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RADIX (Rapid Access Drilling and Ice eXtraction) is a prospecting drilling system that has been designed, realized and tested on polar ice sheets. The goal of RADIX is to provide rapid, deep access for sampling of ice and downhole physical measurements that inform about ice sheet age and history and the integrity of layering. A 20 mm access hole is drilled with a hydraulic coiled tubing system where the tube consists of a plastic hose. The ice cuttings are flushed to the surface in normal circulation, i.e., between the hose and borehole wall, and can be sampled for analysis. After drilling, a dedicated logger with a 15 mm diameter is deployed into the hole for measuring the geometric orientation of the hole, the temperature profile and the dust content in the surrounding ice (optical dust logger). The equipment has been tested and improved during six field projects in Greenland and Antarctica. It is designed to ultimately drill through a 3000 m ice sheet within roughly 1 week. The greatest depth reached so far was 324 m during the last field project at Little Dome C. [ABSTRACT FROM AUTHOR]

The temperature increase at Vostok (Antarctica) from the last glacial maximum to the present warm period is about 8°C based on the deuterium isotope profile. The bore hole temperature (temperature profile in the ice sheet) indicates that the temperature difference may have been much larger, about 15°C. The temperature dependent gas occlusion process is the key to evaluate the two scenarios. Atmospheric air penetrates the porous firn layer of the ice sheet and gets trapped at the firn ice boundary. Consequently the air is younger than the surrounding ice when it gets enclosed in bubbles. This age difference (Δage) between ice and enclosed gas is temperature and accumulation rate dependent. Therefore it is possible to estimate paleotemperatures from a known Δage. We use the linkage between chronologies of CH4 and water isotopes from Byrd station and Vostok to obtain an experimental Δage for Vostok. This experimental Δage is then compared to modeled Δage for the two temperature scenarios. Our results indicate that the temperature reconstruction deduced from the water isotopic composition is the more probable one. [Copyright &y& Elsevier]

We here describe, document, and make available a wide range of data sets used for annual-layer identification in ice cores from DYE-3, GRIP, NGRIP, NEEM, and EGRIP. The data stem from detailed measurements performed both on the main deep cores and shallow cores over more than 40 years using many different setups developed by research groups in several countries and comprise both discrete measurements from cut ice samples and continuous-flow analysis data. The data series were used for counting annual layers 60 000 years back in time during the construction of the Greenland Ice-Core Chronology 2005 (GICC05) and/or the revised GICC21, which currently only reaches 3800 years back. Now that the underlying data are made available (listed in Table 1) we also release the individual annual-layer positions of the GICC05 timescale which are based on these data sets. We hope that the release of the data sets will stimulate further studies of the past climate taking advantage of these highly resolved data series covering a large part of the interior of the Greenland ice sheet. [ABSTRACT FROM AUTHOR]

We here describe, document, and make available a wide range of data sets used for annual layer identification in ice cores from DYE-3, GRIP, NGRIP, NEEM, and EGRIP. The data stem from detailed measurements performed both on the main deep cores and shallow cores over more than forty years using many different setups developed by research groups in several countries, and comprise both discrete measurements from cut ice samples and continuous-flow analysis data. The data series were used for the construction of the Greenland Ice-Core Chronology 2005 (GICC05) and/or the revised GICC21. Now that the underlying data are made available, we also release the individual annual layer positions of the GICC05 time scale which are based on these data sets. We hope that the release of the data sets will stimulate further studies of the past climate taking advantage of these highly resolved data series covering a large part of the interior of the Greenland ice sheet. [ABSTRACT FROM AUTHOR]

Abstract: Ice sheets and deep ice cores have yielded a wealth of paleoclimate information based on continuous dating methods while independent radiometric ages of ice have remained elusive. Here we demonstrate the application of (234U/238U) measurements to dating the EPICA Dome C ice core based on the accumulation of 234U in the ice matrix from recoil during 238U decay out of dust bound within the ice. Measured (234U/238U) activity ratios within the ice generally increase with depth while the surface areas of the dust grains are relatively constant. Using a newly designed device for measuring surface area for small samples, we were able to estimate reliably the recoil efficiency of nuclides from dust to ice. The resulting calculated radiometric ages range between 80ka and 870ka. Measured samples in the upper 3100m fall on the previously published age-depth profile. Samples in the 3200–3255m section show a marked change from 723–870ka to 85ka indicating homogenization of the deep ice prior to resetting of the (234U/238U) age in the basal layers. The mechanism for homogenization is likely enhanced lateral ice flow due to high basal melting and geothermal heat flux. [Copyright &y& Elsevier]

