305 results on '"X. X. Xi"'
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2. Evolution of Metastable Defects and Its Effect on the Electronic Properties of MoS2 Films
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M. Precner, T. Polaković, Qiao Qiao, D. J. Trainer, A. V. Putilov, C. Di Giorgio, I. Cone, Y. Zhu, X. X. Xi, M. Iavarone, and G. Karapetrov
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Medicine ,Science - Abstract
Abstract We report on structural and electronic properties of defects in chemical vapor-deposited monolayer and few-layer MoS2 films. Scanning tunneling microscopy, Kelvin probe force microscopy, and transmission electron microscopy were used to obtain high resolution images and quantitative measurements of the local density of states, work function and nature of defects in MoS2 films. We track the evolution of defects that are formed under heating and electron beam irradiation. We observe formation of metastable domains with different work function values after annealing the material in ultra-high vacuum to moderate temperatures. We attribute these metastable values of the work function to evolution of crystal defects forming during the annealing. The experiments show that sulfur vacancies formed after exposure to elevated temperatures diffuse, coalesce, and migrate bringing the system from a metastable to equilibrium ground state. The process could be thermally or e-beam activated with estimated energy barrier for sulfur vacancy migration of 0.6 eV in single unit cell MoS2. Even at equilibrium conditions, the work function and local density of states values are strongly affected near grain boundaries and edges. The results provide initial estimates of the thermal budgets available for reliable fabrication of MoS2-based integrated electronics and indicate the importance of defect control and layer passivation.
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- 2018
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3. MgB2 Josephson junctions produced by focused helium ion beam irradiation
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L. Kasaei, T. Melbourne, V. Manichev, L. C. Feldman, T. Gustafsson, Ke Chen, X. X. Xi, and B. A. Davidson
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Physics ,QC1-999 - Abstract
Planar magnesium diboride Josephson junctions are fabricated using focused helium ion beam irradiation. A single track of ion irradiation with a 30 kV He+ beam with nominal beam diameter < 0.5 nm is used to create a normal-metal barrier on a MgB2 film deposited by hybrid physical-chemical vapor deposition. Josephson coupling is observed below the critical temperature of the electrodes for a He+ doses between 8x1015/cm2 to 4x1016/cm2. Analysis of the temperature dependence of the normal resistance and critical voltage of the junctions shows highly uniform barriers with nearly ideal resistively-shunted junction behavior for higher-dose junctions, while nonequilibrium effects dominate the properties of lower-dose junctions over most of the temperature range. These results demonstrate that focused helium ion beam irradiation can produce high-quality proximity-coupled MgB2 Josephson junctions with tailorable properties, promising for use in superconducting devices and circuits.
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- 2018
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4. Hyperspectral Analysis of Soil Total Nitrogen in Subsided Land Using the Local Correlation Mazimization-Complementary Superiority Method
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L. X. Lin, Y. J. Wang, J. Y. Teng, and X. X. Xi
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Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Applied optics. Photonics ,TA1501-1820 - Abstract
The measurement of soil total nitrogen (TN) by hyperspectral remote sensing provides an important tool for soil restoration programs in areas with subsided land caused by the extraction of natural resources. This study used the local correlation maximization-complementary superiority method (LCMCS) to establish TN prediction models by considering the relationship between spectral reflectance and TN based on spectral reflectance curves of soil samples collected from subsided land determined by synthetic aperture radar interferometry (InSAR) technology. Based on the 1655 selected effective bands of the optimal spectrum (OSP) of the first derivate differential of reciprocal logarithm ([log{1/R}]'), (correlation coefficients, P < 0.01), the optimal model of LCMCS method was obtained to determine the final model, which produced lower prediction errors (root mean square error of validation [RMSEV] = 0.89, mean relative error of validation [MREV] = 5.93%) when compared with models built by the local correlation maximization (LCM), complementary superiority (CS) and partial least squares regression (PLS) methods. The predictive effect of LCMCS model was optional in Cangzhou, Renqiu and Fengfeng District. Results indicate that the LCMCS method has great potential to monitor TN in subsided land caused by the extraction of natural resources including groundwater, oil and coal.
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- 2015
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5. MgB2 ultrathin films fabricated by hybrid physical chemical vapor deposition and ion milling
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Narendra Acharya, Matthäus A. Wolak, Teng Tan, Namhoon Lee, Andrew C. Lang, Mitra Taheri, Dan Cunnane, Boris. S. Karasik, and X. X. Xi
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Biotechnology ,TP248.13-248.65 ,Physics ,QC1-999 - Abstract
In this letter, we report on the structural and transport measurements of ultrathin MgB2 films grown by hybrid physical-chemical vapor deposition followed by low incident angle Ar ion milling. The ultrathin films as thin as 1.8 nm, or 6 unit cells, exhibit excellent superconducting properties such as high critical temperature (Tc) and high critical current density (Jc). The results show the great potential of these ultrathin films for superconducting devices and present a possibility to explore superconductivity in MgB2 at the 2D limit.
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- 2016
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6. Enhancement of lower critical field by reducing the thickness of epitaxial and polycrystalline MgB2 thin films
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Teng Tan, M. A. Wolak, Narendra Acharya, Alex Krick, Andrew C. Lang, Jennifer Sloppy, Mitra L. Taheri, L. Civale, Ke Chen, and X. X. Xi
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Biotechnology ,TP248.13-248.65 ,Physics ,QC1-999 - Abstract
For potential applications in superconducting RF cavities, we have investigated the properties of polycrystalline MgB2 films, including the thickness dependence of the lower critical field Hc1. MgB2 thin films were fabricated by hybrid physical-chemical vapor deposition on (0001) SiC substrate either directly (for epitaxial films) or with a MgO buffer layer (for polycrystalline films). When the film thickness decreased from 300 nm to 100 nm, Hc1 at 5 K increased from around 600 Oe to 1880 Oe in epitaxial films and to 1520 Oe in polycrystalline films. The result is promising for using MgB2/MgO multilayers to enhance the vortex penetration field.
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- 2015
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7. Magnesium diboride on inner wall of copper tube: A test case for superconducting radio frequency cavities
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Wenura K. Withanage, N. H. Lee, Sashank V. Penmatsa, M. A. Wolak, A. Nassiri, and X. X. Xi
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Nuclear and particle physics. Atomic energy. Radioactivity ,QC770-798 - Abstract
Superconductor magnesium diboride is considered one of the viable materials to substitute bulk niobium for superconducting radio frequency cavities. Utilizing a MgB_{2} coating on the inner wall of a copper cavity will allow operation at higher temperatures (20–25 K) than Nb cavities due to the high transition temperature of MgB_{2} (39 K) and the high thermal conductivity of Cu. In this paper, we present results of MgB_{2} coating on Cu tubes with similar dimensions to a 3 GHz cavity, as the first step towards coating the actual cavity, using the hybrid physical chemical vapor deposition technique. The results show successful coating of a uniform MgB_{2} layer on the inner wall of the Cu tubes with T_{c} as high as 37 K.
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- 2017
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8. Superconducting magnesium diboride coatings for radio frequency cavities fabricated by hybrid physical-chemical vapor deposition
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M. A. Wolak, T. Tan, A. Krick, E. Johnson, M. Hambe, Ke Chen, and X. X. Xi
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Nuclear and particle physics. Atomic energy. Radioactivity ,QC770-798 - Abstract
We have investigated the coating of an inner surface of superconducting radio frequency cavities with a magnesium diboride thin film by hybrid physical-chemical vapor deposition (HPCVD). To simulate a 6 GHz rf cavity, a straight stainless steel tube of 1.5-inch inner diameter and a dummy stainless steel cavity were employed, on which small sapphire and metal substrates were mounted at different locations. The MgB_{2} films on these substrates showed uniformly good superconducting properties including T_{c} of 37–40 K, residual resistivity ratio of up to 14, and root-mean-square roughness R_{q} of 20–30 nm. This work demonstrates the feasibility of coating the interior of cylindrical and curved objects with MgB_{2} by the HPCVD technique, an important step towards superconducting rf cavities with MgB_{2} coating.
