Method to detect carbon in silicon crystals in the concentration range down to 5 × 1014cm−3by Fourier transform infrared absorption at room temperature

The procedure of Fourier transform infrared absorption (FT-IR) at room temperature for quantifying C impurities in Si crystals was reexamined to improve the detection limit down to 5 × 1014 cm−3. Since the substitutional C absorption peak overlaps with a strong two-phonon absorption, the difference spectroscopy is necessary with using a C-lean reference sample. A baseline flatness of less than 0.0005 in absorbance and a thickness uniformity of less than 0.001 mm are required to realize a detection limit of 5 × 1014 cm−3for 2 mm thick samples. To check the flatness, we define the Si/Si baseline which is the difference in the absorbance spectra measured twice with the removal and attachment of the same Si sample. Four organizations participated in the FT-IR round-robin test for ten samples with the C concentration ranging from 3.6 × 1014to 3.3 × 1015 cm−3. The obtained C concentrations were almost within 30% deviation from the values determined by reliable secondary ion mass spectroscopy.