Search

Multivariate and statistical tool advancements help to assess potential pollution threats, their geochemical distribution, and the competition between natural and anthropogenic influences, particularly on sediment contamination with potentially toxic metals (PTMs). For this, riverine sediments from 25 locations along urban banksides of the River Ravi, Pakistan, were collected and analyzed to explore the distribution, pollution, ecological, and toxicity risk indices of PTMs like Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Sn, Sr, V, and Zn using Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES) technique. Additionally, techniques such as X-ray Diffraction (XRD) and Scanning Electron Microscopy–Energy Dispersive X-ray Spectroscopy (SEM-EDS) were employed to investigate the mineralogical and morphological aspects. The results indicated that mean concentrations (mg kg−1) of Cd (2.37), Cr (128), Hg (16.6), Pb (26.6), and Sb (2.44) were significantly higher than reference values given for upper continental crust (UCC) and world soil average (WSA), posing potential threats. Furthermore, the geochemical pollution indices showed that sediments were moderately polluted with Cd (Igeo = 2.37, EF = 12.1, and CF = 7.89) and extremely polluted with Hg (Igeo = 4.54, EF = 63.2, and CF = 41.41). Ecological and toxicity risks were calculated to be extremely high, using respective models, predominantly due to Hg (Eri = 1656 and ITRI = 91.6). SEM-EDS illustrated the small extent of anthropogenic particles having predominant concentrations of Zn, Fe, Pb, and Sr. Multivariate statistical analyses revealed significant associations between the concentrations of PTMs and the sampling locations, highlighting the anthropogenic contributions linked to local land-use characteristics. The present study concludes that River Ravi sediments exhibit moderate levels of Cd and extreme pollution by Hg, both of which contribute highly to extreme ecological and toxicity risks, influenced by both natural and anthropogenic contributions. [ABSTRACT FROM AUTHOR]

The issues related to soil environmental contamination caused by heavy metals have garnered increasing attention. In particular, the soil pollution risk in the eastern coastal regions of China has attracted widespread concern. This study surveyed heavy metals in the soils near the Jiahe River Basin of Yantai City in Shandong Province, China. A total of 213 soils were sampled and analyzed for 12 items: Cr, Hg, As, Pb, Cd, Cu, Ni, Zn, Co, V, Mn, and pH. The 11 heavy metals were evaluated using the national standard GB15618-2018, with three risk levels of background, screening, and intervention, and using pollution indices, including the contamination factor (Cf), ecological risk factor (Er), enrichment factor (EF), and index of geo-accumulation (Igeo), with different respective risk levels. The results indicate a strong consistency between the evaluations both for the index Igeo and for GB15618-2018 on five metals (i.e., Cr, Hg, As, Pb, and Cd). Therefore, the index Igeo may serve as a supplementary indicator for assessing the pollution risks of heavy metals in agricultural soils regarding samples of Cu, Ni, and Zn that exceed the screening values in GB15618-2018, as well as for Co, V, and Mn, which have not yet been established in GB15618-2018. According to the three-level classification of risk in GB15618-2018, the seven commonly used levels of the index Igeo are also incorporated into the three levels of background, screening, and intervention. The overall pollution risk of 11 heavy metals in the soils of the Jiahe River Basin of Yantai City belongs to the background level. Specifically, Hg and Pb in the total area are classified at the background level. Manganese, V, Co, Zn, Ni, and Cr are recognized at the screening level sporadically, while Cu, As, and Cd are found at the screening level in small areas. No areas within the region are classified at the intervention level. [ABSTRACT FROM AUTHOR]

Despite the beneficial role of aquatic food, bioaccumulation of trace metals can increase health risk for consumers. We conducted a comprehensive study to understand the levels of various trace metals (Cd, Co, Cr, Cu, Fe, Ni, Pb, Zn and Mn) in fish (Nematalosa nasus, Gerres filamentosus, Arius arius, Gerres erythrourus, Sardinella fimbriata, Caranx ignobilis, Etroplus suratensis, Mugil cephalus, Sillago sihama, and Euryglossa orientalis) and crab (Portunus pelagicus and Scylla serrata) species collected from Netravathi-Gurupur estuary, India and evaluated the potential health risks to humans by measuring target health hazard (THQ), hazard index (HI), estimated daily (EDI) and weekly (EWI) intake and cancer risk (CR). The hierarchy of toxic metal content in studied species was Fe>Pb>Cr>Mn>Zn>Cu>Ni>Cd>Co. The concentration of heavy metals were distinctly lower than the threshold value as suggested by World Health Organization and Food Safety and Standards Authority of India, except for Cr and Pb in few species. THQ values were below the acceptable limit. However, the estimated mean HI values were >1 for children, indicating they may be vulnerable to health risk due to continuous consumption of contaminated aquatic species from the study area. In contrast, the cancer risk for Cr, Cd, and Pb was below the acceptable range. Principal component analysis (PCA) discerned nearby petrochemical industry, electroplating industry, pesticides and fertilizer from agricultural runoff, as the potential sources of metal bioaccumulation in different tissues. Although the study reveals that metal contamination in aquatic species does not pose any immediate human health effect, continuous monitoring of the study area is recommended, as some metals have demonstrated their ability to accumulate in the tissues. [ABSTRACT FROM AUTHOR]

