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Abstract Reusing reclaimed wastewater became a practical resource for water utilization in groundwater recharge and irrigation activities. However, the quality of reclaimed wastewater needs improvement to meet the environmental regulations and reduce contamination risks. A laboratory-scale study simulated a soil aquifer treatment (SAT) system, exploring the synergistic effects of wet and dry cycles alongside key physicochemical parameters on pollutant removal efficiency using a glass column filled with quartz sand as the filtration medium. The investigation focused on the cyclic wetting and drying phases to unravel their impact on removing NH4 +, NO3 −, and PO4 3−. The synthetic wastewater introduced into the system exhibited varying pollutant concentrations during wet and dry periods, influenced by dynamic soil water content (WC%), pH, dissolved oxygen (DO), and oxidation–reduction potential (ORP). The high removal rates of 93% for PO4 3− and 43% for Total N2 demonstrate the system’s capability to reduce concentrations significantly under dynamic alternating between wet and dry conditions. Results unveiled that the wet period consistently yielded higher removal rates for N2 species. Interestingly, for PO4 3−, the dry periods demonstrated a higher removal efficiency. Moreover, the study identified an average NO3 − production during the experimental phases as a byproduct of nitrification. The average NO3 − production in wet periods was 2.5 mg/L, whereas it slightly decreased to 2.2 mg/L in dry periods. These findings underscore the nuanced influence of wet and dry conditions on specific pollutants within SAT systems. Applying the logistic regression model and principal component analysis demonstrated the statistical significance of WC, pH, DO, and ORP in predicting wet/dry conditions, providing quantitative insights into their influential roles on the nutrient dynamic concentrations. This study contributes valuable data to our understanding of SAT systems, offering practical implications for designing and implementing sustainable wastewater treatment practices and pollution management across diverse environmental contexts.

Soil aquifer treatment (SAT) has been widely applied for wastewater reclamation, which cooperates secondary treatment (i.e. A2O process) and disinfection treatment (chlorination) in wastewater treatment plants (WWTPs), to remove organic matter. This study compared dissolved organic carbon (DOC) characteristics, substrate utilisation patterns, and microbial communities between pre-chlorination SAT and SAT columns, and effective removals of DOC were observed in the pre-chlorination SAT and SAT columns. However, the composition of HiA in SAT columns without chlorination was less than in pre-chlorination SAT columns for DOC fraction. In comparison to A2O effluent, different metabolic patterns and the composition of the microbial community were demonstrated by the top layer of SAT column and pre-chlorination SAT column. Furthermore, deeper layers showed similarities in the metabolic pattern and composition of the microbial community. Overall, pre-chlorination minimised the change of the microbial communities from A2O effluent in the top layer of SAT except for deeper layers, and DOC concentrations decreased in pre-chlorination SAT column. Thus, the cooperation of SAT and wastewater treatments could be suitable for wastewater reclamation. [ABSTRACT FROM AUTHOR]

Soil aquifer treatment (SAT) is a managed aquifer recharge technology that involves the utilization of treated wastewater as a source. Widely implemented in countries like Australia, Israel, and Spain, SAT offers technical (flexibility), economic (lower investment cost), and environmental (lower energy consumption) advantages that invite people in other countries to assess its potential. There have been numerous research studies and experiments conducted on the process level of SAT, focusing on how to eliminate pollutants and improve water quality. However, research at the system level is limited, which hampers its widespread application, especially in developing countries. In this paper, I provide a comprehensive guideline that highlights important factors to consider when implementing SAT as a technology. Proper site selection and careful planning steps, including pretreatment, hydrogeological factors, and economic calculations, can significantly improve the performance of an SAT system. The regulatory component acts as a barrier to the expansion of SAT facilities worldwide due to the lack of harmonization in regulations. This study includes the details and results of an examination of the legal framework and establishes comparative guidelines and water quality parameters that must be met by SAT projects utilizing reclaimed water. The maintenance and monitoring of the SAT system are also essential to anticipating and addressing potential issues such as clogging. Lastly, the social aspect, which is of utmost importance, should be carefully considered. It is advisable to ensure transparent communication with end users from the early stages of the project. These key elements are interconnected, and none should be considered less significant than the others. [ABSTRACT FROM AUTHOR]

Manganese (Mn2+) and cobalt (Co2+) metals have been reported to exhibit complex interactions with phosphate (PO43-) ions, which can influence their mobility, reactivity, and removal behavior in soil aquifer treatment system (SAT). This study aimed to investigate the role of manganese (Mn2+) and cobalt (Co2+) in phosphate (PO43-) removal within a soil aquifer treatment system. A lab-scale column experiment was conducted using sand as the filtration media, and a synthetic wastewater containing 20 mg/L PO43-, 60 mg/L Mn2+, and 40 mg/L Co2+ was used. The breakthrough curves showed efficient removal of PO43- during the infiltration process, with concentrations reaching as low as 1 mg/L. The regression analysis revealed that Mn2+ had a strong negative correlation effect on PO43- concentration, indicating its stimulatory role in PO43- removal. Conversely, Co2+ showed a strong positive correlation effect, suggesting its promoting effect on PO43- concentration. Optimization analysis identified optimal concentrations of 57.4 mg/L for Mn2+ and 4.8 mg/L for Co2+ that interacted with lower PO43- concentrations, achieving the desired outcome of reducing PO43- levels. These findings highlight the importance of considering Mn2+ and Co2+ concentrations in soil aquifer treatment systems for effective phosphate removal. [ABSTRACT FROM AUTHOR]

Autochthonous carbon fixation by algae and subsequent deposition of particulate organic matter can have significant effects on redox conditions and elimination of trace organic chemicals (TOrCs) in managed aquifer recharge (MAR). This study investigated the impacts of different algae loadings (0–160 g/m2) and infiltration rates (0.06–0.37 m/d) on overall oxygen consumption and elimination of selected TOrCs (diclofenac, formylaminoantipyrine, gabapentin, and sulfamethoxazole) in adapted laboratory sand columns. An infiltration rate of 0.37 m/d in conjunction with an algae load of 80 g/m2 (dry weight) sustained oxic conditions in the sand bed and did not affect the degradation of TOrCs. Thus, the availability of easily degradable organic carbon from algae did not influence the removal of TOrCs at an influent concentration of 1 µg/L. In contrast, a lower infiltration rate of 0.20 m/d in combination with a higher algae loading of 160 g/m2 caused anoxic conditions for 30 days and significantly impeded the degradation of formylaminoantipyrine, gabapentin, sulfamethoxazole, and diclofenac. Especially the elimination of gabapentin did not fully recover within 130 days after pulsed algae deposition. Hence, measures like micro-sieving or nutrient control are required at bank filtration or soil aquifer treatment sites with low infiltration rates. [ABSTRACT FROM AUTHOR]