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- 2014
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9. MgB_{2} nonlinear properties investigated under localized high rf magnetic field excitation
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Tamin Tai, B. G. Ghamsari, T. Tan, C. G. Zhuang, X. X. Xi, and Steven M. Anlage
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Nuclear and particle physics. Atomic energy. Radioactivity ,QC770-798 - Abstract
The high transition temperature and low surface resistance of MgB_{2} attracts interest in its potential application in superconducting radio frequency accelerating cavities. However, compared to traditional Nb cavities, the viability of MgB_{2} at high rf fields is still open to question. Our approach is to study the nonlinear electrodynamics of the material under localized rf magnetic fields. Because of the presence of the small superconducting gap in the π band, the nonlinear response of MgB_{2} at low temperature is potentially complicated compared to a single-gap s-wave superconductor such as Nb. Understanding the mechanisms of nonlinearity coming from the two-band structure of MgB_{2}, as well as extrinsic sources of nonlinearity, is an urgent requirement. A localized and strong rf magnetic field, created by a magnetic write head, is integrated into our nonlinear-Meissner-effect scanning microwave microscope [T. Tai et al., IEEE Trans. Appl. Supercond. 21, 2615 (2011)ITASE91051-822310.1109/TASC.2010.2096531]. MgB_{2} films with thickness 50 nm, fabricated by a hybrid physical-chemical vapor deposition technique on dielectric substrates, are measured at a fixed location and show a strongly temperature-dependent third harmonic response. We propose that several possible mechanisms are responsible for this nonlinear response.
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- 2012
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10. Study on the effects of quercetin on brain cell apoptosis and HMGB-1 and TLR-4 level in rats with encephalitis
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Y-L, Chen, H-X, Yang, X, Wang, D-L, Lu, X-X, Xi, and C, Yang
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Neurons ,Toll-Like Receptor 4 ,Disease Models, Animal ,Animals ,Brain ,Encephalitis ,Apoptosis ,Female ,Quercetin ,HMGB1 Protein ,Rats - Abstract
To explore the therapeutic effects of quercetin on rats with encephalitis, especially on cell apoptosis, and the levels of HMGB-1 and TLR-4.32 healthy rats were equally assigned into ZC group (healthy group), NY group (encephalitis group), DJ group (60 ml quercetin group), and GJ group (240 ml quercetin group) followed by analysis of cell apoptosis, brain tissue water content, neurons, HMGB-1, TLR-4 and other inflammatory factors.The ZC group showed normal neuron volume and equitable staining; compared with ZC group, NY group showed neuron volume shrinkage and chromatin condensation; the neuron and color in DJ group were slightly better than NY group; the neuron volume in GJ group increased significantly and chromatin is distributed evenly. TLR-4, IL-4, IL-6, HMGB-1 in ZC and DJ group were significantly lower than those in NY group (p0.05); IL-4, IL-6, HMGB-1 in GJ group significantly decreased compared with DJ group (p0.05); MMP-9 enzyme activity in ZC and DJ group was significantly lower than NY group (p0.05) with lower level in GJ group than DJ group (p0.05). The water content was higher in brain tissue of NY group than ZC group (p0.05) and lower in DJ group than NY group (p0.05) with lower level in GJ group than DJ and NY group (all p0.05). The hippocampal neurons and cortical neurons in ZC and DJ group were higher than those in NY group (p0.05) and elevated in GJ group compared with DJ group and NY group (p0.05).Quercetin is effective in treating encephalitis rats possibly through inhibition of neuronal cell apoptosis and level of HMGB-1 and TLR-4.
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- 2021
11. Dual-heater reactor design for hybrid physical-chemical vapor decomposition of [MgB.sub.2] thin films
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Lamborn, D. R., Wilke, R. H. T., Q. Li, X. X. Xi, Snyder, D. W., and Redwing, J. M.
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Dielectric films -- Electric properties ,Thin films -- Electric properties ,Chemical vapor deposition -- Usage ,Magnesium compounds -- Thermal properties ,Magnesium compounds -- Electric properties ,Business ,Electronics ,Electronics and electrical industries - Abstract
The development and synthesis of a new configuration of the dual-heater reactor for hybrid physical-chemical vapor decomposition of [MgB.sub.2] thin films are being discussed. The new reactor allows the growth of thick films, as well as thin films at lower substrate temperatures.
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- 2007
12. Polycrystalline [MgB.sub.2] films on flexible YSZ substrates grown by hybrid physical-chemical vapor deposition
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Pogrebnyakov, A. V., Maertz, E., Redwing, J. M., Wilke, R. H. T., Schlom, D. G., Qi Li, Soukiassian, A., Findikoglu, A., and X. X. Xi
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Chemical vapor deposition -- Usage ,Dielectric films -- Electric properties ,Thin films -- Electric properties ,Superconductive devices -- Design and construction ,Business ,Electronics ,Electronics and electrical industries - Abstract
The study explains the various properties of the polycrystalline [MgB.sub.2] films that are deposited on flexible yttium-stabilized zirconia (YSZ) substrates grown by hybrid physical-chemical vapor deposition. These films can be widely used in superconducting digital circuits.
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- 2007
13. Mechanism of light detection in current-biased superconducting [MgB.sub.2] microbridges
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Khafizov, Marat, X. Li, Y. Cui, X. X. Xi, and Sobolewski, Roman
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Dielectric films -- Electric properties ,Dielectric films -- Magnetic properties ,Thin films -- Electric properties ,Thin films -- Magnetic properties ,Superconductors -- Electric properties ,Superconductors -- Magnetic properties ,Induction, Electromagnetic -- Analysis ,Business ,Electronics ,Electronics and electrical industries - Abstract
Several measurements are conducted to study the mechanism of light detection in various current-biased superconducting [MgB.sub.2] microbridges.
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- 2007
14. Effects of neutron irradiation on magnesium diboride thin films
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Ferrando, V., Pallecchi, I., Putti, M., Aebersold, H. U., Lehmann, E., Orgiani, P., Tumino, A., X. X. Xi, and Ferdeghini, C.
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Dielectric films -- Electric properties ,Dielectric films -- Chemical properties ,Thin films -- Electric properties ,Thin films -- Chemical properties ,Magnetic fields -- Measurement ,Magnesium compounds -- Electric properties ,Magnesium compounds -- Chemical properties ,Business ,Electronics ,Electronics and electrical industries - Abstract
The analysis presents and explains the effects of neutron irradiation on the normal state and superconducting properties of the magnesium diboride ([MgB.sub.2]) thin films. The results show that the irradiation causes a high increase in the residual resistivity of the films.
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- 2007
15. Systematic study of disorder induced by neutron irradiation in Mg[B.sub.2] thin films
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Ferrando, V., Pallecchi, I., Tarantini, C., Marre, D., Putti, M., Gatti, F., Aebersold, H.U., Lehmann, E., Haanappel, E., Sheikin, I., Orgiani, P., and X. X. Xi
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Dielectric films -- Chemical properties ,Thin films -- Chemical properties ,Chemical vapor deposition -- Analysis ,Radiation chemistry -- Research ,Physics - Abstract
A series of films grown by hybrid physical chemical vapor deposition (HPCVD) that are neutron irradiated at different fluences up to [10.sup.20] [cm.sup.-2] is reported. The measured critical field values are extremely high and turn out to be rather independent of the experimental resistivity at least at low fluences.
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- 2007
16. [Study on prevalence and vertical transmission rate of
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X X, Xi and F, Jiang
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Adult ,Young Adult ,Pregnancy ,Seroepidemiologic Studies ,Pregnancy Complications, Parasitic ,Infant, Newborn ,Prevalence ,Antibodies, Protozoan ,Humans ,Female ,Cities ,Toxoplasma ,Toxoplasmosis - Abstract
To investigate the prevalence and vertical transmission rate ofParturient women's venous blood samples and neonatal heel blood samples were collected in Wuhu City and prepared into filter-paper blood samples. The prevalence and vertical transmission rate ofThere were three positive samples detected in the 475 filter-paper blood samples from the parturient women, with a mean positive rate of 0.63%. The prevalence ofThere is
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- 2020
17. Hyperspectral Analysis of Soil Total Nitrogen in Subsided Land Using the Local Correlation Mazimization-Complementary Superiority Method
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Lixin Lin, X. X. Xi, Yunjia Wang, and Jiyao Teng
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lcsh:Applied optics. Photonics ,Logarithm ,Soil test ,lcsh:T ,lcsh:TA1501-1820 ,Hyperspectral imaging ,lcsh:Technology ,Correlation ,Geography ,lcsh:TA1-2040 ,Interferometric synthetic aperture radar ,Total nitrogen ,Soil restoration ,lcsh:Engineering (General). Civil engineering (General) ,Synthetic aperture radar interferometry ,Remote sensing - Abstract
The measurement of soil total nitrogen (TN) by hyperspectral remote sensing provides an important tool for soil restoration programs in areas with subsided land caused by the extraction of natural resources. This study used the local correlation maximization-complementary superiority method (LCMCS) to establish TN prediction models by considering the relationship between spectral reflectance and TN based on spectral reflectance curves of soil samples collected from subsided land determined by synthetic aperture radar interferometry (InSAR) technology. Based on the 1655 selected effective bands of the optimal spectrum (OSP) of the first derivate differential of reciprocal logarithm ([log{1/R}]'), (correlation coefficients, P < 0.01), the optimal model of LCMCS method was obtained to determine the final model, which produced lower prediction errors (root mean square error of validation [RMSEV] = 0.89, mean relative error of validation [MREV] = 5.93%) when compared with models built by the local correlation maximization (LCM), complementary superiority (CS) and partial least squares regression (PLS) methods. The predictive effect of LCMCS model was optional in Cangzhou, Renqiu and Fengfeng District. Results indicate that the LCMCS method has great potential to monitor TN in subsided land caused by the extraction of natural resources including groundwater, oil and coal.