The ecological and health risks posed by heavy metals (HMs) have been a major concern of the world. This study aimed to assess the potential health and ecological risks of Fe, Pb, Cr, Zn, Co, Ni, and Cd metals in the sugarcane and its growing soil at Sanka farmland, Northeast Ethiopia. The sampling was conducted at six locations in three potential sugarcane cultivation Kebeles. HMs were quantified using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). They were found in the range of 2297 (Fe) to 3.750 (Co) mg/kg for soil and 0.557 (Fe) to 0.020 (Zn) mg/L for sugarcane. The metal transfer factors of the investigated HMs were 0.0002 (Fe) to 0.384 (Co), indicating a low sugarcane response to HMs. Six pollution indices (three multi-metal ecological impact indicators and three single-metal ecological effect indicators) were applied to the data. All multi-metal ecological impact indicators show that the soil is severely polluted. In contrast, the single-metal ecological effect indicators showed severe pollution by Fe and Cd, moderate pollution by Pb and Cr, and low pollution levels by Ni, Co and Zn. Apart from Cd, Cr and Pb in the soil sample and Zn and Cd in the sugarcane juice sample, all HMs concentrations were below allowable limits set by World Health Organization (WHO). The contribution of each exposure route to the total intake of HMs showed the trend of non-dietary oral intake > dermal contact > juice drinking > inhalation route. Single-metal health risk assessment (hazard quotient) revealed no significant non-carcinogenic risk for adults and children, while multi-metal health risk assessment (hazard index) indicated children have high non-cancer risks. Similarly, the single-metal cancer risk assessment showed no cancer risk, except Cr, whereas the multi-metal cancer risk assessment showed children and adults inhabitants likely to have cancer in their lifetime. [ABSTRACT FROM AUTHOR]

The road shipping has become one of the major metal contamination sources that could impact on roadside soils. Therefore, this study was conducted to determination, possible source identification and potential ecological and human health risks assessment of trace elements (Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn) in roadside surface soil samples in Hamedan, west of Iran in 2018. In so doing, a total of 63 roadside soil specimens from three main highways, including Goltapeh (G), Razan (R), and Kermanshah (K), were collected. Then, the contents of elements in roadside soils were determined using ICP-OES. Based on the results obtained, the highways with heavy traffic have the highest accumulation of all the metals, suggesting the effect of traffic density on metals concentrations. Computed values of pollution indices with mean of 0.970 for I-geo and 2.16 for PI pointed out that the soils collected from R and K roads primarily contaminated by Zn. The results of potential ecological risk assessment (RI) indicated that the surface soNo potential conflict of interest was reported by the author(s).ils at all the sites with RI < 150 have low ecological risk. Also, based on the results of human health risk assessment there was no substantial non-carcinogenic risk found to both children and adults through exposure to studied metals in roadside soil. The carcinogenic risk of Cr for both target populations was at the tolerable or acceptable level, while the other metals have no considerable carcinogenic risk. Hazard quotient (HQ) values demonstrated that ingestion was the main path of road soil metal exposure to man beings. Multivariate statistical analyses represented that Mn in the roadside soils derived from both soil minerals erosion and exhaust sources. Other metals also derived from non-exhaust sources (e.g. wear and tear of brakes, tires, engines, and lubricating oil). Our findings could be provided a theoretic basis and data support for pollution monitoring and control, soil remediation treatment and the implementation of public prevention in roadside areas of Hamedan. [ABSTRACT FROM AUTHOR]

In this study, the pollution intensity, spatial distribution, and index-based risk distribution in campuses, which are a small prototype of cities, were mapped and the sources of heavy metals in the soil were investigated. Soil samples were taken from 9 different points from the Aksaray University Central campus, which was determined as the study area. It has been determined that the pH value in the collected soil samples varies between 8.7 and 11.0. This situation created an effect on reducing the accumulation and mobility of heavy metals in the soil. When the study area was evaluated based on the geo-accumulation index, Pb heavy metal was much denser in the places indicated as circulation areas and where students were actively present. Based on the pollution load index, it was concluded that 75% of the study area was moderately/highly polluted, and the rest consisted of unpolluted soils. Pearson correlation analysis and APCS-MLR analyses conducted to determine the source distribution showed that the contributions of natural sources, mixed sources of industrial and traffic activities, agricultural activity-based sources, and other sources were 57.49%, 21.44%, 12.67%, and 8.40%, respectively. Pb is mainly related to the mixed sources of industrial and traffic activities. Therefore, to clear up its long-term impact on the accumulation of heavy metals in the soil, it is important to conduct continuous heavy metal monitoring in the soil throughout the campus. [ABSTRACT FROM AUTHOR]

The heavy metal contents in soil fractions were determined using selective solutions and a sequential extraction procedure and then the amounts of heavy metals were calculated in these fractions of soils generated on the volcanic material of Mount Karadağ. Heavy metal status and contamination levels were determined by using pollution indices instead of comparing them with the reference rock alone. Different pollution indices were used such as Geoaccumulation index (Igeo), pollution load index (PLI), Enrichment factor (EF) and Contamination factor (CF) index. According to all indices used, there was no or very little contamination, except for RAC, and it was determined that these levels did not cause any pollution in the soil. RAC values showed a high risk especially for Cd. Although not high risk, low risk points were detected in Ni and Pb. This situation clearly reveals that in the pollution assessments, indexes that take mobile fractions into account rather than total values should be used for sensitive areas. [ABSTRACT FROM AUTHOR]

