3,183 results on '"Oils chemistry"'
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2. Enhanced demulsification of alkaline-surfactant-polymer flooding O/W emulsion by multibranched polyether-polyquaternium based on the size effect of oil droplets.
- Author
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Sun H and Li X
- Subjects
- Oils chemistry, Water chemistry, Adsorption, Water Pollutants, Chemical chemistry, Particle Size, Molecular Dynamics Simulation, Surface-Active Agents chemistry, Polymers chemistry, Emulsions chemistry
- Abstract
In the alkaline-surfactant-polymer flooding emulsion, oil droplets with various sizes exhibited different interfacial properties, resulting in different stabilization and destabilization behaviors. In view of this, it is expected to achieve outstanding oil-water separation efficiency by screening targeted demulsifier for oil droplets with different size ranges (0-1, 1-5 and 5-10 μm). Based on the size effect of oil droplets, a series of multibranched polyether-polyquaternium demulsifiers that integrated different charge neutralization and interfacial displacement functionalities were designed by regulating the cationicity and EO:PO ratios. As a result, the most effective polyether-polyquaternium variant for each size range of oil droplet was screened out. By employing these three selected polyether-polyquaternium variants in a sequential batch demulsification test, the maximum demulsification efficiency of 95.1% was obtained, which was much higher than that using a single polyether-polyquaternium variant (82.5%, 80.5% and 83.8%). The adsorption behaviors of polyether-polyquaternium variants on the oil/water interface were investigated by the molecular dynamics simulation. Moreover, the interfacial properties and oil droplet size variations during the demulsification process were monitored, so as explore the demulsification mechanism. This demulsification protocol based on the size effect of oil droplets with its excellent oil-water separation performance offered significant technical promise for the emulsified oil wastewater disposal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
3. A mechanistic kinetic model for lipid oxidation in Tween 20-stabilized O/W emulsions.
- Author
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Nguyen KA, Boerkamp VJP, van Duynhoven JPM, Dubbelboer A, Hennebelle M, and Wierenga PA
- Subjects
- Kinetics, Water chemistry, Particle Size, Models, Chemical, Oils chemistry, Emulsions chemistry, Oxidation-Reduction, Polysorbates chemistry, Lipids chemistry
- Abstract
Models predicting lipid oxidation in oil-in-water (O/W) emulsions are a requirement for developing effective antioxidant solutions. Existing models do, however, not include explicit equations that account for composition and structural features of O/W emulsions. To bridge this gap, a mechanistic kinetic model for lipid oxidation in emulsions is presented, describing the emulsion as a one-dimensional three phase (headspace, water, and oil) system. Variation in oil droplet sizes, overall surface area of oil/water interface, oxidation of emulsifiers, and the presence of catalytic transition metals were accounted for. For adequate predictions, the overall surface area of oil/water interface needs to be determined from the droplet size distribution obtained by dynamic and static light scattering (DLS, SLS). The kinetic model predicted well the formation of oxidation products in both mono- and polydisperse emulsions, with and without presence of catalytic transition metals., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Arend Dubbelboer and John P.M. Van Duynhoven are employed by companies that manufacture and market oil based food products., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)
- Published
- 2024
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4. Performance evaluation of nano-graphene lubricating oil with high dispersion and low viscosity used in diesel engines.
- Author
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Kuang X, Yang X, Bian H, Kuang R, Hu N, and Li S
- Subjects
- Viscosity, Gasoline analysis, Nanostructures chemistry, Oils chemistry, Lubrication, Vehicle Emissions analysis, Graphite chemistry, Lubricants chemistry
- Abstract
The basic tribological experiments have reported that nano-graphene lubricating oil has excellent anti-friction and anti-wear properties, which has been widely concerned. However, the real anti-friction effect of nano-graphene lubricating oil and its impact on engine power performance, economic performance and emission performance remain to be proved. This has seriously hindered the popularization and application of nano-graphene lubricating oil in the engine field. In this paper, nano-graphene powder was chemically grafted to prepare nano-graphene lubricating oil with high dispersion stability. The influence of nano-graphene on physicochemical properties of lubricating oil was studied, and the influence of nano-graphene on engine power performance, economic performance and emission performance was explored. The results show that after modification, the dispersion of nano-graphene in lubricating oil is improved. Compared with pure lubricating oil, the addition of nano-graphene makes the kinematic viscosity of lubricating oil slightly lower, and has little effect on the density, flash point, pour point and total acid value of lubricating oil. The reversed towing torque of nano-graphene lubricating oil is reduced by 1.82-5.53%, indicating that the friction loss decreases. The specific fuel consumption of the engine is reduced, which indicates that the fuel economic performance is improved. Engine HC+NOX, CH4, CO2 emissions do not change much, but particulate matter (PM) emissions increase by 8.85%. The quantity concentration of nuclear particles, accumulated particles and total particles of nano-graphene lubricating oil are significantly higher than that of pure lubricating oil. And the increase of the quantity concentration of accumulated particles is more obvious than that of nuclear particles, and the larger the load, the more obvious this phenomenon. In order to apply nano-graphene lubricating oil to the engine, it is also necessary to further study its impact on the post-processing system, adjust the control strategy of the post-processing system and then test and calibrate., Competing Interests: The authors have declared that no competing interests exist., (Copyright: © 2024 Kuang et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.)
- Published
- 2024
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5. Hydrophobic deep eutectic solvent (HDES) as oil phase in lipid-based drug formulations.
- Author
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Panbachi S, Beranek J, and Kuentz M
- Subjects
- Polysorbates chemistry, Lauric Acids chemistry, Chemistry, Pharmaceutical methods, Sulfonamides chemistry, Sulfonamides administration & dosage, Oils chemistry, Hydrophobic and Hydrophilic Interactions, Solvents chemistry, Surface-Active Agents chemistry, Solubility, Drug Liberation, Lipids chemistry, Molecular Dynamics Simulation, Drug Compounding methods
- Abstract
There is increasing pharmaceutical interest in deep eutectic solvents not only as a green alternative to organic solvents in drug manufacturing, but also as liquid formulation for drug delivery. The present work introduces a hydrophobic deep eutectic solvent (HDES) to the field of lipid-based formulations (LBF). Phase behavior of a mixture with 2:1 M ratio of decanoic- to dodecanoic acid was studied experimentally and described by thermodynamic modelling. Venetoclax was selected as a hydrophobic model drug and studied by atomistic molecular dynamics simulations of the mixtures. As a result, valuable molecular insights were gained into the interaction networks between the different components. Moreover, experimentally the HDES showed greatly enhanced drug solubilization compared to conventional glyceride-based vehicles, but aqueous dispersion behavior was limited. Hence surfactants were studied for their ability to improve aqueous dispersion and addition of Tween 80 resulted in lowest droplet sizes and high in vitro drug release. In conclusion, the combination of HDES with surfactant(s) provides a novel LBF with high pharmaceutical potential. However, the components must be finely balanced to keep the integrity of the solubilizing HDES, while enabling sufficient dispersion and drug release., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.)
