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Organic scintillators, pivotal in security and medical applications, face challenges due to limited X‐ray absorption and exciton utilization. Herein, a novel class of organic scintillators is introduced, named guest‐induced thermally activated delayed fluorescence (TADF) within supramolecular macrocycles via host‐guest through‐space charge transfer (TSCT). Four co‐crystals are obtained through orthogonal crystallizations involving calix[3]acridan (C[3]A) and calix[3]phenothiazine (C[3]P) macrocycles as hosts, along with 1,2‐dicyanobenzene (DCB) and 4‐bromo‐1,2‐benzenedicarbonitrile (BrDCB) as guests. Interestingly, DCB@C[3]A and BrDCB@C[3]A co‐crystals exhibit strong host‐guest TSCT with reduced single‐triplet energy gap for efficient TADF emission, which leads to enhanced exciton utilization and X‐ray absorption, yielding radioluminescence intensities over 29 and 25 times higher than C[3]A. Similarly, substituting C[3]A with C[3]P, the obtained TADF co‐crystals also outperform C[3]P in scintillation performance. Additionally, the scintillation color of co‐crystals can be adjusted by varying the electron‐donating abilities of macrocycles and the electron‐accepting abilities of guests, offering a simpler color‐tuning mechanism than covalent‐bonded scintillators. Furthermore, the flexible film based on DCB@C[3]A exhibits promising application in X‐ray radiography, showcasing a high spatial resolution of 20 lp mm−1 @MTF = 0.77. The innovative strategy of fabricating organic scintillators via reversible non‐covalent interactions presents a novel solution for designing color‐tunable and high‐performance scintillators. [ABSTRACT FROM AUTHOR]

Abstract The ability to distinguish multiple forms of plutonium from one another, such as oxide and metal, is paramount in areas of nuclear nonproliferation and international safeguards. In its metal form, plutonium can be readily used in a nuclear weapon, while oxide forms are associated with nuclear reactor fuel. Oxide-based plutonium forms emit neutrons with an energy spectrum that is significantly different from the fission neutrons that are emitted from plutonium metal. Organic scintillation detectors output pulses that are proportional to the neutron energy deposited, and therefore present a means of distinguishing these plutonium forms based on their energy spectra. In this work, metal and oxide forms of plutonium were measured using a handheld detection system based on an organic glass scintillator. Monte Carlo modeling of these experiments was performed to provide insight into the origin of the features in the observed light output spectra. Through analysis of multiple regions of these spectra, in a matter of minutes we were able to unambiguously discriminate oxide and metal plutonium forms from one another and from a plutonium-beryllium neutron source, which was considered for comparison because these sources are commonly used in industrial applications. The ability to discriminate weapons-usable material from nuclear reactor fuel has applications in nuclear treaty verification and safeguards.

The ability to distinguish multiple forms of plutonium from one another, such as oxide and metal, is paramount in areas of nuclear nonproliferation and international safeguards. In its metal form, plutonium can be readily used in a nuclear weapon, while oxide forms are associated with nuclear reactor fuel. Oxide-based plutonium forms emit neutrons with an energy spectrum that is significantly different from the fission neutrons that are emitted from plutonium metal. Organic scintillation detectors output pulses that are proportional to the neutron energy deposited, and therefore present a means of distinguishing these plutonium forms based on their energy spectra. In this work, metal and oxide forms of plutonium were measured using a handheld detection system based on an organic glass scintillator. Monte Carlo modeling of these experiments was performed to provide insight into the origin of the features in the observed light output spectra. Through analysis of multiple regions of these spectra, in a matter of minutes we were able to unambiguously discriminate oxide and metal plutonium forms from one another and from a plutonium-beryllium neutron source, which was considered for comparison because these sources are commonly used in industrial applications. The ability to discriminate weapons-usable material from nuclear reactor fuel has applications in nuclear treaty verification and safeguards. [ABSTRACT FROM AUTHOR]

Organic scintillators have recently gained considerable attentions in X‐ray detection for their potential applications in biomedical radiograph and security inspection. However, the weak X‐ray absorption and/or inefficient exciton utilization have limited the development and commercialization of organic scintillators. Currently, high‐performance X‐ray organic scintillators are scarce and organic scintillators with dual triplet‐harvesting channels have not been explored before. Here, we develop several proof‐of‐concept sulfone‐based organic molecules, C1–C7, using different alkoxy chains to manipulate molecular packing mode. These materials exhibit dual triplet‐harvesting channels of thermally activated delayed fluorescence (TADF) and room‐temperature phosphorescence (RTP) in aggregated state. Inspiringly, these molecules display distinct radioluminescence under the X‐ray stimulation. Among them, C6 behaves the highest light yield of 16,558 photons MeV−1. Moreover, clear X‐ray images are demonstrated in both aggregated state and single‐molecule level. High spatial resolutions of 15.0 and 10.6 line pairs per millimeter (lp mm−1) are achieved for rigid and flexible scintillator screens, exceeding most reported organic and conventional inorganic scintillators. These results highlight the great potential of organic molecules with TADF and RTP nature for efficient X‐ray scintillation and imaging. [ABSTRACT FROM AUTHOR]

