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The development of detectors for the European Spallation Source is an important parallel element to the effort put into the design and construction of the neutron source and instruments. The 10Boron-film-based detector developments that started over a decade ago as basic detector concepts have now reached technical maturity after intense prototyping work and numerous testing campaigns. Several of the ESS beamlines that will soon enter the commissioning phase started welcoming the detector systems built with the 10B-film converter technology. The real-size demonstrators evolved in the last 2–3 years into a diverse suite of gas proportional counters for use in diffraction, reflectometry and small-angle scattering studies in spite of the operational complexity posed by the requirements for large-area coverage, low material budget and robustness for operation in the high-flux and high-radiation environment of ESS. The detectors are now being shipped to ESS or undergoing the last performance and calibration tests before being handed over to the instrument teams for installation in the host beamlines. A common feature of these detector systems is the very large number of readout channels that they are instrumented with in order to fulfill the demanding requirements for sensitivity, spatial resolution and count-rate capability. Across all of the detector types that will operate at ESS, the integration, testing and commissioning of the read-out technologies and software tools for data reduction, calibration and analysis are the focus of the detector and integration teams. These will yield a wealth of knowledge about their operation as well as initial results on the in-situ performance, a very important asset to ensure rapid commissioning of the detectors when neutrons from the ESS source become available. In this paper we will give an overview of the 10B-film-based detector technologies included in the ESS detector suite that are currently facing the transition from the production phase to installation and integration with the other beamline components, which comes with its own specific challenges of both organizational and technical nature. [ABSTRACT FROM AUTHOR]

Accreting stellar-mass black holes represent unique laboratories for studying matter and radiation under the influence of extreme gravity. They are highly variable sources going through different accretion states, showing various components in their X-ray spectra from the thermal emission of the accretion disc dominating in the soft state to the up-scattered Comptonisation component from an X-ray corona in the hard state. X-ray polarisation measurements are particularly sensitive to the geometry of the X-ray scatterings and can thus constrain the orientation and relative positions of the innermost components of these systems. The IXPE mission has observed about a dozen stellar-mass black holes with masses up to 20 solar masses in X-ray binaries with different orientations and in various accretion states. The low-inclination sources in soft states have shown a low fraction of polarisation. On the other hand, several sources in soft and hard states have revealed X-ray polarisation higher than expected, which poses significant challenges for theoretical interpretation, with 4U 1630–47 being one of the most puzzling sources. IXPE has measured the spin of three black holes via the measurement of their polarisation properties in the soft emission state. In each of the three cases, the new results agree with the constraints from the spectral observations. The polarisation observations of the black hole X-ray transient Swift J1727.8–1613 across its entire outburst has revealed that the soft-state polarisation is much weaker than the hard-state polarisation. Remarkably, the observations furthermore show that the polarisation of the bright hard state and that of the 100 times less luminous dim hard state are identical within the accuracy of the measurement. For sources with a radio jet, the electric field polarisation tends to align with the radio jet, indicating the equatorial geometry of the X-ray corona, e.g., in the case of Cyg X–1. In the unique case of Cyg X–3, where the polarisation is perpendicular to the radio jet, the IXPE observations reveal the presence and geometry of obscuring material hiding this object from our direct view. The polarisation measurements acquired by the IXPE mission during its first 2.5 years have provided unprecedented insights into the geometry and physical processes of accreting stellar-mass black holes, challenging existing theoretical models and offering new avenues for understanding these extreme systems. [ABSTRACT FROM AUTHOR]

In this review, we present a self-contained introduction to axion-like particles (ALPs) with a particular focus on their effects on photon polarization: both theoretical and phenomenological aspects are discussed. We derive the photon survival probability in the presence of photon–ALP interaction, the corresponding final photon degree of linear polarization, and the polarization angle in a wide energy interval. The presented results can be tested by current and planned missions such as IXPE (already operative), eXTP, XL-Calibur, NGXP, XPP in the X-ray band and like COSI (approved to launch), e-ASTROGAM, and AMEGO in the high-energy range. Specifically, we describe ALP-induced polarization effects on several astrophysical sources, such as galaxy clusters, blazars, and gamma-ray bursts, and we discuss their real detectability. In particular, galaxy clusters appear as very good observational targets in this respect. Moreover, in the very-high-energy (VHE) band, we discuss a peculiar ALP signature in photon polarization, in principle capable of proving the ALP existence. Unfortunately, present technologies cannot detect photon polarization up to such high energies, but the observational capability of the latter ALP signature in the VHE band could represent an interesting challenge for the future. As a matter of fact, the aim of this review is to show new ways to make progress in the physics of ALPs, thanks to their effects on photon polarization, a topic that has aroused less interest in the past, but which is now timely with the advent of many new polarimetric missions. [ABSTRACT FROM AUTHOR]

The Imaging X-ray Polarimetry Explorer (IXPE) has confirmed that X-ray polarimetry is a valuable tool in astronomy, providing critical insights into the emission processes and the geometry of compact objects. IXPE was designed to be sensitive in the 2–8 keV energy range for three primary reasons: (1) celestial X-ray sources are bright within this range, (2) the optics are effective, and (3) most sources across various classes were expected to exhibit some level of polarization. Indeed, IXPE is a great success, and its discoveries are necessitating the revision of many theoretical models for numerous sources. However, one of IXPE's main limitations is its relatively narrow energy band, coupled with rapidly declining efficiency. In this paper, we will demonstrate the benefits of devising a mission focused on a broader energy band (0.1–79 keV). This approach leverages current technologies that align well with theoretical expectations and builds on the successes of IXPE. [ABSTRACT FROM AUTHOR]

Radiation from X-ray pulsars (XRPs) was expected to be strongly linearly polarized owing to a large difference in their ordinary and extraordinary mode opacities. The launch of IXPE allowed us to check this prediction. IXPE observed a dozen X-ray pulsars, discovering pulse-phase dependent variation of the polarization degree (PD) and polarization angle (PA). Although the PD showed rather erratic profiles resembling flux pulse dependence, the PA in most cases showed smooth variations consistent with the rotating vector model (RVM), which can be interpreted as a combined effect of vacuum birefringence and dipole magnetic field structure at a polarization-limiting (adiabatic) radius. Application of the RVM allowed us to determine XRP geometry and to confirm the free precession of the NS in Her X-1. Deviations from RVM in two bright transients led to the discovery of an unpulsed polarized emission likely produced by scattering off the accretion disk wind. [ABSTRACT FROM AUTHOR]