A quantitative microbial risk assessment was conducted to assess the health risks associated with the exposure of agricultural workers to tertiary treated wastewater in irrigated fields through soil ingestion in Cyprus. Three pathogenic microorganisms were chosen, particularly E. coli (bacteria), rotavirus (viruses) and Cryptosporidium. Two extreme exposure scenarios were investigated. Monte Carlo simulations were performed using input data from literature, and the model outputs were compared to the health standards of the World Health Organization (WHO). The results suggested that additional treatment is required for all pathogens to satisfy the health standards. Sensitivity analysis identified the source concentration and pathogen reduction due to soil aquifer passage as the most influential factors in the model outputs. Additional computations were performed to evaluate the minimum pathogen reduction due to soil aquifer passage so that the health targets are achieved for the 95 % of the output values. Rotavirus and Cryptosporidium were found to require more treatment than E. coli. The inclusion of these reference pathogens to the monitoring network of the local authorities is recommended, and the role of soil aquifer passage is emphasized on reducing the concentration of the contaminants. [ABSTRACT FROM AUTHOR]

In order to select efficient media and find the optimum operation conditions for contaminant removal in soil aquifer treatment (SAT), column experiments with three different media were carried out under two different dry-wet ratio conditions. Phreeqc and Hydrus-1D were used to simulate the hydrogeochemical interactions. The results based on dissolution kinetics and cation exchange showed that the water-rock interaction in the columns led to the increase of Ca2+ and decrease of K+ in reclaimed water. The transfers of Ca2+ by cation exchange and calcite dissolution were 0.16–0.24 mmol/L and 0.13–0.22 mmol/L, respectively. The adsorption distribution coefficients (Kd) of NH4-N in columns ranged from 0.02 to 4 cm3/g. Higher Kd values were obtained in the columns of finer particle size or with the addition of biochar. The nitrification rates of NH4-N ranged from 0.08 to 0.4 day−1, but the denitrification rates of NO3-N were low (0–0.005 day−1). This indicated that NO3-N removal in the columns was insignificant. The increase of the drying period from 1 to 3 days promoted the microbial-mediated nitrification that transforms NH4-N to NO3-N. Our results indicated that the sand with a 15-cm biochar layer on the top reduced saturated hydraulic conductivity and was suitable for NH4-N removal. A low dry-wet ratio (i.e., 2:2 days) could be selected to prevent the transformation of NH4-N to NO3-N. The findings are helpful to assess hydrochemical characteristic change in SAT and provide a basis for the selection of a reasonable dry-wet ratio. Highlights: Hydrogeochemical processes were studied by 2-m column experiments and modeling. Dissolution kinetics of minerals was considered in reclaimed water chemical change. Cation exchange and dissolution/precipitation were quantified by inverse modeling. Water flux simulation showed that biochar reduced saturated hydraulic conductivity. Biochar addition significantly enhanced NH4+ removal in soil aquifer treatment. [ABSTRACT FROM AUTHOR]

Globally, sustainable water management is required to minimize water security, and soil aquifer treatments (SATs) are widely applied in wastewater reclamation. Clogging problems limit the sustainable operation of SATs (i.e., the decrease of infiltration rate), and Physical clogging has been widely studied. However, the effect of biological clogging on the operation of SATs is still unclear. Thus, this study focuses on the effects of biological clogging in an SAT system and demonstrates that the clogging process in an SAT column. In this study, the infiltration rate in the A2O ​+ ​NaN3 water column decreased slightly, to 6–7 ​cm/h with an average rate of 0.01 ​cm/h per month after 240 ​d, compared with an average rate of 0.3 ​cm/h per month in the columns fed by filtered A2O water. The fastest reduction in infiltration rate, caused by biological clogging, occurred in the first 60 ​d and corresponded to the highest reduction in hydraulic conductivity of 0–2.5 ​cm layer. For alleviating clogging, this study illustrated that removing suspended solids from A2O water by filtration helped reduce approximately 25% of polysaccharides and heterotrophic bacteria. In comparison, pre-ozonation of A2O water helped to reduce approximately 70% of the biomass in the surface layer of the A2O ​+ ​O3 column. Thus, ozonation of wastewater effluent helps control biological clogging in SAT.

To mitigate groundwater level decline, managed aquifer recharge (MAR) with secondary treated wastewater (STWW) is increasingly considered and implemented. However, the effectiveness and potential risks of such systems need evaluation prior to implementation. In this study, we present a large-scale sand tank experiment to analyse processes related to the infiltration of real STWW through the vadose zone and subsequent mixing with oxic native groundwater. The varying composition of STWW from 15 infiltration cycles over six months of operation and the retention times were the main drivers of the observed processes, which were characterized by a wide range of analytical techniques such as in situ high-resolution oxidation-reduction potential (ORP) measurements, closed mass balances of solutes, characterization of dissolved organic carbon (DOC), stable nitrate isotopes analysis, as well as numerical flow and transport modelling. Depending on the composition and infiltration rates of the STWW, both nitrification and denitrification could be observed, even simultaneously at different locations in the tank. Furthermore, due to the variability of the real STWW we observed enhanced arsenic mobilisation during times of elevated phosphate concentrations of the infiltrating STWW. Additionally, uranium was mobilised in our experimental system via carbonate mineral dissolution caused by the infiltrating STWW which was undersaturated of calcite for all infiltration cycles. Overall, our results showed the importance of conducting studies with waters of complex matrix, such as real STWW, and considering mixing with groundwater to assess the full range of possible processes encountered at MAR field sites., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Soil aquifer treatment (SAT), as a gravity-based wastewater reuse process, is limited by oxygen availability to the microbial community in the soil. Using oxygen from enzymatic degradation of H2O2 to generate hyper-oxygen conditions can exceed solubility limitations associated with aeration, but little is known about the effect of hyper-oxygen conditions on the microbial community and the dominant bio-reactions. This study examined the impact of H2O2 addition on the community structure and process performance, along with SAT depth. Overall, two soil columns were incrementally fed synthetic secondary effluents to simulate infiltration through SAT. The experimental column received 14 mg/L hydrogen peroxide to double the level of natural oxygen available. The microbial kinetics of nitrifiers and heterotrophs were evaluated. We found that all of the H2O2 was degraded within the top 10 cm of the column, accompanied by a higher removal of COD (23 ± 0.25%) and ammonia (31 ± 3%) in comparison to the reference column. Higher nitrogen removal (23 ± 0.04%) was obtained for the whole process using H2O2. Analysis of nitrifiers indicated that ammonia-oxidizing bacteria were most influenced, obtaining higher concentration and abundance when exposed to H2O2. DNA sequencing analysis of samples exposed to H2O2 revealed significant community structure and diversity differences among heterotrophs. This study shows that not only aerobic, but also anoxic, microbial activity and process performance in a SAT system could be accelerated in existing infrastructure with H2O2, which could significantly decrease the associated environmental footprint. [ABSTRACT FROM AUTHOR]

