1. A Bio‐Inspired Dendritic MoOx Electrocatalyst for Efficient Electrochemical Nitrate Reduction to Ammonia.
- Author
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Xu, Yuan‐Zi, Abbott, Daniel F., Dürr, Robin N., Huan, Tran Ngoc, and Mougel, Victor
- Subjects
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DENITRIFICATION , *ELECTROLYTIC reduction , *MOLYBDENUM oxides , *OXYGEN reduction , *RAMAN spectroscopy , *NITRATE reductase - Abstract
Drawing inspiration from the nitrate reductase enzymes, which catalyze nitrate to nitrite in nature, here a bio‐inspired, reduced molybdenum oxide (MoOx) shell is introduced that is grown on top of a dendritic nickel foam core (NiNF). The resulting MoOx/NiNF material is prepared via a facile, two‐step electrodeposition strategy using commercially available, low‐cost precursors. This catalytic material displays a remarkable faradaic efficiency (FE) of 99% at −0.5 V versus RHE and a high ammonia (NH3) yield rate of up to 4.29 mmol h−1 cm−2 at −1.0 V versus RHE in neutral media. Most importantly, MoOx/NiNF exhibits exceptional stability for the nitrate reduction reaction (NO3RR), maintaining operation for over 3100 h at a high current density of −650 mA cm−2, with a yield rate of 2.6 mmol h−1 cm−2 and a stable average NH3 FE of ≈83%. Through combined XPS and in situ Raman spectroscopy it is shown that the pronounced affinity of MoOx/NiNF for nitrate is associated with a substantial presence of oxygen vacancies within the material. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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