- Published
- 2024
- Full Text
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6. Construction of CS-SDAEM long-chain polysaccharide derivative on TA@CNTs coated PVDF membrane with effective oil-water emulsion purification and low contamination rate.
- Author
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Zhao J, Liu H, Zhao Y, Qi Y, Wang R, Lv Z, Yu Y, Sun S, Wang Y, and Xie A
- Subjects
- Tannins chemistry, Polysaccharides chemistry, Water chemistry, Wastewater chemistry, Oils chemistry, Hydrophobic and Hydrophilic Interactions, Filtration methods, Fluorocarbon Polymers, Membranes, Artificial, Water Purification methods, Chitosan chemistry, Emulsions, Polyvinyls chemistry, Nanotubes, Carbon chemistry
- Abstract
Currently, the most effective way to improve the anti-fouling performance of water treatment separation membrane is to enhance the hydrophilicity of the membrane surface, but it can still cause contamination, leading to the occurrence of flux reduction. The construction of a strong hydration layer to resist wastewater contamination is still a challenging task. In this study, a defect-free hydration layer barrier was achieved by grafting chitosan polysaccharide derivatives (CS-SDAEM) on the membrane, which achieved in effective fouling prevention and low flux decline rate. A layer of tannic acid-coated carbon nanotubes (TA@CNTs) has been uniformly deposited on the commercial PVDF membrane so that the surface was rich in -COOH groups, providing sufficient reaction sites. These reactive groups facilitate the grafting of amphiphilic polymers onto the membrane. This modification strategy achieved in enhancing the antifouling performance. The modified membrane achieved low contamination rate with DR of 16.9 % for wastewater filtration, and the flux recovery rate was above 95 % with PWF of 1100 (L·m
-2 ·h-1 ). The membrane had excellent anti-fouling performance, which provided a new route for the future development of water treatment membrane., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
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7. Extending the Lifetime of Frying Oil through Optimization of Fryer Cleaning.
- Author
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Ohyagi N, Watanabe Y, Sugita-Konishi Y, Morita T, and Mochizuki M
- Subjects
- Restaurants, Food Quality, Oils chemistry, Time Factors, Cooking methods, Detergents chemistry
- Abstract
With increases in consumer demand for fried foods in Japan over the last several decades, the consumption of frying oil has also steadily increased. Fryers used in restaurants to cook large quantities of food are typically cleaned using neutral kitchen detergents at the end of the day after removing the oil from the tank. However, significant amounts of debris can remain in the fryer after cleaning, possibly accelerating oil deterioration and thus reducing the quality of the fried foods. In this study, debris obtained from fryer tanks used in actual restaurants was assessed using scanning electron microscopy-energy dispersive X-ray spectroscopy together with Fourier transform infrared spectroscopy, and were determined to comprise polymerized oil and carbonized organic matter. Experiments using artificially prepared debris confirmed that these materials increased the acid value (AV) of frying oil. Trials in two restaurants serving similar amounts of fried chicken, French fries and doughnuts examined the effects of cleaning the fryer with either an alkaline detergent or a neutral kitchen detergent on debris removal and oil life. The alkaline detergent was found to completely remove debris while the neutral detergent left significant amounts of debris. After cleaning, the fryers were operated with new oil as usual and the deterioration of this oil was monitored by assessing the color difference, AV, carbonyl value and peroxide value. These indices increased 1.3 to 2.0 times faster in the case that the neutral kitchen detergent was used, suggesting that cleaning fryer tanks with an alkaline detergent could contribute to extending the lifetime of frying oil, reducing food losses and thus achieving sustainable development goals.
- Published
- 2024
- Full Text
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8. Synthesis of aminopropyl triethoxysilane/melamine incorporated superhydrophilic membranes for simultaneous removal of oil, metals, and Salt ions from produced water.
- Author
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Abdullahi AA and Saleh TA
- Subjects
- Metals chemistry, Oils chemistry, Propylamines chemistry, Salts chemistry, Hydrophobic and Hydrophilic Interactions, Ions, Polyvinyls chemistry, Water Purification methods, Membranes, Artificial, Silanes chemistry, Water Pollutants, Chemical chemistry
- Abstract
Water treatment has turned out to be more important in most societies due to the expansion of most economies and to advancement of industrialization. Developing efficient materials and technologies for water treatment is of high interest. Thin film nanocomposite membranes are regarded as the most effective membranes available for salts, hydrocarbon, and environmental pollutants removal. These membranes improve productivity while using less energy than conventional asymmetric membranes. Here, the polyvinylidene fluoride (PVDF) membranes have been successfully modified via dip single-step coating by silica-aminopropyl triethoxysilane/trimesic acid/melamine nanocomposite (Si-APTES-TA-MM). The developed membranes were evaluated for separating the emulsified oil/water mixture, the surface wettability of the membrane materials is therefore essential. During the conditioning step, that is when the freshwater was introduced, the prepared membrane reached a flux of about 27.77 L m
-2 h-1 . However, when the contaminated water was introduced, the flux reached 18 L m-2 h-1 , alongside an applied pressure of 400 kPa. Interestingly, during the first 8 h of the filtration test, the membrane showed 90 % rejection for ions including Mg2+ , and SO4 2- and ≈100 % for organic pollutants including pentane, isooctane, toluene, and hexadecane. Also, the membrane showed 98 % rejection for heavy metals including strontium, lead, and cobalt ions. As per the results, the membrane could be recommended as a promising candidate to be used for a mixture of salt ions, hydrocarbons, and mixtures of heavy metals from wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)- Published
- 2024
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9. Fabrication of water/oil-resistant paper by nanocellulose stabilized Pickering emulsion and chitosan.
- Author
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Liu J, Chen X, and Wang H
- Subjects
- Hydrophobic and Hydrophilic Interactions, Tensile Strength, Nanofibers chemistry, Chitosan chemistry, Cellulose chemistry, Emulsions chemistry, Water chemistry, Paper, Oils chemistry
- Abstract
Developing plastic/fluorine/silicon-free and degradable water/oil-resistant coatings for paper-based packaging materials to replace disposable plastic products is a very effective way to solve the problem of 'white pollution' or microplastics pollution. A novel water/oil-resistant coating was developed by alkyl ketene dimer (AKD)-based Pickering emulsion and chitosan in this work. Cellulose nanofibrils (CNF) were used as a stabilizing solid for AKD emulsion, with the addition of chitosan as an oil-resistance agent. The coating provides excellent hydrophobicity, water/oil resistance as well as good barrier properties. The water contact angle was as high as 130° and the minimum Cobb60 value was 5.7 g/m
2 , which was attributed to the hydrophobicity of AKD. In addition, the kit rating reached maximum 12/12 at coating weight of 8.26 g/m2 and the water vapor transmittance rate (WVTR) was reduced to 153.4 g/(m2 ⋅day) at the coating weight of 10.50 g/m2 . The tensile strength of the paper was increased from 28.1 to 43.6 MPa after coating. Overall, this coating can effectively improve the performance of paper-based materials, which may play an important role in the process of replacing disposable plastic packaging with paper-based materials., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
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10. Development of xanthan gum intelligent oil-in-water ink and its application in pork freshness preservation.