Objectives: The metal contamination levels in soil, water, and fish samples from the Sundarbans in Bangladesh were thoroughly examined. Key pollutants were identified using Principal Component Analysis (PCA), and pollution and health risks were evaluated using indices like TRI, Igeo, and Pearson correlation coefficients. Metal concentrations (Mn, Cu, Zn, Pb, Cd, Cr, As, Ni, Hg) were analyzed in various regions of the Sundarbans. In addition, the study extensively evaluated pollution severity and toxicity using indices like PLI, MPI, and TRI to assess the health risks associated with consuming fish. Methods: The study utilized different techniques to evaluate metal pollution in the Sundarbans. Fifteen locations were sampled for soil, water, and fish and then analyzed for metal concentrations using AAS. To evaluate the health risks related to fish consumption, the study measured the Estimated Daily Intake (EDI) and examined bioconcentration patterns in various fish species. Risk assessments utilized indices like Pollution Load Index (PLI), Metal Pollution Index (MPI), Toxicity Risk Index (TRI), Enrichment Factor (EF), Geoaccumulation Index (Igeo), and Contamination Factor (CF). Statistical methods such as Pearson correlation coefficients and PCA were used to assess the connection between metal concentrations and pollution risks. Specific contamination levels were emphasized using contamination factors and modified contamination factors. Results: Significant levels of metal contamination were uncovered in the Sundarbans during the study. Pb, Cd, Mn, Ni, Hg, and Cr were detected at high concentrations in soil, water, and fish samples from fifteen sites. Soil showed moderate pollution (Igeo: 1–2) for Mn, Pb (highest 1.7783), and Zn (lowest-1.2153). Water had Pb with the highest Igeo of 1.9951. Fish showed the highest Igeo values for Pb at 1.9259 and Cd at 1.9510. The Gangetic mystus had a high EDI of Zinc (Zn) at 2.3 µg/kg body weight per day, posing health risks if consumed. The concentration of mercury in Goby fish was 0.45 mg/kg, whereas Pama croaker had only 0.12 mg/kg of zinc. High Total Target Cancer Risk values of (1.7 × 103), PLI 3.2–5.6, MPI 2.7–4.8, and TRI 4.1–6.3 underscored severe pollution. The EF values ranged from 4.5 to 7.2, and Pb (3.2) and Cd (2.8) showed significant geoaccumulation as per the Igeo. The CF indicated significant contamination, ranging from 2.5 to 6.1. The results of Pearson correlation coefficients and PCA confirm that pollution risks have a significant impact on both aquatic life and human health. Conclusion: The study uncovered severe metal contamination in soil, water, and fish samples from the Sundarbans. High TRI values indicated substantial toxicity risks, threatening ecosystems, human health, and water quality. Principal Component Analysis identified critical pollutants, revealing that Pb, Cd, Mn, Ni, Hg, and Cr levels were dangerously high. Immediate action is needed to mitigate these risks, especially for children consuming contaminated fish, highlighting urgent health and environmental concerns. [ABSTRACT FROM AUTHOR]

Small rivers and other surface and groundwater sources form the basis for the functioning of river basin systems, shaping streamflow, providing water supply for rural areas, and supporting biodiversity. Local surface and groundwater sources are extremely sensitive to anthropogenic impacts and climate change. Changes in the quality and quantity of water in these sources are a primary factor influencing their use for various purposes, objects, methods, and technical conditions. Therefore, the research aimed to assess the quality of natural waters in the southern part of the Mohyliv-Podilskyi district, within the basin of the small river Kotlubayevka (a right tributary of the Dniester River). The primary research methods were analytical and statistical. The analytical method was used to determine the chemical composition of water samples according to standardized procedures. The statistical method was used to find out the reliability of measurement results and to provide a generalized assessment of water quality. Experimental results were processed for water samples based on ecological and sanitary criteria from eight potential sources of economic use located along the slopes of the Dniester and Kotlubayevka river basins, ranging from elevations of 215–206 to 78–55 m a.s.l. According to the ecological classification of surface water quality, the studied sources are classified as fresh oligotrophic (class I), and based on ion composition criteria, they are categorized as bicarbonate waters of type I ( > Ca2+ + Mg2+). The study identified a trend of water source contamination in the research area concerning copper, iron (Fetotal), and saprophytic bacteria Escherichia coli. A generalized ecological assessment of water was calculated using block indices for salinity composition, ecological-sanitary, and specific toxic indicators, which ranged from 2.33 to 3.00 along the slope above the river currents. The results indicate that the quality of the studied water sources ranges from "very good," "clean," to "good," "fairly clean." However, based on the block index for specific toxic indicators, the water quality tends to approach "fairly good" or "slightly polluted." Among the water contaminants, elevated levels of Fetotal, Cu2+, and E. coli primarily contribute to the deterioration of water quality and safety. Iron and copper contamination should be regarded as a natural factor, while microbiological contamination by E. coli should be considered a result of anthropogenic impact. The obtained research results impose limitations on the economic use of certain water sources, particularly in agricultural production. [ABSTRACT FROM AUTHOR]

Sediment serves as a heavy metal store in the riverine system and provides information about the river’s health. To understand the distribution of heavy metal content in the Ganga River basin (GRB), a total of 25-bed sediment and suspended particulate matter (SPM) samples were collected from 25 locations in December 2019. Bed sediment samples were analyzed for different physio-chemical parameters, along with heavy metals. Due to insufficient quantity of SPM, the samples were not analyzed for any physio-chemical parameter. The metal concentrations in bed sediments were found to be as follows: Co (6–20 mg/kg), Cr (34–108 mg/kg), Ni (6–46 mg/kg), Cu (14–210 mg/kg), and Zn (30–264 mg/kg) and in SPM, the concentrations were Co (BDL-50 mg/kg), Cr (10–168 mg/kg), Ni (BDL-88 mg/kg), Cu (26–80 mg/kg), and Zn (44–1186 mg/kg). In bed sediment, a strong correlation of 0.86 and 0.93 was found between Ni and Cr, and Cu and Zn respectively and no significant correlation exists between organic carbon and metals except Co. In SPM, a low to moderate correlation was found between all the metals except Zn. The risk indices show adverse effects at Pragayraj, Fulhar, and Banshberia. Two major clusters were formed in Hierarchal Cluster Analysis (HCA) among the sample points in SPM and bed sediment. This study concludes that the Ganga River at Prayagraj, Banshberia, and Fulhar River is predominately polluted with Cu and Zn, possibly posing an ecological risk. These results can help policymakers in implementing measures to control metal pollution in the Ganga River and its tributaries. [ABSTRACT FROM AUTHOR]

