1. Near-Infrared Room Temperature Emission from a Novel Class of Ru(II) Heteroleptic Complexes with Quinonoid Organometallic Linker
- Author
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Marie Noelle Rager, Hani Amouri, Anny Jutand, Andrea Barbieri, Aurélie Damas, Maria Pia Gullo, Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Istituto per la Sintesi Organica e la Fotoreattività (ISOF-CNR), National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR), Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL), Processus d'Activation Sélective par Transfert d'Energie Uni-électronique ou Radiatif (UMR 8640) (PASTEUR), Université Pierre et Marie Curie - Paris 6 (UPMC)-Département de Chimie - ENS Paris, École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Département de Chimie - ENS Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL), Architectures Moléculaires (A.R.C), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Consiglio Nazionale delle Ricerche (CNR), École normale supérieure - Paris (ENS Paris), and Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS Paris)
- Subjects
Inorganic chemistry ,design ,transition-metal-complexes ,chemistry.chemical_element ,polypyridine complexes ,010402 general chemistry ,Ligands ,01 natural sciences ,7. Clean energy ,Catalysis ,Ruthenium ,octahedral bimetallic assemblies ,Coordination Complexes ,Materials Chemistry ,Organometallic Compounds ,[CHIM]Chemical Sciences ,photophysical properties ,absorption-spectra ,electrochemical-behavior ,Spectroscopy, Near-Infrared ,luminescence properties ,010405 organic chemistry ,Ligand ,Near-infrared spectroscopy ,Metals and Alloys ,Quinones ,Temperature ,General Chemistry ,ray molecular-structure ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Crystallography ,Octahedron ,chemistry ,Ceramics and Composites ,Electronics ,Luminescence ,Linker ,Oxidation-Reduction - Abstract
WOS:000317352600022; A novel class of luminescent octahedral ruthenium complexes 2-4 displaying a pi-bonded quinonoid ligand is described. Remarkably, the presence of this organometallic ligand affects their UV-vis properties and transforms them into panchromatic absorbers. Furthermore, it turns on room temperature NIR emissions.
- Published
- 2013
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