- Author
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Song A, Wu Y, Li H, and Li C
- Subjects
- Animals, Swine, Rheology, Viscosity, Food Preservation methods, Particle Size, Emulsions chemistry, Food Packaging methods, Pork Meat analysis, Soybean Oil chemistry, Oils chemistry, Polysaccharides, Bacterial chemistry, Ink, Water chemistry
- Abstract
To optimize the stability of oil-based inks and ensure their wide application in freshness indication, new natural indicator inks were prepared using a stable oil-in-water structure. This study selected natural Lycium ruthenicum anthocyanin as the dye and glucose as the pigment carrier. Soybean oil was introduced as a linker and xanthan gum as a thickener, and an oil-in-water ink with the function of freshness indication was successfully developed. In ensuring the safety of ink labels for use on food packaging, particular attention is paid to the origin and properties of the materials used. All ingredients are of food-grade or bio-friendly provenance, thereby ensuring the safety of the product when in direct contact with food. We measured the viscosity, particle size and fineness of the ink for micro characterization and evaluated its macro printing performance by its printing effect on A4 paper. According to the experimental results, when the water-oil ratio of the ink is 10:5, the average particle size of the emulsion system is 822.83 nm, and the fineness reaches 5 μm. These values are relatively low, which indicates that the stability of the ink system is high at this time, and the ink shows excellent rheological and printing characteristics. With this water-to-oil ratio, the ink can show the best results when printed on A4 paper, clearly displaying image details. In addition, in fresh pork applications, inks with a 10: 5 water-to-oil ratio provide an accurate and highly sensitive indication of the freshness of pork. When the freshness of the pork changes, the ink color responds promptly. This high sensitivity makes the ink ideal for use as a food freshness indication tool, providing consumers with an intuitive and reliable reference for pork freshness. As a further innovation, combining this ink-printed label with a WeChat app not only allows consumers to know the freshness of the food in real-time but also tracks the supply chain information of the food, providing a more comprehensive application prospect for freshness-indicating products., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. This work is original research and the data presented in the manuscript has not been published elsewhere., (Copyright © 2024 Elsevier B.V. All rights reserved.)
- Published
- 2024
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11. Enhancing oil-water emulsion separation via synergistic filtration using graphene oxide-silver oxide nanocomposite-embedded polyethersulfone membrane.
- Author
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Goyat R, Singh J, Umar A, Saharan Y, Ibrahim AA, Akbar S, and Baskoutas S
- Subjects
- Silver Compounds chemistry, Oils chemistry, Wastewater chemistry, Water chemistry, Hydrophobic and Hydrophilic Interactions, Oxides, Graphite chemistry, Nanocomposites chemistry, Sulfones chemistry, Polymers chemistry, Membranes, Artificial, Filtration methods, Emulsions
- Abstract
This study introduces an innovative approach for enhancing oil-water emulsion separation using a polyethersulfone (PES) membrane embedded with a nanocomposite of graphene oxide (GO) and silver oxide (AgO). The composite membrane, incorporating PES and polyvinyl chloride (PVC), demonstrates improved hydrophilicity, structural integrity and resistance to fouling. Physicochemical characterization confirms successful integration of GO and AgO, leading to increased tensile strength, porosity and hydrophilicity. Filtration tests reveal substantial improvements in separating various oils from contaminated wastewater, with the composite membrane exhibiting superior efficiency and reusability compared to pristine PES membranes. This research contributes to the development of environmentally friendly oil-water separation methods with broad industrial applications., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.
- Published
- 2024
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12. Impact of Air Bubbles on the Saltiness Perception of NaCl-Loaded Oleogel-Stabilized Water-in-Oil Emulsions.
- Author
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Bai C, Wang L, Li B, McClements DJ, Liu S, and Li Y
- Subjects
- Humans, Sodium Chloride chemistry, Monoglycerides chemistry, Taste, Oils chemistry, Air, Male, Emulsions chemistry, Organic Chemicals chemistry, Water chemistry
- Abstract
Reducing salt intake without affecting the saltiness perception remains a great challenge for the food industry. Herein, the demulsification of water droplets and air bubbles was controlled to modulate the release of sodium from oleogel-stabilized water-in-oil emulsions (OGEs) stabilized by monoglyceride crystals. The effect of monoglycerides with carbon chain length (glycerol monolaurate-GML, glyceryl monostearate-GMS, and glycerol monopalmitate-GMP) and homogenization methods (hand-shaking or high-speed blender) on sodium release and saltiness was investigated by in vitro and in vivo oral processing tests. Milky-white stable emulsions were formed with both water droplets and air bubbles dispersing in the oil phase, regardless of the selected homogenization methods. Air bubbles were more unstable than water droplets during oral digestion. GML OGEs with more and larger air bubbles and the lowest hardness exhibited the highest sodium release rate and the strongest saltiness, independent of homogenization methods. The balance between air bubbles and water droplets in the GMS and GMP OGEs caused slower sodium release and lower saltiness. Overall, the presence of air bubbles in NaCl-loaded W/O oleogel-based emulsions was shown to have important implications for tailoring their sodium release and saltiness.
- Published
- 2024
- Full Text
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13. Prolonged joint cavity retention of tranexamic acid achieved by a solid-in-oil-in-gel system: A preliminary study.