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- 2015
- Full Text
- View/download PDF
18. Real-Time Observation of Phonon-Mediated σ−π Interband Scattering in MgB2
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Alexey B. Kuzmenko, T. Tan, Andreas Mann, Sergey V. Eremeev, Edoardo Baldini, Angela Acocella, S. Borroni, Fabrizio Carbone, Viatcheslav M. Silkin, X. X. Xi, Roberto Merlin, Francesco Zerbetto, Emmanuele Cappelluti, and Lara Benfatto
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Superconductivity ,Physics ,education.field_of_study ,Condensed matter physics ,Phonon ,Graphene ,Scattering ,Population ,General Physics and Astronomy ,02 engineering and technology ,Electronic structure ,021001 nanoscience & nanotechnology ,01 natural sciences ,law.invention ,law ,Condensed Matter::Superconductivity ,0103 physical sciences ,Femtosecond ,Cuprate ,010306 general physics ,0210 nano-technology ,education - Abstract
In systems having an anisotropic electronic structure, such as the layered materials graphite, graphene, and cuprates, impulsive light excitation can coherently stimulate specific bosonic modes, with exotic consequences for the emergent electronic properties. Here we show that the population of E_{2g} phonons in the multiband superconductor MgB_{2} can be selectively enhanced by femtosecond laser pulses, leading to a transient control of the number of carriers in the σ-electronic subsystem. The nonequilibrium evolution of the material optical constants is followed in the spectral region sensitive to both the a- and c-axis plasma frequencies and modeled theoretically, revealing the details of the σ-π interband scattering mechanism in MgB_{2}.
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- 2017
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19. Real-Time Observation of Phonon-Mediated σ − π Interband Scattering in MgB2
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E, Baldini, A, Mann, L, Benfatto, E, Cappelluti, A, Acocella, V M, Silkin, S V, Eremeev, A B, Kuzmenko, S, Borroni, T, Tan, X X, Xi, F, Zerbetto, R, Merlin, F, Carbone, Baldini, E., Mann, A., Benfatto, L., Cappelluti, E., Acocella, A., Silkin, V. M., Eremeev, S. V., Kuzmenko, A. B., Borroni, S., Tan, T., Xi, X. X., Zerbetto, F., Merlin, R., and Carbone, F.
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Physics and Astronomy (all) ,Condensed Matter::Superconductivity ,ddc:500.2 - Abstract
In systems having an anisotropic electronic structure, such as the layered materials graphite, graphene, and cuprates, impulsive light excitation can coherently stimulate specific bosonic modes, with exotic consequences for the emergent electronic properties. Here we show that the population of E_{2g} phonons in the multiband superconductor MgB_{2} can be selectively enhanced by femtosecond laser pulses, leading to a transient control of the number of carriers in the σ-electronic subsystem. The nonequilibrium evolution of the material optical constants is followed in the spectral region sensitive to both the a- and c-axis plasma frequencies and modeled theoretically, revealing the details of the σ-π interband scattering mechanism in MgB_{2}.
- Published
- 2017
20. Modeling studies of an impinging jet reactor design for hybrid physical–chemical vapor deposition of superconducting MgB2 films
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David W. Snyder, Joan M. Redwing, X. X. Xi, Daniel R. Lamborn, Qi Li, and Rudeger H. T. Wilke
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Hybrid physical-chemical vapor deposition ,Ion plating ,chemistry.chemical_element ,Chemical vapor deposition ,Condensed Matter Physics ,Evaporation (deposition) ,Inorganic Chemistry ,Chemical engineering ,chemistry ,Physical vapor deposition ,Materials Chemistry ,Deposition (phase transition) ,Thin film ,Boron - Abstract
An impinging jet reactor was developed for the deposition of superconducting MgB2 thin films by hybrid physical–chemical vapor deposition, a technique that combines Mg evaporation with the thermal decomposition of B2H6 gas. A transport and chemistry model for boron film deposition from B2H6 was initially used to investigate the effect of carrier gas, Mg crucible temperature and gas flow rates on boron film growth rate and uniformity. The modeling studies, which were validated experimentally, demonstrated a reduction in B2H6 gas-phase depletion and an increased boron film growth rate using an argon carrier gas compared to hydrogen. The results were used to identify a suitable set of process conditions for MgB2 deposition in the impinging jet reactor. The deposition of polycrystalline MgB2 thin films that exhibited a transition temperature of 39.5 K was demonstrated at growth rates up to ∼50 μm/h.
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- 2009
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21. Anisotropy in the optical response of superconducting MgB2 films
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Norbert Klein, Dagmar Chvostova, Alexander Tarasenko, V. Zelezny, and X. X. Xi
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Superconductivity ,Condensed matter physics ,business.industry ,Chemistry ,Metals and Alloys ,Physics::Optics ,Surfaces and Interfaces ,Dielectric ,Electronic structure ,Polarization (waves) ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Optics ,Ellipsometry ,Materials Chemistry ,Thin film ,Electronic band structure ,business ,Anisotropy - Abstract
The anisotropy of the dielectric function of c -axis oriented MgB 2 thin films has been revealed by a combined study of normal-incident reflectance and spectroscopic ellipsometry. The application of this procedure enabled us to determine the complete set of optical response functions and to show that the dominant effect responsible for the anisotropy is due to interband transitions, which distinctly screen the plasma edge depending on the polarization of incident radiation. The most important transition occurs at 23,800 cm − 1 and is polarized in the ab-plane. This is in good agreement with the results obtained previously for single crystals. Our results are also in a qualitative agreement with those obtained by band structure calculations.
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- 2008
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22. Growth of nanoscale BaTiO3/SrTiO3 superlattices by molecular-beam epitaxy
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Y. Li, J. H. Haeni, Xiaoqing Pan, Dmitri A. Tenne, P. Reiche, Costel Constantin, Haiping Sun, Wei Tian, Kj J. Choi, Long Qing Chen, D. G. Schlom, V. Vaithyanathan, Randall M. Feenstra, M. Bernhagen, Arsen Soukiassian, Q. X. Jia, X. X. Xi, Reinhard Uecker, and C. B. Eom
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Diffraction ,Reflection high-energy electron diffraction ,Materials science ,Condensed matter physics ,Mechanical Engineering ,Superlattice ,Condensed Matter Physics ,Epitaxy ,Crystallography ,symbols.namesake ,Electron diffraction ,Mechanics of Materials ,symbols ,General Materials Science ,Thin film ,Raman spectroscopy ,Molecular beam epitaxy - Abstract
Commensurate BaTiO3/SrTiO3 superlattices were grown by reactive molecular-beam epitaxy on four different substrates: TiO2-terminated (001) SrTiO3, (101) DyScO3, (101) GdScO3, and (101) SmScO3. With the aid of reflection high-energy electron diffraction (RHEED), precise single-monolayer doses of BaO, SrO, and TiO2 were deposited sequentially to create commensurate BaTiO3/SrTiO3 superlattices with a variety of periodicities. X-ray diffraction (XRD) measurements exhibit clear superlattice peaks at the expected positions. The rocking curve full width half-maximum of the superlattices was as narrow as 7 arc s (0.002°). High-resolution transmission electron microscopy reveals nearly atomically abrupt interfaces. Temperature-dependent ultraviolet Raman and XRD were used to reveal the paraelectric-to-ferroelectric transition temperature (TC). Our results demonstrate the importance of finite size and strain effects on the TC of BaTiO3/SrTiO3 superlattices. In addition to probing finite size and strain effects, these heterostructures may be relevant for novel phonon devices, including mirrors, filters, and cavities for coherent phonon generation and control.