Purpose: The study aims to assess the ecological risks posed by metal contamination in Montenegrin marine sediments, focusing on both Boka Kotorska Bay and the coastal part of the open sea. By analyzing metal concentrations and identifying potential pollution hotspots and sources, the research seeks to contribute to a better understanding of the escalating threats to coastal regions and their ecological implications due to anthropogenic activities. Methods: Total concentrations of Fe, Mn, Cr, Ni, Zn, Cu, Pb, As, Hg, and Cd were determined in surface sediment samples collected from 10 sites along the Montenegrin coast, targeting areas influenced with different sources and levels of anthropogenic pollution. Statistical analysis was performed, and various pollution indices (contamination factor (Cf), geo-accumulation index (Igeo), potential ecological risk factor ( E r i) , pollution load index (PLI), risk index (RI), mean ERM quotient (MERMQ), and toxic risk index (TRI)) were calculated to assess contamination status, severity of pollution, and potential ecological risks. Results: The results showed varying levels of metals, with elevated concentrations of Fe, Mn, Ni, and Cr at location S10 (Ada Bojana), and higher Cu, Pb, Hg, and Zn levels at S5 (Bijela). Cf and Igeo values indicated mainly moderate to considerable pollution, with Pb concentrations of particular concern. Ecological risks were posed by Hg and, in some cases, Cd, while Ni concentrations presented the highest toxic risk to marine organisms according to TRIi values. Overall, pollution was present in the entire area, with mainly moderate ecological risk according to RI values, but considerable to very high toxic risks highlighted by MERMQ and TRI values at various locations. Conclusion: This study revealed overall pollution presence in surface sediments along the Montenegrin coast, predominantly associated with anthropogenic sources, thereby posing potential ecological risks, particularly in Boka Kotorska Bay and at S10 (Ada Bojana). The obtained results highlighted the need for continued monitoring and management strategies to mitigate environmental impacts. [ABSTRACT FROM AUTHOR]

Abstract Swiftly increasing population and industrial developments of urban areas has accelerated the worsening of the water quality in recent years. Groundwater samples from different locations of the Doon valley, Garhwal Himalaya were analyzed to measure concentrations of six potential toxic elements (PTEs) viz. chromium (Cr), nickel (Ni), arsenic (As), molybdenum (Mo), cadmium (Cd), and lead (Pb) using Inductively Coupled Plasma Mass Spectrometer (ICP-MS) with the aim to study the spatial distribution and associated hazards. In addition, machine learning algorithms have been used for prediction of water quality and identification of influencing PTEs. The results inferred that the mean values (in the units of µg L−1) of analyzed PTEs were observed in the order of Mo (1.066) > Ni (0.744) > Pb (0.337) > As (0.186) > Cr (0.180) > Cd (0.026). The levels and computed risks of PTEs were found below the safe limits. The radial basis function neural network (RBF-NN) algorithms showed high level of accuracy in the predictions of heavy metal pollution index (HPI), heavy metal evaluation index (HEI), non-carcinogenic (N-CR) and carcinogenic (CR) parameters with determination coefficient values ranged from 0.912 to 0.976. However, the modified heavy metal pollution index (m-HPI) and contamination index (CI) predictions showed comparatively lower coefficient values as 0.753 and 0.657, respectively. The multilayer perceptron neural network (MLP-NN) demonstrated fluctuation in precision with determination coefficient between 0.167 and 0.954 for the prediction of computed indices (HPI, HEI, CI, m-HPI). In contrast, the proficiency in forecasting of non-carcinogenic and carcinogenic hazards for both sub-groups showcased coefficient values ranged from 0.887 to 0.995. As compared to each other, the radial basis function (RBF) model indicated closer alignments between predicted and actual values for pollution indices, while multilayer perceptron (MLP) model portrayed greater precision in prediction of health risk indices.

The untreated municipal solid wastes (MSWs) dumping and improper management causes major concerns of environmental degradation and human health risks. In this study, we collected soil and vegetable from the MSWs dumpsites of Khulna City Corporation (KCC) in southwestern Bangladesh. Trace metals (Pb, Cd, Co, Cr, Cu, Ni, Zn, Fe, Mn) were measured to explore the health risk of cultivated vegetables from dumpsites. Soil contamination was evaluated by geoaccumulation index (Igeo), enrichment factor (EF), contamination factor (CF), and pollution load index (PLI), while health risk was evaluated by transfer factor (TF), estimated daily intake (EDI), target hazard quotient (THQ). Results exhibited that the average trace metals in soil and vegetables followed in the order of Fe > Pb > Mn > Zn > Cu > Cr > Ni > Cd > Co. The Igeo, EF, CF, and PLI values revealed that the soil contamination was dominated by Pd, Cd, Mn, and Zn. The EDI of metals in vegetables were exceed the maximum daily intake only for Fe, Pb, and Cr. The total THQ was > 1, implying potential health hazards for the local people due to the long-term consumption of the cultivated vegetables. The multivariate analysis reveled that the sources of trace metals in the soils and vegetables of dumpsites were natural and anthropogenic. Overall, the findings suggest that growing vegetables in dumpsite is unsafe for long-term consumption by local inhabitants. Immediate action should be taken to protect the environment and human health from trace metal hazards.

Municipal solid waste is considered an environmental threat in Iran. The study was performed on soil near the Saravan dumpsite and measured the concentrations of 8 metals (Zn, Cu, As, Hg, Pb, Cr, Cd, and Ni) in soil, by inductively coupled plasma mass spectrometry. The average content of As, Cu, Cr, Pb, Zn, Hg, Ni, and Cd in soil were 10.48, 20.22, 19.07, 24.95, 28.83, 0.13, 19.91, and 0.1 mg/kg, respectively. The mobility factors based on water-soluble and exchangeable fractions were As (8.85%), Zn (4.19%), Pb (1.85%), Cu (1.60%), and Cr (0.02%), and not detectable for Hg, Ni, and Cd. Evaluation of metals contamination by pollution index, integrated pollution index, and Nemerowʼs pollution index for each metal showed that PI for all metals except Hg was in the range of low to moderate, and for Hg, 50% in high pollution grade; the average of the IPI (1.21), indicated a moderate pollution condition; the mean value of the PINemerow (1.20), which was in slight pollution grade. The correlations between total concentrations of metals, and bioavailable fractions with microbial biomass carbon, basal respiration, microbial quotient, metabolic quotient, urease, and alkaline phosphatase activities were moderate (r = 0.4-0.6). The activity of urease was from 37.79 to 1414.31 µg N gˉ1 dm.2 hˉ1 and alkaline phosphatase from 34.66 to 698.78 µg nitrophenyl gˉ1 dm. hˉ1. Due to the rainy climate and the continuous leaching of the surface soil, we suggested performing waste separation and the treatment of leachate produced before flowing downstream. [ABSTRACT FROM AUTHOR]