Abstract Organic scintillators have recently gained considerable attentions in X‐ray detection for their potential applications in biomedical radiograph and security inspection. However, the weak X‐ray absorption and/or inefficient exciton utilization have limited the development and commercialization of organic scintillators. Currently, high‐performance X‐ray organic scintillators are scarce and organic scintillators with dual triplet‐harvesting channels have not been explored before. Here, we develop several proof‐of‐concept sulfone‐based organic molecules, C1–C7, using different alkoxy chains to manipulate molecular packing mode. These materials exhibit dual triplet‐harvesting channels of thermally activated delayed fluorescence (TADF) and room‐temperature phosphorescence (RTP) in aggregated state. Inspiringly, these molecules display distinct radioluminescence under the X‐ray stimulation. Among them, C6 behaves the highest light yield of 16,558 photons MeV−1. Moreover, clear X‐ray images are demonstrated in both aggregated state and single‐molecule level. High spatial resolutions of 15.0 and 10.6 line pairs per millimeter (lp mm−1) are achieved for rigid and flexible scintillator screens, exceeding most reported organic and conventional inorganic scintillators. These results highlight the great potential of organic molecules with TADF and RTP nature for efficient X‐ray scintillation and imaging.

Traditional‐metal‐containing scintillators are widely used in X‐ray imaging due to their efficient X‐ray absorption and output of visible light. However, they suffer from heavy‐metal toxicity, environmental stability, harsh preparation, and afterglow. Metal‐free organic scintillators show a rising momentum, especially organic‐halogen‐containing molecules. Halogens are introduced to improve their X‐ray absorption, but the resulting increase in spin–orbit coupling leads to significant delayed fluorescence or phosphorescence, affecting the response speed to X‐rays. Moreover, there is still insufficient practice in fabricating microstructured organic scintillators for high spatial resolution of imaging. Herein, the preparation of nano organic co‐crystals (t‐Bpe‐IFB co‐crystal, abbreviated as BIC, t‐Bpe for trans‐1,2‐bis(4‐pyridyl)ethylene, and IFB for 1,3,5‐trifluoro‐2,4,6‐triiodobenzene) and its application in X‐ray imaging are explored. In contrast to previous single organic‐halogen‐containing molecules, BIC generates nanosecond‐scale fluorescence through the charge‐transfer state of the donor–acceptor. Its high iodine content ensures large X‐ray absorption, strong radioluminescence, and a low detection limit of 85 nGyair s−1. The composite film made of nano‐sized BICs and polydimethylsiloxane exhibits a high spatial resolution of 16.7 lp mm−1. Herein, the application of organic co‐crystals is expanded and ideas are provided for the development of new scintillators. [ABSTRACT FROM AUTHOR]

The multi-institution Single-Volume Scatter Camera (SVSC) collaboration led by Sandia National Laboratories (SNL) is developing a compact, high-efficiency double-scatter neutron imaging system. Kinematic emission imaging of fission-energy neutrons can be used to detect, locate, and spatially characterize special nuclear material. Neutron-scatter cameras, analogous to Compton imagers for gamma ray detection, have a wide field of view, good event-by-event angular resolution, and spectral sensitivity. Existing systems, however, suffer from large size and/or poor efficiency. We are developing high-efficiency scatter cameras with small form factors by detecting both neutron scatters in a compact active volume. This effort requires development and characterization of individual system components, namely fast organic scintillators, photodetectors, electronics, and reconstruction algorithms. In this presentation, we will focus on characterization measurements of several SVSC candidate scintillators. The SVSC collaboration is investigating two system concepts: the monolithic design in which isotropically emitted photons are detected on the sides of the volume, and the optically segmented design in which scintillation light is channeled along scintillator bars to segmented photodetector readout. For each of these approaches, we will describe the construction and performance of prototype systems. We will conclude by summarizing lessons learned, comparing and contrasting the two system designs, and outlining plans for the next iteration of prototype design and construction.

The organic scintillator crystal 1,3,5-Triphenylbenzene (TPB) is a promising material for high-energy particle detection applications. The bulk size of unidirectional ( plane) TPB cylindrical crystal was grown by the unidirectional growth technique and their optical properties were analyzed to couple with a photomultiplier tube for detector device fabrications. The gamma retorts of the grown cylindrical crystal were tested with varying gamma energy sources ranging from 356 to 1275 keV. The Time of flight (TOF) experimental setup was constructed with a grown TPB crystal and Neutron-Gamma discrimination was demonstrated with a 252Cf fission source. The developed TPB crystal exhibits strong timing characteristics operates consistently and offers a great capability for discrimination over gamma radiations.

X‐ray induced photodynamic therapy (X‐PDT) circumvents the poor penetration depth of conventional PDT with minimal radio‐resistance generation. However, conventional X‐PDT typically requires inorganic scintillators as energy transducers to excite neighboring photosensitizers (PSs) to generate reactive oxygen species (ROS). Herein, a pure organic aggregation‐induced emission (AIE) nanoscintillator (TBDCR NPs) that can massively generate both type I and type II ROS under direct X‐ray irradiation is reported for hypoxia‐tolerant X‐PDT. Heteroatoms are introduced to enhance X‐ray harvesting and ROS generation ability, and AIE‐active TBDCR exhibits aggregation‐enhanced ROS especially less oxygen‐dependent hydroxyl radical (HO•−, type I) generation ability. TBDCR NPs with a distinctive PEG crystalline shell to provide a rigid intraparticle microenvironment show further enhanced ROS generation. Intriguingly, TBDCR NPs show bright near‐infrared fluorescence and massive singlet oxygen and HO•− generation under direct X‐ray irradiation, which demonstrate excellent antitumor X‐PDT performance both in vitro and in vivo. To the best of knowledge, this is the first pure organic PS capable of generating both 1O2 and radicals (HO•−) in response to direct X‐ray irradiation, which shall provide new insights for designing organic scintillators with excellent X‐ray harvesting and predominant free radical generation for efficient X‐PDT. [ABSTRACT FROM AUTHOR]

