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A novel lightweight foamed cement-based electromagnetic wave (EMW) absorbing material (Density<0.5 g/cm3) is prepared using secondary aluminum ash (SAA) as a foaming agent and carbon black (CB) as an efficient EMW absorbent, providing a new way to recycle SAA. The pore structure parameters, reflection loss (RL), mechanical strength and thermal conductivity are systematically investigated. The experimental test results indicate that the pore structure of cement matrix prepared by SAA exhibits better EMW loss performance than those prepared by traditional foaming agent. The analysis of the pore structure images indicates that the average pore size is reduced, and pore size distribution shifts towards smaller sizes due to the addition of CB. Furthermore, the roundness of pores is increased due to the formation of more irregular pores. Increasing CB content and thickness can reduce RL, enhance absorbing performance at low frequencies, and broaden effective absorbing bandwidth (EAB). The absorbing performance was tested using the arch reflection method in the frequency range of 1.1–18 GHz, the excellent absorbing performance and the widest EAB (RL<−10 dB) reach −36.34 dB and 14.46 GHz, respectively, at a thickness of 4 cm. Benefiting from excellent pore structure, the foamed cement-based material also exhibits better mechanical strength, and good thermal insulation properties are maintained after adding CB. The compressive and flexural strength can reach 2.18 MPa and 1.02 MPa, respectively, while the thermal conductivity remains below 0.122 W/(m·K). • Lightweight cement-based absorber was firstly prepared using SAA as foaming agent. • The effect of CB on pore structure and EMW absorbing property is investigated. • EAB and minimum RL of the developed absorber reach 14.46 GHz and − 36.34 dB. • A new way to recycle SAA is provided. [ABSTRACT FROM AUTHOR]

In this study, a multi-functional guar gum aerogel with the oriented lamellar structure, which introduced sodium silicate (Na 2 O·nSiO 2) and phytic acid (PA) as thermal insulation additives and flame-retardant agents, respectively, was fabricated via freeze drying. Our aerogel's chemical structure, morphology, and thermal and mechanical properties were analyzed. The oriented lamellar structure was attributed to the orientated growth of ice crystals, which was induced by the "silicate-guar, guar-phytate, and phytate-silicate" multiple hydrogen bonds formed between Na 2 O·nSiO 2 , PA, and guar gum. The density of the sample with 2 wt% PA could reach 0.0335 g·cm−3, and the porosity was 5 %, along with a specific pore volume of 0.8144 cm3·g−1. The mechanical properties and thermal insulation performed significant differences in the radial and axial direction of the oriented lamella (nearly 100 % resilience while 50 % deformation quantity and 0.0235 W/(m*K) of thermal conductivity in the radial direction, up to 0.079 MPa of compressive strength in the axial direction). The presence of PA attached a good flame-retardant ability to our aerogel (The Limiting Oxygen Index (LOI) was 30.77 %). This work provides a novel and promising method for developing anisotropic aerogel with excellent potential in building energy efficiency and flame-retardant. [ABSTRACT FROM AUTHOR]

Needle-punched fabric reinforced nanoporous phenolic composite (NPC) is a kind of promising ablative thermal protection material for spaceflight. However, in practical applications, typically anisotropic microstructure of NPC may lead to different performances and damage mechanisms under various directional mechanical or thermal loads. Herein, NPC is prepared and cut into specimens along three typical plane directions including XY -plane (0°), Z -plane (90°), and transitional-plane (45°), and their mechanical, thermal insulation, and ablation behaviors are systematically investigated. Benefiting from the woven fabric in XY -plane, NPC in 0°-plane direction exhibits highest tensile strength (169.2 ± 12.6 MPa), and CT image-based simulation further verifies that woven fabrics are primary load-bearing structure. Meanwhile, NPC in 45°-plane direction shows highest compressive strength (443.1 ± 18.2 MPa) but low compressive stress at low strain, demonstrating a weak bonding between two layers of woven fabrics. Moreover, the heat transfer simulation indicates that horizontally stacked woven fabrics effectively protect the internal material from thermal erosion, thus NPC in 0°-plane direction exhibits optimal thermal insulation. The ablation testing and micro-CT observations further demonstrate that the angle between woven fabric and thermal load significantly influences the ablation mechanism. The present work will further promote the structural reliability and optimization of needle-punched composites. [Display omitted] [ABSTRACT FROM AUTHOR]

The anisotropic cellulose nanofiber (CNF)/carbon nanotube (CNT) aerogels hold a great promise in directional applications due to their distinct xylem-like aligned penetrating pore structures. The aspect ratio of CNF plays a crucial role in the pore structures of aerogels, directly dominating the final macroscopic properties of materials. Herein, three types of CNF with different aspect ratios were extracted through the 2,2,6,6-tetrmethylpiperidine-1-oxyl radical (TEMPO) oxidation process by changing the doses of oxidant. The corresponding anisotropic CNF/CNT aerogels were prepared by the unidirectional freeze-drying method and then their pore morphologies and properties were investigated in detail. The resulting aerogel with the shortest aspect ratio of CNF exhibited the densest porous structure, thereby obtaining the highest compressive strength of 110 kPa and elastic modulus of 383 kPa, while that containing the longest CNF possessed the highest thermal conductivity coefficient of 0.17 W m−1 K−1 and the worst thermal insulation. This research explored the relationship between the properties of the CNF/CNT aerogels and devisable pore structures caused by various aspect ratios of CNF, thus providing a new insight into the development of CNF/CNT aerogels with tunable performances. [ABSTRACT FROM AUTHOR]

Polyurethane (PU) possesses excellent thermal properties, making it an ideal material for thermal insulation. Incorporating Phase Change Materials (PCMs) capsules into Polyurethane has proven to be an effective strategy for enhancing building envelopes. This innovative design substantially enhances indoor thermal stability and minimizes fluctuations in indoor air temperature. To investigate the thermal conductivity of the Polyurethane-Phase Change Materials foam composite, we propose a hierarchical multi-scale model utilizing Physics-Informed Neural Networks (PINNs). This model allows accurate prediction and analysis of the material's thermal conductivity at both the meso-scale and macro-scale. By leveraging the integration of physics-based knowledge and data-driven learning offered by Physics-Informed Neural Networks, we effectively tackle inverse problems and address complex multi-scale phenomena. Furthermore, the obtained thermal conductivity data facilitates the optimization of material design. To fully consider the occupants' thermal comfort within a building envelope, we conduct a case study evaluating the performance of this optimized material in a detached house. Simultaneously, we predict the energy consumption associated with this scenario. All outcomes demonstrate the promising nature of this design, enabling passive building energy design and significantly improving occupants' comfort. The successful development of this Physics-Informed Neural Networks-based multi-scale model holds immense potential for advancing our understanding of Polyurethane-Phase Change Material's thermal properties. It can contribute to the design and optimization of materials for various practical applications, including thermal energy storage systems and insulation design in advanced building envelopes. [ABSTRACT FROM AUTHOR]

• Rigid polyurethane foam as the preferred thermal insulation. • Analysis of the influence of fly ash on material thermal conductivity. • Calculation of the heat balance for a wall with polyurethane insulation. • Study of the temperature field in the cross-section of the wall. Limitations in natural resource availability have a significant impact on prices of thermal energy. As a result, a growth of interest in the technology of insulation materials is observed. The paper presents a comparative analysis of rigid polyurethane foams, which are widely used as insulation materials. Rigid polyurethane foam with 10 wt.% addition of coal fly ash is compared to a reference foam, without any addition. The thermal conductivity coefficient of polyurethane materials was determined by the Hot Disk device. Heat transfer for both types of foams was modelled. As a result of the numerical modelling, the temperature field for the wall was obtained. The results of the computations have shown differences in energy losses. Conducted analyses demonstrate that the modified polyurethane foam (with the addition of coal fly ash) performs better as an insulation material. The reduction of heat requirement is 2.9 %. An environmental analysis of the insulation materials was also carried out. Using the SUBRAW index method it was calculated that embodied energy and the carbon footprint are lower in the case of the modified polyurethane compared to the unmodified foam. [ABSTRACT FROM AUTHOR]

[Display omitted] • A novel type of PI/SIO 2 composite aerogel was prepared by a confined filling strategy. • The PI/SiO 2 composite aerogels exhibit ultra-low density and super thermal insulation. • The sound insulation and mechanical properties are significantly enhanced owing to the "honeycomb-like" structure. Aerogels have enormous potential in integrated thermal insulation and noise reduction applications. According to the knowledge of the favorable mechanical and acoustic properties of honeycomb structures. We employed anisotropic "honeycomb-like" polyimide (PI) aerogels as the matrix and utilized a confined filling strategy to directionally filled continuous SiO 2 aerogels into the PI aerogel matrix. This resulted in the creation of an exceptional organic–inorganic composite aerogel (PISis) with outstanding thermal and acoustic insulation performance. The radial thermal conductivity of PISis ranged from 22.37 to 27.65 mW·m−1·K−1, and the initial decomposition temperature was approximately 524–557 °C. In the frequency range of 500–6300 Hz, the average sound transmission loss (STL) of the 18 mm thick composite material reached 30.67 ∼ 31.89 dB, and the compressive strength at 10 % strain is 0.416 MPa. The PISis exhibits a density ranging from 0.1012 to 0.1302 g/cm3. These make it an ideal lightweight, high-strength, and efficient material for thermal and acoustic insulation. [ABSTRACT FROM AUTHOR]