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- 2008
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23. Mechanism of Light Detection in Current-Biased Superconducting ${\rm MgB}_{2}$ Microbridges
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Y. Cui, M. Khaflzov, X. Li, X. X. Xi, and Roman Sobolewski
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Cryostat ,Resistive touchscreen ,Materials science ,business.industry ,Nanosecond ,Condensed Matter Physics ,Kinetic inductance ,Photon counting ,Electronic, Optical and Magnetic Materials ,Optics ,Transmission line ,Picosecond ,Electrical and Electronic Engineering ,Ion milling machine ,business - Abstract
We report on time-resolved, transient photoimpedance measurements performed on current-biased microbridges excited by 100-fs wide, 800-nm wavelength, and 76-MHz repetition-rate optical pulses. Our bridges had dimensions of 20 mum by 40 mum and were patterned by conventional photolithography and ion milling from 150-nm-thick, epitaxial MgB2 films grown by a hybrid physical-chemical vapor-deposition technique. For high-speed detection experiments, the microbridges were embedded into coplanar-strip transmission lines and connected to a 20-GHz-bandwidth sampling oscilloscope via a semirigid coaxial cable. The test structures were placed inside an optical cryostat and studies were performed in the temperature range between 15 K and 40 K. At temperatures, e.g., 20 K, far below the bridge critical temperature and under low optical excitation, large and fast (130 ps in duration) photoresponse transients were observed, which we associate with the kinetic-inductive (Cooper-pair breaking) mechanism. At temperatures approaching the MgB2 critical temperature and/or under intense light illumination, an additional slow component of the photoresponse with a nanosecond decay time was measured. We interpret this second photoimpedance component as a resistive response, resulting from the hot-electron heating effect. The observed picosecond kinetic photoresponse makes our MgB2 bridges attractive candidates for fast and efficient optical detectors and photon counters.
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- 2007
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24. Dual-Heater Reactor Design for Hybrid Physical-Chemical Vapor Deposition of ${\rm MgB}_{2}$ Thin Films
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Rudeger H. T. Wilke, Joan M. Redwing, X. X. Xi, Qi Li, Daniel R. Lamborn, and D.W. Snyder
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Materials science ,Hybrid physical-chemical vapor deposition ,chemistry.chemical_element ,Substrate (electronics) ,Chemical vapor deposition ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Physical vapor deposition ,Magnesium diboride ,Deposition (phase transition) ,Electrical and Electronic Engineering ,Thin film ,Boron - Abstract
A new reactor configuration for the hybrid physical-chemical vapor deposition (HPCVD) of MgB2 thin films was developed. In this new design, the substrate is resistively heated and inversely mounted in the gas stream. The Mg supply is placed downstream of the substrate and is inductively heated. The dual-heater reactor is designed to enable the growth of MgB2 thin films at lower substrate temperatures, permit the growth of thick films and is amenable to scale-up for film deposition over larger substrate areas than the original HPCVD design. Computational fluid dynamics (CFD) based reactor modeling was used to simulate the gas flow, temperature and gas phase concentration profiles in the reactor in order to identify conditions suitable for film deposition. A study of boron thin film deposition from B2H6 in the dual-heater configuration was carried out and the experimental results were compared to CFD simulations which utilized a previously developed gas-phase and surface chemistry model to predict the growth rate. The boron film growth rate slightly decreased as the substrate temperature was increased from 650degC to 750deg C in both the experiments and model simulation. The modeling results indicate that boron deposition is limited by the mass transfer of BH3 to the substrate under these conditions and the temperature dependency arises due to the upstream depletion of the boron precursor. MgB2 films were grown at a substrate temperature of 710degC and Mg temperature of 720degC using the dual-heater configuration. The film properties were consistent with previously published results of MgB2 on sapphire in the original HPCVD configuration with a superconducting transition temperature, Tc, of 40.3 K and residual resistivity ratio (RRR) of 13.
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- 2007
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25. Polycrystalline ${\rm MgB}_{2}$ Films on Flexible YSZ Substrates Grown by Hybrid Physical-Chemical Vapor Deposition
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D. G. Schlom, Qi Li, E. Maertz, Rudeger H. T. Wilke, X. X. Xi, Alp T. Findikoglu, Alexej Pogrebnyakov, Joan M. Redwing, and Arsen Soukiassian
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Materials science ,Hybrid physical-chemical vapor deposition ,Chemical vapor deposition ,Condensed Matter Physics ,Epitaxy ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Physical vapor deposition ,Magnesium diboride ,Cubic zirconia ,Electrical and Electronic Engineering ,Composite material ,Sheet resistance ,Yttria-stabilized zirconia - Abstract
We report properties of polycrystalline MgB2 films deposited on thin flexible yttium-stabilized zirconia (YSZ) substrates by hybrid physical-chemical vapor deposition. The MgB2 films show a transition temperature of 38.9 K with a narrow superconducting transition (0.1 K). The self-field critical current density in the films reaches 107 A/cm2 at low temperatures. These properties do not change after repeated bending over a radius of 10 mm. Low microwave surface resistance comparable to those obtained in epitaxial MgB2 films on single-crystalline sapphire substrate was observed. The result shows promise of polycrystalline MgB2 films for applications in superconducting digital circuits as well as in coated conductor wires.
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- 2007
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26. ${\rm MgB}_{2}/{\rm insulator/Pb}$ Josephson Junctions With Different Tunnel Barriers
- Author
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J. M. Rowell, Y. Cui, Qi Li, Ke Chen, and X. X. Xi
- Subjects
Josephson effect ,High-temperature superconductivity ,Materials science ,Condensed matter physics ,Supercurrent ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,law.invention ,chemistry.chemical_compound ,Tunnel effect ,chemistry ,Tunnel junction ,law ,Physical vapor deposition ,Magnesium diboride ,Electrical and Electronic Engineering ,Quantum tunnelling - Abstract
High quality MgB2/insulator/Pb Josephson tunnel junctions with two different barriers were studied. The junctions were fabricated using MgB2 films grown by hybrid physical-chemical vapor deposition and the barriers were formed at different temperature regions. Both kinds of junctions show clear tunneling characteristics with clear Josephson supercurrent, high IcRN products, and the expected Ic(B) pattern. The junctions with barriers formed at 200 to 450degC have higher IcRN, larger MgB2 pi gap values, thinner barriers and higher barrier heights than the junctions with barriers formed over 700degC. In addition, some intermediate temperature barrier junctions show features due to the sigma gap of MgB2, which were not observed in the high temperature barrier junctions. High device yield indicates that the approaches to form tunnel barriers are promising for device fabrications.
- Published
- 2007
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27. Modeling studies of the chemical vapor deposition of boron films from B2H6
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David W. Snyder, Joan M. Redwing, Daniel R. Lamborn, and X. X. Xi
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inorganic chemicals ,Sticking coefficient ,Hybrid physical-chemical vapor deposition ,chemistry.chemical_element ,Boranes ,Chemical vapor deposition ,Condensed Matter Physics ,Inorganic Chemistry ,chemistry.chemical_compound ,Chemical engineering ,chemistry ,Materials Chemistry ,Deposition (phase transition) ,Physical chemistry ,Thin film ,Boron ,Diborane - Abstract
The effect of growth conditions on the chemical vapor deposition of boron thin films from diborane (B2H6) was investigated using a combination of experimental studies and computational fluid dynamics-based reactor modeling. A multi-physics computational model was developed to simulate the thermal-fluid environment in the reactor. The proposed chemistry model incorporated into the simulations includes gas-phase decomposition and formation of B2H6 and surface adsorption and reaction of borane (BH3). The model accurately predicts the experimentally measured temperature and partial pressure dependence of the boron growth rate using the sticking coefficient of BH3 on the growth surface as the only adjustable parameter in the calculations. The results indicate that at lower growth temperatures ( 500 °C) the growth rate is limited by mass transfer of BH3 to the substrate surface. The studies of boron thin film growth are relevant to the deposition of superconducting MgB2 thin films, in which B2H6 is used as the boron precursor.