- Author
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Yu Y, Ren S, Shang L, Zuo B, Li G, Gou J, and Zhang W
- Subjects
- Animals, Male, Polyethylene Glycols chemistry, Particle Size, Rats, Sprague-Dawley, Gels, Delayed-Action Preparations, Drug Liberation, Oils chemistry, Rats, Polyesters chemistry, Drug Carriers chemistry, Polyglactin 910, Tranexamic Acid administration & dosage, Tranexamic Acid pharmacokinetics, Tranexamic Acid chemistry, Antifibrinolytic Agents administration & dosage, Antifibrinolytic Agents chemistry, Antifibrinolytic Agents pharmacokinetics, Emulsions, Nanoparticles chemistry
- Abstract
Tranexamic acid (TXA) is an anti-fibrinolysis agent widely used in postoperative blood loss management. As a highly water-soluble drug, TXA is suffering from rapid clearance from the action site, therefore, large amount of drug is required when administered either by intravenously or topically. In this study, a TXA preparation with prolonged action site residence was designed using the nano-micro strategy. TXA nanoparticles were dispersed in oil by emulsification followed by lyophilization to give a solid-in-oil suspension, which was used as the oil phase for the preparation of TXA-loaded solid-in-oil-in-water (TXA@S/O/W) system. The particle size of TXA in oil was 207.4 ± 13.50 nm, and the particle size of TXA@S/O/W was 40.5 μm. The emulsion-in-gel system (TXA@S/O/G) was prepared by dispersing TXA@S/O/W in water solution of PLGA-b-PEG-b-PLGA (PPP). And its gelling temperature was determined to be 26.6 ℃ by a rheometer. Sustained drug release was achieved by TXA@S/O/G with 72.85 ± 7.52 % of TXA released at 120 h. Formulation retention at the joint cavity was studied by live imaging, and the fluorescent signals dropped gradually during one week. Drug escape from the injection site via drainage and absorption was investigated by a self-made device and plasma TXA concentration determination, respectively. TXA@S/O/G showed the least drug drainage during test, while more than 70 % of drug was drained in TXA@S/O/W group and TXA solution group. Besides, low yet steady plasma TXA concentration (less than 400 ng/mL) was found after injecting TXA@S/O/G into rat knees at a dosage of 2.5 mg/kg, which was much lower than those of TXA dissolved in PPP gel or TXA solution. In conclusion, sustained drug release as well as prolonged action site retention were simultaneously achieved by the designed TXA@S/O/G system. More importantly, due to the steady plasma concentration, this strategy could be further applied to other highly water-soluble drugs with needs on sustained plasma exposure., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)
- Published
- 2024
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14. Optical tuning of copolymer-in-oil tissue-mimicking materials for multispectral photoacoustic imaging.
- Author
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Khodaverdi A, Cinthio M, Reistad E, Erlöv T, Malmsjö M, Zackrisson S, and Reistad N
- Subjects
- Mineral Oil chemistry, Ink, Biomimetic Materials chemistry, Humans, Turpentine chemistry, Oils chemistry, Photoacoustic Techniques methods, Phantoms, Imaging, Polymers chemistry
- Abstract
Objective . The availability of tissue-mimicking materials (TMMs) for manufacturing high-quality phantoms is crucial for standardization, evaluating novel quantitative approaches, and clinically translating new imaging modalities, such as photoacoustic imaging (PAI). Recently, a gel comprising the copolymer styrene-ethylene/butylene-styrene (SEBS) in mineral oil has shown significant potential as TMM due to its optical and acoustic properties akin to soft tissue. We propose using artists' oil-based inks dissolved and diluted in balsam turpentine to tune the optical properties. Approach . A TMM was fabricated by mixing a SEBS copolymer and mineral oil, supplemented with additives to tune its optical absorption and scattering properties independently. A systematic investigation of the tuning accuracies and relationships between concentrations of oil-based pigments and optical absorption properties of the TMM across visible and near-infrared wavelengths using collimated transmission spectroscopy was conducted. The photoacoustic spectrum of various oil-based inks was studied to analyze the effect of increasing concentration and depth. Main results . Artists' oil-based inks dissolved in turpentine proved effective as additives to tune the optical absorption properties of mineral oil SEBS-gel with high accuracy. The TMMs demonstrated long-term stability and suitability for producing phantoms with desired optical absorption properties for PAI studies. Significance . The findings, including tuning of optical absorption and spectral shape, suggest that this TMM facilitates the development of more sophisticated phantoms of arbitrary shapes. This approach holds promise for advancing the development of PAI, including investigation of the spectral coloring effect. In addition, it can potentially aid in the development and clinical translation of ultrasound optical tomography., (Creative Commons Attribution license.)
- Published
- 2024
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15. MIL-53(Al)-oil/water emulsion composite as an adjuvant promotes immune responses to an inactivated pseudorabies virus vaccine in mice and pigs.
- Author
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Yang B, Nie J, Guo A, Xie N, Cui Y, Sun W, Li Y, Li X, Wu Y, and Liu Y
- Subjects
- Animals, Mice, Swine, Herpesvirus 1, Suid immunology, Pseudorabies Vaccines immunology, Mice, Inbred BALB C, Oils chemistry, Female, Water chemistry, Vaccines, Inactivated immunology, Pseudorabies prevention & control, Pseudorabies immunology, Antibodies, Viral blood, Antibodies, Viral immunology, Cytokines metabolism, Adjuvants, Immunologic pharmacology, Emulsions chemistry
- Abstract
Although vaccination with inactivated vaccines is a popular preventive method against pseudorabies virus (PRV) infection, inactivated vaccines have poor protection efficiency because of their weak immunogenicity. The development of an effective adjuvant is urgently needed to improve the efficacy of inactivated PRV vaccines. In this study, a promising nanocomposite adjuvant named as MIL@A-SW01-C was developed by combining polyacrylic acid-coated metal-organic framework MIL-53(Al) (MIL@A) and squalene (oil)-in-water emulsion (SW01) and then mixing it with a carbomer solution. One part of the MIL@A was loaded onto the oil/water interface of SW01 emulsion via hydrophobic interaction and coordination, while another part was dispersed in the continuous water phase using carbomer. MIL@A-SW01-C showed good biocompatibility, high PRV (antigen)-loading capability, and sustained antigen release. Furthermore, the MIL@A-SW01-C adjuvanted PRV vaccine induced high specific serum antibody titers, increased splenocyte proliferation and cytokine secretion, and a more balanced Th1/Th2 immune response compared with commercial adjuvants, such as alum and biphasic 201. In the mouse challenge experiment, two- and one-shot vaccinations resulted in survival rates of 73.3 % and 86.7 %, respectively. After one-shot vaccination, the host animal pigs were also challenged with wild PRV. A protection rate of 100 % was achieved, which was much higher than that observed with commercial adjuvants. This study not only establishes the superiority of MIL@A-SW01-C composite nanoadjuvant for inactivated PRV vaccine in mice and pigs but also presents an effective method for developing promising nanoadjuvants. STATEMENT OF SIGNIFICANCE: We have developed a nanocomposite of MIL-53(Al) and oil-in-water emulsion (MIL@A-SW01-C) as a promising adjuvant for the inactivated PRV vaccines. MIL@A-SW01-C has good biocompatibility, high PRV (antigen) loading capability, and prolonged antigen release. The developed nanoadjuvant induced much higher specific IgG antibody titers, increased splenocyte proliferation and cytokine secretion, and a more balanced Th1/Th2 immune response than commercial adjuvants alum and biphasic 201. In mouse challenge experiments, survival rates of 73.3 % and 86.7 % were achieved from two-shot and one-shot vaccinations, respectively. At the same time, a protection rate of 100 % was achieved with the host animal pigs challenged with wild PRV., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.)
- Published
- 2024
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16. Intact NMR Approach Quickly Reveals Synchronized Microstructural Changes in Oil-in-Water Nanoemulsion Formulations.
