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Fabrication of flexible polyimide/rGO composite foams and their derived carbon foams for thermal insulation and EMI shielding applications.
- Source :
-
Polymer . Oct2023, Vol. 284, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- In this work, a facile microwave-assisted foaming and thermal imidization treatment method was proposed to fabricate flexible polyimide (PI)/rGO composite foams with anisotropic pore structures. The PI/rGO composite foams (PIF/rGO) were used as the starting derivatives to prepare carbon foams that demonstrated excellent anisotropic thermal insulation and electromagnetic interference (EMI) shielding applications. The directional growth of pore structures during the foaming period resulted in the formation of aligned ellipsoidal strip-like pore structure in the horizontal direction (i.e., perpendicular to the pore growth direction), which was attributed to the escape of foaming gases such as tetrahydrofuran, methanol and H 2 O. The homogeneous dispersion of rGO in the PI-derived carbon skeleton endowed corresponding carbon foams with excellent mechanical and thermal stability, high thermal insulation and electrical conductivity (σ) as well as absorption dominated EMI shielding performance. The σ and EMI shielding effectiveness (SE) of carbon foams showed an increasing trend with increasing rGO content. The σ, EMI SE and specific EMI SE of the carbon foams reached up to 33.0 S/m, 49.0 dB and 8792.8 dB/(g/cm2) in the horizontal direction, respectively. Therefore, this work provided a facile strategy to fabricate lightweight and anisotropic pore structure rGO-containing PIFs and carbonized derivatives, which demonstrated promising applications in high-end industrial fields. [Display omitted] • A facile strategy was proposed to prepare PIF/rGO and CF/rGO. • The directional growth of pores endowed foams with anisotropic properties. • The foams showed excellent mechanical and thermal insulation properties. • CF/rGO showed absorption-dominated EMI shielding performances. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00323861
- Volume :
- 284
- Database :
- Academic Search Index
- Journal :
- Polymer
- Publication Type :
- Academic Journal
- Accession number :
- 171922815
- Full Text :
- https://doi.org/10.1016/j.polymer.2023.126296