- Published
- 2007
- Full Text
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28. Microwave and Terahertz Surface Resistance of MgB2 Thin Films
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Petr Kuzel, Yueliang Zhou, Filip Kadlec, Sung-Ik Lee, Eun-Mi Choi, Bonghwan Jin, Alexej Pogrebnyakov, Shuai-Hua Wang, X. X. Xi, Thomas Dahm, Joan M. Redwing, A. I. Gubin, Hyun-Jung Kim, Woun Kang, and Nigel Klein
- Subjects
Superconductivity ,Materials science ,business.industry ,Terahertz radiation ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Resonator ,Surface conductivity ,Electrical resistivity and conductivity ,Optoelectronics ,Thin film ,business ,Sheet resistance ,Microwave - Abstract
The knowledge of the surface resistance R s of superconducting thin film at microwave and terahertz (THz) regions is significant to design, make and assess superconducting microwave and THz electronic devices. In this paper we reported the R s of MgB2 films at microwave and THz measured with sapphire resonator technique and the time-domain THz spectroscopy, respectively. Some interesting results are revealed in the following: (1) A clear correlation is found between R s and normal-state resistivity right above T c, ρ0, i.e., R s decreases almost linearly with the decrease of ρ0. (2) A low residual R s, less than 50 μΩ at 18 GHz is achieved by different deposition techniques. In addition, between 10 and 14 K, MgB2 has the lowest R s compared with two other superconductors Nb3Sn and the high-temperature superconductor YBa2Cu3O7−δ(YBCO). (3) From THz measurement it is found that the R s of MgB2 up to around 1 THz is lower than that of copper and YBCO at the temperature below 25 K. (4) The frequency dependence of R s follows ω n , where ω is angular frequency, and n is power index. However, n changes from 1.9 at microwave to 1.5 at THz. The above results clearly give the evidences that MgB2 thin film, compared with other superconductors, is of advantage to make superconducting circuits working in the microwave and THz regions.
- Published
- 2006
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29. Carbon-Doped<tex>$rm MgB_2$</tex>Thin Films Grown by Hybrid Physical-Chemical Vapor Deposition
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C. B. Eom, D. G. Schlom, V. Vaithyanathan, Chun-Lin Jia, J. E. Giencke, Qi Li, Y. F. Hu, Alexej Pogrebnyakov, J. Chen, Arsen Soukiassian, Joan M. Redwing, S. B. Mi, Y. Cui, and X. X. Xi
- Subjects
Materials science ,Hybrid physical-chemical vapor deposition ,Analytical chemistry ,chemistry.chemical_element ,Chemical vapor deposition ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Amorphous solid ,chemistry.chemical_compound ,chemistry ,Physical vapor deposition ,Magnesium diboride ,Grain boundary ,Electrical and Electronic Engineering ,Thin film ,Carbon - Abstract
Carbon-doped MgB/sub 2/ thin films have been produced with hybrid physical-chemical vapor deposition (HPCVD) by adding a carbon-containing metalorganic magnesium precursor, bis(methylcyclopentadienyl)magnesium, to the carrier gas. The amount of the carbon added, thus the carbon content in the films, was controlled by the flow rate of a secondary hydrogen gas flow through the precursor bubbler. X-ray diffraction and electron microscopy showed that the carbon-doped MgB/sub 2/ films are textured with c-axis oriented columnar nano-grains and highly resistive amorphous areas at the grain boundaries. When the amount of carbon in the films increases, the resistivity increases dramatically while T/sub c/ decreases much more slowly as the current-carrying cross section is reduced by the grain boundaries. The temperature-dependent part of the resistivity, /spl Delta//spl rho//spl equiv//spl rho/(300 K)-/spl rho/(50 K), increases only modestly until the highly resistive grain boundaries completely cut off the conducting path. The impact of the reduced cross section on critical current density J/sub c/ is discussed.
- Published
- 2005
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30. Nonlinearity in the Microwave Properties of<tex>$rm MgB_2$</tex>Thin Films: Power Dependence and Intermodulation Distortion
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G. Lamura, M. Aurino, G. Cifariello, X. X. Xi, R. Vaglio, E. Di Gennaro, Antonello Andreone, and Pasquale Orgiani
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Materials science ,business.industry ,Chemical vapor deposition ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Residual resistivity ,Electrical resistivity and conductivity ,Low-power electronics ,Physical vapor deposition ,Optoelectronics ,Electrical and Electronic Engineering ,Thin film ,business ,Microwave ,Intermodulation - Abstract
We present here measurements carried out by using a dielectrically loaded copper cavity operating at 7 GHz on MgB/sub 2/ thin films synthesized by hybrid physical-chemical vapor deposition. Microwave data on samples having critical temperatures above 41 K, very low resistivity values, and residual resistivity ratio between 15 and 17, are presented. The dependence of the nonlinear surface losses and of the third order intermodulation products on the power feeding the cavity is analyzed, with the aim of shedding a light on the primary dissipation mechanisms. At low power, data from both power dependence and third order products seem to indicate that we are observing a nonlinear response which is inherent to the conventional s-wave nature of this novel compound. At intermediate-to-high circulating power values, vortex penetration appears to be the limiting mechanism for the power handling capability of MgB/sub 2/ films.
- Published
- 2005
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31. Investigations of<tex>$rm MgB_2/rm MgO$</tex>and<tex>$rm MgB_2/rm AlN$</tex>Heterostructures for Josephson Devices
- Author
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Joan M. Redwing, D. G. Schlom, V. Vaithyanathan, Pasquale Orgiani, X. X. Xi, Y. Cui, and Alexej Pogrebnyakov
- Subjects
Josephson effect ,Materials science ,Condensed matter physics ,Hybrid physical-chemical vapor deposition ,Heterojunction ,Chemical vapor deposition ,Condensed Matter Physics ,Epitaxy ,Electronic, Optical and Magnetic Materials ,Pulsed laser deposition ,chemistry.chemical_compound ,chemistry ,Physical vapor deposition ,Magnesium diboride ,Electrical and Electronic Engineering - Abstract
We report structural and transport proprieties of MgB/sub 2//MgO and MgB/sub 2//AlN multilayers for MgB/sub 2/ Josephson junctions. The MgB/sub 2/ layers were grown by hybrid physical chemical vapor deposition (HPCVD). The epitaxial MgB/sub 2//MgO/MgB/sub 2/ trilayers were grown in situ in the HPCVD system. The AlN layers were grown at room temperature by pulsed laser deposition, and the MgB/sub 2//AlN/MgB/sub 2/ trilayers were deposited ex situ with the deposition of the AlN layer between the depositions of the top and bottom MgB/sub 2/ layers. Although slightly less perfect than in films grown directly on sapphire and SiC substrates, excellent superconducting and transport properties were obtained in the MgB/sub 2/ layers in both heterostructures. The result addressed only the first of many issues about the adequacy of using MgO and AlN as the barrier materials for all-MgB/sub 2/ planar Josephson junctions, i.e. the ability to obtain good structural and superconducting properties in both electrode layers using the trilayer deposition process. It allows us to further investigate the conditions for better wetting and coverage of the insulator layers, as well as other critical issues in the fabrication of all-MgB/sub 2/ planar Josephson junctions.
- Published
- 2005
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32. Magneto-Optical Imaging Studies of Flux Propagation in Ultra-Pure and Carbon-Doped<tex>$rm MgB_2$</tex>Thin Films
- Author
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Alexej Pogrebnyakov, Qiang Li, Joan M. Redwing, Qi Li, Yufeng Hu, Zuxin Ye, Y. Cui, and X. X. Xi
- Subjects
Superconductivity ,Materials science ,Condensed matter physics ,Hybrid physical-chemical vapor deposition ,Chemical vapor deposition ,Condensed Matter Physics ,Magnetic flux ,Electronic, Optical and Magnetic Materials ,Pulsed laser deposition ,Condensed Matter::Materials Science ,Nuclear magnetic resonance ,Sputtering ,Condensed Matter::Superconductivity ,Physical vapor deposition ,Electrical and Electronic Engineering ,Thin film - Abstract
The mixed state in c-axis oriented ultra-pure MgB/sub 2/ thin films and carbon-doped MgB/sub 2/ thin films produced by hybrid physical-chemical vapor deposition was studied using magneto-optical imaging (MOI) technique. In the ultra-pure MgB/sub 2/ films, a regular magnetic flux penetration pattern was observed, as expected from the Bean critical state model. This is in striking contrast to earlier MOI observations of MgB/sub 2/ films made by pulse laser deposition, where dentritic flux jumps were usually abundant at temperature below 10 K. In our carbon-doped MgB/sub 2/ thin films, similar dentritic flux jumps were also observed at low temperature and low applied magnetic field. It is evident that the dendritic flux jumps or stability of the film is strongly influenced by the material parameters of the films, rather than inherent in all MgB/sub 2/ thin films.