Global water supplies are threatened by climate changes and the expansion of urban areas, which have led to an increasing interest in nature-based solutions for water reuse and reclamation. Reclaimed water is a possible resource for recharging aquifers, and the addition of an organic reactive barrier has been proposed to improve the removal of pollutants. There has been a large focus on organic pollutants, but less is known about multifunctional barriers, that is, how barriers also remove nutrients that threaten groundwater ecosystems. Herein, we investigated how compost- and woodchip-based barriers affect nitrogen (N) removal in a pilot soil aquifer treatment facility designed for removing nutrients and recalcitrant compounds by investigating the composition of microbial communities and their capacity for N transformations. Secondary-treated, ammonium-rich wastewater was infiltrated through the barriers, and the changes in the concentration of ammonium, nitrate, and dissolved organic carbon (DOC) were measured after passage through the barrier during 1 year of operation. The development and composition of the microbial community in the barriers were examined, and potential N-transforming processes in the barriers were quantified by determining the abundance of key functional genes using quantitative PCR. Only one barrier, based on compost, significantly decreased the ammonium concentration in the infiltrated water. However, the reduction of reactive N in the barriers was moderate (between 21 and 37%), and there were no differences between the barrier types. All the barriers were after 1 year dominated by members of Alphaproteobacteria, Gammaproteobacteria, and Actinobacteria, although the community composition differed between the barriers. Bacterial classes belonging to the phylum Chloroflexi showed an increased relative abundance in the compost-based barriers. In contrast to the increased genetic potential for nitrification in the compost-based barriers, the woodchip-based barrier demonstrated higher genetic potentials for denitrification, nitrous oxide reduction, and dissimilatory reduction of nitrate to ammonium. The barriers have previously been shown to display a high capacity to degrade recalcitrant pollutants, but in this study, we show that most barriers performed poorly in terms of N removal and those based on compost also leaked DOC, highlighting the difficulties in designing barriers that satisfactorily meet several purposes. [ABSTRACT FROM AUTHOR]

In recent decades, groundwater overexploitation has caused an important aquifer level decline in arid zones each year. In addition to this issue, large volumes of effluent are produced each year in metropolitan areas of these regions. In this situation, an aquifer storage and recovery system (ASR) using the reclaimed domestic wastewater can be a local solution to these two challenges. In this research, a post-treatment of reclaimed municipal wastewater has been investigated through unsaturated–saturated porous media. A large-scale, L-shaped experimental model was set up near the second-stage wastewater treatment plant (WWTP) in the west of greater Tehran. The water, soil, and treated wastewater of the experimental model were supplied from the aquifer, site, and WWTP, respectively. The 13 physicochemical parameters, temperature and fecal coliform were analyzed every 10 days in seven points for a period of four months (two active periods of 40 days with a 12-h on–off rate (wet cycles) and a rest period of 40 days (dry cycle) between the two wet cycles). The results showed that the effects of the saturated zone were twice as great as those of the unsaturated zone and two-thirds of the total treatment efficiency. Furthermore, a discontinuous wet–dry–wet cycle had a significant effect on effluent treatment efficiency and contaminants' reduction. In conclusion, an aquifer storage and recovery system using treated wastewater through the unsaturated–saturated zones is a sustainable water resource that can be used for agriculture, environmental and non-potable water demands. [ABSTRACT FROM AUTHOR]

Global water supplies are threatened by climate changes and the expansion of urban areas, which have led to an increasing interest in nature-based solutions for water reuse and reclamation. Reclaimed water is a possible resource for recharging aquifers, and the addition of an organic reactive barrier has been proposed to improve the removal of pollutants. There has been a large focus on organic pollutants, but less is known about multifunctional barriers, that is, how barriers also remove nutrients that threaten groundwater ecosystems. Herein, we investigated how compost- and woodchip-based barriers affect nitrogen (N) removal in a pilot soil aquifer treatment facility designed for removing nutrients and recalcitrant compounds by investigating the composition of microbial communities and their capacity for N transformations. Secondary-treated, ammonium-rich wastewater was infiltrated through the barriers, and the changes in the concentration of ammonium, nitrate, and dissolved organic carbon (DOC) were measured after passage through the barrier during 1 year of operation. The development and composition of the microbial community in the barriers were examined, and potential N-transforming processes in the barriers were quantified by determining the abundance of key functional genes using quantitative PCR. Only one barrier, based on compost, significantly decreased the ammonium concentration in the infiltrated water. However, the reduction of reactive N in the barriers was moderate (between 21 and 37%), and there were no differences between the barrier types. All the barriers were after 1 year dominated by members of Alphaproteobacteria, Gammaproteobacteria, and Actinobacteria, although the community composition differed between the barriers. Bacterial classes belonging to the phylum Chloroflexi showed an increased relative abundance in the compost-based barriers. In contrast to the increased genetic potential for nitrification in the compost-based barriers, the woodchip-based barrier demonstrated higher genetic potentials for denitrification, nitrous oxide reduction, and dissimilatory reduction of nitrate to ammonium. The barriers have previously been shown to display a high capacity to degrade recalcitrant pollutants, but in this study, we show that most barriers performed poorly in terms of N removal and those based on compost also leaked DOC, highlighting the difficulties in designing barriers that satisfactorily meet several purposes.

