Search

Abstract: The rotation around the amide bond in N,N-diethyl-m-toluamide (m-DEET) has been studied extensively and often used in laboratory instructions to demonstrate the phenomenon of chemical exchange. Herein, we show that a simple modification to N,N-diethyl-o-toluamide (o-DEET) significantly alters the dynamics of the restricted rotation around the amide bond due to steric interactions between the ring methyl group and the two N-ethyl groups. This alters the classic two-site exchange due to restricted rotation around the amide bond, to a three-site exchange, with the third conformation trapped at a higher-energy state compared to the other two. This often overlooked phenomenon is elucidated using variable-temperature NMR, two-dimensional exchange spectroscopy and molecular modeling studies. [Copyright &y& Elsevier]

Using vision, humans can accurately judge distances to locations on the ground surface up to distances of at least 20 m. Most theories of depth perception assume that this ability is associated with the fact that we live in a terrestrial world in which locations of interest often appear on the ground and for which feedback about distance is often available from nonvisual sources such as walking. Much less is known about the ability of humans to judge absolute distances to locations other than on or supported by the ground plane beyond a few meters, at which point binocular stereo provides at best limited information about distance scaling. We show that one commonly used action measure for probing absolute distance perception exhibits accurate performance, even for targets located on the ceiling of a large room. We follow this with evidence that distance to ceiling locations is recovered with a mechanism that depends, at least in part, on the angle from the line of sight to the target location and a gravity-based frame of reference. [ABSTRACT FROM AUTHOR]

It is typically assumed that basic features of human gait are determined by purely biomechanical factors. In two experiments, we test whether gait transition speed and preferred walking speed are also influenced by visual information about the speed of self-motion. The visual flow during treadmill locomotion was manipulated to be slower than, matched to, or faster than the physical gait speed (visual gains of 0.5, 1.0, 2.0). Higher flow rates elicit significantly lower transition speeds for both the Walk–Run and Run–Walk transition, as expected. Similarly, higher flow rates elicit significantly lower preferred walking speeds. These results suggest that visual information becomes calibrated to mechanical or energetic aspects of gait and contributes to the control of locomotor behavior. [ABSTRACT FROM AUTHOR]

In the real world, people are quite accurate in judging distances to locations in the environment, at least for targets resting on the ground plane and distances out to about 20 m. Distance judgments in visually immersive environments are much less accurate. Several studies have now shown that in visually immersive environments, the world appears significantly smaller than intended. This study investigates whether or not the compression in apparent distances is the result of the low-quality computer graphics utilized in previous investigations. Visually directed triangulated walking was used to assess distance judgments in the real world and in three virtual environments with graphical renderings of varying quality. [ABSTRACT FROM AUTHOR]

Describes a prototype of a reverse engineering system which uses manufacturing features as geometric primitives. Representation of part geometry in terms of manufacturing features; Determination of feature type; Segmentation of relevant three dimensional points.

Stability of a one-dimensional slab of plasma is considered for the simplest case of a static equilibrium with negligible pressure. A special class of deformations is considered that satisfies a magnetohydrodynamic (MHD) constraint except in a particular surface. These deformations, which resemble those considered for tearing modes, form a continuous path away from the equilibrium. The deformed configurations are not equilibria and their magnetic energies are, therefore, always larger than those of associated equilibria. It is shown that except for a special class of equilibria [previously discussed by Taylor, Phys. Rev. Lett. 33, 1139 (1974)] there exist deformations for which the magnetic energy is continuously decreasing, a result that is interpreted as showing that only this class is stable. The arguments, though asymptotic, are simple, essentially geometric, and do not require linearization. The results differ from those of the traditional linear tearing mode calculation [Furth, Killeen, and Rosenbluth, Phys. Fluids 6, 459 (1963)], making the class of stable equilibria smaller. [ABSTRACT FROM AUTHOR]

The ability to navigate without getting lost is an important aspect of quality of life. In 5 studies, we evaluated how spatial learning is affected by the increased demands of keeping oneself safe while walking with degraded vision (mobility monitoring). We proposed that safe low vision mobility requires attentional resources, providing competition for those needed to learn a new environment. In Experiments 1 and 2, participants navigated along paths in a real-world indoor environment with simulated degraded vision or normal vision. Memory for object locations seen along the paths was better with normal compared with degraded vision. With degraded vision, memory was better when participants were guided by an experimenter (low monitoring demands) versus unguided (high monitoring demands). In Experiments 3 and 4, participants walked while performing an auditory task. Auditory task performance was superior with nonnal compared with degraded vision. With degraded vision, auditory task performance was better when guided compared with unguided. In Experiment 5, participants performed both the spatial learning and auditory tasks under degraded vision. Results showed that attention mediates the relationship between mobility-monitoring demands and spatial learning. These studies suggest that more attention is required and spatial learning is impaired when navigating with degraded viewing. [ABSTRACT FROM AUTHOR]