- Published
- 2005
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33. <tex>$rm MgB_2$</tex>Thin Films Grown at Different Temperatures by Hybrid Physical-Chemical Vapor Deposition
- Author
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D. G. Schlom, V. Vaithyanathan, X. X. Xi, and B.T. Liu
- Subjects
Materials science ,Hybrid physical-chemical vapor deposition ,Analytical chemistry ,Chemical vapor deposition ,Condensed Matter Physics ,Epitaxy ,Electronic, Optical and Magnetic Materials ,Residual resistivity ,chemistry.chemical_compound ,chemistry ,Physical vapor deposition ,Magnesium diboride ,Deposition (phase transition) ,Electrical and Electronic Engineering ,Thin film - Abstract
We have grown MgB/sub 2/ films at different substrate temperatures by hybrid physical-chemical vapor deposition. X-ray diffraction analysis shows epitaxial growth at all temperatures, as measured at the substrate surface, between 550-700/spl deg/C. An optimal deposition temperature was found around 650/spl deg/C, at which the rocking curve is the narrowest, the residual resistivity is the lowest, and T/sub c/ is the highest. For the films deposited at lower temperatures, the rocking curve broadens, indicating a decreasing quality of crystallinity. The residual resistivity increases but the superconducting transition temperature remains nearly constant around 40 K when the deposition temperature is decreased to 550/spl deg/C. The deposition of epitaxial films with excellent superconducting properties at low substrate temperatures is important for device and circuit processing utilizing MgB/sub 2/.
- Published
- 2005
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34. Degradation of<tex>$rm MgB_2$</tex>Thin Films in Water
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J. E. Jones, Pasquale Orgiani, X. X. Xi, D. Lishego, Alexej Pogrebnyakov, Joan M. Redwing, Y. Cui, E. Maertz, Amber M. Beckley, and R. Donovan
- Subjects
Superconductivity ,High-temperature superconductivity ,Materials science ,Analytical chemistry ,Chemical vapor deposition ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,law.invention ,Amorphous solid ,chemistry.chemical_compound ,chemistry ,law ,Physical vapor deposition ,Magnesium diboride ,Thermal stability ,Electrical and Electronic Engineering ,Thin film - Abstract
We have studied the degradation of MgB/sub 2/ thin films, grown by hybrid physical-chemical vapor deposition (HPCVD), by submerging MgB/sub 2/ films into de-ionized water at different temperatures. The thickness, room temperature resistance, and superconducting transition were measured as a function of time in water and the temperature of the water. Results show that the films degrade faster at room temperature than at 0/spl deg/C. The room temperature resistance increases with time. The thickness of the MgB/sub 2/ films decreases rapidly initially, but then saturates. The resultant material is amorphous and insulating. Both T/sub c/(onset) and T/sub c/(0) of the MgB/sub 2/ films decrease with time in water, while the superconducting transition become broader. The effects of the exposure to other solvents and photoresist were also studied, and it was found that isopropanol does not cause MgB/sub 2/ films to degrade.
- Published
- 2005
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35. Lattice dynamics in BaxSr1−xTiO3 thin films studied by Raman spectroscopy
- Author
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H. Choosuwan, Arsen Soukiassian, X. X. Xi, Amar S. Bhalla, Ruyan Guo, and D. A. Tenne
- Subjects
Permittivity ,Materials science ,Condensed matter physics ,Phonon ,Analytical chemistry ,General Physics and Astronomy ,Soft modes ,Atmospheric temperature range ,Ferroelectricity ,Condensed Matter::Materials Science ,symbols.namesake ,Condensed Matter::Superconductivity ,symbols ,Thin film ,Raman spectroscopy ,Raman scattering - Abstract
We present a Raman spectroscopy study of the lattice-dynamical properties of the BaxSr1−xTiO3 thin films with x=0.05, 0.1, 0.2, 0.35, and 0.5 in the temperature range of 5–300K. Soft phonon modes were observed, and the temperature dependence of their frequencies and Raman intensities were investigated. The Raman spectra of the BaxSr1−xTiO3 films are compared with the single crystals of the same compositions. The essential differences in the lattice-dynamical properties of the thin films and single crystals are observed, such as the forbidden first-order Raman scattering in the films well above the phase-transition temperature in bulk, hardening of the soft phonon modes in films compared to crystals, and significantly larger range of the soft-mode overdamping in the films. On the other hand, the lattice-dynamics behavior in the BaxSr1−xTiO3 films is found similar to that of the relaxor ferroelectrics. Analogous to the relaxors, the presence of the polar nanoregions existing in the films at the temperatures...
- Published
- 2004
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36. Dependence of penetration depth, microwave surface resistance and energy gap of MgB2 thin films on their normal-state resistivity
- Author
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Joan M. Redwing, Won Nam Kang, Yueliang Zhou, Hyun-Jung Kim, Shoulin Wang, Thomas Dahm, A. I. Gubin, Biaobing Jin, C. Iniotakis, Eun-Mi Choi, Alexej Pogrebnyakov, Sung Ik Lee, Nigel Klein, and X. X. Xi
- Subjects
Superconductivity ,Materials science ,Condensed matter physics ,Mean free path ,Scattering ,Metals and Alloys ,London penetration depth ,Condensed Matter Physics ,Coherence length ,Electrical resistivity and conductivity ,Condensed Matter::Superconductivity ,Materials Chemistry ,Ceramics and Composites ,Electrical and Electronic Engineering ,Penetration depth ,Sheet resistance - Abstract
The dependences of magnetic field penetration depth at zero temperature lambda(0), microwave surface resistance R(s) and pi -band energy gap at zero temperature Delta(pi)(0) on the normal-state resistivity fight above the critical, rho(0), were studied for MgB(2) thin films prepared by different temperature. techniques by employing a sapphire resonator technique. We found that the zero-temperature penetration depth lambda(0) data could be well fitted by lambda(L)(1 + xi(0)/l)(1/2) yielding a London penetration depth lambda(L) of 34.5 nm, where xi(0) is the coherence length, and l is the mean free path determined from rho(0). The surface resistance R(s) at 15 and 20 K increases roughly linearly with rho(0). The observed increase of Delta(pi)(0) with rho(0) and the decrease of T(c) indicate the expected effects of interband impurity scattering within an extended BCS approach. The low values of R(s) and lambda(0) in conjunction with the large coherence length for epitaxial films are potentially attractive for applications in electronics and microwave technology.
- Published
- 2004
- Full Text
- View/download PDF
37. Hole doping dependence of the coherence length in La 2 − x Sr x CuO 4 thin films
- Author
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S. L. Li, W. D. Si, H. H. Wen, H. P. Yang, X. X. Xi, A. A. Soukiassian, and X. H. Zeng
- Subjects
Superfluidity ,Superconductivity ,Magnetization ,Materials science ,Condensed matter physics ,Condensed Matter::Superconductivity ,Pairing ,General Physics and Astronomy ,Condensed Matter::Strongly Correlated Electrons ,Pseudogap ,Anisotropy ,Coherence length ,Vortex - Abstract
By measuring the field and temperature dependence of magnetization on systematically doped $La_{2-x}Sr_xCuO_4$ thin films, the critical current density $j_c(0)$ and the collective pinning energy $U_p(0)$ are determined in single vortex creep regime. Together with the published data of superfluid density, condensation energy and anisotropy, for the first time we derive the doping dependence of the coherence length or vortex core size in wide doping regime directly from the low temperature data. It is found that the coherence length drops in the underdoped region and increases in the overdoped side with the increase of hole concentration. The result in underdoped region clearly deviates from what expected by the pre-formed pairing model if one simply associates the pseudogap with the upper-critical field.