Water percolation through infiltration ponds is creating significant synergies for the broad adoption of water reuse as an additional non-conventional water supply. Despite the apparent simplicity of the soil aquifer treatment (SAT) approaches, the complexity of site-specific hydrogeological conditions and the processes occurring at various scales require an exhaustive understanding of the system's response. The non-saturated zone and underlying aquifers cannot be considered as a black box, nor accept its characterization from few boreholes not well distributed over the area to be investigated. Electrical resistivity tomography (ERT) is a non-invasive technology, highly responsive to geological heterogeneities that has demonstrated useful to provide the detailed subsurface information required for groundwater modeling. The relationships between the electrical resistivity of the alluvial sediments and the bedrock and the difference in salinity of groundwater highlight the potential of geophysical methods over other more costly subsurface exploration techniques. The results of our research show that ERT coupled with implicit modeling tools provides information that can significantly help to identify aquifer geometry and characterize the saltwater intrusion of shallow alluvial aquifers. The proposed approaches could improve the reliability of groundwater models and the commitment of stakeholders to the benefits of SAT procedures. [ABSTRACT FROM AUTHOR]

Soil aquifer treatment (SAT), as a gravity-based wastewater reuse process, is limited by oxygen availability to the microbial community in the soil. Using oxygen from enzymatic degradation of H2O2 to generate hyper-oxygen conditions can exceed solubility limitations associated with aeration, but little is known about the effect of hyper-oxygen conditions on the microbial community and the dominant bio-reactions. This study examined the impact of H2O2 addition on the community structure and process performance, along with SAT depth. Overall, two soil columns were incrementally fed synthetic secondary effluents to simulate infiltration through SAT. The experimental column received 14 mg/L hydrogen peroxide to double the level of natural oxygen available. The microbial kinetics of nitrifiers and heterotrophs were evaluated. We found that all of the H2O2 was degraded within the top 10 cm of the column, accompanied by a higher removal of COD (23 ± 0.25%) and ammonia (31 ± 3%) in comparison to the reference column. Higher nitrogen removal (23 ± 0.04%) was obtained for the whole process using H2O2. Analysis of nitrifiers indicated that ammonia-oxidizing bacteria were most influenced, obtaining higher concentration and abundance when exposed to H2O2. DNA sequencing analysis of samples exposed to H2O2 revealed significant community structure and diversity differences among heterotrophs. This study shows that not only aerobic, but also anoxic, microbial activity and process performance in a SAT system could be accelerated in existing infrastructure with H2O2, which could significantly decrease the associated environmental footprint.

In recent decades, groundwater overexploitation has caused an important aquifer level decline in arid zones each year. In addition to this issue, large volumes of effluent are produced each year in metropolitan areas of these regions. In this situation, an aquifer storage and recovery system (ASR) using the reclaimed domestic wastewater can be a local solution to these two challenges. In this research, a post-treatment of reclaimed municipal wastewater has been investigated through unsaturated–saturated porous media. A large-scale, L-shaped experimental model was set up near the second-stage wastewater treatment plant (WWTP) in the west of greater Tehran. The water, soil, and treated wastewater of the experimental model were supplied from the aquifer, site, and WWTP, respectively. The 13 physicochemical parameters, temperature and fecal coliform were analyzed every 10 days in seven points for a period of four months (two active periods of 40 days with a 12-h on–off rate (wet cycles) and a rest period of 40 days (dry cycle) between the two wet cycles). The results showed that the effects of the saturated zone were twice as great as those of the unsaturated zone and two-thirds of the total treatment efficiency. Furthermore, a discontinuous wet–dry–wet cycle had a significant effect on effluent treatment efficiency and contaminants’ reduction. In conclusion, an aquifer storage and recovery system using treated wastewater through the unsaturated–saturated zones is a sustainable water resource that can be used for agriculture, environmental and non-potable water demands.

To increase the opportunities and reduce the cost of indirect potable reuse, soil aquifer treatment (SAT) was evaluated at the City of Los Angeles' Donald C. Tillman Water Reclamation Plant (DCTWRP) in a 2.5‐year pilot study. Six soil columns were operated between February 2016 and November 2018 treating DCTWRP effluent. The goal was to reduce the dissolved organic carbon (DOC) in the effluent to lower concentrations in order to increase the allowable volumes for reclamation. An integrated part of the study was to evaluate the biodegradability of organics in different waters using biodegradable (BDOC) analyses. BDOC has been used in similar research in the past, and in this research, BDOC was an accurate predictor of column performance in removing organic carbon. The total organic carbon in tertiary DCTWRP effluent was reduced from 7 to 10 mg/L to 0.9 to 2.5 mg/L through a process train beginning with ozonation of the tertiary effluent, followed by biological activated carbon, and finally to the soil column effluents. Additional short‐term treatments including reverse osmosis, additional ozonation, and low‐pressure UV were also evaluated. The soil columns removed N‐nitrosodimethylamine to detection limits. Finally, results from SAT and BDOC were used to develop a kinetic model to predict biodegradation of organic matter of wastewater origin through a soil aquifer system. Practitioner points: Soil aquifer treatment is often used in indirect potable reuse projects to protect aquifers.Soil aquifer treatment was simulated in six pilot columns for 2.5 years.Columns were fed tertiary effluent from a nutrient‐removal type‐activated sludge plant.Effluent TOC was reduced from 10 mg/L to 0.9 to 2.5 mg/L, and nitrosodimethylamine (NDMA) was also removed.Biodegradable organic carbon analyses accurately predicted soil column performance in removing organic carbon. [ABSTRACT FROM AUTHOR]

Soil aquifer treatment (SAT), applied after activated sludge treatment (AST), has been widely used for wastewater reclamation. AST and SAT show potential for removing micropollutants, including pharmaceuticals and personal care products (PPCPs). However, the role of sequential combination of AST and SAT on the biodegradation of PPCPs was not clear in previous studies. In this study, the removal characteristics of PPCPs in AST and SAT were evaluated to assess the legitimacy of sequential combination of AST and SAT. SAT showed effective removals of antibiotics (> 80%), including fluoroquinolones and macrolides by sorption, but poor removals of amide pharmaceuticals (i.e. carbamazepine and crotamiton) were observed in both AST and SAT. Additionally, biodegradation contributed to the effective removal of carboxylic PPCPs (i.e. ketoprofen and gemfibrozil) in both ASTs and SAT, but effective biodegradation of halogenated acid and polycyclic aromatic compounds (i.e. clofibric acid and naproxen) was observed only in SAT (82.1% and 81.8%, respectively). Furthermore, the microbial substrate metabolic patterns showed that amino acids, amines, and polymers were biodegradable in SAT, which was fit for the biodegradation characteristics of PPCPs in SAT. For microbial communities, Proteobacteria were dominant in AST and SAT, but Acidobacteria and Actinobacteria were more abundant in SAT than AST, which could contribute to the effective removals of halogenated acid in SAT. Considering PPCP biodegradation and substrate metabolism, SAT displays a wider range on the biodegradation than AST. Therefore, we conclude that these two processes can complement each other when used for controlling PPCPs. [ABSTRACT FROM AUTHOR]