Plastic, organic scintillators have been tailored in composition to achieve an ultrafast temporal response, thereby enabling the design and development of fast neutron detection systems with high timing resolution. Eljen Technology's plastic, organic scintillators- EJ-230, EJ-232, and EJ-232Q- are prospective candidates for use in emerging neutron imaging systems, where fast timing is paramount. To support the neutron response characterization of these materials, the relative proton light yields (PLYs) of EJ-230, EJ-232, and EJ-232Q were measured at the 88-Inch Cyclotron at the Lawrence Berkeley National Laboratory. Using a broad-spectrum neutron source and a double-Time-of-flight technique, the PLY relations were obtained over a proton recoil energy range of approximately 300 keV to 4 MeV. The EJ-230, EJ-232, and EJ-232Q scintillators exhibited similar PLY relations to each other and to other plastic scintillators with the same polymer base material. A comparison of the relative PLY of different sized cylindrical EJ-232 and EJ-232Q scintillators also revealed consistent results. This article provides key input data for the realistic computational modeling of neutron detection technologies employing these materials, thereby supporting new capabilities in near-field radionuclide detection for national security applications.

Organic fluorescence scintillators, owing to the ultrafast response time, versatile chemical structures, low processing temperature, and low cost, are considered as one of the promising materials for medical diagnostics, radiation detection, and X‐ray astronomy. However, the low radioluminescence (RL) intensity and low sensitivity hinder their practical applications. In this work, a highly efficient organic fluorescent scintillator, 4,4′‐bis(9‐carbazolyl)biphenyl (CBP), is presented, exhibiting a high X‐ray RL intensity, narrow full width at half‐maximum of 49 nm, and ultrafast decay time of 1.15 ns. More importantly, it has a low detection limit of 25.5 nGy s−1, which is only 1/215 dose rate compared with the commercial X‐ray diagnostics. Such an excellent scintillation performance is mainly attributed to its high photoluminescence quantum yield (PLQY = 61.92%) and good carrier transport (average hole mobility of 0.094 cm2 V−1 s−1). By mixing the CBP into polydimethylsiloxane, the fabricated large area flexible film can be applied in X‐ray radiography, which exhibits a high spatial resolution of 14.3 lp mm−1 at MTF > 0.2. This work paves a way for the implementation of organic fluorescence dyes with high PLQY, high carrier mobility in efficient X‐ray scintillation and imaging. [ABSTRACT FROM AUTHOR]

Recent progress in the development of novel organic scintillators necessitates modern characterization capabilities. As the primary means of energy deposition by neutrons in these materials is n-p elastic scattering, knowledge of the proton light yield is paramount. This work establishes a new model-independent method to continuously measure the proton light yield in organic scintillators over a broad energy range. Using a deuteron breakup neutron source at the 88-in. Cyclotron at Lawrence Berkeley National Laboratory and an array of organic scintillators, the proton light yield of EJ-301 and EJ-309, commercially available organic liquid scintillators from Eljen Technology, was measured via a double time-of-flight technique. The light yield was determined using a kinematically over-constrained system in the proton energy range of 1–20 MeV. The effect of the pulse integration length on the magnitude and shape of the proton light yield relation was also explored. This work enables accurate simulation of the performance of advanced neutron detectors and supports the development of next-generation neutron imaging systems. [ABSTRACT FROM AUTHOR]

Organic scintillators have rapidly emerged in recent years for X-ray scintillation and imaging, benefiting from their inherent advantages of abundant raw materials, low-temperature processing, high mechanical flexibility, and easy of large-scale fabrication. However, conventional organic scintillators suffer from weak X-ray absorption and inefficient exciton utilization, limiting their commercial viability. To overcome these challenges, new-generation organic scintillators have recently been developed with innovative emission mechanisms to ensure exciton utilization efficiency and the incorporation of heavy atoms to improve X-ray absorption. In recent years, these advancements have led to remarkable progress in high-performance X-ray scintillation and imaging. Here, we present a concept article on new-generation organic scintillators with high exciton utilization efficiency, focusing on molecular design, emission mechanisms, scintillation performance, and X-ray imaging applications. We also discuss future development trends in organic X-ray scintillators., (© 2025 Wiley-VCH GmbH.)