- Published
- 2003
- Full Text
- View/download PDF
38. In situ growth of MgB/sub 2/ thin films by hybrid physical-chemical vapor deposition
- Author
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Yu Zhong, J. Lettieri, E. M. Lysczek, Wei Tian, Joan M. Redwing, Alexej Pogrebnyakov, X. H. Zeng, Zi Kui Liu, Xiaoqing Pan, D. G. Schlom, S. Y. Xu, Qi Li, X. X. Xi, and C. O. Brubaker
- Subjects
Materials science ,Hybrid physical-chemical vapor deposition ,Chemical vapor deposition ,Combustion chemical vapor deposition ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,Chemical engineering ,chemistry ,Physical vapor deposition ,Magnesium diboride ,Deposition (phase transition) ,Metalorganic vapour phase epitaxy ,Electrical and Electronic Engineering ,Thin film - Abstract
We have carried out thermodynamics studies of the Mg-B system with the calculation of phase diagrams (CALPHAD) modeling technique and found that the superconductor MgB/sub 2/ phase is thermodynamically stable only under fairly high Mg pressures at elevated temperatures. This has lead us to the investigation of chemical vapor deposition in which the pressure during the film deposition can be high. Although the initial effort on metal-organic chemical vapor deposition (MOCVD) was not successful due to carbon contamination, a unique hybrid physical-chemical vapor deposition (HPCVD) technique has successfully produced high quality in situ MgB/sub 2/ films. The epitaxially-grown MgB/sub 2/ films show high transition temperature and low resistivity comparable to the best bulk samples, and their surfaces are smooth. In this paper, the details of the technique and the results of the HPCVD films are presented.
- Published
- 2003
- Full Text
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39. Ordered array of nanoscale Ru crystals in the SrRuO3 buffer layer in an SrTiO3/SrRuO3 bilayer film on SrTiO3 substrate
- Author
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C. L. Jia, K. Urban, Jianhua Hao, X. X. Xi, Yueling Qin, and University of Groningen
- Subjects
Nanostructure ,Materials science ,business.industry ,Bilayer ,high resolution transmission electron microscopy ,perovskites ,Mineralogy ,Substrate (electronics) ,ELECTRICAL-PROPERTIES ,Condensed Matter Physics ,Ruddlesden-Popper planar defect ,Inorganic Chemistry ,THIN-FILMS ,Nanocrystal ,Transmission electron microscopy ,nanostructures ,Materials Chemistry ,Optoelectronics ,MAGNETORESISTANCE ,Thin film ,High-resolution transmission electron microscopy ,business ,Layer (electronics) - Abstract
A highly ordered grating pattern is observed in the SrRuO3 buffer layer in an SrTiO3/SrRuO3 bilayer system on (0 0 1) SrTiO3 substrate. By means of high-resolution transmission electron microscopy, the grating lines are found to consist of lattice defects and nanoscale precipitate particles. The particles are identified as pure ruthenium crystals. Correspondingly, Sr-rich Ruddlesden-Popper planar defects occur in the nearby area. This unusual film growth phenomenon may provide a novel way to fabricate ordered structures in oxide films for potential applications. (C) 2003 Elsevier Science B.V. All rights reserved.
- Published
- 2003
- Full Text
- View/download PDF
40. [Untitled]
- Author
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Xiaoqing Pan, Alexej Pogrebnyakov, Haiping Sun, X. H. Zeng, E. M. Lysczek, C. O. Brubaker, Arsen Soukiassian, Joan M. Redwing, Y. F. Hu, Wei Tian, X. X. Xi, E. Wertz, Qi Li, Yu Zhong, Zi Kui Liu, J. Lettieri, D. G. Schlom, and S. Y. Xu
- Subjects
Superconductivity ,Physics ,Physics and Astronomy (miscellaneous) ,Magnesium ,business.industry ,chemistry.chemical_element ,Chemical vapor deposition ,Condensed Matter Physics ,Epitaxy ,Electronic, Optical and Magnetic Materials ,chemistry ,Condensed Matter::Superconductivity ,Deposition (phase transition) ,Optoelectronics ,Thin film ,business ,CALPHAD ,Phase diagram - Abstract
The recently discovered superconductor MgB2 with Tc at 39 K has great potential in superconducting electronics. In this paper, we review the deposition techniques used for MgB2 thin films in the light of a thermodynamic study of the Mg-B system with the calculation of phase diagrams (CALPHAD) modeling technique. This thermodynamic study identifies a growth window in the pressure–temperature phase diagram, in which the magnesium pressure is very high for likely in situ growth temperatures. A Hybrid Physical–Chemical Vapor Deposition (HPCVD) technique that successfully achieves such a high Mg pressure is shown to produce in situ epitaxial MgB2 thin films with bulk superconducting properties.
- Published
- 2003
- Full Text
- View/download PDF
41. Effects of buffer layer thickness and strain on the dielectric properties of epitaxial SrTiO3 thin films
- Author
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X. X. Xi and A. R. James
- Subjects
Permittivity ,Materials science ,Electrode ,Analytical chemistry ,General Physics and Astronomy ,Dielectric loss ,Dielectric ,Thin film ,Composite material ,Epitaxy ,Layer (electronics) ,Pulsed laser deposition - Abstract
The dielectric behavior of SrTiO3 (STO) thin films grown epitaxially on different substrates using pulsed laser ablation is reported in this article. The thickness of the SrRuO3 buffer layer, serving as an electrode, was varied from 500 to 5000 A, to study the dependence of dielectric properties of the STO films on the buffer layer thickness. Strains introduced during the high-temperature deposition of these films, seem to greatly influence the dielectric behavior observed in them in the form of loss peaks. This article also reports the results of tunability and the results of dielectric measurements are correlated to the strain in the films.
- Published
- 2002
- Full Text
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42. Thermodynamics and thin film deposition of MgB2superconductors
- Author
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Arsen Soukiassian, Zi Kui Liu, Xiaoqing Pan, C. O. Brubaker, Wei Tian, Qi Li, X. H. Zeng, J. Lettieri, Y. F. Hu, X. X. Xi, J. E. Jones, Darrell G. Schlom, J. Hotchkiss, E. Wertz, Haiping Sun, and Yu Zhong
- Subjects
Superconductivity ,Materials science ,Annealing (metallurgy) ,Transition temperature ,Metals and Alloys ,Thermodynamics ,Condensed Matter Physics ,Nanocrystalline material ,Pulsed laser deposition ,Materials Chemistry ,Ceramics and Composites ,Electrical and Electronic Engineering ,Thin film ,Critical field ,CALPHAD - Abstract
The recently discovered superconductor MgB2 with Tc at 39 K has great potential in superconducting microelectronics. Thermodynamics studies with the calculation of phase diagrams (CALPHAD) modelling technique show that due to the high volatility of Mg, MgB2 is only thermodynamically stable under fairly high Mg overpressures for likely in situ growth temperatures. This provides a helpful insight into the appropriate processing conditions for MgB2 thin films, including the identification of the pressure–temperature region for adsorption-controlled growth. The initial MgB2 thin films were made by pulsed laser deposition followed by in situ annealing. The cross-sectional transmission electron microscopy reveals a nanocrystalline mixture of textured MgO and MgB2 with very small grain sizes. A zero-resistance transition temperature of 34 K and a zero-field critical current density of 1.3 × 106 A cm−2 were obtained. The qualities of these films are limited by the thermodynamic stability conditions, which favour deposition techniques that can maintain a high flux of Mg.
- Published
- 2002
- Full Text
- View/download PDF
43. Propagation and interaction of {111} planar defects in the SrRuO 3 buffer layer in SrTiO 3 /SrRuO 3 two-layer films on LaAlO 3 substrates
- Author
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J. S. Wu, C. L. Jia, K. Urban, J. H. Hao, and X. X. Xi
- Subjects
Physics and Astronomy (miscellaneous) ,Metals and Alloys ,General Materials Science ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials - Published
- 2002
- Full Text
- View/download PDF
44. Stair-rod dislocations in perovskite films on LaAlO3substrates
- Author
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K. Urban, X. X. Xi, C. L. Jia, Jinsong Wu, and Jianhua Hao
- Subjects
Materials science ,Condensed matter physics ,Inorganic chemistry ,Stacking ,Condensed Matter Physics ,chemistry.chemical_compound ,chemistry ,Transmission electron microscopy ,Strontium titanate ,Partial dislocations ,Thin film ,Dislocation ,Burgers vector ,Perovskite (structure) - Abstract
Two types of stair-rod dislocation formed at junctions of {111} stacking faults in SrTiO3-SrRuO3 two-layer films on LaAlO3 substrates have been studied by high-resolution transmission electron microscopy. The first type, formed by the interaction of two stacking faults situated at the flat SrRuO3-LaAlO3 interface without any step, has a Burgers vector (a/3) . The other type, formed by the interaction of two stacking faults, of which one starts from the SrRuO3-LaAlO3interface area involving an interface step, has a Burgers vector (a/3) . The formation mechanism of the stair-rod dislocations and the effect of the step are discussed.