• Time-dependent pathogen rate reduction in 3-D fracture network fractures. • 3-D E. coli transport simulation in networks of thousands of fractures. • Extended colloid filtration theory predicts pathogen BTC & 3-D plume in groundwater. • Model simulations were supported by field sampling and laboratory filtration tests. • Potential pathogen release to the bathing water is possible during floods. Microbial transport in fractured carbonate rock using enhanced solutions is a significant and neglected research topic in the literature. We propose an extended colloid filtration theory (CFT) combined with a particle-tracking following streamlines (PTFS) model for the rapid prediction of breakthrough curves (BTCs) and plumes of pathogens in three-dimensional (3-D) discrete fracture networks (DFNs). We adapted CFT in porous media to pathogen transport in fractures containing Terra Rossa (soil) deposits. As an example of the model capability, a simulation was used to predict the 3-D motion field and Escherichia coli count in groundwater originating from the Forcatella managed aquifer recharge (MAR) Facility (Brindisi, Italy) using a DFN composed of 3,900 fractures. In arid regions, MAR facilities are significant for sustaining basic human needs, such as freshwater supply for drinking and crop production. The Markov chain Monte Carlo (MCMC) technique was applied to E. coli counts in the collected water samples to increase data representativeness. The pathogen transport coefficients were further supported by batch filtration tests carried out in the CNR/IRSA Laboratory (Bari, Italy). The mean E. coli attachment rate coefficient of 0.15 × 10−8 m2 d–1 (sticking efficiency = 1.1 × 10−8 m) resulted in a 2.1 log 10 removal in 600 m of reclaimed water filtration. The simulation output visualized the E. coli 3-D pathways in groundwater and the positions of contaminated groundwater spring outflows on Forcatella Beach. The simulation results agreed with the mean MCMC output of E. coli concentrations in bathing water under unperturbed geochemical and environmental flow and transport conditions. However, results indicate that concentrations of pathogenic strains, parasites, and enteric viruses may enter the marine environment of MAR sites during flood periods. [Display omitted] [ABSTRACT FROM AUTHOR]

Through a series of long-term column experiments, the fate of three common pharmaceuticals (carbamazepine (CBZ), diclofenac, and indomethacin) and their major phase I metabolites in soil aquifer treatment (SAT) were monitored. CBZ concentration increased by a factor of two (from 37 to ca. 70 ng/L) regardless of the treatment conditions, and its metabolites, 10,11-dihydro-10-hydroxycarbamazepine (approximately 500 ng/L after SAT) and CBZ-10,11-epoxide (12–42 ng/L after SAT) were not effectively removed after SAT. Our results indicated that some metabolites of pharmaceuticals are present at much higher concentration than the original forms in the SAT effluent, and that some metabolites are more persistent during SAT with a relatively short retention time (i.e., 30 days). The study indicated that more attention should be paid to the formation and fate of metabolites in the water quality management of SAT effluent.

This study investigates the impact of pre-treatment options on the performances of soil columns simulating soil aquifer treatment (SAT). For this purpose a conventional activated sludge (CAS) process, a membrane bioreactor (MBR) and vertical flow reed beds were used as single units or in combination before SAT. The influent and effluent from each treatment train were monitored over three successive 6-month periods, corresponding to changes in the operational conditions of the MBR and CAS units from 6 days' sludge retention time (SRT) to 12 and 20 days. All the columns acted as efficient polishing steps for solids and bacteria. The column receiving effluent from the CAS system running at 6 days' SRT also presented high total nitrogen and total phosphorus removals, but this column was also associated with the lowest infiltration rates over that period. While the quality of the effluent from the column following the CAS process increased over 18 months of operation, the effluent quality of the columns receiving MBR effluent degraded. No correlations were found between variations in SRT of the MBR and CAS processes and the columns' performances. Overall, all columns, except the one receiving CAS effluent, underwent a reduction in infiltration rate over 18 months.

Water percolation through infiltration ponds is creating significant synergies for the broad adoption of water reuse as an additional non-conventional water supply. Despite the apparent simplicity of the soil aquifer treatment (SAT) approaches, the complexity of site-specific hydrogeological conditions and the processes occurring at various scales require an exhaustive understanding of the system’s response. The non-saturated zone and underlying aquifers cannot be considered as a black box, nor accept its characterization from few boreholes not well distributed over the area to be investigated. Electrical resistivity tomography (ERT) is a non-invasive technology, highly responsive to geological heterogeneities that has demonstrated useful to provide the detailed subsurface information required for groundwater modeling. The relationships between the electrical resistivity of the alluvial sediments and the bedrock and the difference in salinity of groundwater highlight the potential of geophysical methods over other more costly subsurface exploration techniques. The results of our research show that ERT coupled with implicit modeling tools provides information that can significantly help to identify aquifer geometry and characterize the saltwater intrusion of shallow alluvial aquifers. The proposed approaches could improve the reliability of groundwater models and the commitment of stakeholders to the benefits of SAT procedures.

Abstract Subsurface microorganisms must deal with quite extreme environmental conditions. The lack of light, oxygen, and potentially nutrients are the main environmental stresses faced by subsurface microbial communities. Likewise, environmental disruptions providing an unbalanced positive input of nutrients force microorganisms to adapt to varying conditions, visible in the changes in microbial community diversity. In order to test microbial community adaptation to environmental changes, we performed a study in a surface Managed Aquifer Recharge facility, consisting of a settlement basin (two-day residence time) and an infiltration pond. Data on groundwater hydrochemistry, soil texture, and microbial characterization was compiled from surface water, groundwater, and soil samples at two distinct recharge operation conditions. Multivariate statistics by means of Principal Component Analysis (PCA) was the technique used to map the relevant dimensionality reduced combinations of input variables that properly describe the system behavior. The methodology selected allows including variables of different nature and displaying very different range values. Strong differences in the microbial assemblage under recharge conditions were found, coupled to hydrochemistry and grain-size distribution variables. Also, some microbial groups displayed correlations with either carbon or nitrogen cycles, especially showing abundant populations of denitrifying bacteria in groundwater. A significant correlation was found between Methylotenera mobilis and the concentrations of NO 3 and SO 4 , and also between Vogesella indigofera and the presence of DOC in the infiltrating water. Also, microbial communities present at the bottom of the pond correlated with representative descriptors of soil grain size distribution. Graphical abstract Image 1 Highlights • Environmental variables affect microbial phylotypes presence in recharge systems. • PCA allows identifying most relevant environmental variables. • Microbial signature in porewater changes with infiltration operations. • Grain-size distribution drives microbial population behavior in soils. • Infiltration ponds have an impact on biomediated carbon and nitrogen cycles. [ABSTRACT FROM AUTHOR]