- Author
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Wang D, Li J, and Chen K
- Subjects
- Surface-Active Agents chemistry, Fluprednisolone chemistry, Fluprednisolone analogs & derivatives, Particle Size, Drug Compounding methods, Nanoparticles chemistry, Chemistry, Pharmaceutical methods, Emulsions, Magnetic Resonance Spectroscopy methods, Water chemistry, Oils chemistry
- Abstract
A soft-core oil-in-water (o/w) nanoemulsion (NE) is composed of nanometer (nm) sized oil droplets, stabilized by a surfactant layer and dispersed in a continuous bulky water phase. Characterization of the o/w NE molecule arrangements non-invasively, particularly the drug phase distribution (DPD) and its correlation to oil globule size (OGS), remains a challenge. Here we demonstrated the analytical methods of intact
19 F Nuclear Magnetic Resonance (NMR) and1 H diffusion ordered spectroscopy (DOSY) NMR for their specificity in measuring DPD and OGS, respectively, on three NE formulations containing the active ingredient difluprednate (DFPN) at the same concentration. The results illustrated synchronized molecular rearrangement reflected in the DPD and OGS upon alterations in formulation. Addition of surfactant resulted in a higher DPD in the surfactant layer, and concomitantly smaller OGS. Mechanic perturbation converted most of the NE globules to the smaller thermodynamically stable microemulsion (ME) globules, changing both DPD and OGS to ME phase. These microstructure changes were not observed using 1D1 H NMR; and dynamic light scattering (DLS) was only sensitive to OGS of ME globule in mechanically perturbed formulation. Collectively, the study illustrated the specificity and essential role of intact NMR methods in measuring the critical microstructure attributes of soft-core NE systems quickly, accurately, and non-invasively. Therefore, the selected NMR approach can be a unique diagnostic tool of molecular microstructure or Q3 property in o/w NE formulation development, and quality assurance after manufacture process or excipient component changes., (© 2024. This is a U.S. Government work and not under copyright protection in the US; foreign copyright protection may apply.)- Published
- 2024
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17. Understanding Stabilization of Oil-in-Water Emulsions with Pea Protein─Studies of Structure and Properties.
- Author
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Olsmats E and Rennie AR
- Subjects
- Hydrogen-Ion Concentration, Particle Size, Viscosity, Pisum sativum chemistry, Emulsions chemistry, Water chemistry, Pea Proteins chemistry, Oils chemistry
- Abstract
This study investigates the stability and structure of oil-in-water emulsions stabilized by pea protein. Of the wide range of emulsion compositions explored, a region of stability at a minimum of 5% w/v pea protein and 30-50% v/v oil was determined. This pea protein concentration is more than what is needed to form a layer covering the interface. X-ray scattering revealed a thick, dense protein layer at the interface as well as hydrated protein dispersed in the continuous phase. Shear-thinning behavior was observed, and the high viscosity in combination with the thick protein layer at the interface creates a good stability against creaming and coalescence. Emulsions in a pH range from acidic to neutral were studied, and the overall stability was observed to be broadly similar independently of pH. Size measurements revealed polydisperse protein particles. The emulsion droplets are also very polydisperse. Apart from understanding pea protein-stabilized emulsions in particular, insights are gained about protein stabilization in general. Knowledge of the location and the role of the different components in the pea protein material suggests that properties such as viscosity and stability can be tailored for various applications, including food and nutraceutical products.
- Published
- 2024
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18. Multiphase Under-Liquid Biofabrication With Living Soft Matter: A Route to Customize Functional Architectures With Microbial Nanocellulose.
- Author
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Lu Y, Chun Y, Shi X, Wang D, Ahmadijokani F, and Rojas OJ
- Subjects
- Nanostructures chemistry, Hydrogels chemistry, Biofilms, Porosity, Oils chemistry, Cellulose chemistry
- Abstract
The growth of aerobic microbes at air-water interfaces typically leads to biofilm formation. Herein, a fermentative alternative that relies on oil-water interfaces to support bacterial activity and aerotaxis is introduced. The process uses under-liquid biofabrication by structuring bacterial nanocellulose (BNC) to achieve tailorable architectures. Cellulose productivity in static conditions is first evaluated using sets of oil homologues, classified in order of polarity. The oils are shown for their ability to sustain bacterial growth and BNC production according to air transfer and solubilization, both of which impact the physiochemical properties of the produced biofilms. The latter are investigated in terms of their morphological (fibril size and network density), structural (crystallinity) and physical-mechanical (surface area and strength) features. The introduced under-liquid biofabrication is demonstrated for the generation of BNC-based macroscale architectures and compartmentalized soft matter. This can be accomplished following three different routes, namely, 3D under-liquid networking (multi-layer hydrogels/composites), emulsion templating (capsules, emulgels, porous materials), and anisotropic layering (Janus membranes). Overall, the proposed platform combines living matter and multi-phase systems as a robust option for material development with relevance in biomedicine, soft robotics, and bioremediation, among others., (© 2024 The Authors. Advanced Materials published by Wiley‐VCH GmbH.)
- Published
- 2024
- Full Text
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19. Different interfaces for stabilizing liquid-liquid, liquid-gel and gel-gel emulsions: Design, comparison, and challenges.
- Author
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Lu Y, Zhang Y, Zhang R, Gao Y, Miao S, and Mao L
- Subjects
- Water chemistry, Oils chemistry, Emulsions chemistry, Gels chemistry
- Abstract
Interfaces play essential roles in the stability and functions of emulsion systems. The quick development of novel emulsion systems (e.g., water-water emulsions, water-oleogel emulsions, hydrogel-oleogel emulsions) has brought great progress in interfacial engineering. These new interfaces, which are different from the traditional water-oil interfaces, and are also different from each other, have widened the applications of food emulsions, and also brought in challenges to stabilize the emulsions. We presented a comprehensive summary of various structured interfaces (stabilized by mixed-layers, multilayers, particles, nanodroplets, microgels etc.), and their characteristics, and designing strategies. We also discussed the applicability of these interfaces in stabilizing liquid-liquid (water-oil, water-water, oil-oil, alcohol-oil, etc.), liquid-gel, and gel-gel emulsion systems. Challenges and future research aspects were also proposed regarding interfacial engineering for different emulsions. Emulsions are interface-dominated materials, and the interfaces have dynamic natures, as the compositions and structures are not constant. Biopolymers, particles, nanodroplets, and microgels differed in their capacity to get absorbed onto the interface, to adjust their structures at the interface, to lower interfacial tension, and to stabilize different emulsions. The interactions between the interface and the bulk phases not only affected the properties of the interface, but also the two phases, leading to different functions of the emulsions. These structured interfaces have been used individually or cooperatively to achieve effective stabilization or better applications of different emulsion systems. However, dynamic changes of the interface during digestion are only poorly understood, and it is still challenging to fully characterize the interfaces., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
- Published
- 2024
- Full Text
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20. Inside-out templating: A strategy to decorate helical carbon nanotubes and 2D MoS 2 on ethyl cellulose sponge for enhanced oil adsorption and oil/water separation.