The Detector Response Function Toolkit (DRiFT) post-processes radiation transport output from MCNP and simulates realistic gas, semiconductor, and scintillator nuclear instrumentation response. Scintillator response is the most mature DRiFT capability and includes the ability to simulate light production, photomultiplier tube (PMT) effects, and the digitization of the pulse, all important contributors when assessing an instrument's nuclear safeguards and nonproliferation applicability. Many scintillator, PMT, and digitizer models are supported natively by DRiFT, which also accommodates users adding their own specific instrumentation responses if absent in DRiFT. Until recently use of DRiFT required access to the high performance computing clusters at Los Alamos National Laboratory (LANL) and compiling the code with many additional software dependencies. This paper describes the development, capabilities, and release of an executable version of DRiFT compatible with Linux OS. In addition to scintillator features, many DRiFT diagnostic capabilities relevant to nuclear safeguards including source particle tracking, pileup estimation, cross-talk and correlated event identification, and varied output options are described. [ABSTRACT FROM AUTHOR]

In this work, we propose a prototype of a compact detector assembly capable of discriminating between neutrons and gamma rays, by performing pulse shape analysis. The device takes advantage of recent improvements in silicon photomultiplier (SiPM) technology and the excellent neutron/gamma-ray discrimination capabilities of new plastics and standard liquid scintillators. Our work is focused on the read-out of small-, medium-, and large-sized organic scintillators with large-area SiPM arrays ($4 \times 4$ NUV and RGB-SiPM arrays, 17 mm $\times$ 17 mm). In particular, we used EJ-276 (and its old version EJ-299) and EJ-276G plastic scintillators of several sizes (ranging from 20- to 50-mm diameter) and two large liquid scintillator cells (EJ-301 and EJ-309, 50 mm diameter $\times 50$ mm thickness). Moreover, we show the comparison of neutron/gamma-ray discrimination performance between SiPM and standard photomultiplier read-out configurations. The presented innovative device could be used in different fields, first in fundamental nuclear physics experiments, as an ancillary neutron detector for the active target at the selective production of exotic species (SPES) facility at the Legnaro National Laboratories in Italy. Additionally, it could be used in radiation monitoring applications, as a fast neutron/gamma-ray counter to be embedded in unmanned vehicles for radiation monitoring. [ABSTRACT FROM AUTHOR]

During the neutron detection process, owing to the effects of inelastic scattering and slow neutron capture, a neutron-gamma mixed radiation field is formed, which increases the complexity of neutron detection. Organic scintillators are widely used in neutron detection because of their high flashing efficiency, short decay time, and high detection efficiency. Pulse shape discrimination (PSD) is a key technology for discriminating neutrons and gamma rays according to the difference in pulse shape caused by the difference in particle decay time in organic scintillators. Traditional PSD methods include time-domain and frequency-domain discrimination methods. In recent years, various machine-learning techniques applied to neutron-gamma discrimination have achieved better results. To better use organic scintillators and the corresponding neutron-gamma discrimination methods in neutron detection, we conducted a comprehensive analysis of the glowing mechanism of organic scintillators, PSD principle, organic scintillator types, and neutron-gamma discrimination methods and investigated the performance evaluation indexes of organic scintillators and neutron-gamma discrimination methods. Finally, the future development directions of organic scintillators and neutron-gamma discrimination methods were examined.

We propose a novel approach based on variational autoencoder with Gaussian mixture latent space (GMVAE) to address the challenging problem of pulse shape discrimination (PSD) in organic scintillators, in the presence of pile up. Unlike deterministic charge integration, which is very sensitive to pulse-processing parameters, the GMVAE performances are robust against variations of the hyperparameters. When compared to other supervised machine learning methods, GMVAE requires the fewest training pulses (100) to achieve a classification accuracy within 2% of its optimum performance, i.e. , 98.3% accuracy. GMVAE exhibited excellent classification despite the difference in energy spectra between the training and test data sets, which were 14.1 MeV neutron pulses and 239PuBe pulses, respectively. While requiring minimum supervision, GMVAE showed superior PSD performances compared to both deterministic and supervised machine learning approaches. GMVAE is hence particularly suitable for real-time pulse classification, where expert labeling is unavailable and fine tuning of the discrimination parameters impractical. • A variational autoencoder with Gaussian mixture prior for pulse shape discrimination with pile ups. • Our method outperforms deterministic and ML methods with minimal supervision. • Our GMVAE required only 100 training pulses to achieve near-optimal accuracy. • Proved GMVAE's adaptability to different energy spectra between training and testing. • Potential of GMVAE for real-time applications due to its computational efficiency. [ABSTRACT FROM AUTHOR]

Fast neutron active interrogation is a powerful method for detecting shielded contraband, including explosives, narcotics, and special nuclear material. Pulsed neutron sources can produce intense, time-dependent gamma-ray signatures of contraband, but the detection of those gamma rays is frequently challenging due to high detector pileup. Organic scintillators are fast and cost-effective gamma-ray detectors and thus could be well suited for this application if they can provide adequate gamma-ray spectroscopy. We discuss the use of maximum likelihood estimation maximization based spectral reconstruction techniques for organic scintillators to reconstruct the inelastic scattering and capture gamma-ray spectra produced in neutron active interrogation. Several contraband simulants were irradiated with a pulsed deuterium-tritium neutron generator, and organic liquid scintillators were used to record the emitted radiation signatures. The gamma-ray spectra are time-gated based on the measured neutron pulse time profile, which is shown to be able to improve the signal-to-background ratio for contraband gamma-ray signatures. We isolated several major gamma-ray signatures in the reconstructed spectra that correspond to contraband constituent elements, allowing for the identification of potential contraband objects. We additionally show that the reconstructed gamma-ray spectra can be used to measure sample stoichiometry and discriminate benign from contraband simulant objects. [ABSTRACT FROM AUTHOR]