Abstract Soil columns simulating soil aquifer treatment (SAT), fed with synthetic secondary effluent by intermittent infiltration of flooding/drying cycles, were characterized for nitrogen and organic carbon removal, and microbial ecology and biokinetics. The columns differed in the concentration ratio of chemical oxygen demand (COD) to the summed NH 4 +, NO 2 − and organic nitrogen—2 (C/N2) or 5 (C/N5). Chemical profiles along the column demonstrated a preference for COD oxidation over nitrification and coupled denitrification, with higher nitrogen loss (57% vs. 16%) in the C/N5 column. Unexpectedly, significant dominance of the genus Nitrospira over the genus Nitrobacter and ammonia-oxidizing bacteria (AOB) was strongly correlated at column depths where NH 4 + removal occurred. Moreover, the Nitrospira profile had the strongest correlation to the profile of NH 4 + (positive) and NO 3 − (negative), strongly indicating complete ammonia oxidation. 16S sequencing analysis of the topsoil in C/N2 vs. C/N5 columns revealed double the abundance of microbial aerobic potential (64% vs. 32%) vs. one-third the denitrification potential (13% vs. 31%). The concentrations and degradability levels of organic carbon were the most influential parameters shaping community structure. Niche differentiation within the biofilm attached to the soil is suggested to have an important role in the process's anoxic activity and nitrogen removal. Graphical abstract Image 1 Highlights • Higher C/N ratio in the feed resulted in significantly higher N loss. • The genus Nitrospira showed preponderance over the genus Nitrobacter and AOB. • Nitrospira correlated to ammonia removal show complete ammonia oxidation activity. • At top high C/N column microbial community reflected potential for denitrification. • Niche differentiation within the biofilm is significant in anoxic activity at SAT. [ABSTRACT FROM AUTHOR]

Soil aquifer treatment (SAT) is an established and sustainable wastewater treatment approach for water reuse that has been gaining increased attention in various countries around the world. Increasing volumes of domestic wastewater and escalating real estate prices around urban areas emphasize the urgent need to maximize the treatment efficiency by revisiting the SAT setup. In this study, a novel approach was examined to increase biodegradation rates and improve the quality of SAT topsoil effluent. Experiments with midscale, custom-made columns were carried out with sand collected from an operational SAT and a highly permeable natural material with high internal porosity, tuff, which was maturated (i.e., buried in the SAT infiltration basin) for 3 months. The filtration efficiency, biodegradation rates of organic material, microbial diversity, and outflow quality were compared between the operational SAT sand and the tuff using state-of-the-art approaches. The results of this study indicate that biodegradation rates (9.2 µg C g−1d−1) and filtration efficiency were up to 2.5-fold higher within the tuff than the SAT sand. Furthermore, the biofilm community was markedly different between the two media, giving additional insights into the bacterial phyla responsible for biodegradation. The results highlight the advantage of using highly porous material to enhance the SAT filtration efficiency without extending the topsoil volume. Hence, infusing a permeable medium, comprising highly porous material, into the SAT topsoil could offer a simple approach to upgrade an already advantageous SAT in both developed and developing countries.

The utilization of direct wastewater for irrigation poses many environmental problems such as soil quality deterioration due to the accumulation of salts, heavy metals, micro-pollutants, and health risks due to undesirable microorganisms. This hampers its agricultural reuse in arid and semi-arid regions. To address these concerns, the present study introduces a recent approach that involves using indirectly recharged groundwater (GW) with secondary treated municipal wastewater (STW) for irrigation through a Soil Aquifer Treatment-based system (SAT). This method aims to mitigate freshwater scarcity in semi-arid regions. The study assessed GW levels, physicochemical properties, and microbial diversity of GW, and soil in both impacted (receiving recycled water) and non-impacted (not receiving recycled water) areas, before recycling (2015–2018) and after recycling (2019–2022) period of the project. The results indicated a significant increase of 68–70% in GW levels of the studied boreholes in the impacted areas. Additionally, the quality of indirectly recharged GW in the impacted areas improved notably in terms of electrical conductivity (EC), hardness, total dissolved solids (TDS), sodium adsorption ratio (SAR), along with certain cations and anions (hard water to soft water). No significant difference was observed in soil properties and microbial diversity of the impacted areas, except for EC and SAR, which were reduced by 50% and 39%, respectively, after the project commenced. The study also monitored specific microbial species, including total coliforms, Escherichia coli (as indicator organisms), Shigella , and Klebsiella in some of the harvested crops (beetroot, tomato, and spinach). However, none of the analysed crops exhibited the presence of the studied microorganisms. Overall, the study concludes that indirectly recharged GW using STW is a better sustainable and safe irrigation alternative compared to direct wastewater use or extracted hard GW from deep aquifers. [Display omitted] • Need to reduce the burden on global freshwater supplies • Indirectly recharged groundwater is a sustainable and safe alternative for irrigation • Groundwater levels improved by 68–70% with better groundwater quality • No negative impact of indirectly recharged groundwater on soil properties • Crops irrigated with recharged groundwater were safe from tested microbes [ABSTRACT FROM AUTHOR]