The observation of photosynthetic biofilms growing on the Fine Residue Deposit (FRD) kimberlite produced by the Venetia Diamond Mine, Limpopo, South Africa suggests that processed kimberlite supports bacterial growth. The presence of this biofilm may aid in the acceleration of weathering of this ultra-mafic host material - a process that can sequester CO2 via carbon mineralization. Laboratory and field trial experiments were undertaken to understand the microbe-mineral interactions occurring in these systems, and how these interactions impact geochemical cycling and carbonate precipitation. At laboratory scale it was discovered that using kimberlite as a growth supplement increased biomass production (up to 25-fold) and promoted microbiome diversity, while the inoculation of FRD systems aided in the aggregation, settling, and dewatering of kimberlitic slurries. Field trial studies combining photosynthetic biofilms (cultured in 3 × 1,000 L bioreactors) with FRD material were initiated to better understand microbially enhanced mineral carbonation across different depths, and under field environmental conditions. Over the 15-month experiment the microbial populations shifted with the kimberlitic environmental pressure, with the control and inoculated systems converging. The natural endogenous biosphere (control) and the inoculum accelerated carbonate precipitation across the entire 40 cm bioreactor depth, producing average 15-month carbonation rates of 0.57 wt.% and 1.17 wt.%, respectively. This corresponds to an annual CO2e mine offset of ~4.48% and ~ 9.2%, respectively. Millimetre-centimetre scale secondary carbonate that formed in the inoculated bioreactors was determined to be biogenic in nature (i.e., possessing microbial fossils) and took the form of radiating colloform precipitates with the addition of new, mineralized colonies. Surficial conditions resulted in the largest production of secondary carbonate, consistent with a ca. 12% mine site CO2e annual offset after a 15-month incubation period. [ABSTRACT FROM AUTHOR]

In one and a half years, the Imaging X-ray Polarimetry Explorer has demonstrated the role and the potentiality of Polarimetry in X-ray Astronomy. The next steps include extension to higher energies. There is margin for an extension of the photoelectric approach up to 20–25 keV, but above that energy the only technique is Compton Scattering. Grazing incidence optics can focus photons up to 80 keV, not excluding a marginal extension to 150–200 keV. Given the physical constraints involved, the passage from photoelectric to scattering approach can make less effective the use of optics because of the high background. I discuss the choices in terms of detector design to mitigate the problem and the guidelines for future technological developments. [ABSTRACT FROM AUTHOR]

CdZnTe (CZT) is a new type of compound semiconductor that has emerged in recent years. Compared to other semiconductor materials, it possesses an ideal bandgap, high density, and high electron mobility, rendering it an excellent room-temperature composite semiconductor material for X-ray and γ-ray detectors. Due to the exceptional performance of CZT material, detectors manufactured using it exhibit high energy resolution, spatial resolution, and detection efficiency. They also have the advantage of operating at room temperature. CZT array detectors, furthermore, demonstrate outstanding spatial detection and three-dimensional imaging capabilities. Researchers worldwide have conducted extensive studies on this subject. This paper, building upon this foundation, provides a comprehensive analysis of CZT crystals and CZT array detectors and summarizes existing research to offer valuable insights for envisioning new detector methodologies. [ABSTRACT FROM AUTHOR]

This study explores the suitability of (Cd,Mn)Te and (Cd,Mn)(Te,Se) as room-temperature X-ray and gamma-ray detector materials, grown using the Bridgman method. The investigation compares their crystal structure, mechanical and optical properties, and radiation detection capabilities. Both crystals can yield large-area single crystal samples measuring approximately 30 × 30 mm2. In low-temperature photoluminescence analysis, both materials showed defect states, and annealing in cadmium vapors effectively eliminated donor–acceptor pair luminescence in (Cd,Mn)Te but not in (Cd,Mn)(Te,Se). Moreover, harder (Cd,Mn)(Te,Se) exhibited a higher etch pit density compared to softer (Cd,Mn)Te. X-ray diffraction examination revealed uniform lattice constant distribution in both compounds, with variations at a part per million level. (Cd,Mn)Te crystals demonstrated excellent single crystal properties with narrower omega scan widths, while (Cd,Mn)(Te,Se) exhibited a high contribution of block-like structures with significantly larger misorientation angles. Spectroscopic evaluations revealed better performance of a pixelated (Cd,Mn)Te detector, in comparison to (Cd,Mn)(Te,Se), achieving a mean full width at half maximum of 14% for the 122 keV gamma peak of Co-57. The reduced performance of the (Cd,Mn)(Te,Se) detector may be attributed to deep trap-related luminescence or block-like structures with larger misorientation angles. In conclusion, Bridgman-grown (Cd,Mn)Te emerges as a more promising material for X-ray and gamma-ray detectors when compared to (Cd,Mn)(Te,Se). [ABSTRACT FROM AUTHOR]

The peak detect and sample hold (PDSH) circuit is an important component of the light detection and ranging (LiDAR) system, because the PDSH circuit can correct the walk error of the time discriminator, and distinguish different objects at the same location. However, due to the requirement for high-precision measurement of nanosecond-scale pulse signals, the design of the PDSH circuit presents significant challenges. This paper accomplishes the modeling of the PDSH circuit, including the modeling of the PDSH measurement speed and the voltage step, quantifies various factors that affect the PDSH circuit measurement results, and makes predictions based on the model. Through the derivation and simplification of the rise process in the PDSH circuit, this study establishes a mathematical model to predict the performance of the PDSH circuit. Furthermore, this study also investigates the effect of circuit delay time on the measurement speed of the PDSH circuit. Meanwhile, this study analyzes the voltage step process, and an equivalent circuit model is derived through theoretical analysis. By utilizing a fitting method, the equivalent capacitance value of the diode is obtained. The simulation and experiment results show that the errors between the measurement speed model of the PDSH circuit and the actual circuit are no more than 1.98 ns and 2.03 ns, respectively. Thus, the measurement speed model can accurately predict whether the PDSH circuit meets the requirements. Moreover, the maximum absolute error of the equivalent circuit model is 19.87 mV, which can significantly reduce the error caused by the voltage step. [ABSTRACT FROM AUTHOR]