- Author
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Worajittiphon P, Majan P, Wangkawong K, Somsunan R, Jantrawut P, Panraksa P, Chaiwarit T, Srithep Y, Sommano SR, Jantanasakulwong K, and Rachtanapun P
- Subjects
- Adsorption, Water chemistry, Oils chemistry, Water Purification methods, Cellulose chemistry, Cellulose analogs & derivatives, Disulfides chemistry, Nanotubes, Carbon chemistry, Molybdenum chemistry
- Abstract
Ethyl cellulose (EC)-based composite sponges were developed for oil spillage treatment. The EC sponge surface was decorated with helical carbon nanotubes (HCNTs) and molybdenum disulfide (MoS
2 ) (1 phr) using the inside-out sugar templating method. The inside surface of a sugar cube was coated with HCNTs and MoS2 . After filling the sugar cube pores with EC and the subsequent sugar leaching, the decorating materials presented on the sponge surface. The EC/HCNT/MoS2 sponge had a high level of oil removal based on its adsorption capacity (41.68 g/g), cycled adsorption (∼75-79 %), separation flux efficiency (∼85-95 %), and efficiency in oil/water emulsion separation (92-94 %). The sponge maintained adsorption capacity in acidic, basic, and salty conditions, adsorbed oil under water, and functioned as an oil/water separator in a continuous pump-assisted system. The compressive stress and Young's modulus of the EC sponge increased following its decoration using HCNTs and MoS2 . The composite sponge was robust based on cycled compression and was thermally stable up to ∼120ο C. Based on the eco-friendliness of EC, the low loading of HCNTs and MoS2 , and sponge versatility, the developed EC/HCNT/MoS2 sponge should be good candidate for use in sustainable oil adsorption and separation applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
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21. Mosquito Embryo Microinjection under Halocarbon Oil or in Aqueous Solution.
- Author
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Harrell RA 2nd
- Subjects
- Animals, Embryo, Nonmammalian, Oils chemistry, Water, Microinjections methods, Culicidae embryology
- Abstract
The process of genetically modifying mosquitoes requires skilled delivery of reagents for modification. Plasmids, RNA, DNA, and/or protein must be transported into the developing embryo during an appropriate time in development when these agents will have access to the genome. Embryo microinjection has been the main method by which such modifying agents have been delivered. Ideally the microinjection process will deliver these modifying agents in sufficient quantity to effect the genetic modification without severely damaging or killing the injected embryo in the process. As semiaquatic insects, mosquitoes have embryos that are susceptible to desiccation and the degree to which embryos are susceptible is based on species. Two microinjection methods are outlined here. The first method describes embryo microinjections performed under Halocarbon-27 oil. The oil is used to reduce desiccation during the injection process. A second method limits desiccation by injecting the mosquito embryos in water. In both procedures, the embryos are first aligned and then injected before the embryos cellularize, ∼1 h and 45 min after oviposition., (© 2024 Cold Spring Harbor Laboratory Press.)
- Published
- 2024
- Full Text
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22. 3D Cell Culture Method in Channel-Free Water-in-Oil Droplets.
- Author
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Bae SJ, Choi SH, and Im DJ
- Subjects
- Humans, Cell Culture Techniques, Three Dimensional methods, Cell Culture Techniques methods, Spheroids, Cellular cytology, Water chemistry, Oils chemistry
- Abstract
A new channel-free water-in-oil (WO) droplet 3D cell culture method is proposed to address the challenges while maintaining the advantages of the conventional 3D cell culture methods. The proposed WO method can fundamentally solve the constraint of spheroids size, a common challenge in conventional 3D culture, by using droplet size controllability. The 3D cell culture performance of the WO method is verified by comparing it with the conventional 3D cell culture methods. A systematic investigation of the culture conditions of the WO method confirms the working range of cell concentration and droplet size, as well as the scalability of spheroid size. Adjusting droplet size and cell concentration enables rapid spheroid formation with large and high cell concentration droplets or fast spheroid growth with small and low cell concentration droplets, providing control over the spheroid size and growth rate according to the purpose. Furthermore, long-term culture is demonstrated for 1 month with the proposed method, showing the largest spheroid culture and demonstrating the possibility that this method can be used not only for spheroid formation but also for organoid studies. Finally, if a WO-based automated 3D cell culture system is developed, it will be a useful tool for organoid research., (© 2024 Wiley‐VCH GmbH.)
- Published
- 2024
- Full Text
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23. Encapsulation of Lactobacillus plantarum in W 1 /O/W 2 double emulsions stabilized with the high-intensity ultrasound-treated pea protein and pectin.
- Author
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Zhang C, Zhang Y, Qiu B, Liu Z, Gao X, Zhang N, Liu X, Qi S, Li L, and Liu W
- Subjects
- Particle Size, Water chemistry, Ultrasonic Waves, Sonication, Solubility, Probiotics chemistry, Oils chemistry, Hydrophobic and Hydrophilic Interactions, Lactobacillus plantarum, Emulsions, Pea Proteins chemistry, Pectins chemistry
- Abstract
This study focuses on developing a water-in-oil-in-water (W
1 /O/W2 ) double emulsion system using high-intensity ultrasound (HIU)-treated pea protein isolate (HIU-PPI) and pectin to encapsulate Lactobacillus plantarum (L. plantarum). The effects of ultrasound treatment on pea protein isolate (PPI) characteristics such as solubility, particle size, emulsification, surface hydrophobicity, and surface free sulfhydryl group were examined, determining optimal HIU processing conditions was 400 W for 10 min. The developed W1 /O/W2 double emulsion system based on HIU-PPI demonstrated effective encapsulation and protection of L. plantarum, especially at the HIU-PPI concentration of 4 %, achieving an encapsulation efficiency of 52.65 %. Incorporating both HIU-PPI and pectin as emulsifiers increased the particle size and significantly enhanced the emulsion's viscosity. The highest bacterial encapsulation efficiency of the emulsion, 59.94 %, was attained at a HIU to pectin concentration ratio of 3:1. These emulsions effectively encapsulate and protect L. plantarum, with the concentration of HIU-PPI being a critical factor in enhancing probiotic survival under simulated gastrointestinal digestion. However, the concurrent utilization of pectin and HIU-PPI as emulsifiers did not provide a notable advantage compared to the exclusive use of HIU-PPI in enhancing probiotic viability during in vitro simulated digestion. This research offers valuable perspectives for the food industry on harnessing environmentally friendly, plant-based proteins as emulsifiers in probiotic delivery systems. It underscores the potential of HIU-modified pea protein and pectin in developing functional food products that promote the health benefits of probiotics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
24. Double-drying 3D lamellar-structured aerogel membrane for efficient oil-water separation and long-lasting antibacterial activity.