In the field of material science, foaming agents common are commonly used for enhancing the thermal insulation and phase change materials (PCM) for heat storage. However, PCM tends to agglomerate in the cement slurry with the directly addition, presenting an obstacle to effective dispersion. Moreover, the addition of PCM leads to rapid defoaming. To overcome this issue, a novel nanoparticle-stabilized foam was designed in this study to create a three-component system that enhances the interaction of viscosity modifiers, surfactants, and foam stabilizers. The effect of cement density on thermal insulation was evaluated by analyzing thermal conductivity and heat transfer performance tests, as well as exploring the mechanical properties of the cement-based materials. Scanning electron microscope (SEM) images show that the foam designed in this study remarkably promotes the dispersion of PCM microcapsules, indicating the bridging interactions of foam in the cement paste. The result shows that the thermal conductivity of foam cement with 15 vol% PCM microcapsules drops from 0.11 W/m·k to 0.07 W/m·k compared to that without PCM addition, with a dry density around 600 kg / m 3. Furthermore, the specimens with the addition of PCM achieve the endothermic and exothermic peaks under experimental images. This discovery is of great significance to heat absorption ability of low-density concrete, where the addition of PCM leads to a slower foam bursting under the nanoparticle-reinforced foam system. The dispersion and connectivity of foams, as well as the physical characteristics of PCM, provide new perspectives for coexistence in a relatively stable system in this way. • Nanoparticle-stabilized foam remains stable within the cement slurry. • Stable foam contributes to the low thermal conductivity and superior insulation performance of foam cement. • The sustainable and environmentally friendly energy-saving effects of phase change materials microcapsules in foam cement. • A novel lightweight and eco-friendly cement with thermal regulation capabilities. [ABSTRACT FROM AUTHOR]

• Silica aerogel granules were replaced by quartz sand of 0 to 4.5 wt% to produce lightweight cement-based composite mortars. • SAG has increased the water absorption and porosity of the mortar, while reduced compressive strength and hardened density. • Pores increased with increase in aerogel, SAG tend to agglomerate, and pores accumulate around the aerogel particles. • SAG significantly decreased thermal conductivity from 0.772 to 0.155 W/mK. • SAG also reduced thermal diffusivity and heat storage, and increased specific heat. It has been discovered in recent years that the use of silica aerogel in cement-based materials contributes to the thermal insulation properties of the materials, and studies on this subject have gained importance. However, it was determined that the studies mostly remained at the level of the thermal conductivity coefficient and the main physical and mechanical properties of the materials. In this study, a comprehensive research was carried out with the replacement of micro-sized aerogel particles with quartz sand in different ratios (0, 1, 1.6, 2.4, 3.2, 4 and 4.5 wt%) in lightweight cement-based composite mortar (LCCM) combinations. Specifically, the effect of silica aerogel granules (SAG) on flowability, fresh and hardened densities, porosity, water absorption, compressive strength, macro/microstructural properties (by optic microscope, SEM, XRD analysis), thermal conductivity, specific heat, thermal diffusivity and heat storage capability of LCCMs were investigated. While SAG could increase the flowability (up to 8.4 %) at low using rates, it decreased it at higher rates. It is very effective in reducing fresh and hardened densities. However, it highly increased porosity and water absorption, and greatly decreased compressive strength. On the other hand, generally the poor interfacial properties of the cement matrix and the aerogel were moderately improved in this study. The lowest thermal conductivity was determined as 0.155 W/mK in the highest SAG usage. SAG increased specific heat, decreased thermal diffusivity and decreased heat storage capability of LCCMs up to 45.23 %, 63.49 % and 46.32 %, respectively. As a result of the study, aerogel has been identified as a very suitable material that can be used to highly improve thermal properties in LCCMs. [ABSTRACT FROM AUTHOR]

• Phenolic resin is used as an insulation modifier for geopolymer for the first time. • Phenolic resin can increase the porosity of fly ash geopolymer. • Phenolic resin can reduce the porosity of nanopores but increase more micropores. • Phenolic resin narrows the throat of the ink bottle pores. • An iterative method related thermal conductivity prediction method is proposed. Phenolic resin has been widely used owing to its excellent thermal insulation performance. However, the application of phenolic resin in the field of geopolymer remains unexplored. Here, the foamed fly ash geopolymer samples with high porosity were prepared using phenolic resin for the purpose of foaming materials. The thermal insulation properties of these samples were evaluated by Transient Plane Source Method, and the effect of phenolic resin on pore characteristics was investigated by Mercury Intrusion Porosimetry (MIP), aim to explore how phenolic resin affects the thermal conductivity by changing the pore characteristics of geopolymer. In addition, considering that the internal gas thermal conductivity of pores with different pore sizes is also different (Knudsen effect), in order to predict the thermal conductivity more accurately, this research proposes an iterative calculation method to establish a thermal conductivity model. The results show that phenolic resin can improve the thermal insulation effect of geopolymer, and the minimum thermal conductivity of the sample is 0.17 W/m·K. In addition, according to the test results of MIP, it can be found that phenolic resin mainly promotes the porosity of micron pores (>1 μm) whereas there is slight inhibition on nano pores (<1 μm), but the beneficial effect of the increase of micron-sized pores (>1 μm) on the thermal insulation performance of geopolymer is greater than the negative influence effect of the disappearance of nano pores. Moreover, according to the results of MIP, phenolic resin can narrow the throat in the pore of the ink bottle, limit the thermal convection of the gas between the pores, and reduce the thermal conductivity. Finally, the newly modified Russell model considering the Knudsen effect can effectively predict the thermal conductivity by using the experimental data. This study provides a new method to improve thermal insulation performance of geopolymers and offers a new building insulation product. [ABSTRACT FROM AUTHOR]

• Properties of alkali-excited fly ash aerogel foam concrete were studied. • The microstructure of alkali-excited fly ash aerogel foamed concrete was analyzed. • Test variable included aerogel particles, fly ash, foam and polypropylene fiber. • Developed concrete exhibited excellent thermal performance and mechanical strength. • Aerogel used in concrete had excellent thermal insulation performance. With increasing focus on low-carbon energy conservation and environmental protection, there is a need to consider all aspects of life in future developments. To meet the concept and requirements of energy conservation and environmental protection in the building industry, we have developed alkali-excited aerogel-foamed concrete that exhibits excellent thermal insulation performance and mechanical strength. The variables involved in its production include fly ash, foam, aerogels, and polypropylene fibres. In this study, the microstructure and mechanical and thermal properties of alkali-excited fly ash aerogel foam concrete was analysed. The results indicated that fly ash can replace a portion of the cement, resulting in a reduction in the thermal conductivity of the concrete. The addition of aerogels and foams to the concrete can significantly decrease its thermal conductivity. Specifically, when the aerogel content reaches 12 % and the foam content reaches 75 %, the thermal conductivity of the concrete decreases from 0.498 W/m·K to 0.183 W/m·K and 0.19 W/m·K, respectively. However, this decrease in thermal conductivity comes at a cost of approximately 50 % reduction in the flexural and compressive strengths of the concrete. The findings reveal that the aerogel has excellent thermal insulation performance similar to that of the foam, but it has little influence on the mechanical properties of the concrete. Additionally, an increase in the polypropylene fibre content significantly improves the mechanical properties of alkali-excited fly ash aerogel concrete, but the thermal properties of the concrete remain mostly unaffected. [ABSTRACT FROM AUTHOR]

• Mechanical and thermal properties of straw boards with high densities are studied. • Tensile strength prediction method of straw boards is proposed. • Correlation between thermal conductivity and density of straw boards is revealed. • Feasibility of using straw boards for load bearing and insulation is verified. • Wheat straw strand board is identified as transversely isotropic material. Straw is an environmentally friendly, cost-effective, and abundant raw material for building boards. To assess the feasibility of using straw boards in building envelops, such as being alternative sheathing panels in light-gauge steel-framed members, for instance, walls and floors, both the mechanical and thermal properties of straw boards with high densities were investigated. The straw boards involved in this study include five wheat straw strand boards (WSSB12, WSSB15, WSSB18, WSSB25, and WSSB30) and a paper straw board (PSB58) named with a combination of the respective board type and thickness. Among them, the WSSBs are a type of straw composite, while the PSB is an improved straw bale with sheathing paper, which is mainly for enhancing the board integrality. Moreover, the former is composed of smashed straw fibers and isocyanate resin and has higher densities, while the latter is without using any artificial binders. Mechanical properties, including compression, tension, and bending properties, were investigated by tests and a proposed prediction method of tensile strength. In the experimental studies of compression properties, the failure modes, characteristics of load-deformation curves, and the differences in material directivity were analyzed and discussed. The results show that the WSSBs were considered to be transverse isotropic material with brittle characteristics in the plane. Then, the experimental studies of bending properties were carried out, and the results show that the bending strength is less than the compressive strength for WSSBs, while the bending strength of PSB is greater than its compressive strength. And the bending elastic modulus and the compression elastic modulus are close for either the WSSBs or the PSB. Furthermore, finite element models of the bending test specimens using the user material subroutine UMAT were developed to predict the tensile strength f t , and the constraint checks were conducted. It is verified that the prediction results of f t are believable, and the prediction method proposed is feasible. For the thermal properties of straw boards, tests were performed using the temperature control box - heat flux meter method, and the thermal conductivity λ was mainly focused. It is found that a significant linear correlation exists between the density ρ and λ , and the proposed fitting formula can be used to predict the thermal conductivities of such materials. Finally, brief comparisons of the mechanical and thermal properties between the straw boards and the oriented strand boards (OSBs) were conducted, and the feasibility of applying straw boards in building envelops, such as alternative sheathing panels with load bearing and insulation demands was verified. This study contributes to popularizing the application of straw boards in engineering structures by a compromising consideration of mechanical and thermal properties, which plays a positive role in the development of green buildings. [ABSTRACT FROM AUTHOR]