Managed aquifer recharge (MAR) systems can be operated intermittently through wetting-drying cycles to simultaneously improve the water supply and quality. Although MAR can naturally attenuate considerable amounts of nitrogen, the dynamic processes and control mechanisms of nitrogen removal by intermittent MAR remain unclear. This study was conducted in laboratory sandy columns and lasted for 23 d, including four wetting periods and three drying periods. The hydraulic conductivity, oxidation reduction potential (ORP), and leaching concentrations of ammonia nitrogen and nitrate nitrogen of MAR systems were intensively measured to test the hypothesis that hydrological and biogeochemical controls play an essential role in regulating nitrogen dynamics at different stages of wetting-drying cycles. Intermittent MAR functioned as a sink for nitrogen while providing a carbon source to support nitrogen transformations; however, it occasionally became a source of nitrogen under intense flushes of preferential flow. Nitrogen dynamics were primarily controlled by hydrological processes in the initial wetting phase and were further regulated by biogeochemical processes during the subsequent wetting period, supporting our hypothesis. We also observed that a saturated zone could mediate nitrogen dynamics by creating anaerobic conditions for denitrification and buffering the flush effect of preferential flow. The drying duration can also affect the occurrence of preferential flow and nitrogen transformations, which should be balanced when determining the optimal drying duration for intermittent MAR systems. • Intermittent managed aquifer recharge overall functioned as a sink for nitrogen. • Nitrogen dynamics and their controls vary with different stages of recharging. • Saturated zone can create an anerobic condition for denitrification. • Drying duration can mediate control mechanisms and thus nitrogen dynamics. [ABSTRACT FROM AUTHOR]

Water reclamation through the use of soil aquifer treatment (SAT) is a sustainable water management technique with high potential for application in many regions worldwide. However, the fate of contaminants of emerging concern (CECs) during the infiltration of treated wastewater during SAT is still a matter of research. This study investigates the removal capacity of 27 CECs during SAT by means of infiltration experiments into a 6 m soil column. Additionally, the influence of the hydraulic operation of SAT systems on the removal of CECs is investigated by changing the wetting and drying cycle lengths. Sixteen out of 27 CECs are efficiently removed during SAT under various operational modes, e.g., bezafibrate, diclofenac and valsartan. For six substances (4-methylbenzotriazole, amidotrizoic acid, benzotriazole, candesartan, hydrochlorothiazide and sulfamethoxazole), removal increased with longer drying times. Removal of amidotrizoic acid and benzotriazole increased by 85% when the drying cycle was changed from 100 to 444 min. For candesartan and hydrochlorothiazide, removal improved by 35%, and for 4-methylbenzotriazole and sulfamethoxazole, by 57% and 39%, respectively. Thus, enhanced aeration of the vadose soil zone through prolonged drying times can be a suitable technique to increase the removal of CECs during SAT.

Environmental endocrine-disrupting chemicals have become a global environmental problem, and the distribution, transport, and fate of estrogens in soil and water environments closely relate to human and ecological health as well as to the remediation scheme design. A new micro-extraction technique termed dispersive liquid−liquid micro-extraction (DLLME) combined with high-performance liquid chromatography with fluorescence detector (HPLC-FLD) was developed for the determination of the concentration of steroid estrogens in water samples. The detection limits of HPLC-FLD and DLLME-HPLC/FLD were 0.68−1.73 μg L−1 and 7.16−69.22 ng L−1, respectively. Based on this method, the isothermal adsorption of 17β-E2 on sand and a breakthrough experiment of 17β-E2 and Cu2+ in a soil aquifer treatment (SAT) system were studied. The 17β-E2 adsorption capacity of sand in 17β-E2 solution was detected to be larger than that in a mixed solution of 17β-E2 and Cu(NO3)2 solution, and the breakthrough curves of 17β-E2 and Cu2+ in the mixed solution shifted forward in sand column experiments. Both suggested that the competitive adsorption of 17β-E2 and Cu2+ in the mixed solution might occur on the surface of the sand. In the process of the removal of 17β-E2 in wastewater by SAT, the existence of Cu2+ slightly inhibited the adsorption of 17β-E2 and accelerated the breakthrough of 17β-E2. These results ought to be a warning for SAT application for 17β-E2 removal in water where heavy metals coexist.

Abstract Two column pairs filled with 3.05-m of a sandy soil from the Upper San Gabriel Valley were operated for a period of four and ½ years on municipal effluent from the San Jose Creek Water Reclamation Plant operated by the Sanitation Districts of Los Angeles County (LACSD). One column pair was fed filtered, chlorinated effluent (tertiary effluent) for the entire period. The other pair was fed ozonated secondary effluent for 8-mo, ozonated secondary effluent filtered through biological activated carbon (O 3 /BAC) for 7-mo and tertiary effluent for 38-mo. Each column pair was operated in series, where the first column was operated for a shorter residence time and the second column for a longer residence time. Residence times tested were 5-d, 28-d, 30-d, 58-d, 60-d, 150-d and 180-d. For the last 38-mo, both pairs of columns had a residence time of 30-d in the first column and the total residence time of the two pairs was 150 and 180-d, respectively. Testing showed both of these pairs had the same long-term performance. The column pairs with a 150 to 180-d residence time, which were both fed tertiary effluent, reached an effluent total organic carbon (TOC) of 1.8 mg/L. Column pairs with a 28 to 30-d residence time, which were fed tertiary, ozonated, and O 3 /BAC effluent, reached effluent TOCs of 2.3, 2.1 and 1.8 mg/L respectively. In the latter, some TOC removal was shifted from the soil columns to the BAC. During the last 38 months of testing, using tertiary effluent as the source water, a series of sampling events was performed throughout the soil column system for N -nitrosodimethylamine (NDMA) and chemicals of emerging concern (CECs). NDMA was substantially reduced in all the columns, with a median value of 3 ng/L after 30-d and <2 ng/L after both 150 and 180-d. Twenty-one CECs were found in the majority of tertiary effluent samples, twelve of which were attenuated by the soil columns and the remaining were not. Chemicals found to be recalcitrant were 4-nonylphenol, acesulfame-k, carbamazepine, lidocaine, primidone, simazine, sucralose, sulfamethoxazole, and TCEP. Using excitation-emission matrix (EEM) techniques, soluble microbial products (SMP) peak characteristic of effluent organic matter (EfOM) is nearly eliminated after a 30-d hydraulic retention time (HRT) and completely eliminated in the 150/180-d samples. The intensity of the other peaks is significantly reduced as well, resulting in an EEM much like that of natural groundwater. Graphical abstract Image 1 Highlights • Soil columns fed tertiary effluent reduced the TOC 67% with a 150-day HRT. • NDMA was attenuated through soil columns by more than 99%. • Soil column treatment attenuated 12 of the 21 CECs found in tertiary effluent. • Soil columns were operated over four and ½ year period with tertiary effluent. [ABSTRACT FROM AUTHOR]