The western Bay of Bengal is particularly susceptible to the harmful impacts of increasing coastal pollution, as coastal population and urban development are occurring at unprecedented rates. The rapid urbanization and industrialization along the east coast of India coupled with the transfer of contaminants into the Bay of Bengal through riverine systems, causing a direct impact on marine ecosystems. In the present study, an attempt has been made to understand the heavy metal distribution on shelf sediments in the western part of the Bay of Bengal to infer their source, processes, and historical changes in marine pollution. Three short sediment core samples were collected and analysed for sediment texture, organic matter, and heavy metals. Cores 1 and 2 contain a high amount of sand content, representing shallow marine with moderate to high-energy conditions, and were deposited at a recent time. Core 3 was dominated by muddy sand to sandy mud, which denotes calm sedimentation without any turbulence, and these sediments were deposited under relatively low-energy conditions. The higher concentration of organic matter in the top layers of the core indicates both marine and terrestrial input. The heavy metal contents show quite heterogeneous and variable distributions from one element to another and from one core to another. The calculated pollution indices such as Contamination Factor (CF), and Geoaccumulation Index (Igeo) and Pollution Load Index (PLI) values indicate that all the core sub-samples are severely enriched and highly polluted by Cd and moderately polluted by Pb. The increased heavy metal concentration in the upper portion of the sediment cores and moderate to considerable ecological risks indicate that these metals have been deposited in the study area for the past few decades. [ABSTRACT FROM AUTHOR]

Evidence on prospective remediation of municipal solid waste contaminated with toxic heavy metals by Eudrilus eugeniae (Eu) and Lampito mauritii (L) is very scarce and yet to be explored. In this study, heavy metal detoxification potential of E. eugeniae and L. mauritii in municipal solid waste (MSW) + cowdung (CD) (3:1)–based feedstocks were investigated against Eisenia fetida (E) (a well-known vermi-remediator) and aerobic composting. Excellent reduction (70.01–93.04%) of potentially toxic heavy metals (PTHMs) (Pb, Cr, Cd and Zn) were evident in both E. eugeniae and L. mauritii employed treatments. Moreover, the results on heavy metal budget quotient clearly demonstrated the unique detoxification route undertaken by E. eugeniae and L. mauritii via humic composite facilitated chelation over the nominal bioaccumulation pathway. The principal component analysis (PCA) confirmed the strong negative correlation between the heavy metal (HM) level in earthworm gut and MSW substrate, whereas a strong positive correlation between humic substances and HM remediation. Furthermore, analysis of ecological health parameters indicated substantial reduction of environmental risk and guaranteed negligible risk of PTHM if utilized as manure. Moreover, significant increment in total N content (3.2–3.8-fold), available P (4–5.9-fold), exchangeable K (3.66–fourfold) and enzyme activity along with significant reduction of TOC (~ 87%) confirmed E. eugeniae and L. mauritii could effectively stabilize MSW. Thus, the metal-binding potential of humic substances produced by earthworms during the detoxification of municipal solid waste (MSW), coupled with a metal budget analysis, has offered valuable insights into the usage of E. eugeniae and L. mauritii as effective contenders for sanitizing heavy metal-laden MSW. [ABSTRACT FROM AUTHOR]

This research examined heavy metals distribution and potential environmental impact in seven locations along the Bhavnagar coast in Gujarat, India. The study used several analyses, including hierarchical cluster analysis (HCA), principal component analysis (PCA), and correlation analysis to investigate the harmful heavy metals present in the area. To evaluate the possible risk of Cd, Pb, Cr, Zn, Co, Cu, Ni, Mn, and Fe to the marine environment, pollution indices such as contamination factors (Cf), enrichment factor (Ef), geo-accumulation index (Igeo), ecological risk factor (Er), ecological risk index (RI) and sediment quality guidelines (SQGs) applied. Based on the results, the mean concentration of heavy metals was ranked in the following order (mg/kg): Fe (561.4) > Mn (58.9) > Cr (42) > Zn (12.5) > Pb (8.2) > Ni (7) > Cu (5.2) > Co (2.7) > Cd (.3). Compared to the pre-monsoon and post-monsoon seasons, the results showed a diluting impact on heavy metal concentrations during the monsoon season. The spatial distribution of the heavy metals indicated that the geogenic source and anthropogenic source were the primary contributors to pollution in the studied region. Principal component analysis suggests that Cd, Pb, Co and Cr may have come from shipbreaking activities, municipal discharge and industrial operations. Cf, Igeo, and Ef demonstrated no pollution to moderate pollution, with a maximum contribution of Cd, and the coastal sediment poses a minimal ecological risk for all heavy metals investigated. Shipbreaking, urban runoff, salt-marine, and agricultural runoff release toxic metals into the coastal environment. In conclusion, the information obtained from this geochemical characterization could be valuable to policymakers and stakeholders in developing effective management measures for the Bhavnagar coastal region, Gulf of Khambhat, Gujarat, India. [ABSTRACT FROM AUTHOR]

Dry riverbeds can transport mining waste during torrential rain events, disseminating pollutants from mining areas to natural ecosystems. This study evaluates the impact of these mine wastes on soils, sediments, and runoff/pore water in the La Carrasquilla dry riverbed (southeastern Spain). An integrated approach utilizing geochemical and mineralogical techniques was employed, analyzing water, soil, and sediment samples from both the headwater and mouth of the riverbed. Soil profiles and pore water were collected at 30 cm, 60 cm, and 90 cm deep, alongside sediment and runoff water samples. The assessment of metal(loid) contamination focused on arsenic, cadmium, chromium, copper, iron, nickel, manganese, zinc, and lead, utilizing sequential extraction to evaluate metal partitioning across soil phases. Various pollution indices, including the contamination factor (Cf), pollution load index (PLI), potential ecological risk index (RI), and metal(loid) evaluation index (MEI), were employed to classify contamination levels. The highest level of contamination was reported in the headwater, which suggested anthropogenic activities linked to the presence of mining residues as the major source of metal(loid)s. However, an active deposition of As, Cd, Cu, Fe, Mn, and Zn was reported in the topsoil at the mouth. In the headwater, a quartz and muscovite-rich zone exhibited the highest Cf for Pb (1022), primarily bound to the soil residual fraction (62.8%). At the headwater and mouth, pore water showed higher concentrations of sulfate, Ca, Na, Cl, Mg, and Mn and higher salinity than acceptable limits for drinking water or irrigation established by the World Health Organization. Runoff-water metal concentrations surpassed established guidelines, with MEI values indicating significant contamination by cadmium (36.1) and manganese (19.0). These findings highlight the considerable ecological risk of Pb and underscore the need for targeted remediation strategies to mitigate environmental impacts in the Mar Menor coastal lagoon. [ABSTRACT FROM AUTHOR]

