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This work assessed some properties and effects of biocoal briquettes on environmental pollution compared with utilising coal alone. A mixture of coal fines and rice husks was prepared, with cassava starch gel as a binder, before compaction in a briquetting machine and drying with a solar dryer. Samples of the coal fines, rice husk, cassava flour and briquettes were analysed for their elemental and oxide concentrations via an energy-dispersive X-ray fluorescence analyser. The heat fuels were analysed for their thermal behaviour via thermogravimetric analyser (TGA), whereas the specific surface area, pore size and pore volume were determined using a Brunner–Emmett–Teller (BET) analyser. The conversion of the tested coals to biocoal briquettes resulted in a reduction in the level of arsenic in the briquettes. Additionally, the sulphur level decreased from 1.96 to 1.11% in the Okobo-Enjema briquettes and from 1.78 to 0.90% in the Onyeama briquettes. However, the levels of manganese increased from 0.04 to 0.22% in the Okobo-Enjema briquettes and from 0.04 to 0.21% in the Onyeama briquettes. Thermogravimetric analysis at different heating rates revealed that derivative weight loss increased with increasing heating rate, from 4.4% at 10 °C/min to 5.5% at 20 °C/min. BET analysis revealed that the briquettes had larger pore diameters, volumes and specific surface areas than did the coal samples. The coal samples have greater propensity to pollute the environment as the amount of potentially hazardous elements in the samples is greater than in their biocoal briquettes. [ABSTRACT FROM AUTHOR]

Non-symmetric heat flux distributions in terms of gravity in solar collector tubes influence buoyancy-driven secondary flow which has an impact on the associated heat transfer and pressure drop performance. In this study the influence of the asymmetry angle (0°, 20°, 30° and 40°) with regard to gravity for non-uniform heat flux boundaries in a horizontal circular tube was investigated numerically. A stainless steel tube with an inner diameter of 62.68 mm, a wall thickness of 5.16 mm, and a length of 10 m was considered for water inlet temperatures ranging from 290 K to 360 K and inlet Reynolds numbers ranging from 130 to 2000. Conjugate heat transfer was modelled for different sinusoidal type outer surface heat flux distributions with a base-level incident heat flux intensity of 7.1 kW/m2. It was found that average internal heat transfer coefficients increased with the circumferential span of the heat flux distribution. Average internal and axial local heat transfer coefficients and overall friction factors were at their highest for symmetrical heat flux cases (gravity at 0º) and lower for asymmetric cases. The internal heat transfer coefficients also increased with the inlet fluid temperature and decreased with an increase in the external heat loss transfer coefficient. Friction factors decreased with an increase in fluid inlet temperature or an increase in the external heat loss transfer coefficients of the tube model. [ABSTRACT FROM AUTHOR]