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Surface states of topological materials provide extreme electronic states for unconventional superconducting states. CaAg1−xPdxP is an ideal candidate for a nodal-line Dirac semimetal with drumhead surface states and no additional bulk bands. Here, we report that CaAg1−xPdxP has surface states that exhibit unconventional superconductivity (SC) around 1.5 K. Extremely sharp magnetoresistance, tuned by surface-sensitive gating, determines the surface origin of the ultrahigh-mobility “electrons.” The Pd-doping elevates the Fermi level towards the surface states, and as a result, the critical temperature (Tc) is increased up to 1.7 K from 1.2 K for undoped CaAgP. Furthermore, a soft point-contact study at the surface of Pd-doped CaAgP proved the emergence of unconventional SC on the surface. We observed the bell-shaped conductance spectra, a hallmark of the unconventional SC. Ultrahigh mobility carriers derived from the surface flat bands generate a new class of unconventional SC.

Topological insulators with broken time-reversal symmetry and the Fermi level within the magnetic gap at the Dirac cone provides exotic topological magneto-electronic phenomena. Here, we introduce an improved magnetically doped topological insulator, Fe-doped BiSbTe2Se (Fe-BSTS) bulk single crystal, with an ideal Fermi level. Scanning tunneling microscopy and spectroscopy (STM/STS) measurements revealed that the surface state possesses a Dirac cone with the Dirac point just below the Fermi level by 12 meV. The normalized dI/dV spectra suggest a gap opening with Δmag ∼55 meV, resulting in the Fermi level within the opened gap. Ionic-liquid gated-transport measurements also support the Dirac point just below the Fermi level and the presence of the magnetic gap. The chemical potential of the surface state can be fully tuned by ionic-liquid gating, and thus the Fe-doped BSTS provides an ideal platform to investigate exotic quantum topological phenomena.

Topological insulators with broken time-reversal symmetry and the Fermi level within the magnetic gap at the Dirac cone provides exotic topological magneto-electronic phenomena. Here, we introduce an improved magnetically doped topological insulator, Fe-doped BiSbTe

We studied magnetized topological insulator/superconductor junctions with the expectation of unconventional superconductive states holding Majorana fermions induced by superconductive proximity effects on the surface states of magnetized topological insulators (TIs), attached by conventional superconductors. We introduced Fe-doped BiSbTe2Se as an ideal magnetic TI and used the developed junction fabrication process to access the proximity-induced surface superconducting states. The bulk single crystals of the Fe-doped TI showed excellent bulk-insulating properties and ferromagnetism simultaneously at a low temperature. Meanwhile, the fabricated junctions also showed an insulating behavior above 100 K, as well as metallic conduction at a low temperature, which reflects bulk carrier freezing. In addition, we observed a proximity-induced gap structure in the conductance spectra. These results indicate that the junctions using the established materials and process are preferable to observe unconventional superconducting states which are induced via the surface channels of the magnetized TI. We believe that the developed process can be applied for the fabrication of complicated junctions and suites for braiding operations.

ACrX2 (A = Cu, Ag; X = S, Se) compounds have a layered triangular structure similar to that of delafossites. In addition to a large variety of physical and chemical properties found in centrosymmetric delafossites, the broken inversion symmetry along the c-axis in this system leads to the emergence of additional functionalities such as piezoelectric, pyroelectric, and/or nonlinear optical properties. We found that the chemical vapor transport (CVT) technique using CrCl3 was the best growth method for ACrX2. In the case of A = Cu, however, a standard CVT procedure always produced a certain amount of a secondary phase, identified as the CuCr2X4 spinel, which significantly affected magnetic and transport properties. By a modified CVT technique with appropriate heat treatments, pure single crystals of CuCrX2 were successfully grown. The resistivity of ACrX2 was systematically changed by the combinations of A and X atoms. In contrast to metallic selenides, sulfides were confirmed to be insulators with giant an...

The transport properties of a topological Josephson junction fabricated from a magnetically doped topological insulator (TI) were investigated. The conductance spectra of the Nb/Fe-Bi$_2$Te$_2$Se/Nb junction below 1 K showed an unusual trident-shaped zero-bias conductance peak with a tiny peak width of $\sim$ 6 $\mu$V. The central peak of the trident peak presents the dc-Josephson current, and the side peaks may reflect an induced unconventional Cooper pairing. Additionally, the critical currents followed inverse to temperature, which may also reflect the presence of an unconventional proximity effect. Furthermore, microwave irradiation derived a drastic change in the conductance spectra from the peak structure into oscillatory ones, a hallmark of the ac-Josephson supercurrent. The current-phase relation of the ac-Josephson effect under high power radiofrequency-irradiation was found to be 4$\pi$-periodic. The results suggest that the junction based on magnetically doped 3D TIs may realize an unconventional Cooper pairing, thus enabling access to the basic physics of Majorana bound states and unconventional superconductivity., Comment: 19 pages, 6 figures