Abstract: Reconstructions of past atmospheric concentrations of greenhouse gases provide unique insight into the biogeochemical cycles and the past radiative forcing in the Earth''s climate system. We present new measurements of atmospheric nitrous oxide along the ice cores of the North Greenland Ice Core Project and Talos Dome sites. Using records of several other ice cores, we are now able to establish the first complete composite nitrous oxide record reaching back to the beginning of the previous interglacial about 140,000yr ago. On the basis of such composite ice core records, we further calculate the radiative forcing of the three most important greenhouse gases carbon dioxide, methane and nitrous oxide during more than a full glacial–interglacial cycle. Nitrous oxide varies in line with climate, reaching very low concentrations of about 200 parts per billion by volume during Marine Isotope Stages 4 and 2, and showing substantial responses to millennial time scale climate variations during the last glacial. A large part of these millennial time scale variations can be explained by parallel changes in the sources of methane and nitrous oxide. However, as revealed by high-resolution measurements covering the Dansgaard/Oeschger events 17 to 15, the evolution of these two greenhouse gases may be decoupled on the centennial time scale. Carbon dioxide and methane concentrations do not reach interglacial levels in the course of millennial time scale climate variations during the last glacial. In contrast, nitrous oxide often reaches interglacial concentrations in response to both, glacial terminations and Dansgaard/Oeschger events. This indicates, from a biogeochemical point of view, similar drivers in both temporal cases. While carbon dioxide and methane concentrations are more strongly controlled by climate changes in high latitudes, nitrous oxide emissions changes may mainly stem from the ocean and/or from soils located at low latitudes. Accordingly, we speculate that high latitudes could play the leading role to trigger glacial terminations. [Copyright &y& Elsevier]

After the NEEM (Greenland) deep ice-core drilling was declared terminated with respect to developing stratigraphic climate reconstructions, efforts were turned toward collecting basal icesheet debris and, if possible, drilling into the bedrock itself. In 2010, several meters of banded debrisrich ice were obtained under normal ice-drilling operations with the NEEM version of the Hans Tausen (HT) drill, but further penetration was obstructed by a rock in the path of the drill head at 2537.36 m. During short campaigns in 2011 and 2012, attempts were made to penetrate further using various reinforced ice cutters mounted on the HT drill head, tailored to cut through rock. These had some success in penetrating coarse material, but produced severely damaged cutters. Additionally a 51 mm diameter diamond cutting tipped rock drill was adapted to fit the NEEM drill. With this device, several additional meters of core containing subglacial sediments, rocks and rock fragments were collected. With these tools 1.39 m of additional material were obtained during the 2011 field season, and 7.1 m during 2012. Subglacial water refreezing into the newly formed borehole hindered further penetration, and the bedrock interface was not reached before final closure of the NEEM Camp. [ABSTRACT FROM AUTHOR]

Ozone-depleting substances emitted through human activities cause large-scale damage to the stratospheric ozone layer, and influence global climate. Consequently, the production of many of these substances has been phased out; prominent examples are the chlorofluorocarbons (CFCs), and their intermediate replacements, the hydrochlorofluorocarbons (HCFCs). So far, seven types of CFC and six types of HCFC have been shown to contribute to stratospheric ozone destruction. Here, we report the detection and quantification of a further three CFCs and one HCFC. We analysed the composition of unpolluted air samples collected in Tasmania between 1978 and 2012, and extracted from deep firn snow in Greenland in 2008, using gas chromatography with mass spectrometric detection. Using the firn data, we show that all four compounds started to emerge in the atmosphere in the 1960s. Two of the compounds continue to accumulate in the atmosphere. We estimate that, before 2012, emissions of all four compounds combined amounted to more than 74,000 tonnes. This is small compared with peak emissions of other CFCs in the 1980s of more than one million tonnes each year. However, the reported emissions are clearly contrary to the intentions behind the Montreal Protocol, and raise questions about the sources of these gases. [ABSTRACT FROM AUTHOR]