Pulse shape discrimination (PSD)‐capable plastic scintillator is in demand for the detection of high‐energy neutrons in the presence of gamma radiation background. Conventional PSD plastics are based on delayed fluorescent dye via triplet–triplet annihilation of a fluorescent dye additive, which is inefficient to harvest the energy of triplet excitons. In recent years, thermally activated delayed fluorescence (TADF) emitters have gained substantial success in organic light‐emitting diodes due to their efficient utilization of the energy of triplet excitons and thereby achieving theoretical unity internal quantum efficiencies. Herein, a highly efficient TADF dye 9‐(4‐(4,6‐diphenyl‐1,3,5‐triazin‐2‐yl)‐2‐methylphenyl)‐3,6‐dioctyl‐9H‐carbazole is reported for the PSD application. This TADF dye may be loaded up to 30 wt% in polyvinyltoluene matrix and still retains high optical transparency. High scintillation light yield and PSD figures of merit are obtained from the TADF plastic. With the introduction of a secondary dye to further increase the utilization efficiency of the excitation energy, the light yield is increased to 6948 photons MeV−1. The measured alpha/gamma PSD figure of merit is 1.12 at the energy threshold of 100 keVee and neutron/gamma PSD figure of merit is 1.32 at the threshold of 1000 keVee. [ABSTRACT FROM AUTHOR]

Liquid organic scintillators are important devices for measurements of neutron radiation. Currently, large-scale liquid organic scintillators have capabilities of detecting neutrons, but the determination of the neutron energy spectra is a challenge. This work aims to measure the responses of two liquid two-component scintillators to mono-energetic neutron radiation and to determine their light output function, which is necessary for proper neutron energy spectra determination. Both scintillators are composed of the solvent di-iso-propyl-naphthalene (DIPN) mixed isomers. The first scintillator, labeled PYR5/DIPN, contains the luminophore 1-phenyl-3-(2,4,6-trimethyl-phenyl)-2-pyrazoline with a concentration of 5 g/L. The second scintillator labeled THIO5/DIPN contains the luminophore 2,5-bis(5-tert-butyl-benzoxazol-2-yl)thiophene also with a concentration of 5 g/L. The responses to neutron energies of 1.5 MeV, 2.5 MeV, and 19 MeV are measured at PTB in Braunschweig. The responses to neutron energies of 2.45 MeV and 14 MeV were measured at CTU in Prague using DD and DT reactions. The responses to a silicon filtered beam were measured at Research Centre Řež. The measurements were processed using a two-parameter spectrometric system NGA-01 to discriminate neutrons from gamma rays. The obtained responses are dominated by recoil protons from elastic collisions of neutrons with hydrogen atoms. The edge of the response of recoil protons gives information about the light output of neutrons, compared to gamma rays for the same radiation energy. The light output function for protons in the PYR5/DIPN scintillator is L(Ep)=0.6294Ep−1.00(1−exp(−0.4933Ep0.95)). The light output function for protons in the THIO5/DIPN scintillator is L(Ep)=0.6323Ep−1.00(1−exp(−0.4986Ep0.9883)). The light output functions well resemble the standard shape, and they are quite similar to each other. That suggests a weak influence of the luminophore on the light output function. The light output functions are ready to be incorporated to the response matrix for the neutron energy spectra determination.

Carbazole crystals were grown using self-seeding vertical Bridgman technique, and the scintillation properties for neutron detection were investigated. Results of powder X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses indicated the single phase of the grown carbazole crystal with orthorhombic structure. Photo- and radio-luminescence measurements were carried out, and maxima of both emission peaks were at 420 nm. The light yield under 5.5-MeV alpha-ray irradiation was estimated to be 1.87 times higher than that of lithium glass GS-20. The scintillation decay time under neutron irradiation was estimated to be 11.4 ± 0.3 ns. It follows from the temperature dependence measurements that the light output under 662-keV gamma-ray excitation decreases with increasing temperature. [ABSTRACT FROM AUTHOR]

Liquid organic luminophores (LOLs) have been actively investigated as a new generation of functional materials in various fields of organic optoelectronics and photonics. However, many issues, including the structure–properties relationships and the development of LOLs emitting light in the red spectral range, remain poorly investigated. Here we report on the synthesis and investigation of a series of novel conjugated luminescent molecules consisting of a central 2,1,3-benzothiadiazole electron-withdrawing unit and lateral thiophene or phenylene electron-donating fragments with terminal trialkylsilyl units as solubilizing groups (SGs). Thermal and thermo-oxidative stability, phase behavior, structural properties, rheology, and optical and electrochemical properties of the obtained luminophores were studied and compared to their counterparts without SGs or with ineffective SGs for liquefaction. The target compounds are luminescent liquids with low glass transition temperatures (up to −65 °C) and viscosities (up to 1.7 Pa s) or liquid crystal materials emitting light in almost the entire visible spectral range with high photoluminescence quantum yield (PLQY) both in solutions (up to 97 %) and films (up to 87 %). For the first time, the application of LOLs as a new generation of organic liquid scintillators was demonstrated, achieving a light yield up to 1.7 times higher than that of a standard liquid scintillator. [Display omitted] • Liquid benzothiadiazole-based luminophores with trialkylsilyl groups were reported. • Impact of the type of solubilizing group and conjugated core on properties was evaluated. • Liquid luminophores (LOLs) show efficient fluorescence in the blue to red spectral regions. • For the first time, it was demonstrated that LOLs can be used in liquid scintillators. [ABSTRACT FROM AUTHOR]

In organic scintillators, the energy distribution of gamma rays and neutrons is indirectly measured by the pulse height distribution of light output produced through gamma ray and neutron reactions in the detectors. Accurate estimate of the interaction of gamma and neutrons in the detector and produce charged secondary particles and subsequent scintillation light produced in the calculation of the response function is the most important. Although,, the complexity of the light generation on these scintillators makes modeling their response function difficult with standard Monte Carlo method. The paper reports generate the response function of an NE102 plastic scintillator when exposed to gamma rays and response function of a BC501A liquid scintillator to mono-energetic and Am-Be neutrons using the EVENTBIN card of the FLUKA code and the PTRAC card of the MCNPX code. The comparison between simulated and experimental response functions show that both FLUKA and MCNPX codes generated distributions are in good agreement with corresponding experimental results.