To promote environmentally sustainable behavior, it is meaningful to develop a simple preparation method of polyurethane foam (PUF) with excellent performance and degradability. Herein, PUF composites were economically and conveniently synthesized by mixed foaming of polyurethane prepolymer and cellulose nanocrystals (CNCs). After the hydrolysis of dissolving pulp fibers with formic acid (FA), hydrophobic ester groups were introduced in CNCs, thereby increasing the surface hydrophobicity of PUF composites. CNCs acted as a reinforcement agent capable can replace 10% up to 60% prepolymer for foaming, the modified PUF exhibiting gradient morphology structure and enhanced specific mechanical and thermal properties. When the CNCs replacement ratio was 50%, the maximum compressive stress was 1103.19 kPa, which is 21-fold that of the original foam. Remarkably, the addition of CNCs enhanced thermal insulation performance of the prepared foam, which of thermal conductivity decreased from 0.0780 W/mK to 0.0549 W/mK. The upgraded polyurethane foam composites promise to open exciting new windows on producing fire resistance PUF with enhanced performance. [Display omitted] • PUF composites were fabricated by polyurethane prepolymer and CNCs. • Maximum compressive stress reached 1103.19 kPa at 50% replacement rate of CNCs. • Thermal conductivity of foams decreased from 0.0780 W/mK to 0.0549 W/mK. • Sustainable and economically feasible method for producing fire resistance PUF. [ABSTRACT FROM AUTHOR]

Thermally insulating aramid nanofiber (ANF) aerogels enable a wide range of applications but are limited by their low mechanical elasticity. Efficient design of aerogels' components and microstructures is crucial yet remains highly challenging for effectively improving the flexibility of ANF aerogels. Here, for the first time, we report the incorporation of boron nitride nanoribbons (BNNRs) into ANF aerogel to form a multilayer BNNR/ANF hybrid aerogel, which is prepared by suspension mixing of BNNRs and ANFs followed by a vacuum-assisted and directional solidification process. Flexible BNNRs with a high aspect ratio are uniformly embedded in the ANF networks, giving the ANF aerogel an extremely high mechanical deformability (up to 60 % compressive strain), capable of retaining its elasticity even after 100 compression cycles or in liquid N 2 (−196 °C). Moreover, the introduction of BNNRs does not reduce the thermal insulation capacity of ANF aerogels, while significantly improving their thermal stability and fire resistance. These excellent multifunctionality benefits from the synergistic effect of organic–inorganic components and the multilayer structure of aerogel. This work paves the avenue for developing next-generation elastic and thermal insulating materials with great potential for widespread applications. [Display omitted] [ABSTRACT FROM AUTHOR]

The optical and thermal performances of energy-saving glazing require improvement to reduce peak thermal load and increase solar energy conversion and management efficiency. Herein, it is indispensable to develop novel composite materials that designate the ability to achieve multifunction by thermal load migration as well as radiation transmittance modulation. This study developed a nanoparticle-enhanced phase change material (NEPCM) with spectrally selective and phase change functions. A data-driven algorithm is first developed to evaluate the solar-weighted absorption fraction, integrated irradiance, and spectral irradiance for the considered nanoparticles. The base fluids, nanoparticle diameter, concentrations, and proportions are taken into account in the program, and adjustments to the properties of NEPCM can be easily made. The NEPCM properties exhibit a high blocking performance of near-infrared solar radiation by 30.9%, while keeping visible transmittance at 51.8% using ATO-Al 2 O 3 NEPCM. Furthermore, the photothermal conversion performance of a NEPCM-filled energy-saving prototype window is explored, which yields a heat absorption rate of up to 0.27 °C/min when the solar irradiance is 800 W/m2. In addition, the energy consumption of transparent envelopes with NEPCM filler in a full-scale building is investigated. The results show that NEPCM regulated glazing potentially provides annual heating energy-saving from 5.1 to 41.7 kWh·m−2·year−1 in three representative climatic conditions in different global locations. Outcomes on the spectrally selective capabilities of the energy-saving window provide ideas for advancing the development of low-carbon transparent building envelopes. • A data-driven algorithm is developed to determine optimal parameters of NEPCM. • An algorithm presented to predict thermal conductivity of the phase change material. • Effect of NEPCM for a scale building in three different climate was investigated. • NPRGs reduce the solar transmission through windows by 2229–2580 W per year. • Using NEPCM provide annual heating energy savings of 5.1–41.7 kW h·m−2·yr−1. [ABSTRACT FROM AUTHOR]

In this work, a facile microwave-assisted foaming and thermal imidization treatment method was proposed to fabricate flexible polyimide (PI)/rGO composite foams with anisotropic pore structures. The PI/rGO composite foams (PIF/rGO) were used as the starting derivatives to prepare carbon foams that demonstrated excellent anisotropic thermal insulation and electromagnetic interference (EMI) shielding applications. The directional growth of pore structures during the foaming period resulted in the formation of aligned ellipsoidal strip-like pore structure in the horizontal direction (i.e., perpendicular to the pore growth direction), which was attributed to the escape of foaming gases such as tetrahydrofuran, methanol and H 2 O. The homogeneous dispersion of rGO in the PI-derived carbon skeleton endowed corresponding carbon foams with excellent mechanical and thermal stability, high thermal insulation and electrical conductivity (σ) as well as absorption dominated EMI shielding performance. The σ and EMI shielding effectiveness (SE) of carbon foams showed an increasing trend with increasing rGO content. The σ, EMI SE and specific EMI SE of the carbon foams reached up to 33.0 S/m, 49.0 dB and 8792.8 dB/(g/cm2) in the horizontal direction, respectively. Therefore, this work provided a facile strategy to fabricate lightweight and anisotropic pore structure rGO-containing PIFs and carbonized derivatives, which demonstrated promising applications in high-end industrial fields. [Display omitted] • A facile strategy was proposed to prepare PIF/rGO and CF/rGO. • The directional growth of pores endowed foams with anisotropic properties. • The foams showed excellent mechanical and thermal insulation properties. • CF/rGO showed absorption-dominated EMI shielding performances. [ABSTRACT FROM AUTHOR]

A hierarchical host-guest structural composite was developed via introducing shear stiffening polyborosiloxane gel into robust porous polyimide matrix. The synergistic effect of host and guest phases contributed to favorable balance between mechanical and thermal properties, which endowed the composite with exceptional impact resistance, acoustic and thermal insulation capacity. The composite performed well as a protective wrapping in resisting multiple interferences to ensure the electrical superstability of conductive elements. [Display omitted] • A host-guest composite was developed by introducing PBS into polyimide foam. • The composite showed ideal impact resistance and acoustic insulation property. • The composite had low thermal conductivity and good thermal insulation capacity. • The composite could act as protective wrappings to guarantee electro-stability. The ubiquitous existence of mechanical impact, sound pollution and thermal damage conferred severe risks to both individuals and devices, which catalyzed increasing demand for advanced protective materials. Though biomimetic structures have motivated the development of high-performance protective composites against a simple threat, the realization of multi-mode interference protection remained a challenging issue. This work proposed a host-guest structural composite, consisting of viscoelastic polyborosiloxane (PBS) dispersively distributed in porous polyimide (PI) matrix. The resulting PI-PBS composite presented effective impact force attenuation (85.8%-92.3%), arising from the multi scale energy dissipation mechanism of strain-rate enhancement, structural densification and synergistic stress transfer, which was intuitively demonstrated by an innovative mechano-discoloration approach. The viscous dissipation effect endowed PI-PBS with extraordinary acoustic insulation effectiveness in a wide frequency region (1–6.3 kHz). Due to the low thermal conductivity (0.051 W/(m·K)), PI-PBS presented good thermal insulation performance over a wide temperature range (∼ −80 – 300 °C). The structure dependence of thermal conduction behavior was revealed via FE simulation, while demonstrating various applications in dynamic infrared thermal camouflage. PI-PBS, as a functional wrapping, provided reliable guarantee for electrical stability of conductive elements against impact, ultrasonic and thermal interferences, which indicated significant value in electromagnetic shielding, sensing and electrothermal fields. Therefore, PI-PBS could assist in efforts to lighten, integrate and intelligentize protective materials in the future. [ABSTRACT FROM AUTHOR]

