331 results on '"Single-walled carbon nanohorn"'
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2. Enhanced photocatalytic activity of amphiphilic single-walled carbon nanohorn–In0.2Cd0.8S composites for water splitting
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Yu-Ching Weng, Yi-Hui Li, Wei-Li Yuan, and Li-Wen Huang
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Single-walled carbon nanohorn ,Photocatalyst ,Indium cadmium sulfide ,Hydrogen ,Photoelectrochemistry ,Splitting ,Chemistry ,QD1-999 - Abstract
Amphiphilic SWCNH–In0.2Cd0.8S photocatalysts with various contents of amphiphilic SWCNHs have been prepared and characterized. The photocurrent density and H2 production rate of the 0.38 wt% amphiphilic SWCNH–In0.2Cd0.8S photoelectrode (0.38 mA cm−2 and 3.73 μmol h−1 cm−2, respectively) were 1.6 and 2.88 times higher, respectively, than those of the bare In0.2Cd0.8S photoelectrode. The improved photocatalytic hydrogen evolution efficiency of the 0.38 wt% amphiphilic SWCNH–In0.2Cd0.8S photoelectrode is attributed to a synergetic effect of the intrinsic properties of its components, including excellent charge transfer and separation at the interface between the amphiphilic SWCNHs and the In0.2Cd0.8S photocatalyst.
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- 2024
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3. Enhanced photocatalytic activity of amphiphilic single-walled carbon nanohorn–In0.2Cd0.8S composites for water splitting.
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Weng, Yu-Ching, Li, Yi-Hui, Yuan, Wei-Li, and Huang, Li-Wen
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PHOTOCATALYSTS , *CARBON composites , *HYDROGEN production , *SILVER , *CHARGE transfer , *HYDROGEN evolution reactions , *DYE-sensitized solar cells , *CADMIUM sulfide - Abstract
Amphiphilic SWCNH–In 0.2 Cd 0.8 S photocatalysts with various contents of amphiphilic SWCNHs have been prepared and characterized. The photocurrent density and H 2 production rate of the 0.38 wt% amphiphilic SWCNH–In 0.2 Cd 0.8 S photoelectrode (0.38 mA cm−2 and 3.73 μmol h−1 cm−2, respectively) were 1.6 and 2.88 times higher, respectively, than those of the bare In 0.2 Cd 0.8 S photoelectrode. The improved photocatalytic hydrogen evolution efficiency of the 0.38 wt% amphiphilic SWCNH–In 0.2 Cd 0.8 S photoelectrode is attributed to a synergetic effect of the intrinsic properties of its components, including excellent charge transfer and separation at the interface between the amphiphilic SWCNHs and the In 0.2 Cd 0.8 S photocatalyst. • Amphiphilic SWCNH–In 0.2 Cd 0.8 S composites were synthesized and characterized. • The optimized photoelectrode displays excellent photocatalytic activity. • The optimized photoelectrode possesses high hydrogen production efficiency. • The enhanced photocatalytic activity stems from synergistic intrinsic properties. [ABSTRACT FROM AUTHOR]
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- 2024
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4. Electrical bridging effects of dual-carbon microsphere frameworks in Si-based composite anodes for high-performance Li-ion batteries.
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Hoon Kim, Ji, Kim, Jongmin, Jang, Wooree, Lee, Junwon, and Yang, Cheol-Min
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LITHIUM-ion batteries , *CARBON nanohorns , *ELECTRIC conductivity , *HEAT treatment , *GRAPHENE oxide , *ELECTRIC batteries , *ANODES , *CARBON composites - Abstract
[Display omitted] • A Si-based composite Li-ion battery anode comprising a dual-carbon framework was prepared. • The dual-carbon framework comprised graphene oxide and oxidized single-walled carbon nanohorns. • The nanohorns formed electrical bridges between graphene oxide nanosheets. • The composite anode exhibited high electrochemical performance. Herein, the successful fabrication of a high-performance Si-based composite Li-ion battery (LIB) anode, comprising a dual-carbon framework of reduced graphene oxide (r -GO) and oxidized single-walled carbon nanohorns (o -NHs), was demonstrated using a simple and scalable spray-drying process followed by heat treatment (h - s -GO/Si/NH). The r -GO nanosheets in the h - s -GO/Si/NH anode acted as a robust spherical framework that facilitated the mechanical and electrical connection between the carbon-coated Si (c -Si) nanoparticles, homogeneous dispersion of c -Si and o -NH nanoparticles, and suppression of the volume expansion and pulverization that occur during lithiation/delithiation. Additionally, the o -NH nanoparticles incorporated in the h - s -GO/Si/NH composite served as electrical bridges between the r -GO nanosheets, resulting in enhanced electrical conductivity and effortless Li-ion shuttling. The h - s -GO/Si/NH composite anode exhibited high electrochemical performance with a very high initial gravimetric charge capacity (2961 mAh g−1 at 0.1 A g−1), stable initial Coulombic efficiency (80.6% at 0.2 A g−1), and high cycling stability (983 mAh g−1 at 0.2 A g−1 after 50 cycles). This study highlights the importance of the effective design of electrically conductive three-dimensional frameworks in Si-based composite anodes, which may contribute to the development of high-performance LIB anode materials. [ABSTRACT FROM AUTHOR]
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- 2023
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5. High-density graphene/single-walled carbon nanohorn composite supercapacitor electrode with high volumetric capacitance.
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Hwang, Hyuntae, Kim, Chang Hyo, Wee, Jae-Hyung, Han, Jong Hun, and Yang, Cheol-Min
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CARBON composites , *SUPERCAPACITOR electrodes , *MATERIALS testing , *CARBON electrodes , *COMPOSITE materials , *ELECTRIC capacity - Abstract
The low density of porous carbon nanomaterials for supercapacitor electrodes has limited their widespread application, despite their ultra-high gravimetric capacitance. In this work, we successfully prepared highly densified composite electrodes of graphene and single-walled carbon nanohorns (SWCNHs) using a simple spray-drying method that is suitable for mass production. To prepare the high-density composite electrodes, water-based mixtures of oxidized SWCNHs (NHOs) and graphene oxides (GOs) were spray-dried in heated air; after spray-drying, GOs dispersed in water were agglomerated in spherical clusters containing NHO nanoparticles. The reduced spray-dried GO/NHO (rS-GO/NHO) composite electrodes exhibited an extremely high bulk density of 1.23 g·cm−3, which is almost double that of commercial activated carbon (AC) and reduced NHO (r-NHO) electrodes, and three times higher than that of rS-GO electrodes. Of the materials tested, the rS-GO/NHO composite electrode had the highest volumetric capacitance (80 F·cm−3 at 1 mA·cm−2) and a low sheet resistance (0.005 Ω· sq.−1), which are far superior to those of commercial AC (57 F·cm−3 at 1 mA·cm−2 and 0.293 Ω·sq.−1, respectively), without the need for a conductive material, such as carbon black. We expect that these high-density graphene/SWCNH composite electrodes with high volumetric capacitances can be substituted for commercial AC materials in energy storage devices, such as supercapacitors. Unlabelled Image • High-density graphene/single-walled carbon nanohorn composite was produced by facile spray-drying method. • The proposed method is suitable for mass production of this composite material. • The best composite electrode had a bulk density double that of commercial activated carbon electrodes. • The composite supercapacitor electrode exhibited high volumetric capacitance. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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6. Electrochemical Behavior and Voltammetric Determination of Chloramphenicol and Doxycycline Using a Glassy Carbon Electrode Modified with Single‐walled Carbon Nanohorns
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Hongda Sun, Zhichao Zhang, Shuang Han, Jing Jin, Xuan Zhang, Jinping Wei, Hui Wang, and Shuangyu Wang
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Doxycycline ,Materials science ,Chloramphenicol ,Glassy carbon electrode ,Electrochemistry ,medicine ,Doxycycline hydrochloride ,Single-walled carbon nanohorn ,Analytical Chemistry ,medicine.drug ,Nuclear chemistry - Published
- 2021
7. Single-Walled Carbon Nanohorns for Energy Applications
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Zhichao Zhang, Shuang Han, Chao Wang, Jianping Li, and Guobao Xu
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single-walled carbon nanohorn ,fuel cell ,solar cell ,biofuel cell ,Li-ion batteries ,supercapacitor ,hydrogen storage ,Chemistry ,QD1-999 - Abstract
With the growth of the global economy and population, the demand for energy is increasing sharply. The development of environmentally a benign and reliable energy supply is very important and urgent. Single-walled carbon nanohorns (SWCNHs), which have a horn-shaped tip at the top of single-walled nanotube, have emerged as exceptionally promising nanomaterials due to their unique physical and chemical properties since 1999. The high purity and thermal stability, combined with microporosity and mesoporosity, high surface area, internal pore accessibility, and multiform functionalization make SWCNHs promising candidates in many applications, such as environment restoration, gas storage, catalyst support or catalyst, electrochemical biosensors, drug carrier systems, magnetic resonance analysis and so on. The aim of this review is to provide a comprehensive overview of SWCNHs in energy applications, including energy conversion and storage. The commonly adopted method to access SWCNHs, their structural modifications, and their basic properties are included, and the emphasis is on their application in different devices such as fuel cells, dye-sensitized solar cells, supercapacitors, Li-ion batteries, Li-S batteries, hydrogen storage, biofuel cells and so forth. Finally, a perspective on SWCNHs’ application in energy is presented.
