of injected chemical tracers it is essential that accurate partition coefficients are known. In the context of carbon geosequestration or long-term storage of CO 2 , chemical tracers will be predominantly exposed to an environment consisting of supercritical CO 2 and formation water as the main fluid phases. To estimate/simulate the reservoir properties relevant to injected CO 2 tagged with chemical tracers, it is therefore necessary to incorporate high pressure/temperature CO 2 /water partition coefficients into any model/simulation. In this paper, we present a method to determine these partition coefficients for gaseous chemical tracers using a variation of the widely used EPICS (or equilibrium partitioning in a closed system) method. With this method, only the concentration in one phase (in this case, CO 2 ) needs to be measured. We then report these values for a series of representative chemical tracers (i.e. krypton, xenon, sulfur hexafluoride, perdeuterated methane and R134a) at pressure/temperature conditions that have been previously used at the CO2CRC's Otway CCS demonstration project in Victoria, Australia. These values were generally lower than the corresponding Henry's Law coefficients at comparable temperatures. Experiments also examined the impact of adding CH 4 to the system to mimic feedstock gas at the CO2CRC Otway project and provide data pertinent to scenarios where CO 2 is injected into depleted CH 4 gas fields. These values are compared with Henry's Law coefficients and another recently published set of high pressure/temperature partition coefficients. With computational simulations, we have shown that these differences are potentially significant and demonstrate their impact in three typical CO 2 geo-sequestration scenarios (i.e. injection into two types of aquifers and injection into a depleted reservoir with a gas cap). [ABSTRACT FROM AUTHOR]

This paper discusses the limitations and prospects of using equilibrium-based column models for the dynamic simulation of post-combustion CO 2 capture processes. Based on their features, one of three available commercial process simulators was chosen for this study. A pilot plant configuration adopted from literature was modeled and simulated using this simulator. Simulation results were compared with plant data and with results using standard rate-based models as available in literature. Temperature profiles in columns and overall mass and energy balances were found to be similar to plant data; however, CO 2 capture-rate, reboiler-duty, and rich-loading using the model were overestimated. A method of reduced stage efficiencies in the absorber was used, which improved performance prediction further with a maximum deviation of 5%. Further, this dynamic model was used to analyze the process subjected to variation in flue gas flow-rate with a similar trend of futuristic power plants by controlling either liquid to gas ratio or CO 2 capture-rate. Controlling liquid to gas ratio provided more control over the reboiler-duty while controlling the capture-rate focused on maintaining a certain capture ratio. The advantages and disadvantages of both methods are discussed and based on that, the controlling capture ratio was found suitable for using while power plant works flexibly with stringent emission regulations. [ABSTRACT FROM AUTHOR]

In the present paper, a CO 2 cryogenic capture for flue gas of an LNG-fired power generation system is proposed, in which LNG cold energy can be fully utilized during the gasification process. First of all, the flue gas is compressed to facilitate the CO 2 solid formation and separation. Sequentially, the CO 2 -removed flue gas expands to supply most of the cold energy needed for the cryogenic process. In comparison with traditional CO 2 -capture systems in LNG-fired power generation cycle, the new system does not require gasifying excessive amount of LNG. Based on the HYSYS simulation, the CO 2 capture pressure and temperature are investigated as the key parameters to find the appropriate working conditions of the CO 2 -capture system. The results show that the system can achieve a 90% CO 2 recovery rate or higher if the flue gas temperature can be lowered to less than −140 °C. [ABSTRACT FROM AUTHOR]

Bioenergy with carbon capture and storage (BECCS) can sequester atmospheric CO2, while producing electricity. The CO2 avoidance cost (CAC) is used to calculate the marginal cost of avoided CO2 emissions for BECCS as compared to other established energy technologies. A comparative analysis using four different reference-case power plants for CAC calculations is performed here to evaluate the CO2 avoidance cost of BECCS implementation. Results from this work demonstrate that BECCS can generate electricity at costs competitive with other neutral emissions technologies, while simultaneously removing CO2 from the atmosphere. Approximately 73% of current coal power plants are approaching retirement by the year 2035 in the U.S. After considering CO2 sequestered from the atmosphere and coal power plant CO2 emissions displaced by BECCS, CO2 emissions can be reduced by 1.4 billion tonnes per year in the U.S. alone at a cost of $88 to $116 per tonne of CO2 removed from the atmosphere, for 10% to 90% of available biomass used, respectively. CAC calculations in this paper indicate that BECCS can help the U.S. and other countries transition to a decarbonized electricity grid, as simulations presented in this paper predict that BECCS power plants operate at lower CACs than coal plants with CCS. [ABSTRACT FROM AUTHOR]

