11 results on '"Yokota, Yuui"'
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2. Temperature Characteristics of Resonance Frequency for Double-Layered Thickness-Shear Resonator.
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Ohashi, Yuji, Owada, Yusuke, Yokota, Yuui, Omote, Masaya, Kurosawa, Shunsuke, Kamada, Kei, Sato, Hiroki, Toyoda, Satoshi, Yamaji, Akihiro, Yoshino, Masao, Hanada, Takashi, and Yoshikawa, Akira
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DEBYE temperatures ,ELECTRIC displacement ,RESONANCE ,RESONATORS ,SINGLE crystals - Abstract
The effect of the difference in the thickness ratio of the double-layered thickness-shear resonator on the temperature characteristics of the resonance frequency was investigated using a Ca3TaGa3Si2O14 (CTGS) single crystal. Three specimens with thickness ratios of ${x} =0.25$ , 0.33, and 0.50 were prepared using $122^{\circ } ~{Y}$ - and $171^{\circ }~{Y}$ -cut CTGS substrates. For the specimens with ${x} =0.25$ and 0.33, the temperature characteristics varied depending on the order of the resonance mode. For the specimen with ${x} =0.50$ , on the other hand, almost the same temperature characteristics were observed regardless of the order of the resonance mode. To interpret this phenomenon, a new equation for predicting the temperature characteristics of the fundamental mode (first mode) for the double-layered resonator was created using the electric flux density ratio generated in the two substrates. The expected values using this equation were in good agreement with the result of the first mode temperature characteristics. [ABSTRACT FROM AUTHOR]
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- 2022
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3. Effects of chemical composition control of colquiriite-type neutron scintillator single crystals.
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Yokota, Yuui, Horiai, Takahiko, and Yoshikawa, Akira
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SINGLE crystals , *SCINTILLATORS , *NEUTRON irradiation , *THERMAL neutrons , *NEUTRONS , *CHEMICAL reactions - Abstract
In this study, charge compensation was performed by co-doping Na + ions at the Ca2+ sites of Ce-doped LiCaAlF 6 single crystals to prevent the generation of cation vacancies owing to Ce3+-doping at the Ca2+ sites. Consequently, an improved radiation resistance and increased light yield under neutron irradiation was achieved. In contrast, the Al metal of the starting material used as a substitute for AlF 3 significantly increased the effective segregation coefficient k eff of the Eu2+ ions in Eu-doped LiCaAlF 6 and Eu-doped LiSrAlF 6 single crystals. The Al metal and EuF 3 in the starting materials produced EuF 2 via a chemical reaction, and the Eu2+ ions in EuF 2 could be substituted at the Ca2+ and Sr2+ sites. In addition, the Ca/Sr ratio control of the Li(Ca,Sr)AlF 6 :Eu solid-solution scintillator single crystals improved the light yield through band-gap control, and the Li(Ca,Sr)AlF 6 :Eu single crystal with a 25% Sr concentration exhibited the highest light yield. Charge compensation was conducted using Na co-doping to improve the radiation resistance of the LiCAF:Ce single crystals, thereby preventing the generation of cation defects by the Ce3+-doping at the Ca2+ site. It was determined that the improvement in the radiation resistance of the LiCAF:Ce single crystal via Na co-doping can contribute to the improvement in the durability of the production of LiCAF:Ce single crystals. [Display omitted] • Scintillation properties of LiCaAlF 6 and LiSrAlF 6 single crystals were improved by chemical composition control. • Charge compensation by Na co-doping for LiCAF:Ce single crystals prevents generations of cation vacancies by Ce3+-doping. • Al metal greatly increases the segregation coefficient of Eu ion in the LiCAF and LiSAF single crystals. • Effective segregation coefficient of Eu2%,AlM1%:LiSrAlF 6 crystal was improved to 0.986 using the Al metal. • Ca/Sr ratio control in the Eu:Li(Ca,Sr)AlF 6 single crystals improves the light yield under thermal neutron irradiation. [ABSTRACT FROM AUTHOR]
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- 2023
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4. Microstructure and thermoelectric properties of La-doped SrTiO3/TiO2 eutectic crystals grown by Micro-Pulling-Down method.