Abstract: The atmospheric evolution of eight non-methane hydrocarbons (ethane, acetylene, propane, n-butane, isobutane, n-pentane, isopentane and benzene) and five alkyl nitrates (2-propyl, 2-butyl, 3-methyl-2-butyl and the sum of 2+3-pentyl nitrates) are reconstructed for the latter half of the 20th century based on Arctic firn air measurements. The reconstructed trends of the non-methane hydrocarbons (NMHCs) show increasing concentrations from 1950 to a maximum in 1980 before declining towards the end of last century. These observations provide direct evidence that NMHCs in the northern hemisphere have declined substantially during the period 1980–2001. Benzene concentrations show a smaller increase between 1950 and 1980 than the other NMHCs indicating that additional sources of benzene, other than fossil fuel combustion, were likely important contributors to the benzene budget prior to and during this period. The declining benzene concentrations from 1980 to 2001 would suggest that biomass burning is unlikely to be important in the benzene budget as biomass burning emissions were reportedly increasing over the same period. Methyl and ethyl nitrate show growth patterns in the firn that suggested perturbation by in-situ production from an unidentified mechanism. However, the higher alkyl nitrates show evidence for increasing concentrations from 1950 to maxima in the mid 1990s before decreasing slightly toward the end of the last century. The differing atmospheric evolution of the alkyl nitrates relative to their parent hydrocarbons indicate an increase in their production efficiency per hydrocarbon molecule. Using a steady state analysis of hydrocarbon oxidation and alkyl nitrate production and loss we show that reactive nitrogen oxide (NOx) concentrations in the northern hemisphere have likely increased considerably between 1950 and 2001. [Copyright &y& Elsevier]

Abstract: CO2 measurements on the EPICA (European Project for Ice Coring in Antarctica) DML ice core in depth levels just below the bubble ice–clathrate ice transformation zone (1230–2240m depth) were performed. In the youngest part (1230–1600m), they reveal variations of up to 25ppmv around the mean atmospheric concentration within centimetres, corresponding to a snow deposition interval of a few years. Similar results are found at corresponding depth regions of the Dome C and the Talos Dome ice cores. Since we can exclude all hitherto known processes altering the concentration of CO2 in ice cores, we present a hypothesis about spatial fractionation of air components related to episodically increasing clathrate formation followed by diffusion processes from bubbles to clathrates. This hypothesis is supported by optical line-scan observations and by O2/N2 measurements at the same depth where strong CO2 variations are detected. Below the clathrate formation zone, this small-scale fractionation process is slowly smoothed out, most likely by diffusion, regaining the initial mean atmospheric concentration. Although this process compromises the representativeness of a single CO2 measurement on small ice samples in the clathrate formation zone of an ice core, it does not affect the mean atmospheric CO2 concentration if CO2 values are averaged over a sufficiently long depth scale (>10cm in case of the EPICA DML ice core). [ABSTRACT FROM AUTHOR]

The article presents a study which investigated the temporal and spatial variation of stable-isotope ratios and accumulation rates in the hinterland of Neumayer station in East Antarctica. Different basic parameters were calculated from stable-isotope measurements and characterized using a global meteoric waterline (GMWL). Results showed that the air-sea interaction could influence the dieletrical profiles of the hinterland cores. It concluded that the accumulation rate at the summit of Halvfarryggen acts as a natural barrier for moisture-carrying air masses circulating in the region from east to west.

Abstract: We present records of atmospheric nitrous oxide obtained from the ice cores of the European Project for Ice Coring in Antarctica (EPICA) Dome C and Dronning Maud Land sites shedding light on the concentration of this greenhouse gas on glacial–interglacial and millennial time scales. The extended EPICA Dome C record covers now all interglacials of the last 800,000 years and reveals nitrous oxide variations in concert with climate. Highest mean interglacial nitrous oxide concentrations of 280 parts per billion by volume are observed during the interglacial corresponding to Marine Isotope Stage 11 around 400,000 years before present, at the same time when carbon dioxide and methane reach maximum mean interglacial concentrations. The temperature reconstruction at Dome C indicates colder interglacials between 800,000 and 440,000 years before present compared to the interglacials of the last 440,000 years. In contrast to carbon dioxide and methane, which both respond with lower concentrations at lower temperatures, nitrous oxide shows mean interglacial concentrations of 4–19 parts per billion by volume higher than the preindustrial Holocene value during the interglacials corresponding to Marine Isotope Stage 9–19. At the end of most interglacials, nitrous oxide remains substantially longer on interglacial levels than methane. Nevertheless, nitrous oxide shows millennial-scale variations at the same time as methane throughout the last 800,000 years. We suggest that these millennial-scale variations have been driven by a similar mechanism as the Dansgaard/Oeschger events known from the last glacial. Our data lead to the hypothesis that emissions from the low latitudes drive past variations of the atmospheric nitrous oxide concentration. [Copyright &y& Elsevier]