Virtual environments (VEs) presented via head-mounted displays are typically perceived as smaller in scale than intended. Visual–motor experience in VEs can reduce this underestimation of distance, though the mechanisms underlying this improved accuracy of distance estimates are unknown. To address this question, we created a mismatch between biomechanical and visual indicators of self-movement within the VE, and assessed the effect on distance and size judgments. Our results suggest that visual–motor feedback influences subsequent distance judgments by recalibrating perceptual–motor relationships, but we found no evidence that perceived size, which was substantially underestimated, changed as a function of this feedback. In contrast to recent studies that suggest that feedback in VEs causes a broad rescaling of virtual space, our results are consistent with a visual–motor recalibration account for much of the improvement in distance judgments following VE experience. [ABSTRACT FROM AUTHOR]

Pedestrians with low vision are at risk of injury when hazards, such as steps and posts, have low visibility. This study aims at validating the software implementation of a computational model that estimates hazard visibility. The model takes as input a photorealistic 3D rendering of an architectural space, and the acuity and contrast sensitivity of a low-vision observer, and outputs estimates of the visibility of hazards in the space. Our experiments explored whether the model could predict the likelihood of observers correctly identifying hazards. In Experiment 1, we tested fourteen normally sighted subjects with blur goggles that simulated moderate or severe acuity reduction. In Experiment 2, we tested ten low-vision subjects with moderate to severe acuity reduction. Subjects viewed computer-generated images of a walkway containing five possible targets ahead—big step-up, big step-down, small step-up, small step-down, or a flat continuation. Each subject saw these stimuli with variations of lighting and viewpoint in 250 trials and indicated which of the five targets was present. The model generated a score on each trial that estimated the visibility of the target. If the model is valid, the scores should be predictive of how accurately the subjects identified the targets. We used logistic regression to examine the correlation between the scores and the participants' responses. For twelve of the fourteen normally sighted subjects with artificial acuity reduction and all ten low-vision subjects, there was a significant relationship between the scores and the participant's probability of correct identification. These experiments provide evidence for the validity of a computational model that predicts the visibility of architectural hazards. It lays the foundation for future validation of this hazard evaluation tool, which may be useful for architects to assess the visibility of hazards in their designs, thereby enhancing the accessibility of spaces for people with low vision. [ABSTRACT FROM AUTHOR]

The relationship between biomechanical action and perception of self-motion during walking is typically consistent and well-learned but also adaptable. This perceptual-motor coupling can be recalibrated by creating a mismatch between the visual information for self-motion and walking speed. Perceptual-motor recalibration of locomotion has been demonstrated through effects on subsequent walking without vision, showing that learned perceptual-motor coupling influences a dynamic representation of one's spatial position during walking. Our present studies test whether recalibration of wheelchair locomotion, a novel form of locomotion for typically walking individuals, similarly influences subsequent wheelchair locomotion. Furthermore, we test whether adaptation to the pairing of visual information for self-motion during one form of locomotion transfers to a different locomotion modality. We find strong effects of perceptual-motor recalibration for matched locomotion modalities – walking/walking and wheeling/wheeling. Transfer across incongruent locomotion modalities showed weak recalibration effects. The results have implications both for theories of perceptual-motor calibration mechanisms and their effects on spatial orientation, as well as for practical applications in training and rehabilitation. [ABSTRACT FROM AUTHOR]

Few HMD-based virtual environment systems display a rendering of the user's own body. Subjectively, this often leads to a sense of disembodiment in the virtual world. We explore the effect of being able to see one's own body in such systems on an objective measure of the accuracy of one form of space perception. Using an action-based response measure, we found that participants who explored near space while seeing a fully-articulated and tracked visual representation of themselves subsequently made more accurate judgments of absolute egocentric distance to locations ranging from 4 m to 6 m away from where they were standing than did participants who saw no avatar. A nonanimated avatar also improved distance judgments, but by a lesser amount. Participants who viewed either animated or static avatars positioned 3 m in front of their own position made subsequent distance judgments with similar accuracy to the participants who viewed the equivalent animated or static avatar positioned at their own location. We discuss the implications of these results on theories of embodied perception in virtual environments. [ABSTRACT FROM AUTHOR]