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Yokota, Yuui, Horii, Shigeru, Ogino, Hiraku, Yoshida, Yoshiyuki, and Yoshikawa, Akira
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THERMOELECTRIC materials , *CRYSTALS , *SINGLE crystals , *EUTECTICS , *THERMAL conductivity , *ELECTRICAL resistivity , *PHONON scattering , *EUTECTIC alloys - Abstract
• La-doped SrTiO 3 /TiO 2 eutectic crystals were grown by a micro-pulling-down method. • Grown crystals were composed of the TiO 2 rod phase in the SrTiO 3 matrix phase. • Diameter of TiO 2 rods systematically decreased as the growth rate was increased. • Grown crystal exhibited a lower thermal conductivity than the SrTiO 3 single crystal. • ZT s of crystals grown at 0.02 and 0.5 mm/min were 0.015 and 0.025, respectively. La-doped SrTiO 3 /TiO 2 (La:STO/TO) eutectic crystals were grown by a micro-pulling-down method at various growth rates to control the eutectic morphology and thermoelectric properties. The La:STO/TO eutectic crystals were composed of a TiO 2 (TO) rod phase in the SrTiO 3 (STO) matrix phase for all growth rates. The diameter of the TO rod phase systematically decreased as the growth rate was increased, according to the Jackson–Hunt model, and the diameter reached approximately 1 μm at a growth rate of 1 mm/min. The La:STO/TO eutectic crystal exhibited a lower thermal conductivity than the Nb:STO single crystal, owing to the decrease in the lattice thermal conductivity by phonon scattering at boundaries in the eutectic morphology. The figures of merit, ZT s, of the La:STO/TO eutectic crystals grown at 0.02 and 0.5 mm/min growth rates were 0.015 and 0.025, respectively. The faster growth rate led to an increased ZT, owing to the decrease in electrical resistivity. [ABSTRACT FROM AUTHOR]
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- 2022
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5. Crystal growth of La2Hf2O7 by micro-pulling-down method using W crucible.
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Suda, Takahiro, Yokota, Yuui, Horiai, Takahiko, Yamaji, Akihiro, Yoshino, Masao, Hanada, Takashi, Sato, Hiroki, Toyoda, Satoshi, Ohashi, Yuji, Kurosawa, Shunsuke, Kamada, Kei, and Yoshikawa, Akira
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CRYSTAL growth , *SINGLE crystals , *MELTING points , *CRUCIBLES , *CRYSTALS , *TRANSPARENT ceramics - Abstract
• La 2 Hf 2 O 7 crystals (m.p.: 2418 °C) were grown by the µ-PD method using a W crucible. • The La 2 Hf 2 O 7 grown at a rate of 2.00 mm/min had some cracks. • The La 2 Hf 2 O 7 grown at a rate of 0.07 mm/min was transparent without any cracks. • The LHO[0.07 mm/min] had a transmittance of over 70% in the range of 450–800 nm. • The XRC of the LHO[0.07 mm/min] showed a sharp peak with a FWHM of 138 arcsec. La 2 Hf 2 O 7 crystals with a melting point of ∼2418 °C were grown by the micro-pulling-down method using a W crucible and deoxygenated ZrO 2 insulators. A La 2 Hf 2 O 7 crystal grown at a rate of 0.07 mm/min (LHO[0.07 mm/min]) showed a high transparency without any visible cracks and inclusions, while a La 2 Hf 2 O 7 crystal grown at a rate of 2.00 mm/min had some cracks. The LHO[0.07 mm/min] crystal had a transmittance of over 70% in the wavelength range of 450–800 nm. The X-ray rocking curve of the LHO[0.07 mm/min] crystal showed a symmetric sharp peak with a full width at half maximum of 138 arcsec. The Laue image revealed that the grown crystals were single crystals. [ABSTRACT FROM AUTHOR]
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- 2022
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6. Crystal growth of La2Zr2O7 by micro-pulling-down method using Mo and W crucibles.