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- 2015
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8. Defect engineering of single-walled carbon nanohorns for stable electrochemical synthesis of hydrogen peroxide with high selectivity in neutral electrolytes
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Jianshuo Zhang, Lunhui Guan, Yang Liu, Suqiong He, and Yaqi Cui
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Materials science ,High selectivity ,Energy Engineering and Power Technology ,Defect engineering ,Electrolyte ,Single-walled carbon nanohorn ,Electrochemistry ,chemistry.chemical_compound ,Fuel Technology ,Chemical engineering ,chemistry ,Hydrogen peroxide ,Energy (miscellaneous) - Published
- 2021
9. Enhanced Performance of Dye‐Sensitized Solar Cells (DSSCs) Based on MoS 2 /Single‐Walled Carbon Nanohorns Electrochemically Deposited on Bilayer Counter Electrodes
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Ambapuram Meenakshamma, Maddala Gurulakshmi, Kalvapalli Susmitha, Yerva Pedda Venkata Subbaiah, and Raghavender Mitty
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Tafel equation ,Materials science ,010405 organic chemistry ,Bilayer ,Energy conversion efficiency ,General Chemistry ,Single-walled carbon nanohorn ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,0104 chemical sciences ,law.invention ,Dye-sensitized solar cell ,Chemical engineering ,law ,Solar cell ,Electrode - Abstract
High-performance bilayer counter electrodes (BCEs) for dye-sensitized solar cell (DSSC) applications are gaining considerable attention. In this study, MoS2 /single-walled carbon nanohorn (SWCNHs) BCEs were fabricated by ultrasonic-spray-assisted electrochemical deposition. The BCEs exhibited superior electrocatalytic activity, confirmed through CV, Tafel plots, and electrochemical impedance spectroscopic studies. The fabricated MoS2 /SWCNH-based DSSCs exhibited an impressive photovoltaic power conversion efficiency of 9.48 %, which is higher than the performance of cells with Pt-containing CEs (8.64 %). The simple and reliable growth strategy for bilayer film CEs provides a new route for the preparation of cost-effective and high-performance catalytic BCEs for renewable energy applications involving Pt-free DSSCs.
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- 2020
10. Single walled carbon nanohorns composite for neural sensing and stimulation
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Mirko Prato, Luciano Fadiga, Alice Scarpellini, Elena Zucchini, Francesca Ciarpella, Davide Ricci, Elisa Castagnola, Linda Lambertini, and Stefano Carli
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Materials Chemistry2506 Metals and Alloys ,Materials science ,Therapeutic electrical stimulation ,Multielectrode arrays ,Composite number ,Socio-culturale ,Stimulation ,02 engineering and technology ,Carbon nanotube ,Single-walled carbon nanohorn ,010402 general chemistry ,Electrodeposition ,Neural implants ,Neural sensing and stimulation ,PEDOT ,Single walled carbon nanohorns ,Electronic, Optical and Magnetic Materials ,Instrumentation ,Condensed Matter Physics ,Surfaces, Coatings and Films ,2506 ,Electrical and Electronic Engineering ,01 natural sciences ,law.invention ,Coatings and Films ,PEDOT:PSS ,law ,Electronic ,Materials Chemistry ,Optical and Magnetic Materials ,Metals and Alloys ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Surfaces ,Microelectrode ,Brain implant ,Chemical engineering ,0210 nano-technology - Abstract
Oxidized single walled carbon nanohorns (ox-SWCNH) were electrodeposited onto gold microelectrode arrays in conjunction with poly(3,4-ethylenedioxythiophene) (PEDOT) and polystirenesulfonate (PSS), and the properties of the new composite material for neural recording and stimulation were assessed. PEDOT/ox-SWCNH composites were compared with films prepared with one of the most notorious carbonaceous material in this field, the oxidized multi-walled Carbon Nanotubes (ox-MWCNT). The PEDOT/ox-SWCNH exhibited superior charge transfer capability, reflecting greater electroactive surface, as confirmed by SEM and EIS characterizations. As a consequence, a charge injection limit of 11.6mC/cm2 was observed for the new composite, which is higher than the one of PEDOT/ox-MWCNT (8.7mC/cm2). Having confirmed comparable neural recording performance, the PEDOT/ ox-SWCNH composite results very promising for improving therapeutic electrical stimulation in the central and peripheral nervous systems.
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- 2022
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11. Novel phosphomolybdic acid/single-walled carbon nanohorn-based modified electrode for non-enzyme glucose sensing.
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Chen, Jingchao, He, Ping, Bai, Hongmei, Lei, Hong, Liu, Kaili, Dong, Faqin, and Zhang, Xingquan
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PHOSPHOMOLYBDIC acid , *CARBON nanohorns , *GLUCOSE , *COMPOSITE materials , *CYCLIC voltammetry , *CHRONOAMPEROMETRY - Abstract
A novel phosphomolybdic acid/single-walled carbon nanohorn based amperometric sensing platform was successfully constructed for determination of glucose. Single-walled carbon nanohorn acted as an active matrix and was used to immobilize phosphomolybdic acid. As-prepared phosphomolybdic acid/single-walled carbon nanohorn composite was characterized by SEM, EDX and XRD. Electrochemical behaviors of modified electrodes were characterized by cyclic voltammetry and chronoamperometry. Electrochemical investigations of phosphomolybdic acid/single-walled carbon nanohorn electrode showed three well-defined pairs of redox peaks and rapid electron transfer between electrode and electrolyte. Excellent electrocatalytic performance was obtained due to the synergistic effect of phosphomolybdic acid and single-walled carbon nanohorn. It was concluded that the linear amperometric response to glucose was achieved in the concentration range of 0.035 mM to 4.0 mM, and the detection limit was calculated as 2.4 μM. Moreover, as-prepared phosphomolybdic acid/single-walled carbon nanohorn electrode exhibited prominent selectivity, stability and reproducibility, making it a promising tool for sensitive non-enzymatic determination of glucose. [ABSTRACT FROM AUTHOR]
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- 2017
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12. Efficient Removal of Uranium(VI) from Aqueous Solutions by Triethylenetetramine-Functionalized Single-Walled Carbon Nanohorns
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Wang Chunyan, Tianxiang Jin, Bing Huang, Feiqiang He, Qian Yong, Dejuan Huang, and Xu Jianping
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Materials science ,Aqueous solution ,General Chemical Engineering ,Inorganic chemistry ,chemistry.chemical_element ,Langmuir adsorption model ,Sorption ,General Chemistry ,Uranium ,Single-walled carbon nanohorn ,Article ,symbols.namesake ,chemistry.chemical_compound ,Chemistry ,Adsorption ,chemistry ,Triethylenetetramine ,Selective adsorption ,symbols ,QD1-999 - Abstract
In the present study, SWCNH-COOH and SWCNH-TETA were fabricated using single-walled carbon nanohorns (SWCNHs) via carboxylation and grafting with triethylenetetramine (TETA) for uranium (VI) ion [U(VI)] removal. The morpho-structural characterization of as-prepared adsorbing materials was performed by transmission electron microscopy, X-ray diffractometry, Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Several parameters including the pH value of the aqueous solutions, contact time, temperature, and U(VI) concentration were used to evaluate the sorption efficiency of SWCNH-COOH and SWCNH-TETA. The Langmuir isotherm model could well represent the as-obtained adsorption isotherms, and the kinetics was successfully modeled by pseudo-second-order kinetics in the adsorption process. The maximum adsorption capacity of SWCNH-TETA was calculated as 333.13 mg/g considering the Langmuir isotherm model. Thermodynamic studies showed that adsorption proved to be a spontaneous endothermic process. Moreover, SWCNH-TETA exhibited excellent recycling performance and selective adsorption of uranium. Furthermore, the possible mechanism was investigated by XPS and density functional theory calculations, indicating that the excellent adsorption was attributed to the cooperation capability between uranium ions and nitrogen atoms in SWCNH-TETA. This efficient approach can provide a strategy for developing high-performance adsorbents for U(VI) removal from wastewater.
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- 2020
13. Functionalized Single‐Walled Carbon Nanohorns to Reinforce Sulfonated Poly(ether ether ketone) Electrolyte for Direct Methanol Fuel Cells
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Sudeshna Sarmah, Sreekuttan M. Unni, Arun Torris, Santoshkumar D. Bhat, and Parameswaran Turanelloormana
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Poly ether ether ketone ,Materials science ,Chemical engineering ,Electrochemistry ,Electrolyte ,Single-walled carbon nanohorn ,Methanol fuel ,Catalysis - Published
- 2020
14. Enhancement of the Thermoelectric Power Factor for Bismuth Antimony Telluride Based Composites Containing Single-Walled Carbon Nanohorns
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Ji Hoon Kim, Cheol-Min Yang, and Yoong Ahm Kim
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Antimony telluride ,chemistry.chemical_compound ,Materials science ,chemistry ,Electrical resistivity and conductivity ,General Physics and Astronomy ,chemistry.chemical_element ,Power factor ,Single-walled carbon nanohorn ,Composite material ,Thermoelectric materials ,Thermoelectric power factor ,Bismuth - Published
- 2020
15. Cardanol-Derived Azobenzene-Induced Phototunable Conductance Switching of Single-Walled Carbon Nanohorns
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Devi Renuka Kizhisseri, Sankarapillai Mahesh, and Kuruvilla Joseph
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Green chemistry ,Cardanol ,Materials science ,Renewable Energy, Sustainability and the Environment ,General Chemical Engineering ,Conductance ,02 engineering and technology ,General Chemistry ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Photochromism ,chemistry.chemical_compound ,Azobenzene ,chemistry ,Chemical engineering ,Environmental Chemistry ,Molecule ,0210 nano-technology ,Carbon nanomaterials - Abstract
Photochromic molecules derived from bioresources and their hybrids with various carbon nanomaterials always resulted in devices with outstanding performance. Among different carbon nanomaterials su...
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- 2020
16. A transparent and Pt-free all-carbon nanocomposite counter electrode catalyst for efficient dye sensitized solar cells
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K. Susmitha, A. Meenakshamma, Y.P. Venkata Subbaiah, S. Narendra Babu, Katta Venkateswarlu, M. Raghavender, M. Gurulakshmi, Vadali V. S. S. Srikanth, and N. Charanadhar
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Auxiliary electrode ,Materials science ,Nanocomposite ,Renewable Energy, Sustainability and the Environment ,Graphene ,020209 energy ,Oxide ,02 engineering and technology ,Single-walled carbon nanohorn ,021001 nanoscience & nanotechnology ,Tin oxide ,law.invention ,Dye-sensitized solar cell ,chemistry.chemical_compound ,Chemical engineering ,chemistry ,law ,Solar cell ,0202 electrical engineering, electronic engineering, information engineering ,General Materials Science ,0210 nano-technology - Abstract
Recently, substantial focus has made in the development of cost effective Pt-free dye sensitized solar cells (DSSCs). In this article we report a potential, Pt-free, carbon based nanocomposite as counter electrode catalyst for dye sensitized solar cells. Graphene oxide (GO) was made into reduced graphene oxide (SSrGO) by irradiating with light (Xe source). Suspension of SSrGO in DMF was spray coated onto fluorine doped tin oxide (FTO) coated glass substrate, followed by spray coat of single walled carbon nanohorns (SWCNH) suspension in DMF. SSrGO and SWCNH coated FTO glass substrate was investigated as an effective Pt-free composite counter electrode (CE) for DSSC and also showed the comparable catalytic activity with Pt. The test cell reveals power conversion efficiency (PCE) of 8.27%, whereas the DSSC module exhibited a PCE of 5.18%. By using the fabricated DSSC module, an electric motor (15 mW) was operated both in indoor and outdoor light conditions. The procedures followed in this work pave a way for the easy fabrication of composite CE towards transparent DSSC modules and further the integration of the DSSC module with the standard Si solar cell is of great potential for various real-time application.
