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Enhanced H2 uptake in solvents confined in mesoporous metal-organic framework.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2012 Oct 24; Vol. 134 (42), pp. 17369-71. Date of Electronic Publication: 2012 Oct 10. - Publication Year :
- 2012
-
Abstract
- Hydrogen uptake at 298 K and 30 bar in hybrid sorbents consisting of n-hexane confined in MIL-101 is found to be 22 times larger than in sole n-hexane. The enhanced solubility in MIL-101, found to be 3 times larger than in mesoporous silica of similar pore size, highlights the key roles played by surface chemistry and accessible surface area.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 134
- Issue :
- 42
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 23039787
- Full Text :
- https://doi.org/10.1021/ja308157a