Organic phosphorescent scintillating materials have shown great potential for applications in radiography and radiation detection due to their efficient utilization of excitons. However, revealing the relationship between molecule stacking and the phosphorescent radioluminescence of scintillators is still challenging. This study reports on two phenothiazine derivatives with polymorphism-dependent phosphorescence radioluminescence. The experiments reveal that molecule stacking significantly affects the non-radiation decay of the triplet excitons of scintillators, which further determines the phosphorescence scintillation performance under X-ray irradiation. These phosphorescent scintillators exhibit high radio stability and have a low detection limit of 278 nGys -1 . Additionally, the potential application of these scintillators in X-ray radiography, based on their X-ray excited radioluminescence properties, is demonstrated. These findings provide a guideline for obtaining high-performance phosphorescent scintillating materials by shedding light on the effect of crystal packing on the radioluminescence of organic molecules., (© 2024 Wiley‐VCH GmbH.)

Organic scintillators with efficient X-ray excited luminescence are essential for medical diagnostics and security screening. However, achieving excellent organic scintillation materials is challenging due to low X-ray absorption coefficients and inferior radioluminescence (RL) intensity. Herein, supramolecular interactions are incorporated, particularly halogen bonding, into organic scintillators to enhance their radioluminescence properties. By introducing heavy atoms (X = Cl, Br, I) into 9,10-bis(4-pyridyl)anthracene (BPA), the formation of halogen bonding (BPA-X) enhances their X-ray absorption coefficient and restricts the molecular vibration and rotation, which boosts their RL intensity. The RL intensity of BPA-Cl and BPA-Br fluorochromes increased by over 2 and 6.3 times compared to BPA, respectively. Especially, BPA-Br exhibits an ultrafast decay time of 8.25 ns and low detection limits of 25.95 ± 2.49 nGy s -1 . The flexible film constructed with BPA-Br exhibited excellent X-ray imaging capabilities. Furthermore, this approach is also applicable to organic phosphors. The formation of halogen bonding in bromophenyl-methylpyridinium iodide (PYI) led to a fourfold increase in RL intensity compared to bromophenyl-methyl-pyridinium (PY). It suggests that halogen bonding serves as a promising and effective molecular design strategy for the development of high-performance organic scintillator materials, presenting new opportunities for their applications in radiology and security screening., (© 2023 Wiley‐VCH GmbH.)

A compact radiation imaging system capable of detecting, localizing, and characterizing special nuclear material (e.g. highly-enriched uranium, plutonium...) would be useful for national security missions involving inspection, emergency response, or war-fighters. Previously-designed radiation imaging systems have been large and bulky with significant portions of volume occupied by photomultiplier tubes (PMTs). The prototype imaging system presented here uses silicon photomultipliers (SiPMs) in place of PMTs because SiPMs are much more compact and operate at low power and voltage. The SiPMs are coupled to the ends of eight stilbene organic scintillators, which have an overall volume of 5.74 × 5.74 × 7.11 cm3. The prototype dual-particle imager's capabilities were evaluated by performing measurements with a 252Cf source, a sphere of 4.5 kg of alpha-phase weapons-grade plutonium known as the BeRP ball, a 6 kg sphere of neptunium, and a canister of 3.4 kg of plutonium oxide (7% 240Pu and 93% 239Pu). These measurements demonstrate neutron spectroscopic capabilities, a neutron image resolution for a Watt spectrum of 9.65 ± 0.94° in the azimuthal direction and 22.59 ± 5.81° in the altitude direction, imaging of gamma rays using organic scintillators, and imaging of multiple sources in the same field of view. [ABSTRACT FROM AUTHOR]

In this work, an epithermal neutron multiplicity counter (ENMC) and an organic scintillator multiplicity counter (OSMC) are compared in the assay of 237Np, a potentially weapons-usable isotope, using active neutron multiplicity counting. In active neutron multiplicity counting, the neutron doubles and triples multiplicity rates are used to analytically calculate sample mass. To distinguish the masses of two different samples, the measured triples and doubles rates of each sample must be separated by 1σ. The time it takes each system to separate the measured triples multiplicity rates was compared using 20 metal samples of 237Np with masses logarithmically distributed between 10 and 1000 g. The results show that the OSMC can distinguish the smallest masses (10.0 and 12.7 g) beyond 1σ in 20 min and that the ENMC requires more than 400 times the measurement time to obtain the same precision. Similarly, the OSMC is at least 4.5 times faster than the ENMC in separating the doubles multiplicity rates. [ABSTRACT FROM AUTHOR]

