1. Generic postfunctionalization route from amino-derived metal-organic frameworks
- Author
-
Savonnet, Marie, Bazer-Bachi, Delphine, Bats, Nicolas, Perez-Pellitero, Javier, Jeanneau, Erwann, Lecocq, Vincent, Pinel, Catherine, and Farrusseng, David
- Subjects
Amino compounds -- Chemical properties ,Amino compounds -- Structure ,Amino compounds -- Optical properties ,Azides -- Chemical properties ,Ring formation (Chemistry) -- Analysis ,Organometallic compounds -- Structure ,Organometallic compounds -- Chemical properties ,Organometallic compounds -- Optical properties ,Photoluminescence -- Analysis ,Chemistry - Abstract
A soft, generic, one-pot postfunctionalization method is developed for metal-organic frameworks (MOFs) starting from compounds with an amino group on the linker. The amino group is transformed into azide ([N.sub.3]) by an unconventional route by using tBuONO and TMS[N.sub.3] and the desired functionalized MOF is obtained by the Huisgen 1,3-dipolar cycloaddition of azides to alkynes.
- Published
- 2010