- Published
- 2019
17. Aptamer-based single-walled carbon nanohorn sensors for ochratoxin A detection.
- Author
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Lv, Lei, Cui, Chengbi, Liang, Chengyun, Quan, Wurong, Wang, Sihong, and Guo, Zhijun
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SINGLE walled carbon nanotubes , *APTAMERS , *OCHRATOXINS , *FLUOROPHORES , *QUADRUPLEX nucleic acids - Abstract
Ochratoxin A (OTA), a mycotoxin produced by Aspergillus ochraceus and Penicillium verrucosum , is one of the most significant mycotoxins encountered in foods. In this research, a novel fluorescence biosensing strategy for simple and sensitive OTA detection using an aptamer specific for OTA as recognition element and single-walled carbon nanohorns (SWCNHs) as fluorescence quencher was reported. In the absence of target molecule (OTA), FAM (carboxyfluorescein)-modified aptamer was adsorbed onto the SWCNH surface. In this arrangement, the fluorophore and quencher were in close proximity; thus, FAM fluorescence was readily quenched by fluorescence resonance energy transfer from dye to carbon nanohorn. In the presence of target molecules (OTA), the OTA-specific aptamer form an antiparallel G-quadruplex, which is resistant to being wrapped onto SWCNHs. Therefore, the fluorescence of FAM cannot be quenched, and the fluorescent intensity as a function of OTA concentration was correspondingly measured. We obtained a detection limit of 17.2 nM for our sensing platform based on SWCNHs, with a linear detection range of 20–500 nM. The proposed assay system also exhibited high selectivity for OTA against other mycotoxins. The biosensor was verified for real sample application by testing 1% red wine containing buffer solution spiked with a series of OTA concentrations, and there is a good linear relationship (correlation coefficient = 0.990) between the fluorescence intensity and the logarithm of OTA concentration. Utilization of the proposed biosensor for quantitative determination of mycotoxins in food samples indicated the sensor being a useful tool for verifying the effectiveness of mycotoxin control strategies. [ABSTRACT FROM AUTHOR]
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- 2016
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18. Insight into the Mechanisms of Low Coverage Adsorption of N-Alcohols on Single Walled Carbon Nanohorn
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Piotr Kowalczyk, Artur P. Terzyk, Grzegorz S. Szymański, Anna Kaczmarek-Kedziera, and Monika Zięba
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Technology ,Materials science ,Heteroatom ,Enthalpy ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,01 natural sciences ,DFT ,Article ,Catalysis ,law.invention ,Nanomaterials ,Adsorption ,carbon nanohorn ,law ,General Materials Science ,Graphite ,nanomaterials ,Microscopy ,QC120-168.85 ,Graphene ,QH201-278.5 ,021001 nanoscience & nanotechnology ,Engineering (General). Civil engineering (General) ,0104 chemical sciences ,TK1-9971 ,Chemical engineering ,Descriptive and experimental mechanics ,adsorption ,chromatography ,Electrical engineering. Electronics. Nuclear engineering ,TA1-2040 ,0210 nano-technology - Abstract
We report for the first time the chromatographic study of n-alcohols (from methanol to butanol) adsorption on single walled carbon nanohorn (SWCNH). Using measured temperature dependence of adsorption isotherms (373–433 K) the isosteric adsorption enthalpy is calculated and compared with the data reported for a graphite surface. It is concluded that a graphite surface is more homogeneous, and the enthalpy of adsorption on SWCNHs at zero coverage correlates well with molecular diameter and polarizability, suggesting leading role of dispersive interactions, i.e., no heteroatoms presence in the walls of SWCNH structures. Next using modern DFT approach we calculate the energy of n-alcohols interactions with a graphene sheet and with a single nanocone finally proposing a more realistic—double nanocone model. Obtained results suggest alcohols entrapping between SWCNH with OH groups located toward nanocones ends, leading to the conclusions about very promising future applications of SWCNHs in catalytic reactions with participation of n-alcohols.
- Published
- 2021
19. High-density graphene/single-walled carbon nanohorn composite supercapacitor electrode with high volumetric capacitance
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Jae-Hyung Wee, Jong Hun Han, Chang Hyo Kim, Hyuntae Hwang, and Cheol-Min Yang
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Supercapacitor ,Materials science ,Graphene ,Composite number ,General Physics and Astronomy ,chemistry.chemical_element ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,Carbon black ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Nanomaterials ,law.invention ,Chemical engineering ,chemistry ,law ,Electrode ,0210 nano-technology ,Carbon - Abstract
The low density of porous carbon nanomaterials for supercapacitor electrodes has limited their widespread application, despite their ultra-high gravimetric capacitance. In this work, we successfully prepared highly densified composite electrodes of graphene and single-walled carbon nanohorns (SWCNHs) using a simple spray-drying method that is suitable for mass production. To prepare the high-density composite electrodes, water-based mixtures of oxidized SWCNHs (NHOs) and graphene oxides (GOs) were spray-dried in heated air; after spray-drying, GOs dispersed in water were agglomerated in spherical clusters containing NHO nanoparticles. The reduced spray-dried GO/NHO (rS-GO/NHO) composite electrodes exhibited an extremely high bulk density of 1.23 g·cm−3, which is almost double that of commercial activated carbon (AC) and reduced NHO (r-NHO) electrodes, and three times higher than that of rS-GO electrodes. Of the materials tested, the rS-GO/NHO composite electrode had the highest volumetric capacitance (80 F·cm−3 at 1 mA·cm−2) and a low sheet resistance (0.005 Ω· sq.−1), which are far superior to those of commercial AC (57 F·cm−3 at 1 mA·cm−2 and 0.293 Ω·sq.−1, respectively), without the need for a conductive material, such as carbon black. We expect that these high-density graphene/SWCNH composite electrodes with high volumetric capacitances can be substituted for commercial AC materials in energy storage devices, such as supercapacitors.
- Published
- 2019
20. Voltammetric sensing of fenitrothion in natural water and orange juice samples using a single-walled carbon nanohorns and zein modified sensor
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Bruno C. Janegitz, Orlando Fatibello-Filho, Tiago Almeida Silva, Geiser Gabriel Oliveira, and Marina P.M. Itkes
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Detection limit ,Orange juice ,Chemistry ,General Chemical Engineering ,Analytical chemistry ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Analytical Chemistry ,Electrochemical gas sensor ,Dielectric spectroscopy ,Electrode ,Cathodic stripping voltammetry ,Electrochemistry ,Cyclic voltammetry ,0210 nano-technology - Abstract
A glassy carbon electrode (GCE) modified with single-walled carbon nanohorns (SWCNH) and zein (ZE), a prolamin type-protein find in maize, for the differential pulse adsorptive cathodic stripping voltammetric determination of fenitrothion (FT) is proposed. The proposed film was characterized by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. Regarding the electrochemical characterization, comparing the results obtained by cyclic voltammetry and electrochemical impedance spectroscopy, the modified electrode (SWCNH-ZE/GCE) showed an electroactive surface area 3 times higher and faster electron transfer kinetic than bare GCE. By using differential pulse adsorptive cathodic stripping voltammetry and SWCNH-ZE/GCE the analytical curve exhibited a linear response ranging of 9.9 × 10−7 to 1.2 × 10−5 mol L−1, with a limit of detection of 1.2 × 10−8 mol L−1. The proposed sensor was successfully applied for the determination of FT pesticide in natural water and orange juice samples. Moreover, the electrochemical sensor showed good repeatability and reproducibility arising from the excellent film stability, suggesting that the proposed architecture has broad potential for applications in sensing and biosensing.
- Published
- 2019
21. A novel catalyst of Ni hybridized with single-walled carbon nanohorns for converting methyl levulinate to γ-valerolactone
- Author
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Sanchai Kuboon, Teera Butburee, Kajornsak Faungnawakij, Chompoopitch Termvidchakorn, Noriaki Sano, and Tawatchai Charinpanitkul
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Thermogravimetric analysis ,Materials science ,General Physics and Astronomy ,Nanoparticle ,chemistry.chemical_element ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Catalysis ,chemistry ,Surface modification ,0210 nano-technology ,Selectivity ,Hybrid material ,Carbon ,Nuclear chemistry - Abstract
γ-valerolactone (GVL) is a fine chemical which is widely used as a green solvent, a fuel additive and a green fuel. It can be produced from lignocellulosic biomass and its derivatives, such as methyl levulinate (ML) via catalytic hydrogenation reaction. In this work, novel hybrid materials of Ni nanoparticles and single-walled carbon nanohorns (Ni/CNHs) synthesized from gas-injected arc-in-water (GI-AIW) method was used as catalysts for producing GVL from ML. Effect of surface modification, oxidation and reduction of Ni/CNHs on their catalytic activity was investigated. For comparison of catalytic activities, Ni on other carbon supports prepared by the conventional wet impregnation and unsupported Ni catalysts were examined. X-ray diffractometry (XRD), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM), N2 sorption, thermogravimetric analysis (TGA), Hydrogen-temperature-programmed reduction (H2-TPR), and Fourier Transform Infrared (FT-IR) spectroscopy were employed for elucidating different characteristics of all examined catalysts. It was found that reduced oxidized Ni/CNHs exhibited the highest catalytic performance with 96% conversion of ML, 90% yield, and 93% selectivity of GVL.