Scanning microscopies and spectroscopies like X-ray Fluorescence (XRF), Scanning Transmission X-ray Microscopy (STXM), and Ptychography are of very high scientific importance as they can be employed in several research fields. Methodology and technology advances aim at analysing larger samples at better resolutions, improved sensitivities and higher acquisition speeds. The frontiers of those advances are in detectors, radiation sources, motors, but also in acquisition and analysis software together with general methodology improvements. We have recently introduced and fully implemented an intelligent scanning methodology based on compressive sensing, on a soft X-ray microscopy beamline. This demonstrated sparse low energy XRF scanning of dynamically chosen regions of interest in combination with STXM, yielding spectroimaging data in the megapixel-range and in shorter timeframes than were previously not feasible. This research has been further developed and has been applied to scientific applications in biology. The developments are mostly in the dynamic triggering decisional mechanism in order to incorporate modern Machine Learning (ML) but also in the suitable integration of the method in the control system, making it available for other beamlines and imaging techniques. On the applications front, the method was previously successfully used on different samples, from lung and ovarian human tissues to plant root sections. This manuscript introduces the latest methodology advances and demonstrates their applications in life and environmental sciences. Lastly, it highlights the auxiliary development of a mobile application, designed to assist the user in the selection of specific regions of interest in an easy way. [ABSTRACT FROM AUTHOR]

In our previous studies, the silicon drift detector (SDD) structure with a constant spiral ring cathode gap (g) and a given surface electric field has been partially investigated based on the physical model that gives an analytical solution to the integrals in the calculations. Those results show that the detector has excellent electrical characteristics with a very homogeneous carrier drift electric field. In order to cope with the implementation of the theoretical approach with a complete set of technical parameters, this paper performs different theoretical algorithms for the technical implementation of the detector performance using the Taylor expansion method to construct a model for cases where the parameter "j" is a non-integer, approximating the solution with finite terms. To verify the accuracy of this situation, we performed a simulation of the relevant electrical properties using the Sentaurus TCAD tool 2018. The electrical properties of the single and double-sided detectors are first compared, and then the effects of different equal gaps g (g = 10 μm, 20 μm, and 25 μm, respectively) on the electrical properties of the double-sided detectors are analyzed and demonstrated. By analyzing and comparing the electrical characteristics data from the simulation results, we can show that the double-sided structure has a larger transverse drift electric field, which improves the spatial position resolution as well as the response speed. The effect of the gap size on the electrical characteristics of the detector is also analyzed by analyzing three different gap bifacial detectors, and the results show that a 10 μm equal gap is the optimal design. Such results can be used in applications requiring large-area SDD, such as the pulsar X-ray autonomous navigation. in the future to provide navigation and positioning space services for spacecraft deep-space exploration. [ABSTRACT FROM AUTHOR]

The exhumed Infrahelvetic Flysch Units in the eastern central Alps in Switzerland are a field analog to modern accretionary wedges at active plate boundaries. In these seismically active convergent settings, water‐saturated sediments undergo consolidation, and diagenetic to low‐grade metamorphic processes cause complex fluid‐rock interactions. To contribute to the understanding of structural and fluid processes and their interaction with seismic activity, we present quantitative information on the geometrical and spatial distribution of slate‐hosted calcite veins from the Infrahelvetic Flysch Units that show mutual overprinting relationships with the ductile phyllosilicate‐rich matrix. Two vein systems that form in the deeper part of the inner wedge are characterized: (a) layer‐parallel veins (meter‐scale) forming spatially repetitive vein‐arrays and (b) pervasively distributed, steep micron‐veinlets, that cross‐cut the thicker layer‐parallel veins and the ductile matrix. Synchrotron X‐ray Fluorescence Microscopy (XFM) is instrumental in detecting previously unseen densely spaced micron‐veinlets. The spatial distribution of micron‐veinlets indicates pervasive layer‐perpendicular fluid transport in response to dissolution‐precipitation creep through the wedge. Layer‐parallel veins form vein‐arrays with thicknesses on the meter‐scale suggesting that fluids are progressively localized in channels up‐scale. Both vein sets form in an alternating fashion with two different enhanced flux directions, which could be indicative for a critically stressed wedge with near‐lithostatic fluid pressures. The layer‐parallel veins and vein‐arrays could represent seismic events with low magnitude earthquakes (Mw up to 4.0) or slow‐slip events currently found at active plate boundaries, while micron‐veinlets and dissolution‐precipitation processes accommodate slow interseismic deformation. Plain Language Summary: Convergent plate boundaries are locations where lithospheric plates collide. Plate collision produces a wide variety of seismic activity, which is a major natural hazard posing socio‐economic risks. When oceanic plates are involved in collision, an accretionary wedge made of sediments forms near the plate boundary. Here, we study an ancient accretionary wedge in the Swiss Alps to examine the potential traces of paleo‐seismic activity left in the rock record. We focus on ubiquitous veins, mineralized fractures that acted as fluid pathways in such active seismic domains. We documented veins from the field (m‐scale) to the grain scale (μm‐scale). Synchrotron X‐ray Fluorescence Microscopy (XFM) enabled mapping of trace‐element concentrations in the vein minerals, capturing tracers of paleo‐fluid transport at 2 μm resolution. The innovative XFM technique unveiled the presence of micron‐veinlets with widths less than that of a human hair. These micron‐veinlets form widespread, densely spaced clusters throughout these rock sequences. Our microanalytical observations demonstrate that these micron‐veinlets facilitate fluid transport via dissolution‐precipitation creep during interseismic deformation of the wedge while the m‐scale veins could potentially represent small earthquakes or slow slip events. Key Points: Cyclic fracturing, veining, and pressure solution are characteristic in the sediment‐rich inner part (>250°C) of the accretionary wedgeSynchrotron XFM documents pervasive micron‐veinlets enabling layer‐perpendicular fluid migration during slow wedge deformationLayer‐parallel veins arrange in vein‐arrays indicating localized fluid transport and potentially small seismic or slow‐slip events [ABSTRACT FROM AUTHOR]

Kaonic atom X-ray spectroscopy is a consolidated technique for investigations on the physics of strong kaon–nucleus/nucleon interaction. Several experiments have been conducted regarding the measurement of soft X-ray emission (<20 keV) from light kaonic atoms (hydrogen, deuterium, and helium). Currently, there have been new research activities within the framework of the SIDDHARTA-2 experiment and EXCALIBUR proposal focusing on performing precise and accurate measurements of hard X-rays (>20 keV) from intermediate kaonic atoms (carbon, aluminum, and sulfur). In this context, we investigated cadmium–zinc–telluride (CdZnTe or CZT) detectors, which have recently demonstrated high-resolution capabilities for hard X-ray and gamma-ray detection. A demonstrator prototype based on a new cadmium–zinc–telluride quasi-hemispherical detector and custom digital pulse processing electronics was developed. The detector covered a detection area of 1 cm2 with a single readout channel and interesting room-temperature performance with energy resolution of 4.4% (2.6 keV), 3% (3.7 keV), and 1.4% (9.3 keV) FWHM at 59.5, 122.1, and 662 keV, respectively. The results from X-ray measurements at the DAΦNE collider at the INFN National Laboratories of Frascati (Italy) are also presented with particular attention to the effects and rejection of electromagnetic and hadronic background. [ABSTRACT FROM AUTHOR]

