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Organometallic Quinonoid Linkers: A Versatile Tether for the Design of Panchromatic Ruthenium(II) Heteroleptic Complexes

Authors :
Barbara Ventura
Alessandra Degli Esposti
Lise-Marie Chamoreau
M. Rosa Axet
Andrea Barbieri
Hani Amouri
Aurélie Damas
Istituto per la Sintesi Organica e la Fotoreattività (ISOF-CNR)
Consiglio Nazionale delle Ricerche (CNR)
departament de quimica fisica i quimica inorganica i quimica analitica i quimica organica
Universitat Rovira i Virgili
Institut Parisien de Chimie Moléculaire (IPCM)
Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)
IRPPS-CNR, Salerno
Università degli Studi di Salerno (UNISA)
Architectures Moléculaires (A.R.C)
Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)
National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR)
Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Università degli Studi di Salerno = University of Salerno (UNISA)
Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Source :
Inorganic Chemistry, Inorganic Chemistry, American Chemical Society, 2010, 49 (23), pp.10762-10764. ⟨10.1021/ic102019b⟩, Inorganic chemistry 49 (2010): 10762–10764. doi:10.1021/ic102019b, info:cnr-pdr/source/autori:A. Damas; B. Ventura; M. R. Axet; A. Degli Esposti; L.-M. Chamoreau; A. Barbieri; H. Amouri/titolo:Organometallic quinonoid linkers: A versatile tether for the design of panchromatic Ruthenium(II) heteroleptic complexes/doi:10.1021%2Fic102019b/rivista:Inorganic chemistry/anno:2010/pagina_da:10762/pagina_a:10764/intervallo_pagine:10762–10764/volume:49, Inorganic Chemistry, 2010, 49 (23), pp.10762-10764. ⟨10.1021/ic102019b⟩
Publication Year :
2010
Publisher :
HAL CCSD, 2010.

Abstract

The synthesis, X-ray structure determination, and photophysical investigation of a novel series of heteroleptic ruthenium(II) polypyridine complexes with organometallic linkers are reported. The displayed panchromatic absorption features are assigned by means of time-dependent density functional theory studies.

Subjects

Subjects :
010405 organic chemistry
Chemistry
chemistry.chemical_element
[CHIM.CATA]Chemical Sciences/Catalysis
010402 general chemistry
Photochemistry
01 natural sciences
Combinatorial chemistry
0104 chemical sciences
Ruthenium
Panchromatic film
Inorganic Chemistry
OCTAHEDRAL BIMETALLIC ASSEMBLIES
SENSITIZED SOLAR-CELLS
[CHIM]Chemical Sciences
Density functional theory
[CHIM.COOR]Chemical Sciences/Coordination chemistry
Physical and Theoretical Chemistry
ComputingMilieux_MISCELLANEOUS

Details

Language :
English
ISSN :
00201669 and 1520510X
Database :
OpenAIRE
Journal :
Inorganic Chemistry, Inorganic Chemistry, American Chemical Society, 2010, 49 (23), pp.10762-10764. ⟨10.1021/ic102019b⟩, Inorganic chemistry 49 (2010): 10762–10764. doi:10.1021/ic102019b, info:cnr-pdr/source/autori:A. Damas; B. Ventura; M. R. Axet; A. Degli Esposti; L.-M. Chamoreau; A. Barbieri; H. Amouri/titolo:Organometallic quinonoid linkers: A versatile tether for the design of panchromatic Ruthenium(II) heteroleptic complexes/doi:10.1021%2Fic102019b/rivista:Inorganic chemistry/anno:2010/pagina_da:10762/pagina_a:10764/intervallo_pagine:10762–10764/volume:49, Inorganic Chemistry, 2010, 49 (23), pp.10762-10764. ⟨10.1021/ic102019b⟩
Accession number :
edsair.doi.dedup.....18883b4524c4d42c3c532a57a9dd524e
Full Text :
https://doi.org/10.1021/ic102019b⟩
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