This paper proposes a novel CO 2 capture technology from the integration of partial oxy-combustion and the Calcium-Looping capture process based on the multicycle carbonation/calcination of limestone derived CaO. The concentration of CO 2 in the carbonator reactor is increased by means of partial oxy-combustion, which enhances the multicycle CaO conversion according to thermogravimetric analysis results carried out in our work, thus improving the CO 2 capture efficiency. On the other hand, energy consumption for partial oxy-combustion is substantially reduced as compared to total oxy-combustion. All in all, process simulations indicate that the integration of both processes has potential advantages mainly regarding power plant flexibility whereas the overall energy penalty is not increased. Thus, the resulting energy consumption per kilogram of CO 2 avoided is kept smaller than 4 MJ/kg CO 2 , which remains below the typical values reported for total oxy-combustion and amine based CO 2 capture systems whereas CO 2 capture efficiency is enhanced in comparison with the Calcium-Looping process. [ABSTRACT FROM AUTHOR]

Carbon capture and storage (CCS) will be a critical component of a portfolio of low-carbon energy technologies required to combat climate change ( IEA-GHG, 2013 ). As such, an extensive transportation infrastructure will be required to transport captured CO 2 from different sources to the available sinks. Several studies in the literature suggest that shared oversized pipeline networks may be the most efficient long term option compared to single source to sink pipelines, based on increased CCS deployment over the years and therefore increased CO 2 flowrate to the transport network. However, what is neglected in this vision is that the deployment of intermittent renewable energy tends to displace thermal power generation. This directly reduces the amount of fossil fuel burned, CO 2 produced, captured and transported through the network. This paper presents an optimisation methodology to “right-size” CO 2 transport infrastructure, explicitly accounting for the transient flow of CO 2 arising from the co-deployment of intermittent renewable energy generators. By application of this methodology, we demonstrate that capital cost reductions of up to 28% are possible relative to a business-as-usual design case. [ABSTRACT FROM AUTHOR]

CO 2 carriers are considered as a solution for CO 2 transport as a part of carbon capture and storage (CCS) and ship fuel cost is an important parameter impacting total cost of CO 2 shipping. Heavy fuel oil (HFO) is a traditional marine fuel but alternative marine fuels such as MGO and LNG shall be considered for future researches on CO 2 shipping because low sulphur content fuel is required in sulphur Emission Control Areas (SECAs) from January 2015. However, LNG has not been seriously considered as a marine fuel for CO 2 carriers and its economic feasibility has not been studied so far. This paper assesses economics of LNG fueled CO 2 carriers based on a CO 2 shipping scenario in North Sea and fuel price in June 2016. Parameter studies are conducted to understand the influence of important parameters such as a marine fuel price, LNG fuel system cost, and small LNG distribution cost. The results show that LNG fueled CO 2 carriers are more cost-effective than CO 2 carriers utilizing MGO based on fuel price in June 2016 and when crude oil price is higher than approximately 30–50 USD/bbl. Furthermore, technology development on LNG fuel system and bunkering infrastructure could strengthen the competitiveness of LNG as a marine fuel for CO 2 carriers. [ABSTRACT FROM AUTHOR]

Adsorption is considered as one of the most promising technologies for CCS. Gas adsorption involves the separation of gaseous components from flue gas using solid adsorbents. The gaseous component, adsorbate, is adsorbed from the gas phase on a solid material. Regarding CO2 adsorption, it is important to consider the parameters, that is the high sorption capacity, CO2 selectivity, regeneration and stability in multiple cycles. New directions for the development of adsorbents are focused on increasing their capacity ' for this purpose, amine impregnation is carried out. This paper presents a new approach to obtaining mesoporous material from fly ash and, based on this, a new physico-chemical adsorbent obtained by impregnation. The effectiveness of the process was confirmed by thermogravimetric analysis and FTIR infrared spectroscopy. [ABSTRACT FROM AUTHOR]