- Published
- 2019
22. Dual-type responsive electrochemical biosensor for the detection of α2,6-sialylated glycans based on AuNRs-SA coupled with c-SWCNHs/S-PtNC nanocomposites signal amplification
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Junlin He, Chengli Zhang, Jun Chen, Chao Yu, Weiran Mao, and Jia Li
- Subjects
Materials science ,Biomedical Engineering ,Biophysics ,Metal Nanoparticles ,Nanotechnology ,Biosensing Techniques ,02 engineering and technology ,Single-walled carbon nanohorn ,01 natural sciences ,Signal ,Limit of Detection ,Polysaccharides ,Biomarkers, Tumor ,Electrochemistry ,Humans ,Detection limit ,Nanotubes, Carbon ,010401 analytical chemistry ,Electrochemical Techniques ,General Medicine ,021001 nanoscience & nanotechnology ,Amperometry ,0104 chemical sciences ,Linear range ,Electrode ,Gold ,Differential pulse voltammetry ,0210 nano-technology ,Biosensor ,Biotechnology - Abstract
In this study, a dual-type responsive electrochemical biosensor was developed for the quantitative detection of α2,6-sialylated glycans (α2,6-sial-Gs), a potential biomarker of tumors. The gold nanorods (AuNRs), which exhibited great specific surface area, as well as good biocompatibility, was synthesized by the way of seed growth method. Furthermore, a biotin-streptavidin (biotin-SA) system was introduced to improve the immunoreaction efficiency. Accordingly, a label-free biosensor was fabricated based on AuNRs-SA for the quick detection of α2,6-sial-Gs by recording the signal of differential pulse voltammetry (DPV). Furthermore, to expand the ultrasensitive detection of α2,6-sial-Gs, a carboxylated single-walled carbon nanohorns/sulfur-doped platinum nanocluster (c-SWCNHs/S-PtNC) was synthesized for the first time as a novel signal label, which showed an excellent catalytic performance. The usage of c-SWCNHs/S-PtNC could significantly amplify the electrochemical signal recorded by the amperometric i-t curve. Herein, a sandwich type biosensor was constructed by combining the AuNRs-SA on the electrode and c-SWCNHs/S-PtNC (signal amplifier). The label-free biosensor possessed a linear range from 5 ng mL−1 to 5 μg mL−1 with a detection limit of 0.50 ng mL−1, and the sandwich-type biosensor possessed a wide linear range from 1 fg mL−1 to 100 ng mL−1 with a detection limit of 0.69 fg mL−1. Furthermore, the biosensor exhibited excellent recovery and stability, indicating its potential for use in actual samples.
- Published
- 2019
23. Nitrogen-doped single walled carbon nanohorns enabling effective utilization of Ge nanocrystals for next generation lithium ion batteries
- Author
-
Claudio Capiglia, Remo Proietti Zaccaria, Umair Gulzar, Rosaria Brescia, Tao Li, Subrahmanyam Goriparti, and Xue Bai
- Subjects
Materials science ,Reducing agent ,General Chemical Engineering ,chemistry.chemical_element ,Germanium ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Anode ,chemistry.chemical_compound ,chemistry ,Nanocrystal ,Chemical engineering ,Oleylamine ,Electrochemistry ,Lithium ,0210 nano-technology ,Carbon - Abstract
Among various carbon materials, nitrogen doped single walled carbon nanohorns (N-SWCNHs) have a unique structure of clustered conical cages (2–5 nm in diameter and 40–50 nm in length) arranged in dahlia, bud and seed-like configurations. Each conical cage has five pentagons at their tips which act as potential reactive site with their own distinct chemistry. We exploited these reactive sites of N-SWCNHs by preferentially growing germanium nanocrystals (Ge NCs) onto their conical tips using oleylamine as a mild reducing agent. Therefore, Ge decorated N-SWCNHs (Ge@N-SWCNHs) composite was used, for the first time, as active anode material for lithium ion batteries providing high and stable capacity of 1285 mAh/g at 0.1C after 100 cycles. Our results show that preferential growth of Ge Nanocrystals (NCs) on the tips of N-SWCNHs not only allows high utilization of active material but prevents the aggregation of Ge NCs after multiple cycling. Finally, we highlight the potential role of N-SWCNHs as cheap and industrially scalable conductive host for next generation lithium ion batteries.
- Published
- 2019
24. All-solid-state potentiometric sensor using single-walled carbon nanohorns as transducer
- Author
-
Chengmei Jiang, Jianfeng Ping, Yalu Cai, and Yao Yao
- Subjects
Detection limit ,Materials science ,Potentiometric titration ,Metals and Alloys ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Electrochemistry ,01 natural sciences ,Reference electrode ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Linear range ,Chemical engineering ,Electrode ,Materials Chemistry ,Potentiometric sensor ,Electrical and Electronic Engineering ,0210 nano-technology ,Instrumentation - Abstract
Single-walled carbon nanohorns (SWCNHs) was utilized as an ion-to-electron transducer to fabricate all-solid-state ion-selective electrodes (ISE) for the first time. To evaluate the performance of developed SWCNHs-based calcium ISE, various electrochemical experiments were carried out. A Nernstian response (29.69 ± 0.24 mV/decade, R2 = 0.9996) was acquired across a broad linear range between 10−6 and 10−2 M, and the detection limit of 10−6.1 M was achieved in the meantime. Additionally, water layer test and reversed chronopotentiometry were used to estimate the long-term and short-term stability of SWCNHs-based ISE, respectively, indicating SWCNHs is capable of enhancing potential stability on account of its hydrophobicity. Furthermore, a SWCNHs-based reference electrode (RE) was fabricated by directly coating a photo-polymerised reference membrane (RM) onto a SWCNHs modified electrode. Results demonstrated that the SWCNHs-based RE exhibited slight potential fluctuation for common ions with different charges over a wide concentration range of calibration. Based on these superior results, an integrated all-solid-state SWCNHs-based potentiometric sensing device combined SWCNHs-based ISE and SWCNHs-based RE was constructed for detecting calcium, which shows a Nernstian response with a slope of 27.14 mV/decade. This developed electrode in the aid of SWCNHs exhibits fast response as well as outstanding potential stability, making it extreme promising for routine sensing application.
- Published
- 2019
25. Electrochemical sensing of purines guanine and adenine using single-walled carbon nanohorns and nanocellulose
- Author
-
Tamires dos Santos Pereira, Mônica H. M. T. Assumpção, Bruno C. Janegitz, Túlio Storti Ortolani, Fernando Campanhã Vicentini, and Geiser Gabriel Oliveira
- Subjects
Materials science ,Scanning electron microscope ,General Chemical Engineering ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Nanocellulose ,Chemical engineering ,Dynamic light scattering ,Transmission electron microscopy ,Linear sweep voltammetry ,Electrochemistry ,Zeta potential ,Fourier transform infrared spectroscopy ,0210 nano-technology - Abstract
In this study, we report an electrochemical study based on nanocellulose (NC) and single-walled carbon nanohorns (SWCNH). SWCNH and NC ensure large surface area, good conductivity, high porosity and chemical stability, becoming attractive for electrodes. The materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR), Scanning Electron Micrograph (SEM), Transmission electron microscopy (TEM), dynamic light scattering (DLS) and zeta potential. Using XRD and FTIR it was possible to observe particular characteristics of NC and SWCNH. The presence of dahlia-like assemblies on the NC surface was observed by MEV and TEM. Then, we investigated the electrochemical behavior of NC-SWCNH, which showed the excellent results when it was used guanine and adenine, as proof of concept, by using cyclic and linear sweep voltammetry (LSV). LSV was also employed for simultaneous detection resulting in limits of detection of 1.7 × 10−7 mol L−1 and 1.4 × 10−6 mol L−1, for guanine and adenine, respectively. In addition, the proposed electrode was applied for determination of both bases in synthetic human serum and fish sperm. We demonstrate that it is possible to use NC, a renewable material, in conducting thin films with SWCNH, and due to simplicity in the preparation and high conductivity, this new thin film could be extended for others electrochemical purposes such as sensing and biosensing.
- Published
- 2019
26. Phycocyanin functionalized single-walled carbon nanohorns hybrid for near-infrared light-mediated cancer phototheranostics
- Author
-
Xing-Can Shen, Bang-Ping Jiang, Zhaoxing Lin, Changchun Wen, and Jinzhe Liang
- Subjects
Near infrared light ,medicine.medical_treatment ,Photodynamic therapy ,Nanotechnology ,02 engineering and technology ,General Chemistry ,Single-walled carbon nanohorn ,Photothermal therapy ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Imaging agent ,0104 chemical sciences ,chemistry.chemical_compound ,Adsorption ,chemistry ,Phycocyanin ,medicine ,General Materials Science ,Growth inhibition ,0210 nano-technology - Abstract
Application of carbon nanomaterials to near-infrared light-mediated phototherapy has attracted great interest. However, their practical use in biological systems is severely limited by their poor water dispersibility, inevitable adsorption of plasma proteins, and their single therapeutic function. Herein, we prepared a phycocyanin (PC)-functionalized single-walled carbon nanohorns (PC@SWNHs) hybrid, where PC is used to preform a protein corona around the SWNHs through non-covalent interface interactions. In the PC@SWNHs, the preformed PC corona effectively improves the water dispersibility of the SWNHs and protects them from plasma protein adsorption. In addition, the excellent photodynamic activity of PC overcomes the inability of SWNHs to generate reactive oxygen species. The SWNHs not only give the hybrid a photothermal therapy (PTT) function, but they also enhance the photostability of PC. These characteristics of the PC@SWNHs are confirmed by in vitro and in vivo experiments, where synergistic photodynamic therapy (PDT)/PTT growth inhibition of tumors is achieved. The PC@SWNHs also act as a photoacoustic/thermal imaging agent to visualize the in vivo treatment process. Hence, this work not only paves the way to use the complementarity between SWNHs and proteins for multifunctional cancer theranostics, but it also allows for a better understanding of bio–nano interface interactions between them.