Single-crystal chemical vapour deposition (CVD) diamond detectors are an established transmissive synchrotron beamline diagnostic instrument used for beam position and beam intensity monitoring. A recently commercialized alternative is silicon carbide (4H-SiC) devices. These have the potential to provide the same diagnostic information as commercially available single-crystal CVD diamond X-ray beam position monitors, but with a much larger transmissive aperture. At Diamond Light Source an experimental comparison of the performance of single-crystal CVD diamond and 4H-SiC X-ray beam position monitors has been carried out. A quantitative comparison of their performance is presented in this paper. The single-crystal diamond and 4H-SiC beam position monitors were installed in-line along the synchrotron X-ray beam path enabling synchronous measurements at kilohertz rates of the beam motion from both devices. The results of several tests of the two position monitors' performance are presented: comparing signal uniformity across the surface of the detectors, comparing kHz intensity measurements, and comparing kHz beam position measurements from the detectors. Each test is performed with a range of applied external bias voltages. A discussion of the benefits and limitations of 4H-SiC and single-crystal CVD diamond detectors is included. [ABSTRACT FROM AUTHOR]

We increasingly rely on deep learning algorithms to process colossal amount of unstructured visual data. Commonly, these deep learning algorithms are deployed as software models on digital hardware, predominantly in data centers. Intrinsic high energy consumption of Cloud-based deployment of deep neural networks (DNNs) inspired researchers to look for alternatives, resulting in a high interest in Spiking Neural Networks (SNNs) and dedicated mixed-signal neuromorphic hardware. As a result, there is an emerging challenge to transfer DNN architecture functionality to energy-efficient spiking non-volatile memory (NVM)-based hardware withminimal loss in the accuracy of visual data processing. Convolutional Neural Network (CNN) is the staple choice of DNN for visual data processing. However, the lack of analog-friendly spiking implementations and alternatives for some core CNN functions, such as MaxPool, hinders the conversion of CNNs into the spike domain, thus hampering neuromorphic hardware development. To address this gap, in this work, we propose MaxPool with temporal multiplexing for Spiking CNNs (SCNNs), which is amenable for implementation in mixed-signal circuits. In this work, we leverage the temporal dynamics of internal membrane potential of Integrate & Fire neurons to enable MaxPool decision-making in the spiking domain. The proposed MaxPool models are implemented and tested within the SCNNarchitecture using amodified version of the aihwkit framework, a PyTorch-based toolkit for modeling and simulating hardware-based neural networks. The proposed spiking MaxPool scheme can decide even before the complete spatiotemporal input is applied, thus selectively trading off latency with accuracy. It is observed that by allocating just 10% of the spatiotemporal input window for a pooling decision, the proposed spiking MaxPool achieves up to 61.74% accuracy with a 2-bit weight resolution in the CIFAR10 dataset classification task after training with back propagation, with only about 1% performance drop compared to 62.78% accuracy of the 100% spatiotemporal window case with the 2-bit weight resolution to reflect foundry-integrated ReRAM limitations. In addition, we propose the realization of one of the proposed spiking MaxPool techniques in an NVM crossbar array along with periphery circuits designed in a 130nm CMOS technology. The energy-efficiency estimation results show competitive performance compared to recent neuromorphic chip designs. [ABSTRACT FROM AUTHOR]

The Middle-Jurassic Opalinus Clay is the foreseen host rock for radioactive waste disposal in central northern Switzerland. An extensive drilling campaign aiming to characterize the argillaceous formation resulted in a comprehensive drill core data set. The rheologically weak Opalinus Clay is only mildly deformed compared to the over- and underlying rock units but shows a variety of natural fractures. While these structures are hydraulically indistinguishable from macroscopically non-deformed Opalinus Clay today, their analysis allows for a better understanding of the deformation behaviour in the geological past. Here, we present an overview of the different fracture and fault types recorded in the Opalinus Clay and a detailed microstructural characterization of veins—natural dilational fractures healed by secondary calcite and celestite mineralizations. Macroscopic drill core analysis revealed five different natural fracture types that encompass tension gashes of various orientations with respect to bedding and small-scale faults with displacements typically not exceeding the drill core diameter. The occurrence of different fault types generally fits well with the local tectonic setting of the different drilling sites and with respect to the neighbouring regional fault zones. The microstructural investigations of the various vein types revealed their often polyphase character. Fibrous bedding-parallel veins of presumable early age were found to be overprinted by secondary slickenfibres. The polyphase nature of fibrous bedding parallel veins and slickenfibres is supported by differing elemental compositions, pointing towards repeated fracturing and mineralization events. Direct dating of vein calcites with U–Pb was unsuccessful. Nevertheless, age constraints can be inferred from structural orientations and fault slip kinematics. Accordingly, some of the veins already formed during sediment compaction in Mesozoic times, others possibly relate to Early Cenozoic foreland uplift. The youngest veins are most likely related to Late Cenozoic regional tectonic events, such as the Jura fold-and-thrust belt to the south and the Hegau-Lake Constance Graben to the northeast of the study area. During these latest tectonic events, previously formed veins acted as rheologically stiff discontinuities in the otherwise comparably weak Opalinus Clay along which deformation of the rock formation was re-localized. [ABSTRACT FROM AUTHOR]

There is an urgent need for new, better instrumentation and techniques for detecting and characterizing special nuclear material (SNM), i.e., highly enriched uranium and plutonium. The development of improved instruments and techniques requires experiments performed with the SNM itself, which is of limited availability. This paper describes the findings of experiments performed at the National Criticality Experiments Research Center conducted using new instruments and techniques on unclassified, kg-quantity SNM objects. These experiments, performed in the framework of the Department of Energy, National Nuclear Security Administration Consortium for Monitoring, Technology, and Verification, focused on detecting, characterizing, and localizing SNM samples with masses ranging from 3.3 to 13.8 kg, including plutonium and highly enriched uranium using prototype detectors and techniques. The work demonstrates SNM detection and characterization using recently-developed prototype detection systems. Specifically, we present new results in passive detection and imaging of plutonium and uranium objects using gamma-ray and dual particle (fast neutron and gamma-ray) imaging. We also present a new analysis of the delayed neutron emissions during active interrogation of uranium using a neutron generator. [ABSTRACT FROM AUTHOR]