The Steady State Superconducting Tokamak (SST-1) consists of many distributed and heterogeneous plant/experiment systems viz. Water-Cooling, Power Supplies, Cryogenics, Vacuum, Magnets, Auxiliary-Heating sources, Diagnostics, Front End Electronics (FEE) & Data Acquisition systems, having their own data acquisition & control systems and control & monitor by Central Control System (CCS) during the machine operation. With distributed computing and interdependent systems, it is essential that all the data/event acquired must be with disciplined & precise time-base, so as to make the co-relation of the data/event from various plant and experiment systems easy. Hence it is important to have accurate and precise Time Synchronization in place. The two systems fulfill the requirement of the time synchronization in SST-1. The VME based Timing System (TS) provides synchronization amongst various experiment systems during the plasma discharges and works as discharge control system (DCS) while the GPS based Time Synchronization System (TSS) caters the requirement of synchronization during the continuous operation of various plant systems by feeding a central clock to all the plant systems. This paper presents the Time Synchronization System of SST-1, the results of the integrated testing and engineering validation with various SST-1 subsystems. [ABSTRACT FROM AUTHOR]

The use of natural gas for power generation is becoming increasingly important in many regions in the world. Given that the combined cycle gas turbine (CCGT) power stations are lower in capital cost and carbon intensity than their coal-fired counterparts, natural gas fired power stations are considered a vital part of the transition to a low carbon economy. However, CCGTs are not themselves “low carbon” and in order to reach a carbon intensity of less than 50 kg CO 2 /MWh, it will be necessary to decarbonise them via CCS, with post-combustion CCS currently regarded as being a promising technology for this application. In this study, we present a detailed model of a 420 MW triple-pressure reheat CCGT and evaluate its technical and economic performance under full and part load conditions. We evaluate the technical performance of our CCGT model by comparison to an equivalent model implemented in Thermoflow THERMOFLEX and observe agreement of power output and efficiency to within 4.1% and the temperature profile within the HRSG within 2.9%. We further integrate the CCGT with a dynamic model of an amine based CCS process, and observe a reduction in the base plant efficiency from 51.84% at full-load and 50.23% at 60% load by 8.64% points at full-load and 7.93% points at 60% load. A core conclusion of this paper is that CCGT power plants equipped with post-combustion CCS technologies are well suited to dynamic operation, as might be required in an energy system characterised by high penetrations of intermittent renewable power generation. [ABSTRACT FROM AUTHOR]

Based on a review of the current state of the Carbon Capture, Transport and Storage (CCTS) technology, this paper analyzes the layout and costs of a potential CO2 infrastructure in Europe at the horizon of 2050. We apply the mixedinteger model CCTS-Mod to compute a CCTS infrastructure network for Europe, examining the effects of different CO2 price paths with different regional foci. Scenarios assuming low CO2 certificate prices lead to hardly any CCTS development in Europe. The iron and steel sector starts deployment once the CO2 certificate prices exceed 50 €/tCO2. The cement sector starts investing at a threshold of 75 €/tCO2, followed by the electricity sector when prices exceed 100 €/tCO2. The degree of CCTS deployment is found to be more sensitive to variable costs of CO2 capture than to investment costs. Additional revenues generated from utilizing CO2 for enhanced oil recovery (CO2 -EOR) in the North Sea would lead to an earlier adoption of CCTS, independent of the CO2 certificate price; this case may become especially relevant for the UK, Norway and the Netherlands. However, scattered CCTS deployment increases unit cost of transport and storage infrastructure by 30% or more. [ABSTRACT FROM AUTHOR]