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Suda, Takahiro, Yokota, Yuui, Horiai, Takahiko, Yamaji, Akihiro, Yoshino, Masao, Hanada, Takashi, Sato, Hiroki, Toyoda, Satoshi, Ohashi, Yuji, Kurosawa, Shunsuke, Kamada, Kei, and Yoshikawa, Akira
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CRYSTAL growth , *CRUCIBLES , *MELTING points , *SINGLE crystals , *CRYSTALS - Abstract
• La 2 Zr 2 O 7 crystals were grown by micro-pulling-down method using Mo & W crucibles. • Grown crystals under Ar + 3%H 2 were composed of La 2 Zr 2 O 7 phase including Mo and W. • A grown crystal under Ar using W crucible & deoxygenated insulator was La 2 Zr 2 O 7. • The La 2 Zr 2 O 7 crystal indicated a transmittance exceeding 70% after post-annealing. La 2 Zr 2 O 7 crystals with a melting point of 2283 °C are grown via the micro-pulling-down (μ-PD) method using Mo and W crucibles to expand the possibility of material research of functional single crystals with high melting points by the μ-PD method. La 2 Zr 2 O 7 crystals grown using Mo and W crucibles under an Ar + 3% H 2 atmosphere are composed of a La 2 Zr 2 O 7 main phase, which includes Mo and W. However, a La 2 Zr 2 O 7 crystal without W can be grown under an Ar atmosphere using the μ-PD method using a W crucible and deoxygenated ZrO 2 insulators. After post-annealing in air at 1000 °C, the La 2 Zr 2 O 7 crystal without W becomes colorless and transparent, indicating a transmittance exceeding 70% in wavelengths ranging from 450 to 800 nm. [ABSTRACT FROM AUTHOR]
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- 2021
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7. Single crystal growth of complex layered oxychalcogenide by melt-solidification method.
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Kato, Takahiro, Iwasa, Yuki, Kumar Naik, Sugali Pavan, Yokota, Yuui, Ishida, Shigeyuki, Mino, Yutaro, Horiai, Takahiko, Yoshikawa, Akira, Nishio, Taichiro, Eisaki, Hiroshi, and Ogino, Hiraku
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SINGLE crystals , *CRYSTAL growth , *SOLIDIFICATION , *MELTING points , *ELECTRIC conductivity , *THERMAL analysis - Abstract
We have successfully grown single crystals of layered mixed-anion compound Sr 2 ZnCu 2 Se 2 O 2 by a simple melt-growth method. Single crystals of the layered oxychalcogenides Sr 2 ZnCu 2 Se 2 O 2 were grown by melt-solidification of stoichiometric raw materials. Plate-like single crystals were obtained, and the maximum size of crystals was 2.5 × 1.4 mm2. Thermal analysis result indicates simple melting-solidification-like behavior, and the size of crystals increases significantly above the melting point revealed by this measurement. X-ray rocking curve (XRC) measurement results of the single crystal showed no peak splitting, with a narrow full width half maximum of 30 and 97 arcsec in (105) and (00 12) peaks, respectively. The electrical conductivity of single crystals on the a (b) plane was 4.34 × 10−1 S/cm at room temperature. Obtained single crystals were transparent, and the absorption edge was observed around 560 nm in the transmittance measurement. Although layered oxychalcogenide Sr 2 ZnCu 2 Se 2 O 2 has a complex composition and structure, this compound exhibits congruent melting behavior in a sealed environment. This feature enables us to grow single crystals of mixed-anion compounds easily by the melt-growth method. [ABSTRACT FROM AUTHOR]
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- 2024
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8. Novel optical-guiding crystal scintillator composed of an Eu-doped SrI2 core and glass cladding.