- Author
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Tang S, Wu Z, Wei L, Weng J, Luo J, and Wang X
- Subjects
- Gels chemistry, Porosity, Desiccation methods, Hydrophobic and Hydrophilic Interactions, Freeze Drying methods, Anti-Bacterial Agents chemistry, Anti-Bacterial Agents pharmacology, Oils chemistry, Water chemistry, Membranes, Artificial
- Abstract
Conventional oil-water separation membranes are difficult to establish a trade-off between membrane flux and separation efficiency, and often result in serious secondary contamination due to their fouling issue and non-degradability. Herein, a double drying strategy was introduced through a combination of oven-drying and freeze-drying to create a super-wettable and eco-friendly oil-water separating aerogel membrane (TMA
df ). Due to the regular nacre-like structures developed in the drying process and the pores formed by freeze-drying, TMAdf aerogel membrane finally develops regularly arranged porous structures. In addition, the aerogel membrane possesses excellent underwater superoleophobicity with a contact angle above 168° and antifouling properties. TMAdf aerogel membrane can effectively separate different kinds of oil-water mixtures and highly emulsified oil-water dispersions under gravity alone, achieving exceptionally high flux (3693 L·m-2 ·h-1 ) and efficiency (99 %), while being recyclable. The aerogel membrane also displays stability and universality, making it effective in removing oil droplets from water in corrosive environments such as acids, salts and alkalis. Furthermore, TMAdf aerogel membrane shows long-lasting antibacterial properties (photothermal sterilization up to 6 times) and biodegradability (completely degraded after 50 days in soil). This study presents new ideas and insights for the fabrication of multifunctional membranes for oil-water separation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
25. Highly efficient removal of emulsified oil from oily wastewater by microfiltration carbon membranes made from phenolic resin/coal.
- Author
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Li H, Zhang B, and Wu Y
- Subjects
- Carbon chemistry, Water Purification methods, Waste Disposal, Fluid methods, Water Pollutants, Chemical chemistry, Water Pollutants, Chemical isolation & purification, Emulsions chemistry, Phenols chemistry, Phenols isolation & purification, Oils chemistry, Wastewater chemistry, Membranes, Artificial, Coal, Filtration methods
- Abstract
Oily wastewater treatment is a major problem for a large variety of industrial sectors. Membrane filtration is quite promising for oil-in-water emulsion treatment by virtue of numerous eminent advantages. Here, microfiltration carbon membranes (MCMs) were prepared by the blends of phenolic resin (PR)/coal as precursor materials for efficient removal of emulsified oil from oily wastewater. The functional groups, porous structure, microstructure, morphology and hydrophilicity of the MCMs were analysed by Fourier transform infrared spectroscopy, bubble-pressure method, X-ray diffraction, scanning electron microscope and water contact angle, respectively. The effect of coal amount in precursor materials on the structure and properties of MCMs was mainly investigated. Under operation at 0.02 MPa for trans-membrane pressure and 6 mL min
-1 for feed flowrate, the optimal oil rejection and water permeation flux are correspondingly attained to 99.1% and 21,388.5 kg m-2 h-1 MPa-1 for MCMs made by the precursor containing 25% coal. Besides, the anti-fouling ability of the as-prepared MCMs is greatly improved in comparison with the one merely made by PR. In summary, the result indicates that the as-prepared MCMs are very promising for oily wastewater treatment.- Published
- 2024
- Full Text
- View/download PDF
26. Characterization of oxylipins in Antarctic krill oil (Euphausia superba) during storage based on RPLC-MS/MS analysis.
- Author
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Meng N, Wang X, Song Y, Fan X, Zeng J, Feng T, Cong P, Xu J, and Xue C
- Subjects
- Animals, Tandem Mass Spectrometry, Oxylipins, Oils chemistry, Oxidation-Reduction, Euphausiacea chemistry
- Abstract
Antarctic krill oil (AKO) is rich in polyunsaturated fatty acids (PUFAs), but is prone to oxidative degradation, resulting in the formation of oxylipins, which compromise AKO quality. Herein, we used reversed-phase-high performance liquid chromatography-tandem mass spectrometry (RPLC-MS/MS) to perform qualitative and semi-quantitative analyses of oxylipins in AKO during storage. A total of 27 oxylipins were identified. A notable decrease in epoxy oxylipins (from 41.8 % to 26.9 % of the total oxylipins) was observed, whereas the content of dihydro oxylipins initially increased and then decreased with 48 h, as a pivotal point for AKO quality decline during storage. We suspected that the ratio of dihydroxyl and epoxy oxylipins could be a novel oxidative index to evaluate the oxidation of AKO. Statistical analysis allowed the identification of five oxylipins which showed unique correlations with various indexes. The findings discussed herein provide important new insights into mechanisms of oxidation occurring in AKO during storage., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
27. Demulsification with simultaneous water purification by coupling filtration and enhanced oil droplet coalescence at anode interface in an electrochemical reactor.
- Author
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Li X, Zhang G, Hu C, Lan H, and Liu H
- Subjects
- Oils chemistry, Wastewater chemistry, Water Pollutants, Chemical chemistry, Emulsions chemistry, Electrochemical Techniques methods, Electrochemical Techniques instrumentation, Water Purification methods, Filtration methods, Electrodes, Waste Disposal, Fluid methods
- Abstract
With the increasing demand of recycling disposal of industrial wastewater, oil-in-water (O/W) emulsion has been paid much attention in recent years owing to its high oil content. However, due to the presence of surfactant and salt, the emulsion was usually stable with complex physicochemical interfacial properties leading to increased processing difficulty. Herein, a novel flow-through electrode-based demulsification reactor (FEDR) was well designed for the treatment of saline O/W emulsion. In contrast to 53.7% for electrical demulsification only and 80.3% for filtration only, the COD removal efficiency increased to 92.8% under FEDR system. Moreover, the pore size of electrode and the applied voltage were two key factors that governed the FEDR demulsification performance. By observing the morphology of oil droplets deposited layer after different operation conditions and the behavior of oil droplets at the electrode surface under different voltage conditions, the mechanism was proposed that the oil droplets first accumulated on the surface of flow-through electrode by sieving effect, subsequently the gathered oil droplets could further coalesce with the promoting effect of the anode, leading to a high-performing demulsification. This study offers an attractive option of using flow-through electrode to accomplish the oil recovery with simultaneous water purification., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this article., (Copyright © 2023. Published by Elsevier B.V.)
- Published
- 2024
- Full Text
- View/download PDF
28. Interfacial protein adsorption behavior can be connected across a wide range of timescales using the microfluidic EDGE (Edge-based droplet GEneration) tensiometer.