For the first time, we have compiled a general list of diatoms for the Zarafshan River consisting of 428 species based on our own research and the literature data. Indicator species for nine water parameters were identified, making up more than 90% of the list. Bioindicators and statistical methods revealed that sections of the river around the city of Samarkand and further in the middle reaches reflect the complexity of the impact of the environment on diatom communities. The surveyed sections of the middle reaches of the river are divided into branches and the dynamics of water parameters and diatom communities are shown from the border with Tajikistan to the confluence of the Zarafshan with the Amu Darya. The indices of organic pollution, S, and toxic impact, WESI, were calculated. They show that there is an increase in salinity and turbidity and a decrease in organic pollution downriver. At the same time, the Navoi section is a source of water acidification. Nutrients and heavy metals, as well as phenol pollution, enter the river from various sources, mainly in the middle reaches of the river. The Zarafshan Nature Reserve in the catchment area of the upper section of the river within Uzbekistan is important for maintaining water quality. Bioindicators show an increase in self-purification, with an increase in the species richness and abundance of diatoms in the middle section of the Zarafshan River. The integrated index of river pollution, RPI, shows that most pollution comes from the northern canal of the river in the middle reaches. A general look at the Zarafshan River catchment basin and the dynamics of the identified water parameters and bioindicator species of diatoms shows that the river ecosystem successfully copes with incoming pollution, including transboundary impacts from Tajikistan. Such a conclusion could not be made based on chemical analysis of the water alone. This allowed us to recommend expanding state monitoring points to the lower section of Karakul while including biological indicators in the observations. [ABSTRACT FROM AUTHOR]

Three soil transects located in the granitic regions of Palamaner mandal, Andhra Pradesh, India, were examined to assess the pollution levels of both primary and secondary metals (Si, Al, Fe, Ca, Mg, Na, K, Cu, Mn, P, and Zn) and to ascertain the degree of soil pollution in agricultural areas. The soils along these transects are slightly acid to neutral, with dark brown to red rubified argillic clay-rich B horizons alongside a moderate cation exchange capacity. The A horizon soils display low organic carbon levels with a moderate variability and contain over 70% SiO2, exhibiting low variability due to limited leaching in a semiarid climate. The findings suggest that iron (Fe) and manganese (Mn) oxides play a role in reducing contamination levels through oxidation and precipitation processes. Furthermore, the soils show low to moderate cation exchange capacity, which restricts the retention of absorbed heavy metals, thus lessening their negative impacts. A two-way ANOVA revealed significant differences in CEC, organic carbon, and total zinc content across different horizons and landscape positions. Si, Al, and Cu had small increases and negative geoaccumulation indices in all soil profiles, suggesting no pollution. However, the Nemerow and mean contamination degree over 6 point to slight to moderate pollution. The analysis identified three distinct clusters with significant variations in contamination factors for SiO2 and Cu. Five principal components were determined, explaining 76% of the total variance, primarily derived from geogenic sources and remaining within acceptable limits. This research on soil transects in granitic regions contributes to a better understanding of the distribution, movement, and concentration of elemental oxides based on slope position, which is essential for pollution assessment and soil quality enhancement. [ABSTRACT FROM AUTHOR]

In this study, a total of 180 surface soil samples were collected from a control area and residential, commercial, and industrial regions of Hamedan, Iran during the fall season in 2023. Contents of analyzed elements were then determined using ICP-OES. The results illustrated that the average contents of As, Cd, Cu, Mn, Ni, and Pb were 1.17–2.26 times greater than those reported as local background values, while the mean contents of As, Cd, and Cu were respectively 3.41, 1.25, and 1.00 times greater than the background contents for Iran by implying the possible human sources of these PTEs. The cumulative average ecological risk value with 81.9, demonstrated moderate ecological risk across the study area. The results of source apportionment showed that the PTEs contamination in the soil of the study area mainly originates from the anthropogenic activities (65.6%) and traffic emissions as the primary pollution source (47.3%) had the highest contribution to the PTE pollution in the study area. In conclusion, by providing a useful approach to identifying the sources and contributions of toxic elements across different functional areas, this study has the potential to guide future efforts aimed at managing and mitigating the pollution caused by metal elements. [ABSTRACT FROM AUTHOR]

Background and Objective: The pollution of trace elements in urban soil has attracted wide attention due to its detrimental environmental and health effects. Therefore, this research was conducted to evaluate of the content, pollution levels, and health risks associated with trace elements (Fe, Zn, Pb, Cd, Cu, Mn, and Mo) in the surface soil of Al-Qasim City in Babylon Governate in 2024. Materials and Methods: This descriptive cross-sectional study involved, a total of 50 surface soil samples from a depth of 0-20 cm. The elemental content of the samples was determined using inductively coupled plasma optical spectroscopy (ICP-OES). Additionally,, the enrichment factor (EF), pollution index (PI), pollution load index (PLI), hazard index (HI), and carcinogenic risk (CR) were calculated. Statistical data analyses were done using SPSS software. Results: The average concentrations of Fe, Zn, Cd, Cu, Mn, and Mo in the soil were 27240, 62.7, 0.302, 33.8, 570 and 0.999 mg/kg, respectively. The highest average concentrations of Fe (30,331 mg/kg), Cu (37.3 mg/kg), Mn (639 mg/kg), and Mo (1.08 mg/kg) were found in downtown areasm whilefor the highest concentrations of Zn (65.3 mg/kg) and Cd (0.332 mg/kg) were observed in rural and midtown areas. Conclusion: The results of this research demonstrate the impact of urban activities-such astraffic, industry, and agriculture-on the trace element pollution in the soil of Al-Qasim City. Therefore, regular monitoring of trace element concentrations and identification of their pollution sources are recommended to reduce and manage associated environmental and health risks [ABSTRACT FROM AUTHOR]