The long term behavior of total nitrogen and its components was investigated in a soil aquifer treatment system of the Dan Region Reclamation Project (Shafdan), Tel-Aviv, Israel. Use is made of the previous 40 years' secondary data for the main nitrogen components (ammonium, nitrate and organic nitrogen) in recharged effluent and observation wells located inside an infiltration basin. The wells were drilled to 106 and 67 m, both in a similar position within the basin. The transport characteristics of each nitrogen component were evaluated based on chloride travel-time, calculated by a cross-correlation between its concentration in the recharge effluent and the observation wells. Changes in the source of recharge effluent, wastewater treatment technology and recharge regime were found to be the main factors affecting turnover in total nitrogen and its components. During aerobic operation of the infiltration basins, most organic nitrogen and ammonium will be converted to nitrate. Total nitrogen removal in the upper part of the aquifer was found to be 47–63% by denitrification and absorption, and overall removal, including the lower part of the aquifer, was 49–83%. To maintain the aerobic operation of the infiltration fields, the total nitrogen load should remain below 10 mg/L. Above this limit, ammonium and organic nitrogen will be displaced into the aquifer. [ABSTRACT FROM AUTHOR]

Artificial recharge is used to increase the availability of groundwater storage and reduce saltwater intrusion in coastal aquifers, where pumping and droughts have severely impaired groundwater quality. The implementation of optimal recharge methods requires knowledge of physical, chemical, and biological phenomena involving water and wastewater filtration in the subsoil, together with engineering aspects related to plant design and maintenance operations. This study uses a novel Decision Support System (DSS), which includes soil aquifer treatment (SAT) evaluation, to design an artificial recharge plant. The DSS helps users make strategic decisions on selecting the most appropriate recharge methods and water treatment technologies at specific sites. This will enable the recovery of safe water using managed aquifer recharge (MAR) practices, and result in reduced recharge costs. The DSS was built using an artificial intelligence technique and knowledge-based technology, related to both quantitative and qualitative aspects of water supply for artificial recharge. The DSS software was implemented using rules based on the cumulative experience of wastewater treatment plant engineers and groundwater modeling. Appropriate model flow simulations were performed in porous and fractured coastal aquifers to evaluate the suitability of this technique for enhancing the integrated water resources management approach. Results obtained from the AQUASTRESS integrated project and DRINKADRIA IPA CBC suggest the most effective strategies for wastewater treatments prior to recharge at specific sites. [ABSTRACT FROM AUTHOR]

Soil aquifer treatment (SAT) is an effective natural and economically feasible tertiary treatment for wastewater reuse. An innovative hybrid process based on biofiltration, ozonation and short SAT (sSAT, with ~22 days retention time) was demonstrated in a 6 m3/hr pilot system to remove emerging trace organic compounds (TrOCs), organic matter and control Mn2+dissolution in reclaimed water. The biofiltration stage was proposed for nitrification of ammonia as well as removal of dissolved and particulate organic matter (DOM and POM), to enable efficient ozonation of secondary effluents. The pilot system was operated in two modes, where samples were periodically taken from all pilot stages to observe changes in product water quality. At first (Mode 1), biofiltered effluents were infiltrated through sSAT (i.e., no ozonation prior infiltration). During this operation, ammonia, nitrite and phosphate were completely removed, and pathogens were highly reduced. In addition, all measured TrOCs were effectively removed after sSAT, besides the persistent TrOCs Carbamazepine (CBZ) and Iodine-organic contrast media Iopamidol (IPDL). In Mode 2, biofiltered and ozonated (1.0–1.2 mg ozone/mg DOC) effluents were infiltrated through sSAT. In the final reclaimed product, values of DOC, UVA and Mn2+were reduced to 0.8 mg/L, 2.2 L/m, and 29–35 µg/L, respectively. Furthermore, ammonia and nitrite were not detected in the product, and good bacterial quality was obtained. Following 56–75 days of operation at Mode 2, all TrOCs were reduced down to <100 ng/L. The delay in the effect of the pretreatment stages on TrOCs removal by sSAT (>56 days instead of ~22 days) could be explained by their displacement retardation in the upper soil layers of the pilot SAT (0–25 cm). In-depth sampling in the observation well after 111 days at Mode 2 showed homogeneity along the overall perforated section of the well (from −14 to −26 m) with 0.7–0.9 mg/L DOC, 2.1–2.2 1/m UVA and <10 ng/L CBZ. This result proved that the ozonated water completely covered the area around the observation well and positively affected the quality of the reclaimed water. [ABSTRACT FROM PUBLISHER]

Wastewater reclamation is becoming an important alternative for sustainable water resources management and building climate change resiliency in many regions around the world. This research investigated the polishing of secondary effluents and combined sewer overflows (CSOs) by a laboratory-scale soil aquifer treatment considering local soils and wastewater characteristics of southwestern Ontario. Results show that high permeability soils of southwestern Ontario, have the ability to polish secondary effluents in terms of dissolved organic carbon, Escherichia coli, and total coliforms. Regarding the simulated CSOs, low to moderate improvements of wastewater quality were observed. Denitrification of secondary effluents improved significantly by the addition of readily available organic matter, which supports the importance of protecting recharge wetlands for groundwater quality protection. Soil aquifer treatment in southwestern Ontario is a feasible alternative for the recharge of non-potable and potable aquifers with secondary effluents. However, for potable aquifers further treatment of wastewater effluents may be required. [ABSTRACT FROM AUTHOR]

Bank filtration (BF) and soil aquifer treatment (SAT) are efficient natural technologies in potable water reuse systems. The removal of many organic micro-pollutants (OMPs) depends on redox-conditions in the subsoil, especially on the availability of molecular oxygen. Due to microbial transformation of particulate and dissolved organic constituents, oxygen can be consumed within short flow distances and induce anoxic and anaerobic conditions. The effect of accumulated particulate organic carbon (POC) on the fate of OMPs in BF and SAT systems is not fully understood. Long-term column experiments with natural sediment cores from the bank of Lake Tegel and from a SAT basin were conducted to investigate the impact of accumulated POC on dissolved organic carbon (DOC) release, on oxygen consumption, on mobilization of iron and manganese, and on the elimination of the organic indicator OMPs. The cores were fed with aerated tap water spiked with OMPs to exclude external POC inputs. Complete oxygen consumption within the first infiltration decimeter in lake sediments caused mobilization of iron, manganese, and DOC. Redox-sensitive OMPs like diclofenac, sulfamethoxazole, formylaminoantipyrine, and gabapentin were eliminated by more than 50% in all sediment cores, but slightly higher residual concentrations were measured in effluents from lake sediments, indicating a negative impact of a high oxygen consumption on OMP removal. [ABSTRACT FROM AUTHOR]