We demonstrate the first ever recorded positron-emission tomography (PET) imaging and dosimetry of a FLASH proton beam at the Proton Center of the MD Anderson Cancer Center. Two scintillating LYSO crystal arrays, read out by silicon photomultipliers, were configured with a partial field of view of a cylindrical poly-methyl methacrylate (PMMA) phantom irradiated by a FLASH proton beam. The proton beam had a kinetic energy of 75.8 MeV and an intensity of about 3.5 × 1010 protons that were extracted over 101.5 ms-long spills. The radiation environment was characterized by cadmium–zinc–telluride and plastic scintillator counters. Preliminary results indicate that the PET technology used in our tests can efficiently record FLASH beam events. The instrument yielded informative and quantitative imaging and dosimetry of beam-activated isotopes in a PMMA phantom, as supported by Monte Carlo simulations. These studies open a new PET modality that can lead to improved imaging and monitoring of FLASH proton therapy. [ABSTRACT FROM AUTHOR]

Microbiological weathering of coarse residue deposit (CRD) kimberlite produced by the Venetia Diamond Mine, Limpopo, South Africa enhanced mineral carbonation relative to untreated material. Cultures of photosynthetically enriched biofilm produced maximal carbonation conditions when mixed with kimberlite and incubated under near surface conditions. Interestingly, mineral carbonation also occurred in the dark, under water-saturated conditions. The examination of mineralized biofilms in ca. 150 µm-thick-sections using light microscopy, X-ray fluorescence microscopy (XFM) and backscatter electron—scanning electron microscopy-energy dispersive x-ray spectrometry demonstrated that microbiological weathering aided in producing secondary calcium/magnesium carbonates on silicate grain boundaries. Calcium/magnesium sulphate(s) precipitated under vadose conditions demonstrating that evaporites formed upon drying. In this system, mineral carbonation was only observed in regions possessing bacteria, preserved within carbonate as cemented microcolonies. 16S rDNA molecular diversity of bacteria in kimberlite and in natural biofilms growing on kimberlite were dominated by Proteobacteria that are active in nitrogen, phosphorus and sulphur cycling. Cyanobacteria based enrichment cultures provided with nitrogen & phosphorus (nutrients) to enhance growth, possessed increased diversity of bacteria, with Proteobacteria re-establishing themselves as the dominant bacterial lineage when incubated under dark, vadose conditions consistent with natural kimberlite. Overall, 16S rDNA analyses revealed that weathered kimberlite hosts a diverse microbiome consistent with soils, metal cycling and hydrocarbon degradation. Enhanced weathering and carbonate-cemented microcolonies demonstrate that microorganisms are key to mineral carbonation of kimberlite. Highlights: Kimberlite-water interactions supports the growth of biofilm. Light-limited evaporite conditions produced gypsum, limiting mineral carbonation. Kimberlite weathering was enhanced by adding a cultivated photosynthetic biofilm. Biogeochemical activity is responsible for accelerated mineral carbonation of kimberlite. [ABSTRACT FROM AUTHOR]

A full-field X-ray fluorescence imaging (FXI) station was recently developed at beamline BL8 of Synchrotron Light Research Institute (SLRI), Thailand. An unfocused, synchrotron X-ray beam from the bending magnet with a size of 2 mm (vertical) x 13 mm (horizontal) and photon energy of 10 keV was employed in the FXI experiments. A sample stage was tilted by 7.5° to enlarge the vertical beam size. X-ray fluorescence images were recorded by an energy-dispersive, 256 x 256 array, pn-type charge coupled device detector equipped with a polycapillary optics, providing a full-frame image size of 12.3 mm x 12.3 mm. The incident photon flux per pixel was 3 x 104 photons s-1 (100 mA)-1 and the experimental spatial resolution was 68 mm. Image processing was carried out offline using an in-house MATLAB program capable of elemental selection and inhomogeneity intensity correction. Elemental detection limits of FXI were found to decrease with increasing atomic number, i.e. 0.3 to 0.03 wt% for Z = 19 (K) to 30 (Zn). Compared with the BL6b microbeam imaging (µXI) station at SLRI with higher photon flux per pixel, 3 x 1010 photons s-1 (100 mA)-1, a tenfold sample area can be obtained and 13 times higher peak-to-background (PKB) ratio at Zn Kα measured with the same experimental time (8 h). Simultaneous measurement of FXI is more time-efficient against the long overhead times of mXI scanning over large pixel numbers, >65000. To demonstrate potential applications of the new FXI station, various types of samples were examined: dendritic limestone, ancient bronze and dried fish. Analyzed elemental images enabled us to identify areas rich in Mn on the limestone, Sn and Cu separation in the bronze, and Zn nutrition in the dried fish eye. [ABSTRACT FROM AUTHOR]

Radiation detectors based on Cadmium Zinc Telluride (CZT) compounds are becoming popular solutions thanks to their high detection efficiency, room temperature operation, and to their reliability in compact detection systems for medical, astrophysical, or industrial applications. However, despite a huge effort to improve the technological process, CZT detectors' full potential has not been completely exploited when both high spatial and energy resolution are required by the application, especially at low energies (<10 keV), limiting their application in energy-resolved photon counting (ERPC) systems. This gap can also be attributed to the lack of dedicated front-end electronics which can bring out the best in terms of detector spectroscopic performances. In this work, we present the latest results achieved in terms of energy resolution using SIRIO, a fast low-noise charge sensitive amplifier, and a linear-array pixel detector, based on boron oxide encapsulated vertical Bridgman-grown B-VB CZT crystals. The detector features a 0.25-mm pitch, a 1-mm thickness and is operated at a −700-V bias voltage. An equivalent noise charge of 39.2 el. r.m.s. (corresponding to 412 eV FWHM) was measured on the test pulser at 32 ns peaking time, leading to a raw resolution of 1.3% (782 eV FWHM) on the 59 keV line at room temperature (+20 °C) using an uncollimated 241Am, largely improving the current state of the art for CZT-based detection systems at such short peaking times, and achieving an optimum resolution of 0.97% (576 eV FWHM) at 1 µs peaking time. The measured energy resolution at the 122 keV line and with 1 µs peaking time of a 57Co raw uncollimated spectrum is 0.96% (1.17 keV). These activities are in the framework of an Italian collaboration on the development of energy-resolved X-ray scanners for material recycling, medical applications, and non-destructive testing in the food industry. [ABSTRACT FROM AUTHOR]

Currently, the integration method of silicon PIN radiation detectors faces challenges such as complex processes, poor reliability and thick dead layers. Novel integration methods based on metal bonding technology for realizing the integration of thick and thin PIN detectors are needed with the requirement of reducing signal crosstalk, package volume and weight. Combined with the current research on metal bonding technology, this paper presents an extensive review of metal bonding technology, especially metal Al bonding technology, to provide a certain reference to future research on the bonding processing of high-performance silicon PIN detector devices. [ABSTRACT FROM AUTHOR]