- Published
- 2019
27. Optimization of pore-opening condition in single-walled carbon nanohorns to achieve high capacity in double layer capacitor at high charge-discharge rate: Critical effect of their hierarchical pore structures
- Author
-
Noriaki Sano, Bo Li, Yanli Nan, and Xiaolong Song
- Subjects
Horizontal scan rate ,Materials science ,Diffusion ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,Microporous material ,Single-walled carbon nanohorn ,Electric double-layer capacitor ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Capacitance ,0104 chemical sciences ,Chemical engineering ,chemistry ,Specific surface area ,General Materials Science ,0210 nano-technology ,Carbon - Abstract
We firstly reveal the unique tendency in the capacitance of an electric double layer capacitor (EDLC) made of single-walled carbon nanohorns (SWCNHs), where there is an optimized value of specific surface area (SSA) to achieve the high capacitance value at a high charge-discharge rate. As a result, in the experimental observation, SWCNHs treated by oxidation in air at 550 °C can exhibit 963.4 m2/g of SSA and 286.6 F/g of EDLC capacitance, whereas the ones treated at 500 °C can exhibit 797.5 m2/g and 316.4 F/g at a high scan rate of 100 mV/s, although the SSA-capacitance relation seems ordinal at 5 mV/s. This result is against a common sense that the higher the SSA, the higher the EDLC capacitance. This unique relationship between the SSA of SWCNHs and the capacitance can be explained by consideration of the hierarchical pore structures of SWCNHs, including the internal mesopore zone and inner-core micropore zone, and the diffusion limitation of ionic species in these different structures. These pores are interlinked via the nanowindows opened by the oxidation treatment, and the nanowindow-link can be enhanced by temperature elevation from 500 to 550 °C, while the superficial mesopore can be partially destroyed at 550 °C.
- Published
- 2019
28. Functionalization of single-walled carbon nanohorns for simultaneous fluorescence imaging and cisplatin delivery in vitro
- Author
-
Allison M. Pekkanen, Kameel M. Isaac, Indu Venu Sabaraya, Marissa Nichole Rylander, Dwight K. Romanovicz, Dipesh Das, Neda Ghousifam, Navid B. Saleh, and Timothy Edward Long
- Subjects
Fluorescence-lifetime imaging microscopy ,Chemistry ,Nanoparticle ,02 engineering and technology ,General Chemistry ,Photothermal therapy ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Imaging agent ,3. Good health ,0104 chemical sciences ,Dynamic light scattering ,Drug delivery ,Cancer cell ,Biophysics ,General Materials Science ,0210 nano-technology - Abstract
Single-walled carbon nanohorns (SWNHs) have been shown to be effective photothermal enhancers and drug delivery agents for potential cancer therapy, particularly for the eradication of bladder cancer lesions. In this study, the potential for SWNHs to serve as nanotheranostic vehicles is demonstrated through simultaneous delivery of the chemotherapeutic cisplatin from SWNH cone interiors and imaging of the nanoparticle transport to tumor cells using conjugated quantum dots (QDs). Following the formation of cisplatin-modified SWNH-QD (SWNH-QD + cis) hybrids, their characterization by scanning and transmission electron microscopy (STEM, TEM), energy dispersive spectroscopy (EDS), and dynamic light scattering (DLS) were performed to characterize the composite nanoparticles. Drug release profiles and 50% inhibitory concentration (IC50) determination showed that QDs do not hinder the therapeutic ability of SWNHs. In addition, the hybrids were trackable over the course of a 3 day period, which indicates that internalized SWNHs can continue to deliver therapy after removal of the nano-agents from the cell culture. This unique SWNH hybrid can successfully be used as an imaging agent to study nanoparticle transport and consequently the delivery of a therapeutic to the targeted cancer cells.
- Published
- 2018
29. Preparation, electrical properties, and supercapacitor applications of fibrous aggregates of single-walled carbon nanohorns
- Author
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Kiyohiko Toyama, Masako Yudasaka, Fumiyuki Nihey, and Ryota Yuge
- Subjects
Supercapacitor ,Materials science ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,chemistry ,Chemical engineering ,Yield (chemistry) ,Electrode ,medicine ,General Materials Science ,0210 nano-technology ,Carbon ,Sheet resistance ,Ambient pressure ,Activated carbon ,medicine.drug - Abstract
Fibrous aggregates of single-walled carbon nanohorns (carbon nanobrushes: CNBs) were prepared by CO2 laser ablation of an iron-containing carbon target with rotations under nitrogen atmosphere and ambient pressure. The rotation speed of the target and concentration of iron contained in it were controlled so as to increase the yield of CNBs. As a result, many CNBs were obtained at a rotation speed of 1 rpm and iron concentration above 1 at. %, although the samples still contained spherical single-walled carbon nanohorn aggregates (CNHs). The sheet resistivity of the samples containing both CNBs and CNHs decreased with the CNB content, which indicates that the CNBs formed a good conducting path. By forming supercapacitor electrodes, the capacitances of mixture of CNBs and CNHs, CNHs, and activated carbon were similar, i.e., 20, 21, and 23 F/g, respectively, at 0.1 A/g. However, the capacitance of the mixture of CNBs and CNHs at a discharge current of 5 A/g was about 1.4 and 6 times higher than that of the CNHs and activated carbon. These newly discovered CNBs should definitely increase the advantages of nanocarbon in various fields, especially in electronic devices.
- Published
- 2018
30. Highly sensitive electrochemical sensor based on β-cyclodextrin–gold@3, 4, 9, 10-perylene tetracarboxylic acid functionalized single-walled carbon nanohorns for simultaneous determination of myricetin and rutin.
- Author
-
Ran, Xin, Yang, Long, Zhang, Jianqiang, Deng, Guogang, Li, Yucong, Xie, Xiaoguang, Zhao, Hui, and Li, Can-Peng
- Subjects
- *
ELECTROCHEMICAL sensors , *CYCLODEXTRINS , *CARBOXYLIC acids , *SINGLE walled carbon nanotubes , *MYRICETIN , *RUTIN - Abstract
The application of macrocyclic hosts for construction of different electrochemical devices and separation matrices has attracted much attentions due to their benign biocompatibility and simplicity of synthesis. Myricetin and rutin are considered two of the most bioactive flavonoids, which have been proved to exhibit various physiological functions. This work reports a simple and facile approach for the synthesis of β-cyclodextrin-gold@3, 4, 9, 10-perylene tetracarboxylic acid functionalized single-walled carbon nanohorns (β-CD–Au@PTCA–SWCNHs) nanohybrids. The simultaneous electrochemical determination of myricetin and rutin using a β-CD–Au@PTCA–SWCNHs-modified glassy carbon electrode was established. The results show that the β-CD–Au@PTCA–SWCNHs-modified electrode displayed electrochemical signal superior to those of Au@PTCA–;SWCNHs and SWCNHs towards myricetin and rutin. The proposed modified electrode has a linear response range of 0.01–10.00 μM both for myricetin and rutin with relatively low detection limits of 0.0038 μM for myricetin and 0.0044 μM ( S/N = 3) for rutin, respectively. The excellent performance of the sensing platform is considered to be the synergic effects of the SWCNHs ( e.g. their good electrochemical properties and large surface area) and β-CD ( e.g. a hydrophilic external surface, a high supramolecular recognition, and a good enrichment capability). [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
31. Simultaneous esterification and transesterification for biodiesel synthesis by a catalyst consisting of sulfonated single-walled carbon nanohorn dispersed with Fe/Fe2O3 nanoparticles.
- Author
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Poonjarernsilp, Chantamanee, Sano, Noriaki, and Tamon, Hajime
- Subjects
- *
ESTERIFICATION , *TRANSESTERIFICATION , *BIODIESEL fuels , *CARBON nanohorns , *IRON oxide nanoparticles - Abstract
The simultaneous esterification of palmitic acid and transesterification of tributyrin is investigated using a solid acid catalyst newly developed. This catalyst consists of porous single-walled carbon nanohorn (SWCNH) dispersed with Fe/Fe 2 O 3 -mixed nanoparticles. The esterfication of palmitic acid is initially catalyzed by this catalyst, and the transesterification of tributyrin can be observed after most of palmitic acid was consumed. Contrary to a general expectation that the addition of a free fatty acid usually has poisonous effect on transesterification of tributyrin, the addition of palmitic acid shows an effect to enhance the yield of methyl butyrate. As one of the reasons, the palmitic acid adsorbed on Fe/Fe 2 O 3 particles placed in the pores of the catalyst may attract tributyrin molecules, and tributyrin concentrated thereon may diffuse to the acidic sites on the catalyst. However, this effect seems to be reduced significantly when the reaction temperature is high. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
32. Single-walled Carbon Nanohorn: Electronic Absorption Spectra in Neutral and Oxodized State.
- Author
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Iglesias-Groth, Susana, Cataldo, Franco, Angelini, Giancarlo, and Hafez, Yaser
- Subjects
- *
SINGLE walled carbon nanotubes , *ELECTRONIC spectra , *ABSORPTION spectra , *TETRADECANE , *RADICAL cations , *SULFURIC acid , *SOLUBILITY - Abstract
The electronic absorption spectrum of single-walled carbon nanohorn (SWCNH) shows a relatively broad absorption peak at 256–259 nm when suspended in tetradecane and in decalin. The electronic absorption spectrum is also characterized by a series of small bands recalling the spectra of C60and C70fullerenes. Surprisingly, SWCNH shows a minimal solubility in 1,2,4-trichlorobenzene. SWCNH is also dissolved and oxidized in oleum (fuming sulphuric acid with 20% free SO3), displaying a radical cation band in the near infrared at 1045 nm. The addition of ozone to a suspension of SWCNH in oleum enhances its dissolution and the relative radical cation absorption band. [ABSTRACT FROM AUTHOR]
- Published
- 2014
- Full Text
- View/download PDF
33. Electrocatalytic hydrogen evolution using hybrid electrodes based on single-walled carbon nanohorns and cobalt(ii) polypyridine complexes
- Author
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Stefano Agnoli, Cristiano Zonta, Giulia Licini, Lorenza Destro, Alessandro Niorettini, Mirco Natali, Klaus Wurst, Elisabetta Benazzi, and Federico Begato
- Subjects
Electrolysis ,Denticity ,Hydrogen ,Renewable Energy, Sustainability and the Environment ,Chemistry ,Ligand ,chemistry.chemical_element ,Ambientale ,General Chemistry ,Electrolyte ,Single-walled carbon nanohorn ,Photochemistry ,Catalysis ,law.invention ,law ,General Materials Science ,Cobalt - Abstract
The generation of hydrogen from water represents an important task towards a carbon neutral economy. Within this context, the preparation of hybrid electrodes merging the versatility of solid-state porous substrates and the catalytic ability and tunability of molecular complexes represents a great challenge. In the present work, we report on the preparation of hybrid cathodes for the hydrogen evolution reaction (HER) through an unprecedented combination of single-walled carbon nanohorns (SWCNHs) and two novel cobalt(II) polypyridine complexes based on the tris(2-pyridylmethyl)amine (TPMA) ligand scaffold. Suitable pyrene groups are introduced in the ligand framework in different positions to provide a way for direct anchoring onto the carbonaceous substrate by exploiting non-covalent π–π interactions. The present systems behave as competent cathodes for the HER in neutral aqueous solution with overpotentials of η ∼ 0.5 V and stable current densities (within 1 h electrolysis) up to −0.50 mA cm−2, whose exact values depend on the catalyst used and are mainly related to the respective loading on the electrode surface. In both cases, hydrogen evolution is detected under continuous electrolysis for up to ca. 12 h leading to maximum turnover numbers (TONs) of 4700 and 9180 molH2 molCo−1 for the two different complexes. The progressive deactivation under electrolytic conditions is mainly ascribed to leaching of the metal centre from the polydentate ligand, likely occurring from the competent catalytic intermediates involved in the HER.