• Cyclic loads applied on foam glass aggregates (FGA) at different compaction ratios. • FGA response under deviatoric stresses 25 kPa, 100 kPa, and 200 kPa was investigated. • Resilient modulus (M r) and accumulated plastic strain (ɛ acc) were measured. • Increasing the compaction ratio led to a significant decrease in ɛ acc values. • Revealed that FGA at 40% can be used in infrastructure base layer material. Foam glass aggregate (FGA) is considered as a lightweight and thermal insulation material. It has a wide granular size distribution nature that can influence the material's dynamic response when subjected to moving loads. Therefore, it is crucial to investigate the impact of different compaction ratios on the material's dynamic behavior. This study focused on examining the effects of varying compaction ratios (10%, 20%, 30%, and 40%) on dynamic parameters such as resilient stiffness (M r) and accumulated plastic strains (ɛ acc) of FGA. Uniaxial deviatoric stresses were applied to the material samples in a series to assess their influence on the material's behavior over multiple cycles. The results revealed the significant influence of increasing the compaction ratio to 40% on the material's behavior. At this compaction ratio, the ɛ acc decreased to approximately 71%, 69%, and 86% for deviatoric stresses of 25 kPa, 100 kPa, and 200 kPa, respectively, after subjecting the material to 40,000 cycles. The increase in recoverable strains resulting from the material's fragile property under higher compaction energy led to a decrease in the M r values of FGA samples as the compaction ratios increased. The lower boundary of M r values for FGA ranged from 102 MPa to 189 MPa, while the upper boundary ranged from 150 MPa to 219 MPa under the selected deviatoric stresses. Although the interpretation of the shakedown criterion limitations yielded varying ranges for the colocation of FGA samples, it was found that FGA samples compacted at 40% exhibited robust characteristics suitable for constructing road embankments. This can be beneficial for infrastructure applications due to their excellent lightweight and thermal insulation properties. [ABSTRACT FROM AUTHOR]

[Display omitted] • Porous coral-like Co/CoO/RGO hybrid aerogels are successfully developed. • The special structure brings multiple loss modes and good impedance matching. • Achieving high EM wave loss, hydrophobicity and thermal insulation properties. • DFT simulations are adopted to verify the interface polarization of interfaces. Addressing the growing issue of electromagnetic radiation calls for urgent exploration of effective electromagnetic wave absorbers. Herein, a series of coral-like Co/CoO nanoparticles/reduced graphene oxide (Co/CoO/RGO) hybrid aerogels were synthesized via a freeze drying-thermal reduction strategy. Their advantages involving porous interconnected framework, abundant heterogeneous interfaces, and integration of dielectric/magnetic units could bring multiple loss modes. By manipulating the Co(CO 3) 0.5 (OH)·0.11H 2 O (CCOH) addition and reduction temperature, the electromagnetic parameters could be tuned, ultimately resulting in optimal absorption capability with maximal reflection loss of –32.4 dB and effective bandwidth of 4.2 GHz. More importantly, excepting the high electromagnetic wave loss, Co/CoO/RGO hybrid aerogels also exhibit good hydrophobicity and thermal insulation properties, making them suitable for application in harsh environment. Besides, the special structure and multiple components lead to multiple heterointerfaces in aerogels, the resultant interface polarization is deemed to contribute to electromagnetic wave loss. Here, Density Functional Theory (DFT) simulation based on first-principles is adopted to verify the contribution of interface polarization from the theoretical level. According to the simulation results, the electron-occupied states near the Fermi level are significantly different among the different phases comprising the heterointerfaces, and there is a noticeable accumulation of charge at these interfaces, successfully affirming the interface polarization behavior at different interfaces. [ABSTRACT FROM AUTHOR]

Naturally-derived aerogels have attracted considerable attention owing to their good biocompatibility, biodegradability and sustainability, but their weak mechanical properties largely limit their applications in various fields. Herein, we proposed the use of a directional freeze-drying method to prepare an anisotropic honeycomb three-dimensional porous aerogel with water-soluble chitosan (CS) as a rigid skeleton and water-soluble biobased epoxy resin as cross-linked hard segments, which had low volume shrinkage and density of 13.9 % and 34.3 mg/cm3, respectively. The resultant aerogel had anisotropic mechanical properties, such as rigidity in the axial direction with a maximum axial modulus of 6.71 MPa, which was 51.6 times larger than that of the pure chitosan aerogel, demonstrating a good compressive elasticity in the radial direction. It also had anisotropic thermal management properties, with a lower thermal conductivity in the radial direction than in the axial direction, down to 0.029 W/mK. The introduction of biobased epoxy resin improved the overall thermal stability, flame retardancy, and increased the biomass content in the aerogel, reducing the carbon footprint of the material. This study paves the way for the construction of a special graded porous, structurally and functionally integrated thermal insulation aerogel, which is of great significance for the development of new thermal insulation materials. [Display omitted] • Anisotropic honeycomb bio-based aerogels have been prepared by directional freeze-drying. • The introducing of bio-based epoxy resin improves the comprehensive properties of aerogel. • The aerogel exhibits low thermal conductivity of 0.029 W/mK in the radical direction. • The aerogel shows low volume shrinkage (13.9 %) and density (34.3 mg/cm3). [ABSTRACT FROM AUTHOR]

[Display omitted] • The newly developed synthesis for thin insulating composite layers from silica cryogels and cellulose fibers. • The cellulose fibers have a new role; they give the matrix of composite. • Perfect thin film can be obtained by NaOH-carbamide additive. • The composites can be characterised by low thermal conductivity, 0.048 W/(m⋅K) and low dust loss (0.01 w/w%). • The composites represent a good adhesion to the various substrates (metals, glass, polymers). This study proposed the preparation of light, thin insulating composite layers from potential biocompatible components such as highly porous silica cryogels and cellulose fibers. One of the novelties in this work is the application of cellulose fibers as matrix, and the silica cryogel particles provide the reinforcing phase. The synthesis of silica cryogel was carried out by means of sol-gel chemistry and freeze drying process. The function of additives (NaOH, carbamide, hydroxyethyl cellulose) was to create connections between the components in the composites. The study extended to the investigation of chemical compositions, the time of treatment, as well as the measurements of the dust loss, thermal conductivity, and the adhesion of composites to the various substrates. The bond system of composites was controlled by FTIR, the morphology by SEM. The composites can be characterised by excellent thermal insulation properties (0.048 W/(m⋅K), very low dust loss (0.01 w/w%), and good adhesion to various surfaces. [ABSTRACT FROM AUTHOR]

Cellulose has attracted considerable attention as a potential substitute for plastics. However, the flammability and high thermal insulation properties of cellulose contradict the unique requirements for highly integrated and miniaturized electronics i.e., rapid thermal dissipation and efficient flame retardancy. In this work, cellulose was first phosphorylated to achieve intrinsic flame-retardant properties, and subsequently treated with MoS 2 and BN, ensuring efficient dispersion throughout the material. Via chemical crosslinking, a sandwich-like unit was formed, in the order of BN, MoS 2 , and phosphorylated cellulose nanofibers (PCNF). The sandwich-like units were further self-assembled, layer-by-layer, to successfully create BN/MoS 2 /PCNF composite films exhibiting excellent thermal conductivity and flame retardancy, and comprised a low MoS 2 and BN loading. The thermal conductivity of the BN/MoS 2 /PCNF composite film containing 5 wt% BN nanosheets was higher than that of neat PCNF film. The combustion characterization of BN/MoS 2 /PCNF composite films revealed highly desirable properties that were far more superior than the BN/MoS 2 /TCNF (TCNF, TEMPO-oxidized cellulose nanofibers) composite films. Moreover, the toxic volatiles that escaped from flaming BN/MoS 2 /PCNF composite films were significantly reduced compared to that of the BN/MoS 2 /TCNF composite film alternative. The thermal conductivity and flame retardancy of BN/MoS 2 /PCNF composite films have promising application prospects in highly integrated and eco-friendly electronics. [Display omitted] [ABSTRACT FROM AUTHOR]

Fabric-based electromagnetic wave (EMW) absorption materials are desirable owing to their inherent flexibility, cost-effectiveness, and easily conformable lightweight structures. However, the problems such as high density and susceptibility to abrasion limit their applications and service life. Herein, flexible fabric-based EMW absorption material (FEMWAM) were prepared by a multiscale synergistic approach. At the microscopic scale, CF@NiCo 2 O 4 @MnO 2 absorbents with enhanced impedance matching and interfacial polarization are prepared by solvent method and hydrothermal process. The influence of heterostructure on the electromagnetic response is also examined. At the macroscopic scale, flexible FEMWAM are prepared by freeze-drying. The electromagnetic parameters of FEMWAM was effectively regulated by altering the amount of the CF@NiCo 2 O 4 @MnO 2 absorbents, which achieve excellent EMW absorption performance and thermal insulation property while maintaining flexibility. The minimal reflection loss (RL min) of −27.8 dB can be achieved at a thickness of 2.70 mm, and an EAB covering the complete X-band can be obtained when the thickness is in the range of 3.20–3.26 mm. The large thickness range provides convenience for the control of dimensional accuracy in actual production, so as to better adapt to practical applications. These findings provide effective guidance for the preparation of EMW absorption materials with excellent flexibility, thermal insulation properties and absorption performance. [Display omitted] [ABSTRACT FROM AUTHOR]