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Yajima, Ryuga, Kamada, Kei, Takizawa, Yui, Kutsuzawa, Naoko, Sasaki, Rei, Yoshino, Masao, Horiai, Takahiko, Murakami, Rikito, Kim, Kyoung Jin, Kochurikhin, Vladimir V., Yamaji, Akihiro, Kurosawa, Shunsuke, Yokota, Yuui, Sato, Hiroki, Toyoda, Satoshi, Ohashi, Yuji, Takashi, Hanada, and Yoshikawa, Akira
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SCINTILLATORS , *OPTICAL fibers , *RADIOLUMINESCENCE , *BOROSILICATES , *SINGLE crystals , *CRYSTALS - Abstract
Scintillators are used not only as single crystals in radiation detection systems but also as arrays, columns, and fibers. In this study, a novel optical-guiding crystal scintillator (OCS) was fabricated using an Eu:SrI 2 crystal as the core and borosilicate glass as the cladding. The OCS has an elongated shape and can be flexibly processed like an optical fiber. Furthermore, because inorganic scintillator crystals are used as the core, the OCS has high sensitivity to high-energy radiation, such as γ- and X-ray radiation, unlike plastic scintillators. In this study, by observing the cross section of the fabricated OCS, identifying the crystal structure, and investigating the radioluminescence spectrum under X-ray irradiation, OCS fabrication in accordance with the OCS design specifications was confirmed, and the SrI 2 crystal structure and Eu2+ 5d–4f luminescence were maintained. The γ-ray responses, such as light yield and decay time, were also investigated. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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9. Relationship of single crystal growth and luminescence properties of Cr-doped gadolinium gallium garnet crystals for radiation dose-rate monitoring systems.
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Matsukura, Daisuke, Kurosawa, Shunsuke, Yamaji, Akihiro, Ohashi, Yuji, Yokota, Yuui, Kamada, Kei, Sato, Hiroki, Toyoda, Satoshi, Yoshino, Masao, Hanada, Takashi, Murakami, Rikito, Horiai, Takahiko, and Yoshikawa, Akira
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CRYSTAL growth , *SINGLE crystals , *RADIATION measurements , *SCINTILLATORS , *LUMINESCENCE , *CRYSTALS - Abstract
• (Gd 1-x Ce x) 3 (Ga 0.995 Cr 0.005) 5 O 12 single crystals were grown by micro-pulling down method. • The emission wavelengths of these crystals were approximately 730 nm. • Cr was segregated in the center part of the crystals. • The relationship between Cr segregation and emission intensity was investigated. • The correlation coefficients of thoes relationships were around 0.9. For the decommissioning of Fukushima Daiichi Nuclear Plants, a novel real-time dose-rate monitor consisting of a scintillator, 100-m long optical fiber and CCD spectrometer has been proposed, and this scintillation material is required to have an emission wavelength of longer than approximately 650 nm. In this paper, as a candidate material for the system, we focused on Ce/Cr co-doped Gd 3 Ga 5 O 12 (Ce/Cr:GGG) single crystals grown by the micro-pulling down method. Since the light output of this material was expected to depend on the Cr3+ concentration, we investigated the relationship between Cr segregation and luminescence properties in Ce/Cr:GGG crystal. Generally, a single photon counting method is not available to evaluate its light output accurately due to the long decay time, we used a novel technique "emission-intensity two-dimensional- mapping method" (2D-image method) to verify the light intensity at each point of the sample. This method realized estimation of the light intensity within the sample, though segregation of Cr3+ is observed. The results showed that Cr was concentrated in the center part along the radial direction in the grown crystals, while all parts had an emission wavelength of approximately 730 nm excited by X-ray. Using the 2D-image method, emission intensity was found to correspond to the Cr concentration, and its correlation coefficients between emission intensity and Cr concentration were over 0.8. We found that our material is available for the monitoring system when the Cr dense part of the crystal is cut and used. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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10. Crystal structure, dielectric and magnetic studies of pure and Sr substituted LaFeO3 single crystal grown by optical floating zone technique.