A series of experiments examined the role of the motor system in imagined movement, finding a strong relationship between imagined walking performance and the biomechanical information available during actual walking. Experiments 1 through 4 established the finding that real and imagined locomotion differ in absolute walking time. We then tested whether executed actions could provide a basis for imagined walking rate using 2 approaches. Experiments 5 and 6 used a perceptual-motor recalibration paradigm, finding that after physically walking in a treadmill virtual reality environment, actors recalibrated the time to imagine walking to a previously viewed target. This finding mirrors previous perceptual-motor recalibration work measuring actual walking to previously viewed targets. Experiments 7 and 8 used a dual-task paradigm in which actions performed concurrently with imagined walking increased the similarity between real and imagined walking time, but only when they were biomechanically consistent with the act of walking. The striking influence of biomechanical information on imagined locomotion provides evidence for shared motor systems in imagined and executed movements and is also directly relevant to the mechanisms involved in egocentric spatial updating of environmental layout. [ABSTRACT FROM AUTHOR]

Several studies from different research groups investigating perception of absolute, egocentric distances in virtual environments have reported a compression of the intended size of the virtual space. One potential explanation for the compression is that inaccuracies and cue conflicts involving stereo viewing conditions in head mounted displays result in an inaccurate absolute scaling of the virtual world. We manipulate stereo viewing conditions in a head mounted display and show the effects of using both measured and fixed inter-pupilary distances, as well as bi-ocular and monocular viewing of graphics, on absolute distance judgments. Our results indicate that the amount of compression of distance judgments is unaffected by these manipulations. The equivalent performance with stereo, bi-ocular, and monocular viewing suggests that the limitations on the presentation of stereo imagery that are inherent in head mounted displays are likely not the source of distance compression reported in previous virtual environment studies. [ABSTRACT FROM AUTHOR]

In a series of experiments, we tested the hypothesis that severely degraded viewing conditions during locomotion distort the perception of distance traveled. Some research suggests that there is little-to-no systematic error in perceiving closer distances from a static viewpoint with severely degraded acuity and contrast sensitivity (which we will refer to as blur). However, several related areas of research—extending across domains of perception, attention, and spatial learning—suggest that degraded acuity and contrast sensitivity would affect estimates of distance traveled during locomotion. In a first experiment, we measured estimations of distance traveled in a real-world locomotion task and found that distances were overestimated with blur compared to normal vision using two measures: verbal reports and visual matching (Experiments 1 a, b, and c). In Experiment 2, participants indicated their estimate of the length of a previously traveled path by actively walking an equivalent distance in a viewing condition that either matched their initial path (e.g., blur/blur) or did not match (e.g., blur/normal). Overestimation in blur was found only when participants learned the path in blur and made estimates in normal vision (not in matched blur learning/judgment trials), further suggesting a reliance on dynamic visual information in estimates of distance traveled. In Experiment 3, we found evidence that perception of speed is similarly affected by the blur vision condition, showing an overestimation in perception of speed experienced in wheelchair locomotion during blur compared to normal vision. Taken together, our results demonstrate that severely degraded acuity and contrast sensitivity may increase people's tendency to overestimate perception of distance traveled, perhaps because of an increased perception of speed of self-motion. [ABSTRACT FROM AUTHOR]

This work describes a two-dimensional polymerization at an air/water interface and provides, for the first time, direct spectroscopic evidence for the kind of crosslinks formed and for the conversion reached in a covalently bonded monolayer sheet. This evidence was obtained through a combination of a variety of monolayer characterization techniques before and after transfer onto solid substrates, in particular by tip-enhanced Raman spectroscopy (TERS) and TERS mapping after transfer of both the monomer and polymer monolayer onto Au(111). This work is a major advance for the field of 2D polymers synthesized at the air/water interface as it, in principle, allows estimation of the crystallinity by percolation theory and the location of regions with defects. [ABSTRACT FROM AUTHOR]

This work describes a two-dimensional polymerization at an air/water interface and provides, for the first time, direct spectroscopic evidence for the kind of crosslinks formed and for the conversion reached in a covalently bonded monolayer sheet. This evidence was obtained through a combination of a variety of monolayer characterization techniques before and after transfer onto solid substrates, in particular by tip-enhanced Raman spectroscopy (TERS) and TERS mapping after transfer of both the monomer and polymer monolayer onto Au(111). This work is a major advance for the field of 2D polymers synthesized at the air/water interface as it, in principle, allows estimation of the crystallinity by percolation theory and the location of regions with defects. [ABSTRACT FROM AUTHOR]