The anatomy of the osteochondral junction is complex because several tissue components exist as a unit, including uncalcified cartilage (with superficial, middle, and deep layers), calcified cartilage, and subchondral bone. Furthermore, it is difficult to study because this region is made up of a variety of cell types and extracellular matrix compositions. Using X-ray fluorescence microscopy, we present a protocol for simultaneous elemental detection on fresh frozen samples. We transferred the osteochondral sample using a tape-assisted system and successfully tested it in synchrotron X-ray fluorescence. This protocol elucidates the distinct distribution of elements at the human knee's osteochondral junction, making it a useful tool for analyzing the co-distribution of various elements in both healthy and diseased states. [ABSTRACT FROM AUTHOR]

The history of Compton cameras began with the detection of radiation sources originally for applications in astronomy. A Compton camera is a promising γ-ray detector that operates in the wide energy range of a few tens of keV to MeV. The γ-ray detection method of a Compton camera is based on Compton scattering kinematics, which is used to determine the direction and energy of the γ-rays without using a mechanical collimator. Although the Compton camera was originally designed for astrophysical applications, it was later applied in medical imaging as well. Moreover, its application in environmental radiation measurements is also under study. Although a few review papers regarding Compton cameras have been published, they either focus very specifically on the detectors used in such cameras or the particular applications of Compton cameras. Thus, the aim of this paper is to review the features and types of Compton cameras and introduce their applications, associated imaging algorithms, improvement scopes, and their future aspects. [ABSTRACT FROM AUTHOR]

Since the advent of semiconductor detectors, they have been developed for several generations, and their performance has been continuously improved. In this paper, we propose a new silicon drift detector structure that is different from the traditional spiral SDD structure that has a gap between the cathode ring and the width of cathode ring, increasing gradually with the increase of the radius of the cathode ring. Our new structure of spiral SDD structure has equal cathode ring gap and a given surface electric field, which has many advantages compared with the traditional structure. The novel SDD structure controllably reduces the area of silicon oxide between the spiral rings, which in turn reduces the surface leakage current due to the reduction of total oxide charge in the silicon oxide and electronic states on the silicon/silicon oxide interface. Moreover, it has better controllability to adjust this spiral ring cathode gap to achieve better surface electric field distribution, thus realizing the optimal carrier drift electric field and achieving the optimal detector performance. In order to verify this theory, we have modeled this new structure and simulated its electrical properties using the Sentaurus TCAD tool. We have also analyzed and compared different spiral ring cathode gap structures (from 10 µm to 25 µm for the gap). According to the simulation results of potential, electric field, and electron concentration, we have obtained that a spiral ring cathode gap of 10 µm has the best electrical characteristics, more uniform distribution of potential and surface electric field, and a more smooth and straight electron drift channel. [ABSTRACT FROM AUTHOR]

Frutexites-like microstructures are described from the exhumed Late Devonian reef complexes of the northern Canning Basin, Western Australia. Several high-resolution imaging techniques, including X-ray microcomputerised tomography, scanning electron microscopy and X-ray fluorescence microscopy, were used to investigate morphology and composition in two samples. Three types of Frutexites-like microstructures (Types I-III) have been identified. Type I, found lining an early marine cement-filled cavity in fore-reef grainstone facies, consists of dendritic structures formed primarily of coccoid bacteria with filamentous bacteria embedded in sheets of amorphous extracellular polymeric substances (EPS). These ferromanganiferous dendrites have laminated to spheroidal textures. Types II and III are from a toe-of-slope hardground. Type II grew in a crypt between two corals, is also dendritic and composed of bacilliform and filamentous bacteria embedded in an amorphous EPS sheet. The opaqueness of these ferriferous dendrites precludes more detailed description of textures. Type III grew as branching columnar microstromatolites and is composed of entwined filaments of Girvanella, Rothpletzella and Wetheredella with Fe-enriched outer walls that generate Frutexites-like microstructures. Types I and II resemble Frutexites sensu stricto as defined by Maslov (Stromatolites, Trudy Instituta geologicheskikh nauk Akademiya nauk SSR, 1960) and are the result of the consecutive growth and permineralisation of biofilms composed of mixed bacterial communities growing in cryptic habitats. Type III superficially resembles Frutexites sensu stricto based on macroscopic field observations, however, detailed microscopic analysis reveals that it is composed of Fe-enriched tubular walls surrounded by Mn-enriched calcite., (© 2023 The Authors. Geobiology published by John Wiley & Sons Ltd.)

Seafloor hydrothermal chimneys from back-arc basins are important hosts for metals such as Cu, Zn, Pb, Ag, and Au. Although the general growth history of chimneys has been well documented, recent studies have revealed that the fine-scale mineralogy can be highly complex and reflects variable physicochemical conditions of formation. This study utilized a novel combination of scanning electron microscopy (SEM)-based electron backscattered difraction (EBSD) and synchrotron X‑ray fluorescence microscopy (SXFM) to uncover the detailed growth processes of multiple chalcopyrite-lined conduits within a modern chalcopyrite-sphalerite chimney from Manus Basin and to assess the controls on native gold precipitation. On the basis of previous studies, the chimney conduit was thought to develop from an initial sulfate-dominated wall, which was subsequently dissolved and replaced by sphalerite and chalcopyrite during gradual mixing of hydrothermal fluids and seawater. During this process, sphalerite was epitaxially overgrown by chalcopyrite. Accretionary growth of chalcopyrite onto this early formed substrate thickened the chimney walls by bi-directional growth inward and outward from the original tube wall, also enclosing the outgrown pyrite cluster. A group of similar conduits with slightly diferent mineral assemblages continued to form in the vicinity of the main conduit during the further fluid mixing process. Four types of distinct native gold-sulfide/ sulfosalt associations were developed during the varying mixing of hydrothermal fluids and seawater. Previously unobserved chains of gold nanoparticles occur at the boundary of early sphalerite and chalcopyrite, distinct from gold observed in massive sphalerite as identified in other studies. These observations provide baseline data in a well-preserved modern system for studies of enrichment mechanisms of native gold in hydrothermal chimneys. Furthermore, native gold is relatively rarely observed in chalcopyrite-lined conduit walls. Our observations imply that: (1) native gold is closely associated with various sulfides/sulfosalts in chalcopyrite-lined conduit walls rather than limited to the association with tennantite, Bi-rich minerals, and bornite as reported previously; and (2) the broad spectrum of gold occurrence in chalcopyrite-line conduits is likely to be determined by the various mixing process between hot hydrothermal fluids with surrounding fluids or seawater. Quantitative modeling of fluid mixing processes is recommended in the future to probe the precise gold deposition stages to eficiently locate gold in modern hydrothermal chimneys. [ABSTRACT FROM AUTHOR]