- Published
- 2021
34. Organic–Inorganic Ternary Nanohybrids of Single-Walled Carbon Nanohorns for Room Temperature Chemiresistive Ethanol Detection
- Author
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Octavian Buiu, Niculae Dumbravescu, Cornel Cobianu, Cosmin Cobianu, Marius Bumbac, Bogdan-Catalin Serban, Bogdan Bita, Cristina Pachiu, Cristina Mihaela Nicolescu, and Viorel Avramescu
- Subjects
p-type semiconductor ,oxidized single-walled carbon nanohorn (ox-SWCNH) ,polyvinylpyrrolidone (PVP) ,Materials science ,General Chemical Engineering ,chemistry.chemical_element ,Single-walled carbon nanohorn ,Article ,organic–inorganic ternary nanohybrids ,lcsh:Chemistry ,ethanol vapor detection ,SnO2 and ZnO nanoparticles ,HSAB theory ,electrical percolation threshold ,General Materials Science ,business.industry ,chemiresistive principle ,Response time ,Heterojunction ,Semiconductor ,chemistry ,Chemical engineering ,lcsh:QD1-999 ,Electrode ,Ternary operation ,business ,Carbon ,Stoichiometry - Abstract
Organic&ndash, inorganic ternary nanohybrids consisting of oxidized-single walled carbon nanohorns-SnO2-polyvinylpyrrolidone (ox-SWCNH/SnO2/PVP) with stoichiometry 1/1/1 and 2/1/1 and ox-SWCNH/ZnO/PVP = 5/2/1 and 5/3/2 (all mass ratios) were synthesized and characterized as sensing films of chemiresistive test structures for ethanol vapor detection in dry air, in the range from 0 up to 50 mg/L. All the sensing films had an ox-SWCNH concentration in the range of 33.3&ndash, 62.5 wt%. A comparison between the transfer functions and the response and recovery times of these sensing devices has shown that the structures with ox-SWCNH/SnO2/PVP = 1/1/1 have the highest relative sensitivities of 0.0022 (mg/L)&minus, 1, while the devices with ox-SWCNH/SnO2/PVP = 2/1/1 have the lowest response time (15 s) and recovery time (50 s) for a room temperature operation, proving the key role of carbonic material in shaping the static and dynamic performance of the sensor. These response and recovery times are lower than those of &ldquo, heated&rdquo, commercial sensors. The sensing mechanism is explained in terms of the overall response of a p-type semiconductor, where ox-SWCNH percolated between electrodes of the sensor, shunting the heterojunctions made between n-type SnO2 or ZnO and p-type ox-SWCNH. The hard&ndash, soft acid&ndash, base (HSAB) principle supports this mechanism. The low power consumption of these devices, below 2 mW, and the sensing performances at room temperature may open new avenues towards ethanol sensors for passive samplers of environment monitoring, alcohol test portable instruments and wireless network sensors for Internet of Things applications.
- Published
- 2020
35. Opening the internal structure for transport of ions: improvement of the structural and chemical properties of single-walled carbon nanohorns for supercapacitor electrodes
- Author
-
Piotr Kowalczyk, Wojciech Zięba, Marta E. Plonska-Brzezinska, Piotr Olejnik, Artur P. Terzyk, and Stanisław Koter
- Subjects
Supercapacitor ,Materials science ,General Chemical Engineering ,chemistry.chemical_element ,General Chemistry ,Electrolyte ,Single-walled carbon nanohorn ,Electrochemistry ,Capacitance ,Chemical engineering ,chemistry ,Electrode ,Surface modification ,Carbon - Abstract
We investigated the electrochemical performance of single-walled carbon nanohorns (SWCNHs) for use as supercapacitor electrodes. For the first time, we used acid-treatment for oxidation of SWCNHs and hole creation in their structure. A detailed study was performed on the correlation between the oxidation of SWCNHs via acid treatment and variable acid treatment times, the structural properties of the oxidized carbon nanostructures, and the specific capacitance of the SWCNH electrodes. We showed that simple functionalization of carbon nanostructures under controlled conditions leads to an almost 3-fold increase in their specific capacitance (from 65 to 180 F g−1 in 0.1 M H2SO4). This phenomenon indicates higher accessibility of the surface area of the electrodes by electrolyte ions as a result of gradual opening of the SWCNH internal channels.
- Published
- 2020
36. Hierarchical Composite Nanoarchitectonics with a Graphitic Core, Dendrimer and Fluorocarbon Domains, and a Poly(ethylene glycol) Shell as O 2 Reservoirs for Reactive Oxygen Species Production.
- Author
-
Workie YA, Kuo CY, Riskawati JH, Krathumkhet N, Imae T, Ujihara M, and Krafft MP
- Abstract
Graphene oxide (GO), single-walled carbon nanohorn (CNHox), and nitrogen-doped CNH (N-CNH) were functionalized with fluorinated poly(ethylene glycol) ( F -PEG) and/or with a fluorinated dendrimer ( F -DEN) to prepare a series of assembled nanocomposites (GO/ F -PEG, CNHox/ F -PEG, N-CNH/ F -PEG, N-CNH/ F -DEN, and N-CNH/ F -DEN/ F -PEG) that provide effective multisite O
2 reservoirs. In all cases, the O2 uptake increased with time and saturated after 10-20 min. When graphitic carbons (GO and CNHox) were coated with F -PEG, the O2 uptake doubled. The O2 loading was slightly higher in N-CNH compared to CNHox. Notably, coating N-CNH with F -DEN or F -PEG, or with both F -DEN and F -PEG, was more effective. The best performance was obtained with the N-CNH/ F -DEN/ F -PEG nanocomposite. The O2 uptake kinetics and mechanisms were analyzed in terms of the Langmuir adsorption equation based on a multibinding site assumption. This allowed the precise determination of multiple oxygen binding sites, including on the graphitic structure and in the dendrimer, F -DEN, and F -PEG. After an initial rapid, relatively limited release, the amount of O2 trapped in the nanomaterials remained high (>95%). This amount was marginally lower for the functionalized composites, but the oxygen stored was reserved for longer times. Finally, it is shown that these systems can generate singlet oxygen after irradiation by a light-emitting diode, and this production correlates with the amount of O2 loaded. Thus, it was anticipated that the present nanocomposites hierarchically assembled from components with different characters and complementary affinities for oxygen can be useful as O2 reservoirs for singlet oxygen generation to kill bacteria and viruses and to perform photodynamic therapy.- Published
- 2022
- Full Text
- View/download PDF
37. Multimodal Microscopy Distinguishes Extracellular Aggregation and Cellular Uptake of Single‐Walled Carbon Nanohorns
- Author
-
Donal F. O'Shea, Stephen J. Devereux, Harrison C. Daly, Susan J. Quinn, and Shane Cheung
- Subjects
Cancer cells ,Fluorophore ,Nanoparticle ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,01 natural sciences ,Catalysis ,chemistry.chemical_compound ,Surface functionalisation ,In-vivo ,Live cell imaging ,Extracellular ,Nanotechnology ,Gold nanoparticles ,Carbon nanohorns ,NIR-AZA fluorophores ,Organic Chemistry ,General Chemistry ,021001 nanoscience & nanotechnology ,Fluorescence ,0104 chemical sciences ,Differential interference contrast microscopy ,chemistry ,Colloidal gold ,Drug delivery ,Fluoroscence ,Biophysics ,0210 nano-technology ,Chemical modification - Abstract
The low toxicity, high surface area, and ease of functionalisation of carbon nanohorns (CNH) makes them attractive systems for cellular imaging, diagnostics and therapeutics. However, challenges remain for the biomedical translation of these and other nanomaterials. A significant task is tuning the surface chemistry to achieve optimal cellular interactions. Herein, we combine real-time fluorescent imaging of nanoparticle cellular uptake and real-time differential interference contrast (DIC) imaging of extracellular media to monitor a) nanoparticle/nanoparticle and b) nanoparticle/cell interactions for CNHs covalently modified with an OFF/ON near-IR dye, the fluorescence of which is switched OFF in extracellular environments and triggered upon cellular internalisation. CHN samples modified with different loadings of the hydrophobic dye are taken as a simple model of drug-loaded nanoparticle systems. The punctate fluorescence suggests the CNHs are delivered to lysosomes and other vesicles of the endocytic pathway. DIC imaging highlights the competition that exists for many particle types, between extracellular aggregation and cellular internalization, the efficiency of which would be dependent upon the amount of fluorophore loading. The results of this study illustrate how complementary real-time imaging methods together with physicochemical characterisation can be used to address the challenges involved in optimising nanoparticle/cell interactions for biomedical applications. Irish Research Council Science Foundation Ireland University College Dublin
- Published
- 2018
38. Highly sensitive electrochemiluminescent immunoassay for neuron-specific enolase amplified by single-walled carbon nanohorns and enzymatic biocatalytic precipitation
- Author
-
Wenying Zhong, Li Zhang, Xue Li, Yongling Ai, and Jing Wang
- Subjects
Detection limit ,endocrine system ,Chromatography ,medicine.diagnostic_test ,biology ,Chemistry ,General Chemical Engineering ,Enolase ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Horseradish peroxidase ,Primary and secondary antibodies ,0104 chemical sciences ,Analytical Chemistry ,Immunoassay ,Electrode ,Electrochemistry ,medicine ,biology.protein ,Electrochemiluminescence ,0210 nano-technology - Abstract
A novel amplified electrochemiluminescence (ECL) immunoassay based on single-walled carbon nanohorns (SWCNHs) labels and enzymatic biocatalytic precipitation (BCP) was proposed for the detection of neuron-specific enolase (NSE) for the first time. In this system, the dimercaptosuccinic acid stabilized CdTe (DMSA-CdTe) quantum dots (QDs) as ECL emitter showed excellent ECL behavior and then employed as the NSE antibody (Ab1) immobilization film for the subsequent sandwich-type Ab1-Ag affinity interactions. Improved sensitivity was achieved through using the SWCNHs effectively to expand the amount of secondary antibody (Ab2) and horseradish peroxidase (HRP) loading. In addition to the much enhanced steric hindrance, compared with the single HRP-Ab2, the presence of plentiful HRP would further stimulate the BCP onto the electrode surface for signal amplification, concomitant to the BCP products absorption that lowered ECL intensity. As a result of the multisignal amplification in this ECL immunosensor, it possessed excellent analytical performance. The target NSE could be detected from 1 × 10−9 g L−1 to 1 × 10−3 g L−1 with a detection limit of 4.4 × 10−10 g L−1.