We propose a hierarchical Bayesian model and a state-of-the-art Monte Carlo sampling method to solve the unfolding problem, i.e., to estimate the spectrum of an unknown neutron source from the data detected by an organic scintillator. Inferring neutron spectra is important for several applications, including nonproliferation and nuclear security, as it allows the discrimination of fission sources in special nuclear material (SNM) from other types of neutron sources based on the differences of the emitted neutron spectra. Organic scintillators interact with neutrons mostly via elastic scattering on hydrogen nuclei and therefore partially retain neutron energy information. Consequently, the neutron spectrum can be derived through deconvolution of the measured light-output spectrum and the response functions of the scintillator to monoenergetic neutrons. The proposed approach is compared to three existing methods using the simulated data to enable controlled benchmarks. We consider three sets of detector responses. One set corresponds to a 2.5-MeV monoenergetic neutron source and two sets are associated with (energywise) continuous neutron sources (252Cf and 241AmBe). Our results show that the proposed method has similar or better unfolding performance compared with other iterative or Tikhonov regularization-based approaches in terms of accuracy and robustness against limited detection events while requiring less user supervision. The proposed method also provides a posteriori confidence measures, which offers additional information regarding the uncertainty of the measurements and the extracted information. [ABSTRACT FROM AUTHOR]

Multiplexing of radiation detectors reduces the number of readout channels, which in turn reduces the number of digitizer input channels for data acquisition. We recently demonstrated frequency domain multiplexing (FDM) of pulse mode radiation detectors using a resonator that converts the detector signal into a damped sinusoid by convolution. The detectors were given unique "tags" by the oscillation frequency of each resonator. The charge collected and the time-of-arrival of the detector pulse were estimated from the corresponding resonator output in the frequency domain. In this paper, we demonstrate a new method to recover the detector pulse from the damped sinusoidal output by deconvolution. Deconvolution converts the frequency-encoded detector signal back to the original detector pulse. We have developed a new prototype FDM system to multiplex organic scintillators based on convolution and deconvolution. Using the new prototype, the charge collected under the anode pulse can be estimated from the recovered pulse with an uncertainty of about 4.4 keVee (keV electron equivalent). The time-of-arrival can be estimated from the recovered pulse with an uncertainty of about 102 ps. We also used a CeBr 3 inorganic scintillator to measure the Cs-137 gamma spectrum using the recovered pulses and found a standard deviation of 13.8 keV at 662 keV compared to a standard deviation of 13.5 keV when the original pulses were used. Coincidence measurements with Na-22 using the deconvolved pulses resulted in a timing uncertainty of 617 ps compared to an uncertainty of 603 ps using the original pulses. Pulse shape discrimination was also performed using Cf-252 source and EJ-309 organic scintillator pulses recovered by deconvolution. A figure of merit value of 1.08 was observed when the recovered pulses were used compared to 1.2 for the original pulses. [ABSTRACT FROM AUTHOR]

Abstract This work compares the time resolution obtained from coincidence measurements using combinations of four types of silicon photomultipliers (SiPMs), five types of organic scintillators, and two timing algorithms. Organic scintillators in combination with SiPMs have shown to have equivalent or better time resolution and pulse shape discrimination (PSD) capability than with photo-multiplier tubes (PMTs). In addition, SiPMs are more compact and require low operating voltage. These factors have made them suitable for the development of compact neutron scatter cameras (NSCs) and potentially low-cost positron emission tomography (PET) systems. The following measurements analyze combinations of organic scintillators and SiPMs that could be used for these applications. Measurements and analyses assessed the time resolution of standard-output and fast-output pulses of the various scintillator and SiPM combinations. The coincidence measurements were performed using a Na-22 source to characterize time resolution where all coincident events above about a 40 keVee threshold were analyzed. Uncertainties were determined by applying bootstrapping to the acquired data sets. The full width at half maximum (FWHM) of the time difference distribution for each combination is reported as the time resolution of the system. For standard-output pulses, we found that using a digital implementation of analogue constant fraction discrimination (DIACFD) improved timing resolution greater than a single standard deviation for six of the fourteen tested combinations compared to using digital constant fraction discrimination (DCFD). Conversely, for fast-output pulses, DCFD with a moving average filter produced the best timing resolution. Among the tested non-PSD capable organic scintillators, EJ-228 coupled to a MicroFJ-SMA-60035 SensL SiPM yielded the best time resolution of 303 ± 4 ps for standard-output pulses and 227 ± 4 ps for fast-output pulses. The best time resolution found for PSD capable organic scintillators was obtained using Inrad Optics stilbene coupled to a MicroFJ-SMA-60035 SensL SiPM which yielded a time resolution of 428 ± 6 ps for standard-output pulses and 293 ± 4 ps for fast-output pulses. [ABSTRACT FROM AUTHOR]

Abstract Temperature gradient based unidirectional solution growth set-up was specially designed to felicitate the growth of unidirectional crystals of t-stilbene with cylindrical dimension of 6 cm × 2 cm without the need of post growth machining process for scintillator application. A growth rate of 1 mm/day was achieved along <011> direction. The PXRD establishes the phase purity of the grown material. FT-IR and Micro-Raman spectrometers were utilized to justify the presence of the functional groups of the t-stilbene and anisole (solvent). The recorded narrow aromatic vibrations in FT-IR and Raman ascertain the undetectable limit of solvent inclusion in the grown crystal. Absence of new vibrations other than the expected supports the chemical purity of the crystal. The transparency in visible range establishes the suitability of the material for scintillator application where its characteristic emission wavelength under high energy radiation lies. The thermal stability up to 120 °C without any structural/phase change was evident from TG/DTA. The radioluminescence spectra were carried out under β and γ and found the grown crystal exhibits emissions at 384 and 405 nm which is very similar to the studied photoluminescence characteristics. The scintillation characteristics of the t-stilbene investigated using γ –rays from various radioactive sources such as 137Cs, 133Ba and, 109Cd. The scintillation decay time of the grown crystal also studied using the same 133Cs source and fitted with single exponential component of 12 ns. Highlights • Organic scintillator t-stilbene single crystal has been grown by SR method. • A growth rate of 1 mm/day was achieved along <011> direction. • RL spectra exhibit emissions at 384 and 405 nm under β and γ excitation. • Scintillation properties were studied using γ –rays of various radioactive sources. [ABSTRACT FROM AUTHOR]