Paper-based materials, due to their availability, environmental benefits and high thermal properties, have already been implemented in several building envelope designs. However, most of them either did not optimise the use of the material or did not provide sufficient thermal insulation for use in permanent buildings. The presented research analyses six original paper-based building envelope core proposals, suitable for use in permanent buildings in temperate climate of Europe, in terms of thermal and environmental efficiency. Proposals include cores with embedded paper tubes structural elements, timber-cardboard studs and sandwich designs. The heat transfer coefficient of the envelopes was obtained for repeatable modules via 2D computer simulations (ThermCAD software), and the environmental impact was assessed for a representative square metre of the envelope via LCA analysis, based in ecoinvent 3.8 database. All analysed designs showed high thermal insulation properties and met the requirements for U max = 0.20 W/m2K, did not cause the risk of surface condensation, nor have excessive thermal bridges. The analysed building envelope designs based on embedded frame wall structure showed environmental superiority over conventional envelopes (timber frame and SIP panels). The research may serve as a proof of concept, for using paper-based building envelopes in sustainable architecture. [ABSTRACT FROM AUTHOR]

• Gibbs free energy mainly dominates the formation of bixbyite-structured five-principal rare-earth element HEOs. • Cooling rate is the second factor on the phase structure formation of HEOs. • HEO4 exhibits higher fracture toughness and lower thermal conductivity than Y 2 O 3. • HEO4 shows a superior oxygen barrier property than 8YSZ. Cubic bixbyite-structured high-entropy oxides (HEOs) are regarded as potential candidates in high temperature thermal insulation field in recent years. However, their relevant properties are still needed to be explored for possible applications. In this work, twelve new high-entropy oxides (HEO1-12) of (5Re 0.2) 2 O 3 (Re represents five elements selected from Ce, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb) are prepared by solution combustion synthesis method combined with conventional sintering. Except HEO10 with a single monoclinic phase, other samples have a single bixbyite phase. The average grain size of bixbyite-structured samples is within 0.76 ∼ 4.96 μm. Then, the samples of HEO4, 5, 7–9 are chosen to study their mechanical and thermal properties. Their nano-modulus, nano-hardness, fracture toughness K IC , brittleness M and surface fracture energy are in the range of 152.42 ∼ 237.33 GPa, 9.22 ∼ 12.65 GPa, 1.77 ∼ 2.51 MPa·m1/2, 2.35 ∼ 3.09 μm−1/2 and 9.00 ∼ 22.49 J m−2, respectively. HEO4, i.e., (Ce 0.2 Nd 0.2 Sm 0.2 Dy 0.2 Gd 0.2) 2 O 3 , exhibits higher K IC (1.92 MPa·m1/2) and lower M (2.71 μm−1/2) than another reported cubic bixbyite-structured HEO of (Eu 0.2 Er 0.2 Lu 0.2 Y 0.2 Yb 0.2) 2 O 3. Among the five samples, HEO4 has the lowest thermal conductivity κ (1.88 ∼ 2.55 W·m−1·K−1 in 25 ∼ 500 °C), which is much lower than bixbyite-structured Y 2 O 3. In addition, HEO4 possesses a lower oxygen diffusion compared with 8YSZ in 600 ∼ 700 °C, which endows it the better oxygen barrier property. To sum up, HEO4 could be a promising candidate for high temperature thermal insulation applications due to its excellent comprehensive properties. [ABSTRACT FROM AUTHOR]

It has been a great challenge to prepare high-expansion-ratio polylactide (PLA) foam with eminent thermal insulation and compression performance in packaging field. Herein, a naturally formed nanofiller halloysite nanotube (HNT) and stereocomplex (SC) crystallites were introduced into PLA with a supercritical CO 2 foaming method to improve foaming behavior and physical properties. The compressive performance and thermal insulation properties of the obtained poly(L-lactic acid) (PLLA)/poly(D-lactic acid) (PDLA)/HNT composite foams were successfully investigated. At a HNT content of 1 wt%, the PLLA/PDLA/HNT blend foam with an expansion ratio of 36.7 folds showed a thermal conductivity as low as 30.60 mW/(m·K). Meanwhile, the compressive modulus of PLLA/PDLA/HNT foam was 115% higher than that of PLLA/PDLA foam without HNT. Moreover, the crystallinity of PLLA/PDLA/HNT foam was dramatically improved after annealing, thus the results showed that compressive modulus of the annealed foam increased by as high as 72%, while it still maintained good heat insulation with the thermal conductivity of 32.63 mW/(m·K). This work provides a green method for the preparation of biodegradable PLA foams with admirable heat resistance and mechanical performance. • The PLLA/PDLA/HNT composite foams with high expansion ratios were fabricated by scCO 2. • The thermal conductivity of PLLA/PDLA/HNT composite foams was as low as 30.60 mW/(m·K). • The annealing process further improved the compressive performance of PLLA/PDLA/HNT composite foams. [ABSTRACT FROM AUTHOR]

There is an increasing demand for highly efficient thermal insulating materials in buildings. This study presents a novel solution incorporating nanomaterials, such as silica aerogel, which can achieve low thermal conductivity values (below 0.030 W m−1 K−1) in renders. A key challenge of using aerogels is their low mechanical strength and high capillary water absorption. Here we describe a novel approach employing fibres which mitigates against some key properties which are decreased as a consequence of using aerogel. The incorporation of aramid (0.50%), sisal (0.10%), and biomass (0.10%) fibres (by total volume) was evaluated experimentally in terms of physical, mechanical, and microstructural properties. A synergistic effect between the fibres and aerogel increased mechanical resistance and a reduction in the capillary water absorption, when compared to the reference render (without fibres), whilst maintaining the low thermal conductivity. However, these properties depended significantly on whether the fibres were synthetic or organic. This study is important as it demonstrates that aerogel-based fibre-enhanced thermal renders can contribute to higher energy efficiency in both new construction and retrofitting. The use of these materials will have a direct positive impact on addressing the climate crisis. [ABSTRACT FROM AUTHOR]

• Long-term heat exposure above critical temperature can induce continuous degeneration of thermal insulation property for Fe-based amorphous coating, revealing an importance of kinetic effect. • The coupling effect of microstructure transformation and structural sintering is disclosed, leading to a particular insight into the degeneration mechanism. • The low atomic diffusivity of amorphous phase retards the progress including crystallization transition, grain growth and pore healing, resulting in a sluggish degeneration of thermal insulation property. Fe-based amorphous coatings have been proposed to perform a promising thermal barrier application, however, the uncertain degeneration of properties induced by thermal stimulation is significantly concerned owing to their metastable nature. Herein, Fe 57 Cr 15 Nb 4 B 20 Si 4 amorphous coating with a low thermal conductivity was employed to investigate the degeneration of thermal insulation property and related mechanisms during long-term heat exposure. Excellent stability can be defined for the amorphous coating when annealed below glass transition temperature, despite a slight increase of thermal conductivity induced by structural relaxation. Extraordinary increase of thermal conductivity is found when prolonged annealing time at a critical temperature of 600 °C. The sluggish structural sintering dominates thermal conductivity to increase, whereas the effect of precipitated ultrafine nanocrystals is little. The cooperation of grain coarsening and structural sintering leads to a dramatical increase of thermal conductivity at the initial stage of 850 °C annealing, while the relatively low increase of thermal conductivity with prolonged duration is ascribed to the further grain growth. The obtained results demonstrate a comprehensive understanding on the thermal evolution of Fe-based amorphous coatings and form a basis for future works aiming to shed further light on the degeneration of related metallic coatings at high temperatures. [ABSTRACT FROM AUTHOR]

• Fully bio-sourced building insulation materials from rice straw and natural binders are developed. • A crosslinking method is proposed to prevent the water solubility issue. • The effect of fiber size, binder type and binder ratio on the hygrothermal properties is investigated. • Alginate-based composites shows more serious mold growth than chitosan-based composites. Conversion agricultural straws to building insulation materials has attracted great interest due to their good hygrothermal properties and low carbon footprint. In this study, fully bio-sourced composite materials were designed based on rice straw and natural binders. Sodium alginate and chitosan were used as the binders. A crosslinking method was proposed to prevent the water-soluble issue of the composites using sodium alginate as the binder. The influence of fiber size, binder type and binder ratio on the hygrothermal properties of the composite materials made of rice straw were investigated. It was found that all the materials are insulating with their thermal conductivity values between 0.038 and 0.047 W/(m⋅K). The alginate-based composites had the higher water vapor permeability and moisture sorption capacity than the chitosan-based composites. Larger fiber size and lower binder ratio resulted in lower thermal conductivity and higher water vapor permeability. However, fiber size and binder ratio had a negligible effect on moisture sorption capacity of the composite materials. Additionally, the mold growth was investigated by exposing the composite materials to severe conditions, i.e., 93% RH and 97% RH at 20 °C. Mold proliferation was found to be easier and quicker in the surface of alginate-based composites compared to the chitosan-based composites. [ABSTRACT FROM AUTHOR]