The atmospheric histories of two potent greenhouse gases, tetrafluoromethane (CF4) and hexafluoroethane (C2F6), have been reconstructed for the 20th century based on firn air measurements from both hemispheres. The reconstructed atmospheric trends show that the mixing ratios of both CF4 and C2F6 have increased during the 20th century by factors of ∼2 and ∼10, respectively. Initially, the increasing mixing ratios coincided with the rise in primary aluminum production. However, a slower atmospheric growth rate for CF4 appears to be evident during the 1990s, which supports recent aluminum industry reports of reduced CF4 emissions. This work illustrates the changing relationship between CF4 and C2F6 that is likely to be largely the result of both reduced emissions from the aluminum industry and faster growing emissions of C2F6 from the semiconductor industry. Measurements of C2F6 in the older firn air indicate a natural background mixing ratio of <0.3 parts per trillion (ppt), demonstrating that natural sources of this gas are negligible. However, CF4 was deduced to have a preindustrial mixing ratio of 34 ± 1 ppt (∼50% of contemporary levels). This is in good agreement with the previous work of Harnisch et al. (18) and provides independent confirmation of their results. As a result of the large global warming potentials of CF4 and C2F6, these results have important implications for radiative forcing calculations. The radiative forcings of CF4 and C2F6 are shown to have increased over the past 50 years to values in 2001 of 4.1 × 10-3 Wm-2 and 7.5 × 10-4 Wm-2, respectively, relative to preindustrial concentrations. These forcings are small compared to present day forcings due to the major greenhouse gases but, if the current trends continue, they will continue to increase since both gases have essentially infinite lifetimes. There is, therefore, a large incentive to reduce perfluorocarbon emissions such that, through the implementation of the Kyoto Protocol, the atmospheric growth rates may decline in the future. [ABSTRACT FROM AUTHOR]

Abstract: Large temperature variations on millennial time scales in Greenland characterised the last ice age. Abrupt warmings, known as Dansgaard–Oeschger (DO) events, can be traced in the δ 18Oice record of Greenland ice cores. However, it has been shown that δ 18Oice is not a direct temperature proxy. Measurements of the isotopic composition of gases trapped in the ice can be used to calibrate the paleothermometer. Here we present a continuous temperature record based on high resolution δ 15N measurements and firn model studies. It covers a sequence of 9 DO events (9–17) during the time period from 38 to 64 kyr BP for which temperature changes of 8 to 15 °C were estimated. The difference between the modern and the glacial δ 18Oice–T relationship can be explained by a combination of source temperature changes and changes in the annual distribution of precipitation. A detailed comparison of the temperature evolution with reconstructions of the atmospheric methane (CH4) concentration shows that CH4 rises lag temperature increases at the onset of DO events by 25 to 70 yr within data resolution. The strong correlation between Greenland temperature and CH4 on millennial and submillennial time scales suggests that variations on these time scales were probably of hemispheric extent. [Copyright &y& Elsevier]

The mechanisms involved in the glacial inception are still poorly constrained due to a lack of high resolution and cross-dated climate records at various locations. Using air isotopic measurements in the recently drilled NorthGRIP ice core, we show that no evidence exists for stratigraphic disturbance of the climate record of the last glacial inception (∼123–100 kyears BP) encompassing Dansgaard–Oeschger events (DO) 25, 24 and 23, even if we lack sufficient resolution to completely rule out disturbance over DO 25. We quantify the rapid surface temperature variability over DO 23 and 24 with associated warmings of 10±2.5 and 16±2.5°C, amplitudes which mimic those observed in full glacial conditions. We use records of δ18O of O2 to propose a common timescale for the NorthGRIP and the Antarctic Vostok ice cores, with a maximum uncertainty of 2,500 years, and to examine the interhemispheric sequence of events over this period. After a synchronous North–South temperature decrease, the onset of rapid events is triggered in the North through DO 25. As for later events, DO 24 and 23 have a clear Antarctic counterpart which does not seem to be the case for the very first abrupt warming (DO 25). This information, when added to intermediate levels of CO2 and to the absence of clear ice rafting associated with DO 25, highlights the uniqueness of this first event, while DO 24 and 23 appear similar to typical full glacial DO events. [ABSTRACT FROM AUTHOR]