- Published
- 2018
39. Electrochemical Immunosensor for Monocyte Chemoattractant Protein-1 Detection Based on Pt Nanoparticles Functionalized Single-walled Carbon Nanohorns
- Author
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Zhengshan Gao
- Subjects
Chemical engineering ,Chemistry ,Electrochemistry ,02 engineering and technology ,010501 environmental sciences ,Single-walled carbon nanohorn ,Pt nanoparticles ,021001 nanoscience & nanotechnology ,0210 nano-technology ,01 natural sciences ,0105 earth and related environmental sciences ,Monocyte chemoattractant protein - Published
- 2018
40. Dual Chemodrug-Loaded Single-Walled Carbon Nanohorns for Multimodal Imaging-Guided Chemo-Photothermal Therapy of Tumors and Lung Metastases
- Author
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Jiali Cai, Huilan Su, Jingxing Yang, Shiyuan Liu, Wenshe Sun, Yimin Chai, and Chunfu Zhang
- Subjects
Lung Neoplasms ,Combination therapy ,medicine.medical_treatment ,Medicine (miscellaneous) ,Antineoplastic Agents ,02 engineering and technology ,Single-walled carbon nanohorn ,010402 general chemistry ,Multimodal Imaging ,01 natural sciences ,Mice ,Drug Therapy ,In vivo ,Cell Line, Tumor ,medicine ,Animals ,Doxorubicin ,Molecular Targeted Therapy ,Neoplasm Metastasis ,Pharmacology, Toxicology and Pharmaceutics (miscellaneous) ,Cisplatin ,Drug Carriers ,Chemotherapy ,Chemistry ,Therapeutic effect ,Hyperthermia, Induced ,Phototherapy ,Photothermal therapy ,021001 nanoscience & nanotechnology ,Xenograft Model Antitumor Assays ,Carbon ,0104 chemical sciences ,Disease Models, Animal ,Treatment Outcome ,Chemo-photothermal therapy ,Cancer research ,Heterografts ,Nanoparticles ,Administration, Intravenous ,Single walled carbon nanohorns ,Photoacoustic imaging ,0210 nano-technology ,Tumor metastasis ,Neoplasm Transplantation ,Research Paper ,medicine.drug - Abstract
Tumor combination therapy using nano formulations with multimodal synergistic therapeutic effects shows great potential for complete ablation of tumors. However, targeting tumor metastases with nano structures is a major obstacle for therapy. Therefore, developing a combination therapy system able to target both primary tumors and their metastases at distant sites with synergistic therapy is desirable for the complete eradication of tumors. To this end, a dual chemodrug-loaded theranostic system based on single walled carbon nanohorns (SWNHs) is developed for targeting both primary breast tumors and their lung metastases. Methods: SWNHs were first modified simultaneously with poly (maleic anhydride-alt-1-octadecene) (C18PMH) and methoxypolyethyleneglycol-b-poly-D, L-lactide (mPEG-PLA) via hydrophobic-hydrophobic interactions and π-π stacking. Then cisplatin and doxorubicin (DOX) (2.9:1 molar ratio) were sequentially loaded onto the modified nanohorns in a noninterfering way. After careful examinations of the release profiles of the loaded drugs and the photothermal performance of the dual chemodrug-loaded SWNHs, termed SWNHs/C18PMH/mPEG-PLA-DOX-Pt, the dual drug chemotherapeutic and chemo-photothermal synergetic therapeutic effects on tumor cells were evaluated. Subsequently, the in vivo behavior and tumor accumulation of the drug-loaded SWNHs were studied by photoacoustic imaging (PAI). For chemo-photothermal therapy of tumors, 4T1 tumor bearing mice were intravenously injected with SWNHs/C18PMH/mPEG-PLA-DOX-Pt at a dose of 10 mg/kg b.w. (in SWNHs) and tumors were illuminated by an 808 nm laser (1W/cm2 for 5 min) 24 h post-injection. Results: DOX and cisplatin were loaded onto the modified SWNHs with high efficiency (44 wt% and 66 wt%, respectively) and released in a pH-sensitive, tandem and sustainable manner. The SWNHs/C18PMH/mPEG-PLA-DOX-Pt had a hydrodynamic diameter of 182 ± 3.2 nm, were highly stable in physiological environment, and had both dual drug chemotherapeutic (CI = 0.439) and chemo-photothermal synergistic antitumor effects (CI = 0.396) in vitro. Moreover, the dual drug-loaded SWNHs had a long blood half-life (10.9 h) and could address both the primary breast tumors and their lung metastases after intravenous administration. Consequently, chemo-photothermal combination therapy ablated the primary tumors and simultaneously eradicated the metastatic lung nodules. Conclusion: Our study demonstrates that SWNHs/C18PMH/mPEG-PLA-DOX-Pt is highly potent for chemo-photothermal combination therapy of primary tumors and cocktail chemotherapy of their metastases at a distant site.
- Published
- 2018
41. A novel poly (amic-acid) modified single-walled carbon nanohorns adsorbent for efficient removal of uranium (VI) from aqueous solutions and DFT study
- Author
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Feiqiang He, Jie Huang, Bin Huang, Zhirong Liu, Yong Qian, and Tianxiang Jin
- Subjects
Aqueous solution ,Inorganic chemistry ,technology, industry, and agriculture ,chemistry.chemical_element ,biochemical phenomena, metabolism, and nutrition ,Uranium ,Single-walled carbon nanohorn ,chemistry.chemical_compound ,Colloid and Surface Chemistry ,Adsorption ,chemistry ,Polymerization ,Amide ,Monolayer ,Bifunctional - Abstract
Poly(amic-acid) modified single-walled carbon nanohorns (PAA/SWCNH-COOH) contained dual-functional groups (amide and carboxyl) were synthesized by in-situ polymerization and used for the elimination of uranium (VI). It was found that the adsorption capacity of SWCNH-COOH increased significantly after grafting PAA chains, and the theoretical monolayer adsorption capacity of PAA/SWCNH-COOH could reach 216.0 mg/g. The adsorption capacity of this material could remain up to 90% of the initial value after 5 times of reuse. Moreover, PAA/SWCNH-COOH has an excellent adsorption selectivity, which could be attributed to the synergistic adsorption effects between amide and carboxyl groups. To further study the interaction mechanism between uranium ions and the adsorbents, the quantum chemical calculations were performed using DFT method. The simulation results show that both amide and carboxyl groups have a strong interaction with uranium ions, which ensures the high adsorption capacity of this material. This research proved that the PAA/SWCNH-COOH is a promising adsorption material for removing uranium from wastewater and it also sheds a light on the interaction mechanism between bifunctional adsorbents and uranium ions.
- Published
- 2021
42. Ionic liquid-assisted ultrasonic exfoliation of phosphorene nanocomposite with single walled carbon nanohorn as nanozyme sensor for derivative voltammetric smart analysis of 5-hydroxytryptamine
- Author
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Yifu Zhu, Jingkun Xu, Yingying Sheng, Ting Xue, Weiqiang Li, Xinyu Lu, Liangmei Rao, Xiaoyu Zhu, and Yangping Wen
- Subjects
Nanocomposite ,Materials science ,Derivative ,Single-walled carbon nanohorn ,Electrochemistry ,Exfoliation joint ,Analytical Chemistry ,Crystal ,chemistry.chemical_compound ,Phosphorene ,Chemical engineering ,chemistry ,Ionic liquid ,Spectroscopy - Abstract
Ultrasonic-assisted liquid-phase exfoliation is one of high-efficiency strategies for preparing two-dimensional (2D) materials. Herein, we report a facile and green synthesis of the phosphorene (BP) obtained from bulk black phosphorus crystal in the ionic liquid (IL) 1-ethyl-3-methylimidazoliumtetrafluoroborate ([EMIm]BF4) through ultrasonic-assisted liquid-phase exfoliation under the continuous nitrogen atmosphere. To gain more insight, the morphology and composition of the as-prepared BP were characterized. The prepared BP showed satisfactory stability in ambient condition containing oxygen and water. In the following, single walled carbon nanohorn (SWCNH) was selected to enhance electrocatalytic capacity and endow oxidase-like (nanozyme) characteristics, which was further applied for electrochemical sensing of 5-hydroxytryptamine (5-HT). Derivative techniques were employed for treating voltammograms to obtain sharper and narrower voltammetric peak, transform asymmetric peak into much more symmetrical peak, reduce background interference, eliminate personal error and directly read the accurate value. Machine learning (ML) model based on artificial neural network (ANN) algorithm as an artificial intelligence approach is adopted to establish smart sensing system via the relationship between concentrations and currents in comparison with traditional linear regression model. The BP-IL-SWCNH nanozyme sensor displayed excellent electrocatalytic ability for second-order derivative voltammetric smart analysis of 5-HT range from 0.3 to 115 µM under optimal conditions.