Uncertainty represented in visualizations is often ignored or misunderstood by the non-expert user. The National Hurricane Center displays hurricane forecasts using a track forecast cone, depicting the expected track of the storm and the uncertainty in the forecast. Our goal was to test whether different graphical displays of a hurricane forecast containing uncertainty would influence a decision about storm characteristics. Participants viewed one of five different visualization types. Three varied the currently used forecast cone, one presented a track with no uncertainty, and one presented an ensemble of multiple possible hurricane tracks. Results show that individuals make different decisions using uncertainty visualizations with different visual properties, demonstrating that basic visual properties must be considered in visualization design and communication. [ABSTRACT FROM AUTHOR]

Objective: Our goal was to evaluate the degree to which display technologies influence the perception of size in an image.Background: Research suggests that factors such as whether an image is displayed stereoscopically, whether a user's viewpoint is tracked, and the field of view of a given display can affect users' perception of scale in the displayed image.Method: Participants directly estimated the size of a gap by matching the distance between their hands to the gap width and judged their ability to pass unimpeded through the gap in one of five common implementations of three display technologies (two head-mounted displays [HMD] and a back-projection screen).Results: Both measures of gap width were similar for the two HMD conditions and the back projection with stereo and tracking. For the displays without tracking, stereo and monocular conditions differed from each other, with monocular viewing showing underestimation of size.Conclusions: Display technologies that are capable of stereoscopic display and tracking of the user's viewpoint are beneficial as perceived size does not differ from real-world estimates. Evaluations of different display technologies are necessary as display conditions vary and the availability of different display technologies continues to grow.Applications: The findings are important to those using display technologies for research, commercial, and training purposes when it is important for the displayed image to be perceived at an intended scale. [ABSTRACT FROM AUTHOR]

Three experiments examined perceived absolute distance in a head-mounted display virtual environment (HMD-VE) and a matched real-world environment, as a function of the type and orientation of the distance viewed. In Experiment 1, participants turned and walked, without vision, a distance to match the viewed interval for both egocentric (viewer-to-target) and exocentric (target-to-target) extents. Egocentric distances were underestimated in the HMD-VE while exocentric distances were estimated similarly across environments. Since egocentric distances were displayed in the depth plane and exocentric distances in the frontal plane, the pattern of results could have been related to the orientation of the distance or to the type of distance. Experiments 2 and 3 tested these alternatives. Participants estimated exocentric distances presented along the depth or frontal plane either by turning and walking (Experiment 2) or by turning and throwing a beanbag to indicate the perceived extent (Experiment 3). For both Experiments 2 and 3, depth intervals were underestimated in the HMD-VE compared to the real world. However, frontal intervals were estimated similarly across environments. The findings suggest anisotropy in HMD-VE distance perception such that distance underestimation in the HMD-VE generalizes to intervals in the depth plane, but not to intervals in the frontal plane. [ABSTRACT FROM AUTHOR]

For low vision navigation, misperceiving the locations of hazards can have serious consequences. Poten-tial sources of such misperceptions are hazards that are not visually associated with the ground plane, thus, depriving the viewer of important perspective cues for egocentric distance. In Experiment 1, we assessed ab-solute distance and size judgments to targets on stands under degraded vision conditions. Normally sighted observers wore blur goggles that severely reduced acuity and contrast, and viewed targets placed on either detectable or undetectable stands. Participants in the detectable stand condition demonstrated accurate dis-tance judgments, whereas participants in the undetectable stand condition overestimated target distances. Similarly, the perceived size of targets in the undetectable stand condition was judged to be significantly larger than in the detectable stand condition, suggesting a perceptual coupling of size and distance in conditions of degraded vision. In Experiment 2, we investigated size and implied distance perception of targets elevated above a visible horizon for individuals in an induced state of degraded vision. When par-ticipants' size judgments are inserted into the size-distance invariance hypothesis (SDIH) formula, distance to above-horizon objects increased compared to those below the horizon. Together, our results emphasize the importance of salient visible ground-contact information for accurate distance perception. The absence of this ground-contact information could be the source of perceptual errors leading to potential hazards for low vision individuals with severely degraded acuity and contrast sensitivity. [ABSTRACT FROM AUTHOR]