A record of atmospheric carbon dioxide (CO[sub 2]) concentrations measured on the EPICA (European Project for Ice Coring in Antarctica) Dome Concordia ice core extends the Vostok CO[sub 2] record back to 650,000 years before the present (yr B.P.). Before 430,000 yr B.P., partial pressure of atmospheric CO[sub 2] lies within the range of 260 and 180 parts per million by volume. This range is almost 30% smaller than that of the last four glacial cycles; however, the apparent sensitivity between deuterium and CO[sub 2] remains stable throughout the six glacial cycles, suggesting that the relationship between CO[sub 2] and Antarctic climate remained rather constant over this interval. [ABSTRACT FROM AUTHOR]

The European Project for Ice Coring in Antarctica Dome C ice core enables us to extend existing records of atmospheric methane (CH[sub 4]) and nitrous oxide (N[sub 2]O) back to 650,000 years before the present. A combined record of CH[sub 4] measured along the Dome C and the Vostok ice cores demonstrates, within the resolution of our measurements, that preindustrial concentrations over Antarctica have not exceeded 773 ± 15 ppbv (parts per billion by volume) during the past 650,000 years. Before 420,000 years ago, when interglacials were cooler, maximum CH[sub 4] concentrations were only about 600 ppbv, similar to lower Holocene values. In contrast, the N[sub 2]O record shows maximum concentrations of 278 = 7 ppbv, slightly higher than early Holocene values. [ABSTRACT FROM AUTHOR]

The most direct method of investigating past variations of the atmospheric CO2 concentration before 1958, when continuous direct atmospheric CO2 measurements started, is the analysis of air extracted from suitable ice cores. Here we present a new detailed CO2 record from the Dronning Maud Land (DML) ice core, drilled in the framework of the European Project for Ice Coring in Antarctica (EPICA) and some new measurements on a previously drilled ice core from the South Pole. The DML CO2 record shows an increase from about 278 to 282 parts per million by volume (ppmv) betweenad1000 andad1200 and a fairly continuous decrease to a mean value of about 277 ppmv aroundad1700. While the new South Pole measurements agree well with DML at the minimum atad1700 they are on average about 2 ppmv lower during the periodad1000–1500. Published measurements from the coastal high-accumulation site Law Dome are considered as very reliable because of the reproducibility of the measurements, high temporal resolution and an accurate time scale. Other Antarctic ice cores could not, or only partly, reproduce the pre-industrial measurements from Law Dome. A comparison of the trends of DML and Law Dome shows a general agreement. However we should be able to rule out co-variations caused by the same artefact. Two possible effects are discussed, first production of CO2 by chemical reactions and second diffusion of dissolved air through the ice matrix into the bubbles. While the first effect cannot be totally excluded, comparison of the Law Dome and DML record shows that dissolved air diffusing to bubbles cannot be responsible for the pre-industrial variation. Therefore, the new record is not a proof of the Law Dome results but the first very strong support from an ice core of the Antarctic plateau. [ABSTRACT FROM AUTHOR]

High resolution records of atmospheric CO2 concentration during the Holocene are obtained from the Dome Concordia and Dronning Maud Land (Antarctica) ice cores. These records confirm that the CO2 concentration varied between 260 and 280 ppmv in the Holocene as measured in the Taylor Dome ice core. However, there are differences in the CO2 records most likely caused by mismatches in timescales. Matching the Taylor Dome timescale to the Dome C timescale by synchronization of CO2 indicates that the accumulation rate at Taylor Dome increased through the Holocene by a factor two and bears little resemblance to the stable isotope record used as a proxy for temperature. This result shows that different locations experienced substantially different accumulation changes, and casts doubt on the often-used assumption that accumulation rate scales with the saturation vapor pressure as a function of temperature, at least for coastal locations. [Copyright &y& Elsevier]