The Moran komatiite-hosted Ni sulfide deposit at Kambalda (Australia) is one of the better preserved orebodies at Kambalda. Its geochemical signature is used to investigate the evolution of the sulfide mineralization. The orebody has several parts, including a flanking segment where massive sulfides formed relatively early and a central portion in a 40-m-deep erosional embayment representing a later generation of massive and net-textured sulfides. Basal massive sulfides within the deep embayment vary systematically in their chalcophile element contents (Ni, PGE, Au, Te, As, Bi). Elements compatible in monosulfide solid solution (MSS) exhibit the highest concentration at the edge of the orebody (up to 4.3 ppm Ir + Os + Ru + Rh), whereas incompatible elements are most concentrated in the centre (up to 11.2 ppm Pt + Pd + Au). This difference in element distributions is explained by fractional crystallization of sulfide melt from the edge towards the centre. To explain the vertical movement of the residual fractionated melt, a new model of sulfide crystallization is proposed. A low-viscosity boundary layer containing incompatible elements is formed between MSS and sulfide melt. This melt propagates with the crystallization front towards the centre of the sulfide melt pool. Trace element variations in pentlandite (e.g. Co) and composite Co- and Bi-bearing arsenide-telluride grains suggest that during the final stages of crystallization, an immiscible Co-As-Te-Bi melt is formed. [ABSTRACT FROM AUTHOR]

Purpose: The Cunoniaceae are a major component of the New Caledonian flora with 91 endemic species that are highly unusual in that multiple metals are hyperaccumulated in different species. This makes it an ideal model system for studying the nature of the hyperaccumulation phenomenon. Methods: X-ray fluorescence spectroscopy (XRF) scanning of all herbarium collections of the Cunoniaceae was undertaken at the Herbarium of New Caledonia to reveal incidences of nickel (Ni) and manganese (Mn) accumulation. Following on, the Mn hyperaccumulating P. reticulata and the Ni hyperaccumulating P. xaragurensis were selected for detailed follow-up investigations using synchrotron-based X-ray fluorescence microscopy (XFM). Results: The systematic XRF screening of herbarium specimens showed that numerous species have high foliar Mn and Ni with species either accumulating Ni or Mn, but not both elements simultaneously. Soil 'extractable' Mn and Ni concentrations associated with Pancheria reticulata and P. xaragurensis greatly varies between the species. The XFM data shows that P. reticulata has a distinctive distribution pattern with Mn concentrated in large hypodermal cells. This contrasts with P. xaragurensis where Ni was mainly localized in and around the epidermis, and hypodermal cells were not observed. Conclusions: Manganese and Ni accumulation are differently localized in Pancheria species growing on ultramafic soils, which is not explained by contrasting soils conditions, but represents different ecophysiological adaptations. [ABSTRACT FROM AUTHOR]

Context: Hyperaccumulator plants are of considerable interest for their extreme physiology. Stackhousia tryonii is a nickel (Ni) hyperaccumulator plant endemic to ultramafic outcrops in Queensland (Australia) capable of attaining up to 41 300 μg g−1 foliar Ni. Aims: This study sought to elucidate the distribution of Ni in S. tryonii by using synchrotron X-ray fluorescence micro-computed tomography (XFM-CT), complemented with elemental maps acquired from physically sectioned plant organs. Its Ni-enriched cylindrical photosynthetic stems make them particularly well suited samples for synchrotron XFM-CT. Methods: XFM-CT enables 'virtual sectioning' of a sample, avoiding artefacts arising from physical sample preparation. The method can be used on fresh samples that are frozen during the analysis, which preserves 'life-like' conditions by limiting radiation damage. It also prevents/minimises other artefacts. Key results: The results showed that Ni is mainly concentrated in the apoplastic space surrounding epidermal cells, and in some epidermal cell vacuoles. This finding is significant because this 'free' solute Ni is likely to be lost during physical sectioning. Conclusions and implications: This case study has highlighted the utility of the XFM-CT approach for visualising metals within intact plant organs, which may be used across the plant sciences. [ABSTRACT FROM AUTHOR]

This paper presents the results of an investigation of the incorporation of Au within pyritic ore from the Qiucun epithermal Au deposit, China. The new data provide insights into the mode of occurrence of Au during fluid-rock interactions within epithermal systems. The distribution and mode of occurrence of Au within arsenian pyrite were investigated using a chemical and structural characterization-based approach combining laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) trace element analysis, megapixel synchrotron X‑ray fluorescence analysis (MSXRF), and atom probe tomography (APT). The resulting data indicate that invisible Au is present at elevated concentrations in the form of a homogeneous solid solution within As-rich pyrite domains, which yields Au concentrations that positively correlate with As. Arsenic-induced lattice defects, such as stacking faults and the expansion of the pyrite unit cell, provide evidence of the effect of As on the incorporation of Au into pyrite. The nucleation and crystallization of electrum preferentially occurred at the fluid-pyrite reaction interface or along fractures and grain boundaries within the pre-existing pyrite. This study indicates that changes in physicochemical conditions (e.g., temperature, pH, and sulfur fugacity) during fluid-pyrite interactions are key controls on the development of nanometer- or micrometer-scale clusters of gold. The systematic compositional and textural observations documented in this study provide new insights into the mechanisms responsible for the different modes of occurrence of Au (ionic vs. particulate) and enable us to further understand the processes involved in the formation of Au mineralization. [ABSTRACT FROM AUTHOR]

High-flux X-ray measurements with high-energy resolution and high throughput require the mitigation of pile-up and dead time effects. The reduction of the time width of the shaped pulses is a key approach, taking into account the distortions from the ballistic deficit, non-linearity, and time instabilities. In this work, we will present the performance of cadmium–zinc–telluride (CdZnTe or CZT) pixel detectors equipped with digital shapers faster than the preamplifier peaking times (ballistic deficit pulse processing). The effects on energy resolution, throughput, energy-linearity, time stability, charge sharing, and pile-up are shown. The results highlight the absence of time instabilities and high-energy resolution (<4% FWHM at 122 keV) when ballistic deficit pulse processing (dead time of 90 ns) was used in CZT pixel detectors. These activities are in the framework of an international collaboration on the development of spectroscopic imagers for medical applications (mammography, computed tomography) and non-destructive testing in the food industry. [ABSTRACT FROM AUTHOR]

