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20. Gallium and gallium dichloride, new solid-state reductants in preparative transition metal chemistry. New, lower temperature syntheses and convenient isolation of hexatantalum tetradecachloride octahydrate, Ta (sub)6 (mu-Cl) (sub)12 Cl (sub)2 (OH (sub)2) (sub)4 .4H (sub)2 O, and synthesis and solid-state structure of a tetraalkylammonium derivative, [N(CH (sub)2 Ph)Bu (sub)3] (sub)4 [Ta (sub)6 (mu-Cl) (sub)12 Cl (sub)6], of the reduced [Ta (sub)6 (mu-Cl) (sub)12] (super)2+ cluster core

21. Synthesis and characterization of an air-stable gallium hydride, [t-Bu(H)Ga(mu-NEt (sub)2)] (sub)2, and related chloride derivatives

27. Tungsten tetrachloride: several convenient solid-state syntheses, a solution synthesis of highly reactive (WCl4)x, and the molecular structure of polymeric tungsten tetrachloride

28. Anionic tantalum(V) bis(dicarbollide) complexes with bent-metallocene structures

29. Tetramethyl 1,1,4,4-cyclohexanetetracarboxylate: preparation and conversion to key precursors of fluorinated, stereochemically defined cyclohexanes

30. Synthesis of fluorinated 1,2,3-butatrienes from alpha-halovinyl organometallic reagents

31. Synthesis and characterization of Cp2Zr(CH(Me)(6-ethylpyrid-2-yl))(CO)+, and d0 metal alkyl carbonyl complex. Coordination chemistry of the four-membered azazirconacycle Cp2Zr(eta2-C,N-CH(Me)(6-ethylpyride-2-yl))+

37. Achieving dynamic behaviour and thermal expansion in the organic solid state via co-crystallization† †Electronic supplementary information (ESI) available: Experimental details, single-crystal X-ray data and structures, DSC thermograms, and PASCal thermal expansion results. CCDC 1026670–1026679 and 1400641. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00988j Click here for additional data file. Click here for additional data file

38. Photoreactive salt cocrystal: N+–H⋯N hydrogen bond and cation–π interactions support a cascade-like photodimerization of a 4-stilbazole.

43. Mild, zinc-induced defluorination of butatrienes: stereoselective formation of divinylacetylene derivatives

44. Cobalt(II) 'scorpionate' complexes as models for cobalt-substituted zinc enzymes: electronic structure investigation by high-frequency and -field electron paramagnetic resonance spectroscopy

48. Synthesis and structure of 2,5,8-triazido-s-heptazine: an energetic and luminescent precursor to nitrogen-rich carbon nitrides

49. Semiconducting Organic Assemblies Prepared from Tetraphenylethylene Tetracarboxylic Acid and Bis(pyridine)s via Charge-Assisted Hydrogen Bonding

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