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Generic postfunctionalization route from amino-derived metal-organic frameworks
- Source :
- Journal of the American Chemical Society. April 7, 2010, Vol. 132 Issue 13, 4518-4519
- Publication Year :
- 2010
-
Abstract
- A soft, generic, one-pot postfunctionalization method is developed for metal-organic frameworks (MOFs) starting from compounds with an amino group on the linker. The amino group is transformed into azide ([N.sub.3]) by an unconventional route by using tBuONO and TMS[N.sub.3] and the desired functionalized MOF is obtained by the Huisgen 1,3-dipolar cycloaddition of azides to alkynes.
- Subjects :
- Amino compounds -- Chemical properties
Amino compounds -- Structure
Amino compounds -- Optical properties
Azides -- Chemical properties
Ring formation (Chemistry) -- Analysis
Organometallic compounds -- Structure
Organometallic compounds -- Chemical properties
Organometallic compounds -- Optical properties
Photoluminescence -- Analysis
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 132
- Issue :
- 13
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.223773520