Many of the world's electricity systems are decarbonising, driven in most cases by the deployment of variable renewable energy technologies. This paper studies such systems using generation expansion planning in the form of a linear program to determine and understand least-cost pathways to deep decarbonisation of existing wholesale electricity markets over a 30-year horizon. This work extends previous generation expansion modelling with several, additional options that now enable the substitution of woody biomass for coal and biomethane for natural gas, the retrofit of carbon capture and storage to existing and new build fossil plant, and different constraints on variable renewable energy that differentiate between renewable resource adequacy, system security and economic performance. The most recent, independent, and authoritative technical and financial input data are also used. In all decarbonisation pathways studied, emission reductions are primarily driven by the replacement of the existing coal fleet with utility-scale solar photovoltaic and wind generation. Nonetheless, systematic application of these additional options gives rise to a wide range of different technologies for 'firming' renewable-rich, decarbonised systems, with batteries, pumped hydroelectric energy storage, fossil plant with co-fired biomass and biomethane, carbon capture and storage and nuclear small modular reactors all playing significant roles in different cases. This range of observed pathways is thought to have several implications for system planning, with variable renewable energy tending to be economically competitive up to an imposed technical limit, but with that limit being uncertain and therefore requiring continuous re-evaluation as our understanding evolves. The results of an extensive range of sensitivity studies also suggest that deep decarbonisation is achievable without large increases in costs for consumers, that we should embrace the optionality and competition between different technologies, and that stakeholders have significant choice about non-cost related impacts and preferences, which are manifold. • Generation expansion demonstrates diverse pathways of power system decarbonisation. • ∼90% abatement projected to be achieved via renewables competing solely on cost. • Constraints on VRG integration impact prospects of firm-low carbon technologies. • Additional costs of decarbonisation are relatively insensitive to technology mix. • We should embrace optionality and competition between different technologies. [ABSTRACT FROM AUTHOR]

In this paper, the methods of the integration of a supercritical coal-fired power plant with membrane CCS installation are shown. In addition to membrane modules, the CCS installation also consists of two vacuum pumps and two CO2 compressors. In this paper, the relationship between the auxiliary power required to drive these machines and the recoverable amount of heat is shown. This relationship is the reason for the integration of the supercritical coal unit with the CCS installation, which is used for cooling compressed CO2 in the CCS installation by use of condensate (or feed water) from the supercritical coal unit cycle. This cooling process causes both a reduction of the auxiliary power required to drive the compressors and vacuum pumps and increase of power ratio of a steam turbine. In this paper, the optimisation method for minimising the decrease of overall efficiency of the power plant connected with its integration with CCS installation is shown. This results in choosing the optimal pressure ratios in the applied compressors and vacuum pumps under the condition of sufficient heat transmission to the steam turbine cycle. For investigated units, the cost of CO2 emission avoidance and the break-even price of electricity were also calculated. [Copyright &y& Elsevier]

Integrated gasification combined cycle systems (IGCC) are becoming more popular because of the characteristics, by which they are characterized, including low pollutants emissions, relatively high efficiency of electricity production and the ability to integrate the installation of carbon capture and storage (CCS). Currently, the most frequently used CO2 capture technology in IGCC systems is based on the absorption process. This method causes a significant increase of the internal load and decreases the efficiency of the entire system. It is therefore necessary to look for new methods of carbon dioxide capture. The authors of the present paper propose the use of membrane separation. The paper reviews available membranes for use in IGCC systems, indicates, inter alia, possible places of their implementation in the system and the required operation parameters. Attention is drawn to the most important parameters of membranes (among other selectivity and permeability) influencing the cost and performance of the whole installation. Numerical model of a membrane was used, among others, to analyze the influence of the basic parameters of the selected membranes on the purity and recovery ratio of the obtained permeate, as well as to determine the energetic cost of the use of membranes for the CO2 separation in IGCC systems. The calculations were made within the environment of the commercial package Aspen Plus. For the calculations both, membranes selective for carbon dioxide and membranes selective for hydrogen were used. Properly selected pressure before and after membrane module allowed for minimization of energy input on CCS installation assuring high purity and recovery ratio of separated gas. [ABSTRACT FROM AUTHOR]

Abstract: Automata theory provides two ways of defining an automaton: either by its transition system, defining its states and events, or by its language, the set of sequences (traces) of events in which it can engage. For many classes of automaton, these forms of definition have been proved equivalent. For example, there is a well-known isomorphism between regular languages and finite deterministic automata. This paper suggests that for (demonically) the non-deterministic automata (as treated in process algebra), the appropriate link between transition systems and languages may be a retraction rather than an isomorphism. A pair of automata, defined in the tradition of CCS by their transition systems, may be compared by a pre-ordering based on some kind of simulation or bisimulation, for example, weak, strong, or barbed. Automata defined in the tradition of CSP are naturally ordered by set inclusion of their languages (often called refinement); variations in ordering arise from different choices of basic event, including for example, refusals and divergences. In both cases, we characterise a theory by its underlying transition system and its choice of ordering. Our treatment is therefore wholly semantic, independent of the syntax and definition of operators of the calculus. We put forward a series of retractions relating the above-mentioned versions of CSP to their corresponding CCS transition models. A retraction is an injection that is (with respect to the chosen ordering) monotonic, increasing and idempotent (up to equivalence). It maps the nodes of a transition system of its source theory to those of a system that has been saturated by additional transitions. Each retraction will be defined by a transition rule, in the style of operational semantics; the proofs use the familiar technique of co-induction, often abbreviated by encoding in the relational calculus. The aim of this paper is to contribute to unification of theories of reactive system programming. More practical benefits may follow. For example, we justify a method to improve the efficiency of model checking based on simulation. Furthermore, we show how model checking of a transition network fits consistently with theorem-proving tools, which reason directly about specifications and designs that are expressed in terms of sets of sequences of observable events. [Copyright &y& Elsevier]