- Published
- 2001
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45. Doping dependence of superconducting properties in pulsed-laser-deposited La/sub 2-x/Sr/sub x/CuO/sub 4+δ/ (0≤x≤0.30) thin films
- Author
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Weidong Si, X. X. Xi, X. H. Zeng, and Z.M. Stum
- Subjects
Superconductivity ,Materials science ,High-temperature superconductivity ,Condensed matter physics ,Transition temperature ,Doping ,Analytical chemistry ,Condensed Matter Physics ,Epitaxy ,Electronic, Optical and Magnetic Materials ,law.invention ,Pulsed laser deposition ,law ,Electrical and Electronic Engineering ,Thin film ,Stoichiometry - Abstract
We have studied the Sr doping dependence of the superconducting properties of La/sub 2-x/Sr/sub x/CuO/sub 4+/spl delta// thin films grown by pulsed laser deposition over the range of 0/spl les/x/spl les/0.30. We found that the strain in the films depends on the Sr doping level. In 1000 /spl Aring/ La/sub 2-x/Sr/sub x/CuO/sub 4+/spl delta// films grown on 1000 /spl Aring/ SrLaAlO/sub 4/ buffer layer, the strain changes from compressive to tensile when m increases. For both compressive and tensile strain, films prepared in strongly oxidizing ozone/molecular oxygen mixture are superconducting for all Sr content with x/spl les/0.25. When the films are cooled in pure molecular oxygen the x dependence is similar to that in the bulk, although the transition temperature depends on the strain. The results suggest that the Sr content, epitaxial strain, and oxygenation conditions are all important factors influencing the superconductivity in La/sub 2-x/Sr/sub x/CuO/sub 4+/spl delta// thin films.
- Published
- 2001
- Full Text
- View/download PDF
46. Probing the Nonlinearities Arising in the Microwave Response of Superconductors by Intermodulation Distortion
- Author
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G. Cifariello, Nicolas Emery, Antonello Andreone, P. Lagrange, J. C. Villegier, G. Lamura, X. X. Xi, E. Di Gennaro, Jean-François Marêché, Pasquale Orgiani, C. Herold, Andreone, Antonello, G., Cifariello, DI GENNARO, Emiliano, G., Lamura, N., Emery, C., Herold, J. F., Mareche, P., Lagrange, P., Orgiani, X. X., Xi, and J. C., Villegier
- Subjects
Superconductivity ,Materials science ,High-temperature superconductivity ,Condensed matter physics ,business.industry ,Niobium ,chemistry.chemical_element ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Power (physics) ,law.invention ,Third order ,chemistry ,law ,MGB2 THIN-FILMS ,Condensed Matter::Superconductivity ,WAVE ,Optoelectronics ,Electrical and Electronic Engineering ,Thin film ,business ,Microwave ,Intermodulation - Abstract
We present a systematic study of microwave nonlinearity, undertaken on different types of superconductors (Nb, NbN, MgB2 Y-1 beta a(2)Cu(3)O(7-delta)), in thin film form. Experiments are performed in a dielectrically loaded cavity operating at 7 GHz. The dependence of the surface impedance Z(s) and of the third order intermodulation (IMD) products on the power feeding the cavity is analysed, with the aim of shedding a light on the primary mechanisms of nonlinearity. Data from different superconductors are quantitatively compared.
- Published
- 2007
- Full Text
- View/download PDF
47. High-field superconductivity in alloyed MgB2 thin films
- Author
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V. BRACCINI, A. GUREVICH, M. C. JEWELL, C. B. EOM, D. C. LARBALESTIER, A. POGREBNYAKOV, Y. CUI, B. T. LIU, Y. F. HU, J. M. REDWING, QI LI, X. X. XI, R. K. SINGH, R. GANDIKOTA, J. KIM, B. WILKENS, N. NEWMAN, J. ROWELL, B. MOECKLY, V. FERRANDO, C. TARANTINI, D. MARR, M. PUTTI, C. FERDEGHINI, E. HAANAPPEL, VAGLIO, RUGGERO, V., Braccini, A., Gurevich, Vaglio, Ruggero, M. C., Jewell, C. B., Eom, D. C., Larbalestier, A., Pogrebnyakov, Y., Cui, B. T., Liu, Y. F., Hu, J. M., Redwing, Qi, Li, X. X., Xi, R. K., Singh, R., Gandikota, J., Kim, B., Wilken, N., Newman, J., Rowell, B., Moeckly, V., Ferrando, C., Tarantini, D., Marr, M., Putti, C., Ferdeghini, and E., Haanappel
- Abstract
We investigated the effect of alloying on the upper critical field Hc2 for 12 MgB2 films, in which disorder was introduced by growth, carbon doping or He-ion irradiation, finding a significant Hc2 enhancement in C-alloyed films, and an anomalous upward curvature of Hc2sTd. Record high values of Hc2 's4.2d
- Published
- 2005
48. nonlinearity in the microwave properties response of MgB2 thin films: power dependence and intermodulation distortion
- Author
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ANDREONE, ANTONELLO, DI GENNARO, EMILIANO, VAGLIO, RUGGERO, M. AURINO, G. CIFARIELLO, G. LAMURA, P. ORGIANI, X. X. XI, Andreone, Antonello, M., Aurino, G., Cifariello, DI GENNARO, Emiliano, G., Lamura, P., Orgiani, Vaglio, Ruggero, and X. X., Xi
- Subjects
superconducting films ,microwave measurements ,magnesium compounds ,intermodulation distortion - Abstract
We present here measurements carried out by using a dielectrically loaded copper cavity operating at 7 GHz on MgB2 thin films synthesized by hybrid physical-chemical vapor deposition. Microwave data on samples having critical temperatures above 41 K, very low resistivity values, and residual resistivity ratio between 15 and 17, are presented. The dependence of the nonlinear surface losses and of the third order intermodulation products on the power feeding the cavity is analyzed, with the aim of shedding a light on the primary dissipation mechanisms. At low power, data from both power dependence and third order products seem to indicate that we are observing a nonlinear response which is inherent to the conventional s-wave nature of this novel compound. At intermediate-to-high circulating power values, vortex penetration appears to be the limiting mechanism for the power handling capability of MgB2 films.
- Published
- 2005
- Full Text
- View/download PDF
49. Dielectric properties of SrTiO3 thin films grown on various perovskite electrodes by pulsed laser deposition
- Author
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Bao-Ting Liu, Yi Xuan, Hong-Cheng Li, Rui-Lan Wang, Weidong Si, and X. X. Xi
- Subjects
Materials science ,Misorientation ,Mechanical Engineering ,Analytical chemistry ,Condensed Matter Physics ,Epitaxy ,eye diseases ,Pulsed laser deposition ,Crystallinity ,Tetragonal crystal system ,chemistry.chemical_compound ,chemistry ,Mechanics of Materials ,Strontium titanate ,General Materials Science ,sense organs ,Thin film ,Perovskite (structure) - Abstract
We have investigated systematically the oxygen pressure dependences of the crystalline phases and the crystallographic orientations of BaTiO3 thin films by means of asymmetric rocking curves. Epitaxial BaTiO3 thin films were grown on SrTiO3 (001) substrates by pulsed laser deposition (PLD) under different oxygen pressures. The X-ray diffraction theta/2 theta scans showed no diffraction peaks from impurity phases or randomly oriented grains, indicating that the thin films were single phase BaTiO3. The XRD omega rocking curves indicated that the BaTiO3 thin films had a very high degree of crystallinity. The XRD phi scans showed that no in-plane misorientation existed in the BaTiO3 thin films. The results of asymmetric rocking curves showed that the BaTiO3 thin films grown under higher oxygen pressures(> 12 Pa) were tetragonal with a-axis orientation, those grown under lower oxygen pressures (
- Published
- 1998
- Full Text
- View/download PDF
50. Roles of intrinsic anisotropy and π-band pairbreaking effects on critical currents in tilted-c-axisMgB2films probed by magneto-optical and transport measurements
- Author
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Polyanskii, A. A., Kametani, F., Abraimov, D., Gurevich, A., Yamamoto, A., Pallecchi, I., Putti, Marina, Zhuang, C., Tan, T., and X. X., Xi
- Subjects
superconductivity, thin films ,thin films ,superconductivity - Published
- 2014
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