The BESIII experiment has been collecting data since 2009 at the e + e − collider BEPCII in Beijing, a charm- τ factory characterized by high statistics and high precision. The discovery of exotic charmonium-like states and the still open questions in low-energy QCD led to an extension of the experimental program, with several upgrades. This review focuses on the CGEM-IT, the innovative solution proposed to replace the current inner tracker, which is aging. It consists of three, co-axial, cylindrical triple-GEM detectors and will be the first cylindrical GEM operating inside a 1 T magnetic field with analogue readout. For this purpose, a dedicated mixed-signal ASIC for the readout of CGEM-IT signals and FPGA-based electronics for data processing have been developed. The simultaneous measurement of both ionization charge and time distribution enables three reconstruction algorithms, to cope with the asymmetry of the electron avalanche in the magnetic field and with non-orthogonal incident tracks. The CGEM-IT will not only restore the design efficiency but also improve the secondary vertex reconstruction and the radiation tolerance. The gas mixture and gain settings were chosen to optimize the position resolution to ∼130 µm in the transverse plane and better than 350 µm along the beam direction. This paper addresses the innovative aspects in terms of construction, readout, and software, employed to achieve the design goals as well as the experimental measurements performed during the development and commissioning of the CGEM-IT. [ABSTRACT FROM AUTHOR]

This paper presents microsatellite spacecraft payload study for prompt observation of transient astrophysical objects in X-ray energy range. By combining telescope concepts and miniaturized detectors, the small spacecraft will be able to probe the X-ray temporal emissions of bright events such as Gamma-Ray Bursts (GRBs), X-ray transients or the electromagnetic counterparts of Gravitational Wave Events (GWEs), but also short and long term observations of other types of variable X-ray sources. The spacecraft is based on the CubeSat nanosatellite platform with a volume of 16U. The spacecraft carries two types of X-ray telescopes onboard. The first is intended for X-ray transient monitoring and localization, and the second for detailed spectroscopic observation. The X-ray monitor/localization telescope with wide field of view of several arc degrees is used for localization and flux measurement of X-ray transients, as well as for permanent monitoring of Galactic center area. This telescope is based on Lobster Eye X-ray optics together with pixel detector based on the Timepix3 Quad detector. Rapid follow-up observation by soft X-ray spectroscopy is enabled by a second X-ray spectroscopic telescope with limited FOV (Field of View) of several arcmins with no spatial and/or angular resolution. The spectroscopic telescope uses condenser optics based on replicated parabolic total reflection system (or, alternatively, Wolter system) and a Ketek X-ray SDD detector with energy resolution of about 130 eV as a detector. In addition to technical and instrumental aspects, observational strategy and astrophysical issues and justifications are also addressed in the paper. [ABSTRACT FROM AUTHOR]

Using a combination of microstructural, spectroscopic, and geochemical analyses, we investigate how subgrain rotation recrystallization and fluid migration affect Ti concentration [Ti] in naturally deformed quartz veins from the Prijakt Nappe (Austroalpine Unit, Eastern Alps). These coarse‐grained quartz veins, that formed at amphibolite facies conditions, were overprinted by lower greenschist facies deformation to different degrees. During the overprint, subgrain rotation recrystallization was dominant during progressive deformation to ultramylonitic stages. The initial [Ti] (3.0–4.7 ppm) and cathodoluminescence (CL) signature of the vein crystals decrease during deformation mainly depending on the availability of fluids across the microstructure. The amount of strain played a subordinate role in resetting to lower [Ti] and corresponding darker CL shades. Using a microstructurally controlled analysis we find that the most complete re‐equilibration in recrystallized aggregates ([Ti] of 0.2–0.6 p.m.) occurred (a) in strain shadows around quartz porphyroclasts, acting as fluid sinks, and (b) in localized microshear zones that channelized fluid percolation. [Ti] resetting is mainly observed along wetted high angle boundaries (misorientation angle >10–15°), with partial [Ti] resetting observed along dry low angle boundaries (<10–15°). This study shows for the first time that pure subgrain rotation recrystallization in combination with dissolution‐precipitation under retrograde condition provide microstructural domains suitable for the application of titanium‐in‐quartz geothermobarometry at deformation temperatures down to 300–350°C. Plain Language Summary: For over 10 years, the TitaniQ geothermometer has been used to constrain deformation temperatures in quartz‐rich rocks. The calibration of the thermometer rests on the direct correlation of the titanium trace element concentration in quartz with respect to the ambient temperature. However, the processes and parameters which lead to re‐equilibration of the Ti‐in‐quartz system during deformation are not yet fully understood. Here we analysed deformed quartz veins from the Eastern Alps applying a combination of microstructural, spectroscopic, and geochemical analyses. In contrast to recent studies which highlight the importance of stain, we show that the availability of free grain boundaries, fluids, and their partitioning play the dominant role in Ti resetting toward lower concentrations in our studied case of retrograde deformation. We employ a robust analytical approach to investigate the interplay between grain‐scale deformation, fluid‐rock interactions, and geochemical exchange during increasing strain in the quartz mylonites. With this approach, the microstructures representing most re‐equilibrated sites for the application of the titanium‐in‐quartz geothermometer can be readily identified, even at lower greenschist facies deformation conditions and a recrystallization regime dominated by subgrain rotation. Key Points: Ti‐in‐quartz re‐equilibration is possible during subgrain rotation recrystallization even at lower greenschist facies conditionsTi resetting depends on the availability of aqueous fluids along interconnected grain boundaries, independently of the accumulated strainPartial Ti resetting also takes place along dry subgrain boundaries [ABSTRACT FROM AUTHOR]

X‐ray absorption fine‐structure (XAFS) spectroscopy can assess the chemical speciation of the elements providing their coordination and oxidation state, information generally hidden to other techniques. In the case of trace elements, achieving a good quality XAFS signal poses several challenges, as it requires high photon flux, counting statistics and detector linearity. Here, a new multi‐element X‐ray fluorescence detector is presented, specifically designed to probe the chemical speciation of trace 3d elements down to the p.p.m. range. The potentialities of the detector are presented through a case study: the speciation of ultra‐diluted elements (Fe, Mn and Cr) in geological rocks from a calcareous formation related to the dispersal processes from Ontong (Java) volcanism (mid‐Cretaceous). Trace‐elements speciation is crucial in evaluating the impact of geogenic and anthropogenic harmful metals on the environment, and to evaluate the risks to human health and ecosystems. These results show that the new detector is suitable for collecting spectra of 3d elements in trace amounts in a calcareous matrix. The data quality is high enough that quantitative data analysis could be performed to determine their chemical speciation. [ABSTRACT FROM AUTHOR]