Meeting the Paris Agreement will most likely require the combination of CO 2 capture and biomass in the industrial sector, resulting in net negative emissions. CO 2 capture within the industry has been extensively investigated. However, biomass options have been poorly explored, with literature alluding to technical and economic barriers. In addition, a lack of consistency among studies makes comparing the performance of CO 2 capture and/or biomass use between studies and sectors difficult. These inconsistencies include differences in methodology, system boundaries, level of integration, costs, greenhouse gas intensity of feedstock and energy carriers, and capital cost estimations. Therefore, an integrated evaluation of the techno-economic performance regarding CO 2 capture and biomass use was performed for five energy-intensive industrial sub-sectors. Harmonization results indicate that CO 2 mitigation potentials vary for each sub-sector, resulting in reductions of 1.4–2.7 t CO 2 /t steel (77%–149%), 0.7 t CO 2 /t cement (92%), 0.2 t CO 2 /t crude oil (68%), 1.9 t CO 2 /t pulp (1663%–2548%), and 34.9 t CO 2 /t H 2 (313%). Negative emissions can be reached in the steel, paper and H 2 sectors. Novel bio-based production routes might enable net negative emissions in the cement and (petro)chemical sectors as well. All the above-mentioned potentials can be reached for 100 €/t CO 2 or less. Implementing mitigation options could reduce industrial CO 2 emissions by 10 Gt CO 2 /y by 2050, easily meeting the targets of the 2 °C scenario by the International Energy Agency (1.8 Gt CO 2 /y reduction) for the industrial sector and even the Beyond 2 °C scenario (4.2 Gt CO 2 /y reduction). • Literature review on CO 2 mitigation in steel, cement, chemical, H 2 and paper sectors. • Introduction harmonized methodology to allow comparison between industrial sectors. • All investigated sectors have large reduction potentials for <100 €/t CO 2 avoided. • Negative emissions possible in iron/steel, H 2 and paper sectors. • Potential CO 2 emission reduction of 10 Gt/yr in 2050, easily meeting climate target. [ABSTRACT FROM AUTHOR]

• Alberta's CO 2 emission from the power and industry sectors is 136 Mtpa. • The total mid CO 2 storage capacity in oil and gas fields in Alberta is 5.2 Gt. • A CCS corridor within 200 km from Edmonton is proposed which will mitigate up to 52 Mtpa CO 2 or 38% of Alberta's CO 2 emission. To enable Alberta, Canada to reduce CO 2 emissions by 30% from 2005 levels by 2030, we investigate carbon capture and storage (CCS) opportunities in Alberta, Canada by conducting a plant-by-plant evaluation of CO 2 emissions from 157 power and industrial plants and a field-by-field analysis of CO 2 storage capacity in 15,143 oil fields and 68,327 gas fields. Results show that CO 2 emissions from power and industrial plants is 136 Mtpa. Additionally, the mid CO 2 storage capacity is 41.5 Gt in gas fields and 5.2 Gt in oil fields. Oil fields also have a mid CO 2 -enhanced oil recovery (CO 2 -EOR) potential of 6,895 MMbbl. Based on these findings, this paper proposes a first-of-a-kind CCS corridor within 200 km from Edmonton, which can mitigate up to 52.4 Mtpa CO 2 or 38% of Alberta's emissions from power and industry sectors. There is a mid CO 2 storage capacity of 1.8 Gt and mid CO 2 -EOR potential of 3,550 MMbbl within this CCS corridor. [ABSTRACT FROM AUTHOR]