The correlation between the thermal transport properties and microstructure features of amorphous coatings is crucial for reliable thermal insulation applications. In this work, an Fe 48 Cr 15 Mo 14 C 15 B 6 Y 2 amorphous coating prepared by high-velocity oxygen-fuel spraying (HVOF) was employed to reveal this relationship under long-term heating. From the combined effects of the amorphous phase and unique coating structure, the proposed coating exhibits an extremely low thermal conductivity of 1.92 W/(m∙K), granting a significant potential for being as metal-based thermal barrier coatings. Isothermal annealing experiments below the glass transition temperature demonstrate that the thermal insulation property can maintain stability with prolonged annealing time, despite a slight degradation relative to the as-sprayed coating which is ascribed to structural relaxation. Although nearly full crystallization can be slowly induced by annealing at the critical temperature of 600 °C, the thermal conductivity displays a distinct two-stage variation with annealing time, which is primarily attributed to the sluggish sintering of the coating structure. Moreover, grain growth and rapid structural sintering result in a drastic degradation of thermal insulation in the early stage of annealing at 850 °C, whereas grain growth upon prolonged annealing governs further variation of thermal conductivity. The results of this study not only provide important insights into the degeneration mechanism of thermal insulation of Fe-based amorphous coating, but also present an inspiration for exploring the degeneration mechanism of the most metallic coatings serving at high temperatures. • The Fe-based amorphous coating exhibits an extremely low thermal conductivity of κ = 1.92 W/(m∙K). • The degeneration mechanism of thermal insulation property of Fe-based amorphous coating is disclosed. • The low atomic diffusivity retards the bridge-connection of interlamellar pores, resulting in a sluggish sintering kinetics. [ABSTRACT FROM AUTHOR]

[Display omitted] • Expanded lightweight plates were prepared by combining expanded glass, expanded vermiculite, and expanded perlite particles with an innovative TEOS/MTMS sol-gel binder. • Expanded glass based plate exhibited the greatest compressive strength (7.04 ± 0.44 MPa) and the highest direct tensile strength (0.486 ± 0.04 MPa). • The long term water absorbency values of expanded perlite based plate was found to be 1.76 ± 0.1 v% in the 1st day and increased slightly to 9.96 ± 0.04 v% in the 28th day. • Thermal conductivity coefficient of expanded glass based plate performed the best result which was measured as 0.125 W/m.K at 25 °C. • NIR-reflective property of expanded glass based plate was recorded as 83.2 ± 0.5 %. • All inorganic-based plates exhibited high fire resistance performance (withstand temperatures of up to ∼900 °C for 30 min). Thermal insulation materials are a great solution to minimize energy consumption for construction applications. Especially, expanded inorganic lightweights are excellent candidates in terms of their low thermal conductivity and high fire resistance properties. Sol-gel type inorganic based binders are also useful chemical substances to combine lightweight particles. In current study, inorganic-based plates were developed by using expanded glass, expanded vermiculite, and expanded perlite particles with a novel tetraethoxysilan (TEOS)/methyltrimethoxysilane (MTMS) sol-gel binder. The chemical, physical, mechanical and thermal properties of the plates were examined comparatively to reveal the effect of expanded lightweight particle types in the plates. According to the experimental results, the compressive strength of the developed plates was between 7.04 ± 0.44 MPa and 3.15 ± 0.17 MPa whilst the direct tensile strength ranged from 0.486 ± 0.04 MPa and 0.079 ± 0.04 MPa, respectively. Furthermore, the long term water absorbency values of the plates on the 28th day varied between 9.96 ± 0.04 v% and 49.8 ± 0.8 v%. On the other hand, while the thermal conductivity coefficient of the plates at 25 °C ranged from 0.125 to 0.254 W/m.K, infrared reflectance properties were determined between 83.2 ± 0.5 % and 64.1 1.8 %. Besides, all inorganic-based plates exhibited high fire resistance performance (withstand temperatures of up to ∼900 °C for 30 min). The results demonstrated that utilizing expanded inorganic lightweight particles with TEOS/MTMS sol-gel binder could be a promising combination to construct energy saving insulating plates to overcome poor fire resistance properties of conventional organic materials. [ABSTRACT FROM AUTHOR]

• Part of water was pre-located in the lightweight aggregates (LWA) for producing HPLC. • The increasing amount of LWA decreased the density of HPLC significantly. • The water penetration and ion permeability of HPLC were very low. • The HPLC exhibited high structural efficiency and low thermal conductivity; • The dislocation of mixing water method enhanced the microhardness of the paste matrix. To prepare high-performance concrete, the mixing water was normally blended with the dry constituents directly, whereas in this study part of water was pre-located in the lightweight aggregates (LWA) for producing a high-performance lightweight concrete (HPLC). With the pre-location of water in the LWA, an extremely low w / b ratio paste (ultra high-performance composite) was resulted for producing HPLC. High-performance cement mortar (HPCM) was prepared with similar volumes of natural aggregates for comparison. Based on the initial spatial dislocation of mixing water in two systems, the physical, thermal and durability properties of high-performance cementitious composites were evaluated and compared. The results showed that the HPLC experienced delayed heat evolution when compared with that of the HPCM, while the cumulative heat output and degree of cement hydration of the two systems were similar. With the use of an increasing amount of LWA, the density of HPLC decreased significantly while the water penetration and ion permeability of HPLC were comparable to those of HPCM. More importantly, the HPLC exhibited a higher structural efficiency and much lower thermal conductivity than the HPCM. In addition to the pozzolanic reactivity and internal curing provided by the water-entrained LWA, the dislocation of mixing water method also enhanced the microhardness of the paste matrix, which contributed to the excellent performance of HPLC. [ABSTRACT FROM AUTHOR]

[Display omitted] • This research investigates the composites obtained from EP and camelina stalks. • Thermal, physical and mechanical properties of the new bio-composites were studied. • The thermal conductivity of the composites decreased with the addition of expanded perlite. • The water absorption, UPV and compressive strengths of the composites to which expanded perlite was added increased. • C45 and C45P5 composites can be used as an alternative to thermal insulation materials. • Thermal conductivity, unit weight, compressive strength and UPV decreased as the camelina ratio increased. Increasing urbanization has made lightweight construction materials with low thermal conductivity important. One of these materials, which has gained importance recently, is bio-composite materials consisting of agricultural wastes. The usability of camelina stalks, an agricultural waste, in the production of bio-composite has not been studied. The aim of this research is to develop new lightweight bio-composites with camelina stalks filled. For this, 11 composite mixtures using unsaturated polyester resin as the binder were created. Camelina stalks at 25, 30, 35, 40 and 45 % substitution ratios were used in half of 10 mixtures outside reference. Later, five more different mixtures by adding expanded perlite (EP) up to 5 % of the amount of camelina stalks in each mixture were produced. The physical, mechanical and thermal properties of the bio-composites produced with polyester binder were examined and the microstructure analysis was performed by SEM. The results showed that thermal conductivity, unit weight, compressive strength and ultrasonic pulse velocity (UPV) decreased as the ratio of the camelina stalks increased. The lowest thermal conductivity value was determined as 0.0842 W/(mK) in the 45 % camelina + 5 % EP filled specimen. The highest compressive strength value of the mixtures excluding the reference specimen was found to be 35.78 MPa in the 25 % camelina + 5 % EP-filled specimen. The addition of EP to the composites increased the water absorption, UPV and compressive strengths, but decreased the thermal conductivity. The results showed that camelina stalks can be used to produce sustainable bio-composites. [ABSTRACT FROM AUTHOR]

• Laminated CMPFA membranes were fabricated via electrospinning, vacuum filtration, and magnetron sputtering. • Waster polyester clothes were used to fabricate substrate membranes. • The asymmetrically wettable improve sweat transportation properties of CMPFA membranes. • Laminated CMPFA membranes can reflect thermal radiation and absorb solar energy to achieve dual thermal insulation. • The obtained CMPFA membranes have potential application in human thermal management. Wearable polyester fiber materials with excellent sweat transportation and enhanced thermal management properties have received increasing attention in functional materials and energy saving fields because of not only for wearing comfort but also for developing advanced energy-saving materials. Herein, this work presents an effective and sustainable strategy for fabrication of laminated CNTs-MnO 2 nanowires/PET fibers@Ag (CMPFA) membranes using waste polyethylene terephthalate (PET) fabric, manganese dioxide (MnO 2) nanowires, carbon nanotubes (CNTs) and silver nanoparticles as building blocks through electrospinning, vacuum filtration and subsequent magnetron sputtering processes, as well as its application in personal thermal management. The results indicated that simulated sweat on the PET fibers@Ag side can penetrate quickly into the CNTs-MnO 2 nanowires side within 2.4 s, implying the excellent sweat transport properties of laminated CMPFA membranes. More importantly, the synergistic thermal management properties can be obtained via infrared radiation and absorb sunlight. Compared with bare PET fibers membranes, the laminated CMPFA membranes exhibited excellent thermal insulation properties. The surface temperature of laminated CMPFA membranes is 11.9 °C higher than that of bare PET fibers membranes after 50 s of simulate sunlight exposure. In addition, the laminated CMPFA membranes show antibacterial properties, breathability, and water vapor permeability, which is beneficial to improving the comfort of wearer. This study shows that the fabrication of flexible wearable laminated membranes for personal thermal management application can be extended for the fabricated of other waste plastic based-materials with controlled structures and desired functions for various applications. [ABSTRACT FROM AUTHOR]