- Published
- 2021
43. Electrochemical Determination of Paracetamol Using MXene/single-walled Carbon Nanohorns Composite as Sensor
- Author
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Wei Zhong
- Subjects
Materials science ,Chemical engineering ,Composite number ,Electrochemistry ,Single-walled carbon nanohorn - Published
- 2021
44. Photoelectrochemical aptasensor based on CdTe quantum dots-single walled carbon nanohorns for the sensitive detection of streptomycin
- Author
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Lijun Luo, Libo Li, Xixi Xu, Dong Liu, Kun Wang, and Tianyan You
- Subjects
Detection limit ,Nanocomposite ,Materials science ,Aptamer ,010401 analytical chemistry ,Photoelectrochemistry ,Metals and Alloys ,Nanotechnology ,02 engineering and technology ,Single-walled carbon nanohorn ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Cadmium telluride photovoltaics ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Quantum dot ,Streptomycin ,Materials Chemistry ,medicine ,Electrical and Electronic Engineering ,0210 nano-technology ,Instrumentation ,medicine.drug - Abstract
A novel CdTe quantum dots - single walled carbon nanohorns (CdTe-SWCNHs) nanocomposite was synthesized via a one-pot method for photoelectrochemical (PEC) aptasensing detection of streptomycin (STR). The CdTe-SWCNHs nanocomposite shows 3.2-times amplified PEC activity in comparison with CdTe quantum dots (QDs). By using aptamers as recognition element and CdTe-SWCNHs as photoactive species, a PEC aptasensor was fabricated for the high sensitive and selective detection of STR. Under the optimized conditions, the as-fabricated PEC aptamer sensor exhibits a linear response ranging from 0.1 nM (0.15 μg kg −1 ) to 50 nM (72.85 μg kg −1 ) with a detection limit ( S / N = 3) of 0.033 nM (0.05 μg kg −1 ). The aptasensor has successfully applied for the determination of streptomycin in honey sample, which provides a new method for detection of streptomycin.
- Published
- 2017
45. Flowing nitrogen assisted-arc discharge synthesis of nitrogen-doped single-walled carbon nanohorns.
- Author
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Sun, Li, Wang, Chunlei, Zhou, Ying, Zhang, Xu, Cai, Bing, and Qiu, Jieshan
- Subjects
- *
NITROGEN , *GAS flow , *ELECTRIC arc , *SINGLE walled carbon nanotubes synthesis , *CARBON nanohorns , *STRUCTURAL engineering - Abstract
Highlights: [•] N-SWCNHs have been synthesized by flowing-nitrogen assisted arc discharge method. [•] N-SWCNHs have typical spherical structure with a diameter of 40–80nm. [•] Oxidation treatment can open the intraparticle cavities N-SWCNHs. [•] N atoms are mainly in N-6, N-5 and -CN located at the edges of graphene layers. [Copyright &y& Elsevier]
- Published
- 2013
- Full Text
- View/download PDF
46. Nanogold-Enriched Carbon Nanohorn Label for Sensitive Electrochemical Detection of Biomarker on a Disposable Immunosensor.
- Author
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Zhao , Changrong, Lin, Dajie, Wu, Jie, Ding, Lin, Ju, Huangxian, and Yan, Feng
- Abstract
A novel nanogold-enriched carbon nanohorn structure (nanoAu/CNH) was designed as a trace tag for highly efficient electrochemical detection of tumor marker using a disposable immunosensor. The nanoAu/CNH was synthesized by one-pot in situ growth of nanogold on carboxylated single-walled CNH. The labeling of signal antibody was performed via the inherent interaction between protein and nanogold. The disposable immunosensor was constructed by covalently cross-linking capture antibody on chitosan modified screen-printed carbon electrode. With a sandwich format, the nanoAu/CNH labeled antibody was conjugated on the immunosensor for electrochemical measurement of tumor marker by electrooxidizing the nanoAu at +1.3 V and then cathodic potential scan in 0.1 M HCl. Using α-fetoprotein as model target, the proposed immunoassay showed acceptable precision and wide linear range from 0.1 pg mL−1 to 1 ng mL−1 with a detection limit of 0.07 pg mL−1. The new nanoAu/CNH label as well as the disposable immunosensor showed possessed potential application in point-of-care testing. [ABSTRACT FROM AUTHOR]
- Published
- 2013
- Full Text
- View/download PDF
47. A high poly(ethylene glycol) density on graphene nanomaterials reduces the detachment of lipid–poly(ethylene glycol) and macrophage uptake.
- Author
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Yang, Mei, Wada, Momoyo, Zhang, Minfang, Kostarelos, Kostas, Yuge, Ryota, Iijima, Sumio, Masuda, Mitsutoshi, and Yudasaka, Masako
- Subjects
POLYETHYLENE glycol ,GRAPHENE ,NANOSTRUCTURED materials ,LIPIDS ,MACROPHAGES ,AQUEOUS solutions - Abstract
Abstract: Amphiphilic lipid–poly(ethylene glycol) (LPEG) is widely used for the noncovalent functionalization of graphene nanomaterials (GNMs) to improve their dispersion in aqueous solutions for biomedical applications. However, not much is known about the detachment of LPEGs from GNMs and macrophage uptake of dispersed GNMs in relation to the alkyl chain coverage, the PEG coverage, and the linker group in LPEGs. In this study we examined these relationships using single walled carbon nanohorns (SWCNHs). The high coverage of PEG rather than that of alkyl chains was dominant in suppressing the detachment of LPEGs from SWCNHs in protein-containing physiological solution. Correspondingly, the quantity of LPEG-covered SWCNHs (LPEG-SWCNHs) taken up by macrophages decreased at a high PEG coverage. Our study also demonstrated an effect of the ionic group in LPEG on SWCNH uptake into macrophages. A phosphate anionic group in the LPEG induced lower alkyl chain coverage and easy detachment of the LPEG, however, the negative surface charge of LPEG-SWCNHs reduced the uptake of SWCNHs by macrophages. [Copyright &y& Elsevier]
- Published
- 2013
- Full Text
- View/download PDF
48. A label-free aptasensor for turn-on fluorescent detection of ochratoxin a based on SYBR gold and single walled carbon nanohorns
- Author
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Hansong Yu, Huanhuan Yang, Jing Tian, Ming Yuan, Chengbi Cui, Yan Wang, and Zhijun Guo
- Subjects
Ochratoxin A ,Detection limit ,Chromatography ,biology ,Chemistry ,Aptamer ,Single-walled carbon nanohorn ,biology.organism_classification ,Fluorescence ,chemistry.chemical_compound ,Penicillium verrucosum ,Biosensor ,Aspergillus ochraceus ,Food Science ,Biotechnology - Abstract
Ochratoxin A (OTA), is one of the most commonly found mycotoxins in food. It is primarily produced by Aspergillus ochraceus and Penicillium verrucosum. OTA can causes serious damages to liver and kidney, increases the teratogenicity, and has been considered as a potential carcinogen (group 2 B). In this study, we demonstrated a new detection system for the detection of OTA using fluorescence biosensing according to an anti-OTA aptamer and fluorescence quencher using single-walled carbon nanohorns (SWCNHs). In the presence of OTA, the OTA-specific aptamer underwent the conformation change from a random coil to an antiparallel G-quadruplex. The latter one was resistant to being adsorbed onto SWCNHs, leading to the pertection of the fluorescence of SYBR Gold. As a result, the remained fluorescent intensities correlated with the concentrations of OTA. The detection limit of OTA was 2.3 ng/ml, meanwhile the linear detection range was 5–500 ng/ml, with a satisfactory linear correlation (R2 = 0.992) of the fluorescence intensity and the logarithm of OTA concentrations. The aptasensor was subjected to quantify the concentration of OTA in red wine samples. As a result, this label-free aptasensor was suitable for the test of OTA in food samples.
- Published
- 2021
49. Simultaneous electrochemical determination of uric acid, dopamine, and ascorbic acid at single-walled carbon nanohorn modified glassy carbon electrode
- Author
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Zhu, Shuyun, Li, Haijuan, Niu, Wenxin, and Xu, Guobao
- Subjects
- *
ELECTROCHEMICAL analysis , *URIC acid , *VITAMIN C , *DOPAMINE , *CARBON electrodes , *OXIDATION - Abstract
Abstract: Single-walled carbon nanohorn modified glassy carbon electrode (SWCNH-modified GCE) was first employed for the simultaneous determination of uric acid (UA), dopamine (DA), and ascorbic acid (AA). The SWCNH-modified GCE displayed excellent electrochemical catalytic activities. The oxidation overpotentials of UA, DA, and AA decrease significantly and their oxidation peak currents increase dramatically at SWCNH-modified GCE. Linear sweep voltammetry (LSV) was used for the simultaneous determination of UA, DA, and AA in their ternary mixture. The peak separations between UA and DA, and DA and AA are large up to 152mV and 221mV, respectively. The calibration curves for UA, DA, and AA were obtained in the range of 0.06–10μM, 0.2–3.8μM, and 30–400μM, respectively. The detection limits (S/N=3) were 20nM, 60nM, and 5μM for UA, DA, and AA, respectively. The proposed method improved sensitivity for the determination of UA by more than one order of magnitude. The present method was applied to the determination of UA, DA, and AA in urine sample by using standard adding method and the results were satisfactory. [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
- View/download PDF
50. Single-walled carbon nanohorn as new solid-phase extraction adsorbent for determination of 4-nitrophenol in water sample
- Author
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Zhu, Shuyun, Niu, Wenxin, Li, Haijuan, Han, Shuang, and Xu, Guobao
- Subjects
- *
CARBON nanotubes , *SOLID phase extraction , *NITROPHENOLS , *WATER purification adsorption , *SURFACE area , *VOLTAMMETRY , *WATER sampling - Abstract
Abstract: Single-walled carbon nanohorn (SWCNH) was developed as new adsorbent for solid-phase extraction using 4-nitrophenol as representative. The unique exoteric structures and high surface area of SWCNH allow extracting a large amount of 4-nitrophenol over a short time. Highly sensitive determination of 4-nitrophenol was achieved by linear sweep voltammetry after only 120s extraction. The calibration plot for 4-nitrophenol determination is linear in the range of 5.0×10−8 M–1.0×10−5 M under optimum conditions. The detection limit is 1.1×10−8 M. The proposed method was successfully employed to determine 4-nitrophenol in lake water samples, and the recoveries of the spiked 4-nitrophenol were excellent (92–106%). [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
- View/download PDF
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