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Synthesis of fluorinated 1,2,3-butatrienes from alpha-halovinyl organometallic reagents
- Source :
- Journal of the American Chemical Society. June 30, 1993, Vol. 115 Issue 13, p5430, 10 p.
- Publication Year :
- 1993
-
Abstract
- The dimerization reaction of fluorinated alpha-halovinyl zinc and copper reagents and their thermal stability was explored. The structures of each of the isomeric members of butatrienes were characterized by X-ray crystallography. Dimerization of these vinyl carbenoids to butatrienes occurs when R is an aromatic C6H5 or C6F5 and R' is a perfluoroalkyl group CF3, C2F5, C3F7.
- Subjects :
- Organometallic compounds -- Analysis
Chemistry
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 115
- Issue :
- 13
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.14184634