1. CURING BEHAVIOR AND PROPERTIES OF EPOXY RESINS CURED WITH THE DIAMINE HAVING HETEROCYCLIC RING
- Author
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Sakae Kimura, Kenji Marushima, Yoshio Kasashima, Fumihiko Akutsu, Mari Inoki, and Nobuyoshi Daicho
- Subjects
Bisphenol A ,Diglycidyl ether ,Polymers and Plastics ,Chemistry ,General Chemistry ,Epoxy ,chemistry.chemical_compound ,Quinoxaline ,Differential scanning calorimetry ,Diamine ,visual_art ,Polymer chemistry ,Materials Chemistry ,Ceramics and Composites ,visual_art.visual_art_medium ,Organic chemistry ,Thermal stability ,Curing (chemistry) - Abstract
Diamines having heterocyclic ring, 4,5-bis (4-aminophenyl)-2-phenyl-imidazole (BAPI), 4,5-bis(4-aminophenyl)-2-methyloxazole (BAPO) and novel diamine, 2,3-bis(4-aminophenyl)benzo[g]quinoxaline (BABQ) were prepared as curing agents for epoxy resin. Epoxy resins were obtained by curing diglycidyl ether of bisphenol A (DGEBA) with the above diamines. Properties of these DGEBA-diamine systems were studied and compared to that of DGEBA cured with commercially available diamine, 4,4′-diaminodiphenyl sulfone (DDS). On differential scanning calorimetry (DSC), the peaks of exotherms of the mixtures of DGEBA with these diamines having heterocyclic rings were observed at lower temperature and these reactions were completed in shorter time than that of DGEBA with DDS. The epoxy resins cured with these diamines containing heterocyclic ring showed excellent bonding strength even at high temperature and thermal resistance, e.g., DGEBA-BABQ gives greater bonding strengths as 35.1, 30.0, and 26.2 MPa when tested ...
- Published
- 2002
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