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Bis[2-(cycloheptyliminomethyl)pyridine-κ2 N, N′]silver(I) tetraphenylborate.

Authors :
Massa, Werner
Dehghanpour, Saeed
Tashakori, Gilda
Aoki, Katsuyuki
Source :
Acta Crystallographica: Section E. Jul2007, Vol. 63 Issue 7, pm1872-m1872. 1p. 2 Diagrams, 1 Chart.
Publication Year :
2007

Abstract

In the title complex, [Ag(C26H36N4)2](C24H20B), the AgI atom has a distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the AgI atom via two imine N atoms. One of the cycloheptyl groups and the Ag atom are disordered over two sites, with occupancy factors of ca 0.87 and 0.13. In this arrangement, the closest methylene group is more remote and the Ag atom also moves out by 0.405 (5) Å toward an alternative position. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
7
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
25700492
Full Text :
https://doi.org/10.1107/S1600536807027079