In two experiments we examined the role of visual horizon information on absolute egocentric distance judgments to on-ground targets. Sedgwick [1983, in Human and Machine Vision (New York: Academic Press) pp 425–458] suggested that the visual system may utilize the angle of declination from a horizontal line of sight to the target location (horizon–distance relation) to determine absolute distances on infinite ground surfaces. While studies have supported this hypothesis, less is known about the specific cues (vestibular, visual) used to determine horizontal line of sight. We investigated this question by requiring observers to judge distances under degraded vision given an unaltered or raised visual horizon. The results suggest that visual horizon information does influence perception of absolute distances as evident through two different action-based measures: walking or throwing without vision to previously viewed targets. Distances were judged as shorter in the presence of a raised visual horizon. The results are discussed with respect to how the visual system accurately determines absolute distance to objects on a finite ground plane and for their implications for understanding space perception in low-vision individuals. [ABSTRACT FROM AUTHOR]

We carried out three experiments to examine the influence of field of view and binocular viewing restrictions on absolute distance perception in real-world indoor environments. Few of the classical visual cues provide direct information for accurate absolute distance judgments to points in the environment beyond about 2 m from the viewer. Nevertheless, in previous work it has been found that visually directed walking tasks reveal accurate distance estimations in full-cue real-world environments to distances up to 20 m. In contrast, the same tasks in virtual environments produced with head-mounted displays (HMDs) show large compression of distance. Field of view and binocular viewing are common limitations in research with HMDs, and have been rarely studied under full pictorial-cue conditions in the context of distance perception in the real-world. Experiment 1 showed that the view of one's body and feet on the floor was not necessary for accurate distance perception. In experiment 2 we manipulated the horizontal and the vertical field of view along with head rotation and found that a restricted field of view did not affect the accuracy of distance estimations when head movement was allowed. Experiment 3 showed that performance with monocular viewing was equal to that with binocular viewing. These results have implications for the information needed to scale egocentric distance in the real-world and reduce the support for the hypothesis that a limited field of view or imperfections in binocular image presentation are the cause of the underestimation seen with HMDs. [ABSTRACT FROM AUTHOR]

In 4 experiments, the authors varied the extent and nature of participant movement in a virtual environment to examine the influence of action on estimates of geographical slant. Previous studies showed that people consciously overestimate hill slant but can still accurately guide an action toward the hill (D. R. Proffitt, M. Bhalla, R. Gossweiler, & J. Midgett, 1995). Related studies suggest that one's potential to act may influence perception of slant and that distinct representations may independently inform perceptual and motoric responses. The authors found that in all conditions, perceptual judgments were overestimated and motoric adjustments were more accurate. The virtual environment allowed manipulation of the effort required to walk up simulated hills. Walking with the effort appropriate to the visual slant led to increased perceptual overestimation of slant compared with active walking with the effort appropriate to level ground, while visually guided actions remained accurate. [ABSTRACT FROM AUTHOR]

An accurate perception of the distance between an object and a nearby surface can increase a viewer's sense of presence in an immersive environment, particularly when a user is performing actions that affect or are affected by this distance. Two experiments were conducted examining the effectiveness of stereoscopic viewing, shadows, and interreflections at conveying this distance information. Subjects performed simple tasks based on the perception of the distance between a fixed virtual table and an approaching block in a virtual environment. In the first experiment, subjects lowered a virtual block to a virtual table. For this task, both stereoscopic viewing and shadows had statistically significant effects on subject performance. In the second experiment, subjects mechanically reported the perceived distance between a virtual block and virtual table. For this task, viewing condition, shadows, and interreflections were shown to be statistically significant distance cues. [ABSTRACT FROM AUTHOR]

This paper investigates whether torso force feedback on treadmill-style locomotion interfaces can substitute for treadmill tilt to simulate walking on smooth inclines. The experimental platform is the Sarcos Treadport, whose active mechanical tether can apply horizontal forces to the user to simulate the gravity forces experienced in slope walking. The authors show that users are extremely sensitive to slope while walking, being able to discriminate a 0.5 degree slope change. Comparisons are then made between walking on a tilted treadmill platform versus walking on a level platform but with tether force application. Psychophysical experiments show that users select tether forces that are predicted by the gravity forces, although at a 65% fractional force level. These results demonstrate definitively that torso force feedback can realistically simulate gravity forces during smooth slope walking. [ABSTRACT FROM AUTHOR]