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Sivakumar, N., Vijayakumar, P., Jayavel, R., Alsalme, Ali, Alsulami, Abdullah S., and Yokota, Yuui
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SINGLE crystals , *CRYSTAL structure , *ENERGY dispersive X-ray spectroscopy , *TRANSCRANIAL magnetic stimulation , *PHASE transitions , *DIELECTRIC measurements , *GRAIN - Abstract
The pure and strontium (Sr) substituted LaFeO 3 polycrystalline samples were prepared through solid state synthesis process and good quality single crystals were successfully grown by four mirror optical floating zone technique for dielectric and magnetic measurements. The feed and seed rods were prepared by employing an external pressure of about 70 MPa and sintered at 1350 ⁰C on 12 h. The orthorhombic structure of the pure and Sr substituted materials were confirmed by powder X-ray diffraction analysis. The nonappearance of shoulder peaks in the Sr substituted LaFeO 3 sample reveals single-phase crystal system without any sub-grain boundaries. The composition of the pure and substituted crystals was confirmed by EDS (energy dispersive X-ray spectroscopy) analysis. The dielectric studies were carried out on both samples in the temperature range from 300 to 900 K for the frequency range from 2.5 kHz to 125 kHz. The grown crystals show their Neel temperature at 742 K and the dielectric constant value increased for substituted LaFeO 3 crystal. A colossal dielectric behavior and electrical conductivities were analyzed through dielectric studies. The activation energies of pure and Sr substituted LaFeO 3 crystals were estimated to be 0.19 and 0.16 eV respectively. Magnetic properties of the developed crystals were tested by M-H loop. The M-T plot of Sr substituted LaFeO 3 crystal was discussed with Zero field cooled (ZFC) and Field cooled (FC) modes for its potential magnetic application. • Peak shift of (121) plane confirms the lanthanide contraction in Sr substituted LaFeO 3 • At 742 K, Sr substituted LaFeO 3 crystal show enhanced dielectric constant, ɛ r = 3.25 × 105 • Ea value of LaFeO 3 and LaSrFeO 3 are 0.19 and 0.16 eV respectively • Sr substituted LaFeO 3 exhibits anti-ferro to ferromagnetic phase transition at 135 K • Sr substituted LaFeO 3 crystal shows improved coercivity, H c = 748.8164 Oe [ABSTRACT FROM AUTHOR]
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- 2023
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11. Crystal growth and optical properties of Ce-doped (La,Y)2Si2O7 single crystal.
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Horiai, Takahiko, Paterek, Juraj, Pejchal, Jan, Jarosova, Marketa, Rohlicek, Jan, Kurosawa, Shunsuke, Hanada, Takashi, Yoshino, Masao, Yamaji, Akihiro, Toyoda, Satoshi, Sato, Hiroki, Ohashi, Yuji, Kamada, Kei, Yokota, Yuui, Yoshikawa, Akira, and Nikl, Martin
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CRYSTAL optics , *SINGLE crystals , *SCINTILLATORS , *ACTIVATION energy - Abstract
• (Ce 0.015 La 0.600 Y 0.385) 2 Si 2 O 7 single crystal was grown by the micro-pulling-down method. • Quenching temperature of (Ce 0.015 La 0.600 Y 0.385) 2 Si 2 O 7 was determined to be 526 K. • Light output of (Ce 0.015 La 0.600 Y 0.385) 2 Si 2 O 7 was determined to be ~12,000 photons/MeV. We have grown Ce-doped (La,Y) 2 Si 2 O 7 single crystal by micro-pulling-down method and investigated its optical and scintillation properties. We have successfully prepared the single crystal with (Ce 0.015 La 0.600 Y 0.385) 2 Si 2 O 7 composition. The observed thermal quenching process could be characterized by the quenching temperature (T 50%) of 526 K and its activation energy was determined to be 0.62 eV. Further considering the thermal quenching factors, it was found that the thermal quenching was caused by at least the thermal ionization and maybe also by classical thermal quenching. The light output and scintillation decay time were evaluated to be ~12,000 photons/MeV and ~42 ns, respectively. These results indicate that (Ce 0.015 La 0.600 Y 0.385) 2 Si 2 O 7 has a great potential for application in scintillation materials. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
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