1. Experimental study on the competitive adsorption characteristics of N2, CO2 and O2 with various CO2/N2 blend ratios in coal.
- Author
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Wu, Chunlei, Li, Jia, Zhou, Fubao, and Shi, Bobo
- Subjects
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COAL combustion , *LANGMUIR isotherms , *GAS absorption & adsorption , *COAL , *CARBON dioxide , *ADSORPTION (Chemistry) - Abstract
This study investigated the competitive adsorption of CO 2 , N 2 , and O 2 with different CO 2 /N 2 ratios on residual coal. Isothermal adsorption experiments on DX coal with single and multi-component gases were conducted at 20–40 °C and 0.1–1.0 MPa using a self-developed device. The results showed that O 2 and N 2 adsorption followed the Langmuir model, while CO 2 adsorption fitted the D-R model; The adsorption capacity and isosteric adsorption heat of DX coal for single gases were: CO 2 >O 2 >N 2 ; The adsorption capacity of O 2 , N 2 , and CO 2 increased linearly with CO 2 proportion under the same pressure, with correlation coefficients above 0.9; Higher temperature reduced CO 2 adsorption more than O 2 , decreasing the competitive selectivity of CO 2 over O 2 ; At constant O 2 concentration, the average isosteric adsorption heat of coal adsorbing O 2 decreased with increasing CO 2 proportion; At constant CO 2 /N 2 ratio, the average isosteric adsorption heat of coal adsorbing O 2 decreased with decreasing O 2 concentration. • Adsorption of DX coal in different O 2 and CO 2 /N 2 atmospheres were studied. • Multi-component gas adsorption IAST model with Langmuir and D-R models was formed. • Temperature increase would weaken CO 2 inhibitory effect on coal oxygen adsorption. • The average q st of O 2 progressively diminished as the CO 2 proportion increased. • The average q st of O 2 decline with O 2 concentration at a constant CO 2 /N 2 ratio. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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