Hospitals consume large quantities of energy to produce hot water and offset the distribution and recirculation thermal losses. This paper analyses a solar thermal system combined with gas boilers for domestic hot water production in a medium-size hospital. The solar contribution to the total demand (27%) is below design expectations (75%), resulting in significant gas consumption. The energy audit conducted in the first part of the paper highlights the vast thermal loss through poorly insulated pipes as the primary cause of the poor solar fraction. This issue is endemic to hot water-intensive buildings. The second part of the paper addresses the techno-economic evaluation of energy retrofit measures to reach a solar fraction of 60%. The simulation results indicate that cost-optimised solutions generally expand the solar caption area by 43–57% and improve insulations to reduce thermal losses by 70%. Depending on carbon taxes, the cost of hot water production would be 31–41 cent-€/kWh, which represents a 15–45% reduction from the current costs. Under stringent climate policies, installing heat pumps may further enhance economic competitiveness. The indicators and charts developed in this work are helpful decision-making tools concerning the energy refurbishment of solar domestic hot water systems. • Solar thermal system combined with gas boilers to supply hot water in a hospital. • Solar fraction below design expectations (28% vs. 75%) due to huge thermal losses. • Enhanced thermal insulation and extra collectors to reach 60% solar fraction. • Refurbished system with hot water production cost estimated at 31–41 cent-€/kWh. • A heat pump would minimise carbon taxes in ambitious climate policy scenarios. [ABSTRACT FROM AUTHOR]

[Display omitted] • Millimetric hollow glass microspheres/epoxy(HGMs/EP) hollow spheres were prepared. • HGMs/EP hollow spheres showed low density and excellent mechanical properties. • A lightweight, thermal insulated EP composite with lattice structure was designed. • EP composites showed good thermal insulation properties. • Thermal insulation mechanism of the EP composites was proposed. In this study, a novel, lightweight, thermally insulated epoxy resin (EP) composite was designed and fabricated by arranging hollow glass microspheres/epoxy resin (HGMs/EP) hollow spheres and EP matrices using a combination of templates and a simple casting method. The designed HGMs/EP exhibited low density and excellent thermal insulation properties, and their size was of the order of millimeters. HGMs/EP hollow sphere–reinforced EP composites exhibit considerably lower density (0.73 ± 0.06 g/cm3; 39.16 % lower) and thermal conductivity (0.121 ± 0.016 W/(m·K); 37.31 % lower) than the traditional HGMs/EP composites with the same HGM content. Overall, the designed HGMs/EP hollow sphere–reinforced EP composites are excellent candidates for providing thermal insulation in construction materials. [ABSTRACT FROM AUTHOR]

For the first time, a multiphase closed cell SiC-based composite nanofiber integrating efficient electromagnetic (EM) wave absorption, thermal insulation and high temperature resistance was designed and fabricated through electrospinning technique with zirconium as sintering aid and hollow C/SiO 2 spheres (HCSSs) as pore-forming materials. The unique multi-phase and closed cell structure not only improves the dielectric loss and facilitates the multiple reflection and absorption of EM waves, but also hinders the solid-phase heat transfer and increases the interfacial thermal resistance. Given their 10 % HCSSs content, the nanofibers exhibited a minimum reflection loss of − 48.6 dB at 3.5 mm thickness. Meanwhile, the samples showed ultra-low thermal conductivity (∼ 0.026 W/m K) and excellent thermal stability (∼ 1400 ℃). These superior properties make our nanofibers are expected to be applied for EM wave absorption and high-temperature thermal insulation under extreme conditions. [Display omitted] • A novel strategy for developing porous absorbing material is reported. • Multiphase and closed cell structure improve the microwave absorption and thermal insulation performance simultaneously. • Close cell ZrO 2 /SiC nanofibers show great potential as microwave wave absorption devices in high-temperature. [ABSTRACT FROM AUTHOR]

In this paper, triangular hollow porous polyacrylonitrile (PAN) fibers were prepared by coaxial wet spinning inspired by silver ant hair. These PAN fibers with ideal triangular hollow cross section structure were obtained by adding inorganic salts into the cortex and core spinning solution combined with proper drawing ratio. Its strength increases to 4.3 times compared with that of the nascent fiber without inorganic salt. Subsequently, the light reflection as well as thermal insulation properties of triangular and circular hollow porous fibrous mats were compared and analyzed. The results show that the triangular hollow porous fibers have higher light reflectance and heat insulation performance than the circular fibers, which endows the fabric a shimmering gloss. This research further expands the application of hollow porous fiber in both thermal insulation field and optical field, which is conducive to the design of "heat stealth" materials and flash materials. [Display omitted] [ABSTRACT FROM AUTHOR]

• Polyimide aerogels with nano-porous structure were prepared by ambient drying. • SiO 2 nanoparticles were used as skeleton enhancers and shrinkage inhibitors. • The aerogels exhibit robust mechanical properties and efficient thermal insulation. Ambient drying of polyimide (PI) aerogel is rarely reported due to the strong cross-linking network leading to large shrinkage. In this work, the hydrophobic SiO 2 nanoparticles are used as skeleton enhancers and shrinkage inhibitors to maintain the nano-porous network structure and achieve ambient drying of PI/SiO 2 aerogels. The results show that the PI/SiO 2 aerogel prepared by ambient drying has similar thermal insulation and mechanical properties as the PI aerogel prepared by supercritical drying. The PI/SiO 2 aerogel prepared by ambient drying is low-cost and simple to operate, which is expected to realize the industrialization and wide engineering application. [ABSTRACT FROM AUTHOR]

Phenolic-based composites are the most promising ablative thermal protection materials for space applications, but optimizing their thermal insulation performance while maintaining high strength remains extremely challenging. Herein, phenolic-based composites with co-optimized thermal insulation and mechanical properties are prepared via 2.5D quartz fabric reinforcing nanoporous phenolic. The pore size of phenolic matrix is efficiently refined to ∼35 nm by adjusting resin concentration, enabling composites to exhibit high density but low thermal conductivity by enhancing Knudsen diffusion. Finite element analysis shows that low braiding angle of 2.5D fabric can further weakening heat transfer of composites due to anisotropic thermal conductivity of fiber yarns. In-situ X-ray micro-CT results indicate that 2.5D fabrics can reinforce composites through interwoven yarns, and straighter weft yarns result in higher strength along weft direction than that along warp direction. Compared with dense quartz/phenolic composite, the resulting composites exhibit 16.5% lower density (1.32 g/cm3), 58.8% lower thermal conductivity (0.21 W/(m·K), ≥372.7% higher tensile strength (≥182.0 ± 9.6 MPa) and comparable ablation resistance. The present results will further advance the application of phenolic-based composites in more extreme re-entry environments. [Display omitted] [ABSTRACT FROM AUTHOR]

A stitched integrated thermal protection system (SITPS) has thermal protection/insulation and load-bearing capacity. According to the thermal protection/insulation, loading-bearing, and lightweight requirements, the SITPS has multiple characterizations and optimization parameters. So, it is essential to calculate its thermal and mechanical performance indexes in specific working environments to evaluate its structural efficiency. SITPS contains different components and spans multiple dimensions; therefore, multiscale models and hierarchical statistical methods are tailored to calculate the thermal and mechanical properties of the SITPS. This approach investigates the influences of the two critical structural parameters, stitching density and thermal insulation core thickness, on four key performance indicators of the SITPS. A structural efficiency indicator for the SITPS is proposed, which quantitatively characterizes the thermal insulation, load-bearing, and lightweight performance of the SITPS. It provides new insights into the structural design and optimization of the SITPS in its engineering applications. [ABSTRACT FROM AUTHOR]

Controlling thermal conductivity of nanostructures is a key element in manufacturing tailor-made nanodevices for thermoelectric applications. Moreover, superlattice nanostructures have been demonstrated to be useful in achieving minimal thermal conductivity for the employed nanomaterials. In this work, we model two-dimensional biphenylene, a recently-synthesized sp2-hybridized allotrope of carbon atoms, for the implementation of a biphenylene/hexagonal Boron-Nitride (biphenylene/ h -BN) superlattice nanoribbons. The effects of the length of ribbon and its superlattice period (l p) on the thermal conductivity are explored using molecular dynamics simulations. We calculated the length-independent intrinsic thermal conductivity (K α) of the superlattice nanostructure, which was approximately 68% and 55% lower than the thermal conductivity of pristine h -BN and biphenylene nanosheets, respectively. The superlattice period largely determines the minimum thermal conductivity, which was at 64.1 W m−1k−1 for a period value of l p = 2.51 nm. This work opens a new window to tune and/or minimize thermal conductivity in nanoribbons when designing thermoelectric and thermal insulation materials for favorable applications. • Biphenylene/h-BN superlattice was theoretically born using dynamic MD computation. • Thermal fingerprint of biphenylene/h-BN superlattice microstructure was precisely taken. • Thermal properties of biphenylene sp2-hybridized allotrope of carbon atoms were visualized. • Thermal conductivity of biphenylene/h-BN superlattice in minimal condition was 64.1 W m−1k−1. • Overall, thermal conductivity of this superlattice was 68 and 55% lower than pristine BN and biphenylene, respectively. [ABSTRACT FROM AUTHOR]

