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2. Bis[2-(cycloheptyliminomethyl)pyridine-κ2 N, N′]silver(I) tetraphenylborate.

Author

Massa, Werner, Dehghanpour, Saeed, Tashakori, Gilda, and Aoki, Katsuyuki

Subjects
*ORGANOSILVER compounds, *ORGANOBORON compounds, *TRANSITION metal complexes, *LIGANDS (Chemistry), *IMINES
Abstract

In the title complex, [Ag(C26H36N4)2](C24H20B), the AgI atom has a distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the AgI atom via two imine N atoms. One of the cycloheptyl groups and the Ag atom are disordered over two sites, with occupancy factors of ca 0.87 and 0.13. In this arrangement, the closest methylene group is more remote and the Ag atom also moves out by 0.405 (5) Å toward an alternative position. [ABSTRACT FROM AUTHOR]

Published
2007
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