Contaminated river sediment poses a threat to aquatic life and public health. The focus of this study was to investigate possible contamination of sediments from the Warri River. Triplicate samples were collected from ten sites of intense industrial activities. The sediments were analysed for heavy metals (HMs), anions, and physicochemical properties, including total hydrocarbon content (THC), an indicator of hydrocarbon contamination. The contamination level was evaluated using the following indices: contamination factor index (CF), geo-accumulation index (Igeo), enrichment factor (EF), ecological risk index (ERI), modified degree of contamination (mCd), pollution load index (PLI), risk index (RI) and sediment quality guidelines (SQG). Principal component analysis (PCA) and hierarchical clustering analysis (HCA) were used to identify the sources of HM contamination. The aggregate contamination indices (mCd, PLI and RI) indicate no contamination/pollution or ecological risk. Similarly, the single contamination indices (CF, Igeo, and ERI) showed low contamination and ecological risk for almost all heavy metals except for Cd, which was high in many sample locations. Most of the heavy metals exhibited values below both the threshold-effects level (TEL) and the probable-effects level (PEL), except for Cd, where 80% of locations recorded levels between TEL and PEL, suggesting possible ecological risk for Cd. PCA suggests that PC1, loaded with Fe, Zn, Ni, Cd and Cr, indicates anthropogenic activity. PC2, loaded with Mn and Pb, suggests both anthropogenic and geogenic origins. In conclusion, the possible HM contamination necessitates urgent government intervention to protect aquatic ecosystems and public health. [ABSTRACT FROM AUTHOR]

This study highlights the geochemistry of water and sediments of the karstic springs of the transboundary aquifer (TBA) Žumberak–Samoborsko Gorje Mt. (NW Croatia). After calculating pollution indices, the analysis showed that the sediments are unpolluted. The geo-accumulation index (Igeo) showed only the elements Ba and Rb, indicating moderate levels of pollution, with the highest values in springs Vapnik and Bistrac. Statistical analysis confirmed their natural origin. The water of these springs is under possible anthropogenic influence as indicated by elevated concentrations of total nitrogen (TN) and total phosphorus (TP). According to a principal component analysis (PCA) for elements in sediments, PC1 described a combined lithogenic and oxidative–reductive influence, PC2 described a combined geological background including total organic carbon (TOC) content and oxidative–reductive influence, while TOC had the greatest influence on PC3. Depending on element composition, the factor scores related to PC1 and PC2 resulted in two different groups of sites, while the factor scores concerning PC1 and PC3 did not show separation in two groups. The hierarchical cluster analysis showed three clusters in relation to the content of the elements. The correlation coefficient between the sediment and related water samples showed that the springs placed in a low-permeability formation (dolomite) had a strong positive coefficient of correlation. [ABSTRACT FROM AUTHOR]

Metals and metalloids tainting sediments is an eminent issue, predominantly in megacities like Mumbai and Navi Mumbai, requiring an exhaustive examination to identify metal levels in river bodies that serve various populations. Thus, utilising pollution indices, multivariate analysis, and health risk assessment studies, we propose a novel investigation to examine the metal content in the Ulhas River sediments, a prominent agricultural and drinking water supply (320 million-litre per day) near Mumbai in Maharashtra, India. The eleven metals and metalloids (As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, and Zn) were examined monthly from 10 stations totaling 120 sediment specimens from October 2022 to September 2023. Investigations revealed that average values of Cr, Cu, Hg, and Ni exceeded Australian and New Zealand Environment and Conservation Council and Agriculture and Resource Management Council values, while all metals exceeded World surface rock average limits except As. Various pollution indices showed that upstream sites had none to low level contamination, whereas downstream locations had moderate to considerable contamination, suggesting anthropogenic influences. Furthermore, multivariate analysis including correlation, cluster, and principal component analysis identified that sediment pollution was mostly caused by anthropogenic activities. Lastly, health risk assessment indicated Fe was non-carcinogenic to children, whereas Cr and Ni were carcinogenic to children and adults, with children being more susceptible. Thus, from the findings of the study it is clear that, despite low to moderate pollution levels, metals may have significant repercussions, thus requiring long-term planning, frequent monitoring, and metal abatement strategies to mitigate river contamination. [ABSTRACT FROM AUTHOR]

This work is mainly concerned with the effect of anthropogenic activities, the presence of black sand spots, factory construction, and shipping, in addition to other activities like agriculture, on soil heavy metal pollution along the Mediterranean shores of Lake El-Burullus, Egypt, to assess the contamination levels and to identify possible sources and the distribution of these metals. This study focuses on the various heavy metal contamination levels in El-Burullus Lake coastal sediments. Sediment samples were collected and analyzed by the XRF technique for heavy metals, including Cr, Cu, Ni, Zn, Zr, Pb, Ba, Sr, Ga, Rb, V, and Nb. Statistical analyses, including correlation coefficient, factor analysis, and cluster analysis, were employed to understand the interactions and sources of these metals. The highest concentrations recorded were for Zr (84–1436 mg/kg) and Pb (1–1166 mg/kg), with average concentrations of 455.53 mg/kg and 79.27 mg/kg, respectively. Cr, Zr, Nb, and Pb showed average values higher than the average shale concentration, indicating potential pollution. Correlation analysis revealed strong associations between several metals, suggesting common sources of both natural and anthropogenic origin and similar distribution patterns. Factor analysis indicated four main factors accounting for 94.069% of the total variance, with the first factor heavily dominated by Cr, Ni, Zn, and Ba. The contamination factor (Cf) and degree (DC) analyses revealed varying contamination levels, with most metals exhibiting the greatest values in the western half of the area. The pollution load index (PLI) indicated high-quality sediment samples without significant pollution. Our findings highlight the importance of continued monitoring and management techniques to reduce possible environmental and health concerns associated with these pollutants. [ABSTRACT FROM AUTHOR]