• Elaborate and characterize new ecological acoustic absorbers/sound insulation panels and thermal insulation panels. • Acoustic and thermal properties were measured experimentally using standardized methods. • Morphological analysis of the different fibers was carried out using scanning electron microscopy. • Bulk density, air flow resistivity and water absorption were measured experimentally. • The new panels are good candidates for the development of local materials with the required acoustic and thermal properties. This work aims to elaborate and characterize new ecological composite materials from cardboard waste and abandoned natural fibers for the manufacture of local acoustic absorbers/sound insulation panels and thermal insulation panels. For this purpose, twenty-eight samples were prepared by mixing a mass fraction of 60 % of cardboard waste and 40 % of natural fibers available in the south-east region of Morocco, i.e. Doum, Wheat straw, Reed, Esparto, Bagasse, Fig, and Olive. Firstly, the morphological analysis of the different fibers was carried out by scanning electron microscopy (SEM). Secondly, the acoustic and thermal properties were measured experimentally using standardized methods. In addition, bulk density, air flow resistivity and water absorption were measured. The experimental results showed that the studied panels have good acoustic and thermal performances. The sound absorption coefficient, sound transmission loss, bulk density, thermal conductivity, and heat capacity were in the range of 0.4–0.8; 20–45 dB; 278.6–343.8 kg/m3; 0.072–0.10 W/m.K; 1254.5–1807.5 J/kg.K, respectively. Consequently, the new panels developed in this study are good candidates for the development of local materials with the required acoustic and thermal insulation properties for applications in buildings. Their main advantages are: low environmental impact, low cost, and they can even compete with commercialized synthetic materials. [ABSTRACT FROM AUTHOR]

• Lightweight, flexible aerogels using renewable curdlan and wood waste chips as raw materials. • Low thermal conductivity (30.1 × 10−3 W/(m·K)) and high thermal stability up to 300 °C. • Hydrophobic and good compression-resilience behavior. Developing flexible and lightweight materials with elevated thermal insulation performance from renewable biomass is significant for green and sustainable energy. In this work, a multifunctional biomass aerogel using wood waste as a raw material is proposed. The composite aerogel consists of curdlan as a structural framework, wood fibers and nano-hydroxyapatite as reinforcing phases. By employing thermogravimetry (TG), infrared thermal imager and thermal conductivity tester, the thermal stability and thermal insulation performance of the aerogel were evaluated. The consequent thermal conductivity reaches 30.1 × 10−3 W/(m·K). As the strength and toughness of the aerogel is improved by introducing cellulose into the matrix, it shows a maximum compressive modulus of 1.65 MPa. The hydrophobicity of the aerogel is achieved by an alkylation method and the contact angle is over 120°. This nontoxic aerogel composite with high thermal and mechanical performance indicates a potential utilization in the thermal management of food and electronic industry. [Display omitted] [ABSTRACT FROM AUTHOR]

• Phenolic resin aerogel is synthesized from linear and boron phenolic resin. • The ultralow shrinkage attributes to the strong B-O bond in boron phenolic resin. • Thermal conductivity of aerogel with a density of 0.105 g/cm3 is 0.0352 W/(m·K). • Aerogel shows excellent mechanical stability and resilience capacity. Lightweight phenolic resin aerogel with excellent thermal insulation and mechanical properties is an attractive material for thermal engineering applications. However, to synthesize such material, generally, a significant volume shrinkage would occur during the aerogel formation and the processing time is long. To conquer such issues, the lightweight phenolic resin aerogel with excellent thermal insulation and mechanical properties was synthesized by an elaborately designed process, where linear thermoplastic phenolic resin (LPR) and boron-modified thermosetting phenolic resin (BPR) were used as the raw materials. It was found that the shrinkage rate and the processing time of the phenolic resin aerogel were significantly reduced. By optimizing the synthesis process, the aerogel with a density of 0.105 g/cm3 and a thermal conductivity of 0.0352 W/(m·K) was achieved. [ABSTRACT FROM AUTHOR]

Rigid polyimide foams (PIFs) with excellent mechanical and thermal properties were fabricated by thermal foaming of active cross-linkable units terminated polyester ammonium salts (PEAS) precursor powders. The active cross-linking strategy was realized by breaking C C bonds in maleic anhydride under heating treatment. Results showed that the formation of cross-linked structure before complete imidization effectively resisted matrix shrinkage and endowed PIFs with outstanding mechanical properties. The room temperature compressive strength and modulus of PIFs with four repeating units reached as high as 2.34 and 56.1 MPa, respectively. Moreover, the PIFs exhibited excellent thermal properties with onset decomposition temperatures ranging from 490 to 550 °C and the glass transition temperatures exceeding 290 °C. The PIFs displayed better thermal insulation, and the values of thermal conductivity fell within a range of 0.056–0.090 W m−1 K−1, which demonstrates potential application as high temperature resistant structural materials in aerospace and energy sectors. [Display omitted] • Rigid PIFs were fabricated by thermal foaming of active cross-linkable units terminated PEAS precursor powders. • Cross-linking structure was formed before complete imidization which endowed PIFs with outstanding mechanical properties. • Relationship between chain structure and properties of rigid PIFs were investigated. [ABSTRACT FROM AUTHOR]

• Preparation of Casein based zinc oxide nanocolloids using the two-step approach. • Thermal diffusivity studies of prepared samples using dual-beam thermal lens techniques. • Tunable behavior of thermal diffusivity depending on volume fraction and morphology. Nanofluids with suitable heat transfer properties were found to be applied in thermal insulators, transport, nanodevices, medicine, etc. Their heat transfer properties are influenced by the particle size, morphology, and concentration of the nanoparticles present in the nanofluids. Nanofluids of different morphologies of zinc oxide such as nanospheres, nanoflowers, and nanorods were synthesized and their thermal properties were evaluated using a dual-beam thermal lens technique. All these nanofluids were found to exhibit tunable thermal diffusivity depending on concentration. The nanofluids with flower-like morphology show maximum deviation in diffusivity due to the layered structure and the increased surface area. As compared to pristine zinc oxide nanofluids, casein-capped zinc oxide nanofluids show excellent thermal insulation properties at 60 μg/ml. The findings suggest that biofunctionalized zinc oxide nanofluid is a promising candidate for a variety of thermal applications. [ABSTRACT FROM AUTHOR]

Epoxy (EP) resin insulations are widely used in electronic devices and power systems. They are gradually finding their way as winding insulation material for medium frequency transformers (MFT) due to their attractive insulating and adhesive properties along with low cost and easy processing. However, their dielectric insulation properties are compromised at high frequencies and high temperatures due to poor thermal properties. In this context, the surface-treated hexagonal boron nitride (h-BN) micro fillers and core-shell TiO 2 @SiO 2 nanofillers are doped in epoxy (EP) to enhance their thermal and electrical insulation properties under high frequencies and high temperatures. Results reveal that the thermal conductivity of the EP increases continually, whereas the electrical breakdown strength is reduced above the threshold content of micro/nano fillers. Particularly, the micro h-BN addition is beneficial for thermal conductivity enhancement, whereas the core-shell structure of TiO 2 @SiO 2 improves the electrical insulation properties of the EP. The multi-layer core model is used to explain the dynamics of the fillers. The homogeneous dispersion and optimal content of suitable micro-nano fillers can produce efficient EP composites as the electrical insulation for medium frequency transformers. [Display omitted] [ABSTRACT FROM AUTHOR]

• The chemical grafting of ammonium polyphosphate onto the surface of HGM was reported for the first time. • Composites aerogel have excellent thermal insulation properties. • Composites aerogel have excellent flame retardancy, and the LOI value is as high as 100. • Composites aerogel have good mechanical properties. The development of high-performance flame-retardant materials with better thermal insulation properties is of great significance to modern building energy conservation. In this study, we report the facile and scalable fabrication of novel aerogels (SA-HGM-APP) based on the building blocks of ammonium polyphosphate (APP) coated hollow glass microspheres (HGM) and matrix material sodium alginate (SA) by freeze drying method. The as-prepared composite aerogel exhibits better thermal stability (decomposition temperature over 210°C). In addition, SA-HGM-APP composite aerogels have good thermal insulation properties and low thermal conductivity, which is 0.035 W m−1 K−1. More importantly, the peak heat release rate (pHRR) is 14.14 kW m−2, the limiting oxygen index (LOI) value is as high as 100%, and the aerogel composite material can reach UL-94 V-0 grade, so it shows excellent flame retardancy. These results attributed to a synergistic effect, which combines the rich porous structure derived from HGM, so that SA and APP have better thermal insulation and excellent non flammability, thus providing excellent flame retardancy. SA-HGM-APP aerogel composite has many advantages, such as simple preparation method and high mechanical strength. It has great potential in future thermal insulation and flame retardancy applications. [ABSTRACT FROM AUTHOR]

The novel multifunctional lightweight composites (MLCs) reinforced with integrated preform were prepared for thermal protection system (TPS) of hypersonic vehicles in extreme aerothermodynamic environment. The high-temperature behavior including thermal physical properties decomposition performance, and the ablation resistance were tested by the oxy-acetylene torch system, as well as the micro-morphologies of MLCs from non-destructive testing were investigated. An integration factor was proposed to evaluate the comprehensive performance of MLCs. The results show that MLCs had high structural efficiency without delamination and defelting, excellent thermal insulation performance, and superior ablation resistance ability. The comprehensive performance of MLCs had obvious advantages to polymer-matrix composites (PMCs). The novel MLC reinforced with integrated preform can help for the development of thermal protection materials of hypersonic aircrafts. [ABSTRACT FROM AUTHOR]