Abstract Rep-rated diagnostics are a necessity for present and future laser facilities focused on the study of high-energy-density (HED) phenomena. Electromagnetic fields in HED systems are of particular interest to the community, but are inherently difficult to diagnose due to the high mass-densities involved. By utilizing high-energy protons that penetrate through dense plasmas, fields may be visualized by detecting variations in proton fluence caused by the Lorenz interaction of the protons with the field. Typical detecting media used for proton imaging are single-use and do not scale well to rep-rated operation. We propose here the use of a scintillator-based detector and characterize the energy and spatial responses to demonstrate its feasibility as a viable option for rep-rated proton imaging and other diagnostics. [ABSTRACT FROM AUTHOR]

Abstract Design of deuterium–tritium (DT) neutron generator facilities requires a careful assessment of radiation shielding. In the models of such facilities an isotropic distribution of neutron flux produced by the neutron generator is usually assumed. However, prior studies have shown that neutron flux surrounding the neutron generator can be anisotropic. This anisotropy results mostly from the design of the generator tube, as well as the angular dependence of DT fusion reaction cross section. In this work, the angular neutron flux was measured for a standard commercially available DT generator (Thermo Fisher Scientific, Model P211) using an organic scintillator and a significant degree of anisotropy was confirmed to exist. The experimentally determined flux was then used in Monte Carlo simulations to examine the impact of anisotropy on the effectiveness of radiation shielding. Although the shielding effectiveness is not considerably affected by the anisotropy, the dose rates in air around the unshielded generator can be significantly different from those predicted when an assumption of isotropic flux is made. These considerations need to be included in modeling of the dose rate around the generator in neutron generator facilities that employ typical neutron generators, which exhibit some degree of anisotropy in neutron flux. [ABSTRACT FROM AUTHOR]

Abstract An analysis of various n/ γ separation algorithms for a digital neutron spectrometer based on a stilbene crystal is performed. The same set of digital signals is used to test the following n/ γ separation algorithms: the algorithm based on the correlation analysis; the algorithms based on the direct comparison of the pulse fast component and the pulse tail; SDCC (Simplified Digital Charge Collection) algorithm; PGA (Pulse Gradient Analysis) and FGA (Frequency Gradient Analysis) algorithms. It is shown that the algorithm based on the correlation analysis makes it possible to carry out the most effective n/ γ separation for the entire pulse areas range. The shape of the distributions of the separation parameter for electrons and protons is analyzed. The correctness of these distributions approximation by the Gaussian curve is justified. An algorithm for the selection of the recoil protons resulting from the neutron interaction with the scintillator is proposed. It is based on the dynamic change of the separation parameter threshold depending on the pulse area. The distributions of the separation parameter for electrons and recoil protons strongly overlap for small pulse areas. In this case, the threshold for the separation parameter is chosen on the basis of the fixed probability of the event false identification. In our work, for example, the contribution of false events was fixed at 1%. With the increase of the pulse area, the distributions for electrons and protons begin to separate well. In this case it is convenient to set the threshold on the separation parameter at the point of their intersection. The use of this algorithm makes it possible to control the fraction of the falsely identified events for the entire range of the pulse areas. This is especially important for low-energy recoil protons, for which the probability of false event identification reaches its maximum. This algorithm was applied to the measurements performed by the time-of-flight method with a 252 Cf source. The suppression degree of the prompt gamma-ray peak was 1100 at the neutron detection threshold of 275 keV. The contribution of the falsely identified events for the different parts of the time-of-flight spectrum using the proposed event selection algorithm was studied. The largest contribution to the false pulses was found for the neutron distribution edges — for the neutrons with the energies above 8 MeV and below 0.5 MeV, and it did not exceed 0.23% in the entire range of the pulse areas. [ABSTRACT FROM AUTHOR]

Generally for numerical solution of the differential equations the mesh generation process is a major problem in classical mesh-based methods, especially in irregular domains. Contrary to the meshed based methods, Mesh Free (MFree) methods have been developed to avoid mesh generation. In the MFree methods a set of scattered nodes is used without requiring any mesh grid. So in this work the application of MFree collocation method is examined to solve S N neutron transport equation. The MFree collocation method uses the formulation of strong form which is truly mesh less method. Since MFree method is flexible for distributing arbitrary and irregular nodes, this method can be easily applied for high heterogeneous nuclear reactor problems with complicated geometry. To validate the proposed method some test problems including regular and irregular geometries have been modeled. Our results show that the mesh free collocation method can be used for discrete ordinate neutron transport equation as an efficient and accurate method without hardness and limitations of the mesh-based methods like finite element method. [ABSTRACT FROM AUTHOR]