The agro-waste derived valuable products are prime interest for effective management of toxic heavy metals (THMs). The present study investigated the efficacy of biochars (BCs) on immobilization of THMs (Cr, Zn, Pb, Cu, Ni and Cd), bioaccumulation and health risk. Agro-wastes derived BCs including wheat straw biochar (WSB), orange peel biochar (OPB), rice husk biochar (RHB) and their composite biochar (CB) were applied in industrial contaminated soil (ICS) at 1% and 3% amendments rates. All the BCs significantly decreased the bioavailable THMs and significantly (p < 0.001) reduced bioaccumulation at 3% application with highest efficiency for CB followed by OPB, WSB and RHB as compared to control treatment. The bioaccumulation factor (BAF), concentration index (CI) and ecological risk were decreased with all BCs. The hazard quotient (HQ) and hazard index (HI) of all THMs were <1, except Cd, while carcer risk (CR) and total cancer risk index (TCRI) were decreased through all BCs. The overall results depicted that CB at 3% application rate showed higher efficacy to reduce significantly (p < 0.001) the THMs uptake and reduced health risk. Hence, the present study suggests that the composite of BCs prepared from agro-wastes is eco-friendly amendment to reduce THMs in ICS and minimize its subsequent uptake in vegetables. Novelty statement: The present study has a scientific research scope, based on reduction of bioavailability and bioaccumulation of toxic heavy metals (THMs) by the addition of biochars derived from agro-wastes and their composite biochar (CB), thereby decreasing the potential health risk. Limited study has been conducted, especially on the impact of CB in THMs-contaminated soil. This study could fill the scientific research gap and provides useful information for mitigation of THMs present in contaminated soil, which could be followed by the Environmental Protection Agency, Ministry of Agriculture and farmers in degraded lands. [ABSTRACT FROM AUTHOR]

Quarries are regarded as crucial cornerstones of national economic development in Palestine. But they also have detrimental effects on the ecosystem and biological resources. Determination of the amount of heavy metals (chromium, cadmium, and lead) in quarries stumps is the main objective of the current research study. To accomplish this, 20 quarry stump samples were collected from four distinct regions of the Hebron Governorate in Palestine, using the quadrat method, and they were afterward calorimetrically assessed using a UV-visible spectrophotometer and pollution indices. The results reveal that the stumps possess Cr and Pb concentration below the international declared levels (1–1000 mg/l and 15–40 mg/l, respectively), while the Cd is above the declared level (0.2 mg/kg). The Cr and Pb content ranges from 0.128 to 0.611 mg/L and 0.125 to 0.779 mg/L, respectively. On contrary, the Cd contents varies from 0.362 to 8.572 mg/L in Hebron governorate. This level of Cd content, somehow, locate above their declared level by the international standards. In addition, the heavy metals content seems to be site-specific in the selected regions in Hebron governorate. The risk of cadmium is due to its high concentration, while the risk of Pb is because of its high toxicity. Moreover, the four regions are considered as uncontaminated and are clean based on PI Nemerow for Cr and Pb, but not for Cd. In conclusion, working on quarries in Hebron governorate is still safe from the levels of heavy metals point of view. However, more control and restriction must be implanted in order to mitigate its environmental and health consequences. Moreover, more research is needed to assess the occurrence of other heavy metals and their consequences on biological life and environmental issues. [ABSTRACT FROM AUTHOR]

Abstract: The increasing population has subjected rivers and streams to high levels of both industrial and domestic pollution. Significant environmental challenges have been brought about by their effects, particularly with regard to biota, ecosystem processes, soil quality, and groundwater pollution. This study examined the effects of human activity by applying pollution index models to evaluate the input of toxic elements in river sediments. Prior to sediment quality analysis, the total amount of arsenic (As), lead (Pb), cadmium (Cd), mercury (Hg), thorium (Th), and uranium (U) was determined in the concentration range of 1.09–10.0 mg/kg, 8.53–475 mg/kg, 0.12–0.16 mg/kg, 4.85–77.5 mg/kg, 3.14–5.9 mg/kg and 0.93–2.86 mg/kg, respectively. The enrichment factor, contamination factor, pollution load index, and geo-accumulation index revealed alarmingly high levels of Pb and Hg contamination at some sampling points, which are related to possible human input, ranging from severe enrichment to considerable contamination. The low ranges of pollution indices of some toxic elements suggest enrichment through the natural weathering process and atmospheric deposition. The Pearson correlation coefficient revealed a significant correlation between Pb-Fe and As-Fe, suggesting the possibility of acid mine contamination. Continual monitoring of river sediment is essential to minimize the impact of toxic elements to sustain sediment health and quality. [ABSTRACT FROM AUTHOR]

Assessing groundwater quality is essential for ensuring the sustainability of agriculture and ecosystems. This study evaluates groundwater contamination by heavy metals (HMs) using GIS approaches, multivariate statistical analysis (MSA), pollution indices (heavy metal pollution index (HPI), metal index (MI), degree of contamination (Cd), ecological risk index (ERI), and pollution index (PI)), and human health risk assessment (HHRA). The results revealed significant variations in heavy metal concentrations across the study area, with the highest concentrations found in the southern and southeastern parts, characterized by intense agricultural activities and uncontrolled landfills. Statistical analyses indicated both natural and anthropogenic sources of contamination. Pollution indices showed medium to high water pollution levels, with HPI values ranging from 20.23 to 128.60, MI values from 3.34 to 12.17, and Cd values from 2.90 to 11.73, indicating varying degrees of contamination. ERI values suggested a low ecological risk across all samples. However, health risk assessments highlighted significant non-carcinogenic and carcinogenic risks, particularly for children, with TCR values for some heavy metals like Ni and Cr exceeding safe limits, indicating potential health hazards. The findings provide a valuable framework for policymakers to develop targeted strategies for mitigating groundwater contamination and ensuring sustainable water quality management. [ABSTRACT FROM AUTHOR]