- Author
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Porto Santos T, Deng B, Corstens M, Berton-Carabin C, and Schroën K
- Subjects
- Adsorption, Air, Alkanes chemistry, Oils chemistry, Particle Size, Surface Properties, Microfluidic Analytical Techniques instrumentation, Surface Tension, Whey Proteins chemistry, Water chemistry
- Abstract
Hypothesis: Our hypothesis is that dynamic interfacial tension values as measured by the partitioned-Edge-based Droplet GEneration (EDGE) tensiometry can be connected to those obtained with classical techniques, such as the automated drop tensiometer (ADT), expanding the range of timescales towards very short ones., Experiments: Oil-water and air-water interfaces are studied, with whey protein isolate solutions (WPI, 2.5 - 10 wt%) as the continuous phase. The dispersed phase consists of pure hexadecane or air. The EDGE tensiometer and ADT are used to measure the interfacial (surface) tension at various timescales. A comparative assessment is carried out to identify differences between protein concentrations as well as between oil-water and air-water interfaces., Findings: The EDGE tensiometer can measure at timescales down to a few milliseconds and up to around 10 s, while the ADT provides dynamic interfacial tension values after at least one second from droplet injection and typically is used to also cover hours. The interfacial tension values measured with both techniques exhibit overlap, implying that the techniques provide consistent and complementary information. Unlike the ADT, the EDGE tensiometer distinguishes differences in protein adsorption dynamics at protein concentrations as high as 10 wt% (which is the highest concentration tested) at both oil-water and air-water interfaces., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Inc. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
29. The dispersibility of biphasic stabilized oil-in-water emulsions improved by the interaction between curdlan and soy protein isolate.
- Author
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Wang F, Li J, Wang Y, Liu H, Yu B, Zhao H, Zhang R, Tao H, Ren X, and Cui B
- Subjects
- Viscosity, Molecular Docking Simulation, Particle Size, Oils chemistry, Hydrogen Bonding, Emulsions chemistry, beta-Glucans chemistry, Soybean Proteins chemistry, Rheology, Water chemistry
- Abstract
Curdlan, a natural polysaccharide, exhibits emulsion-stabilizing and viscosity-modifying properties. However, when employed solely in the aqueous phase, curdlan's adhesive nature impedes droplet dispersion, resulting in a gel-like structure with limited applicability. This investigation formulated a biphasic stabilized oil-in-water emulsion by supplementing the oil phase with beeswax and the aqueous phase with curdlan and soy protein isolate (SPI). The addition of SPI transformed the structural characteristics from a gel-like to a mayonnaise-like structure. Maximal electrostatic repulsion was observed at an internal phase volume fraction of 30%, effectively precluding droplet aggregation owing to the absolute zeta potentials surpassing 40 mV. The emulsions displayed shear-thinning rheological behavior, with a higher storage modulus than the loss modulus, indicative of favorable elastic properties. Molecular docking revealed the predominant role of polar amino acids in facilitating hydrogen bond formation. This study provides a template for developing emulsions with biphasic stability and desirable dispersibility., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)
- Published
- 2024
- Full Text
- View/download PDF
30. Water/oil interfacial behaviors of soy hull polysaccharide revealed by molecular dynamics simulation and particle tracking microrheology.
- Author
-
Yang H, Wu X, Ge W, Wang S, Xu Y, Liu H, Liu J, and Zhu D
- Subjects
- Oils chemistry, Viscosity, Pectins chemistry, Microgels chemistry, Molecular Dynamics Simulation, Water chemistry, Rheology, Glycine max chemistry, Polysaccharides chemistry, Emulsions chemistry
- Abstract
The soy hull polysaccharide (SHP) exhibits excellent interfacial activity and holds potential as an emulsifier for emulsions. To reveal the behavior of SHP at the water/oil (W/O) interface in situ, molecular dynamics (MD) simulations and particle tracking microrheology were used in this study. The results of MD reveal that SHP molecular spontaneously move toward the interface and rhamnogalacturonan-I initiates this movement, while its galacturonic acids on it act as anchors to immobilize the SHP molecules at the W/O interface. Microrheology results suggest that SHP forms microgels at the W/O interface, with the lattices of the microgels continually undergoing dynamic changes. At low concentrations of SHP and short interfacial formation time, the network of the microgels is weak and dominated by viscous properties. However, when SHP reaches 0.75 % and the interfacial formation time is about 60 min, the microgels show perfect elasticity, which is beneficial for stabilizing emulsions., Competing Interests: Declaration of competing interest The authors have declared no conflict of interest., (Copyright © 2024 Elsevier B.V. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
31. Superhydrophobic cotton for addressing fatbergs through oily wastewater treatment.
- Author
-
Gosiamemang T and Heng JYY
- Subjects
- Oils chemistry, Water chemistry, Adsorption, Hydrophobic and Hydrophilic Interactions, Wastewater chemistry, Cotton Fiber analysis, Water Purification methods
- Abstract
Fats, oils and grease (FOGs) deposits in sewers have recently become a significant problem, causing financial strain on water companies, damaging sewer lines, and exposing the environment to dirty water through sanitary sewer overflows. Despite the proactive use of grease traps/interceptors for physical oil-water separation, the issue of FOG deposits persists. This study proposes the use of adsorption-based oil-water separation, employing superhydrophobic cotton, as a new alternative method for removing FOGs. Durable superhydrophobic cotton was successfully prepared using a simple two-step sol-gel method, with octadecyltrimethoxysilane (ODTMS) as a modifying silane. The resulting cotton samples demonstrated remarkable superhydrophobicity, evidenced by water contact angle (WCA) above 154°. Additionally, it exhibited exceptional durability and stability when exposed to hot water, harsh acidic and alkaline solutions, as well as during a laundry test. Moreover, the cotton displayed excellent oil-water separation efficiency (> 98 %) and maintained consistent performance throughout 20 reuse cycles, highlighting its high reusability. This approach holds the potential to address the prevailing FOG deposit issues and contribute to more efficient and sustainable wastewater management practices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
32. Microorganisms immobilized hydroxyethyl cellulose/luffa composite sponge for selective adsorption and biodegradation of oils in wastewater.
- Author
-
Chen L, Lu H, Jiang X, Qu N, Hasi Q, Zhang Y, Zhang B, and Jiang S
- Subjects
- Adsorption, Luffa chemistry, Hydrophobic and Hydrophilic Interactions, Porosity, Oils chemistry, Water Purification methods, Cellulose chemistry, Cellulose analogs & derivatives, Biodegradation, Environmental, Wastewater chemistry, Water Pollutants, Chemical chemistry, Water Pollutants, Chemical isolation & purification
- Abstract
The highly efficient removal of oils such as oils or dyes from wastewater has aroused wide concern and is of great significance for clean production and environmental remediation. The synthesis of a novel aerogel (designated as HEC/LS) is reported herein, achieved through a sol-gel method followed by freeze-drying utilizing loofa and hydroxyethyl cellulose as the raw materials. The new HEC/LS aerogel exhibits excellent porosity and specific surface area, with a porosity of 88.70 %, a total pore area of 0.607 m
2 g-1 , and a specific surface area of 230 m2 g-1 . The prepared HEC/LS aerogel exhibits exceptional hydrophilicity and self-floatability, facilitating its rapid absorption of water up to 21 times its own weight within a mere 3 s. Additionally, it demonstrates good adsorption performance for methylene blue (MB), with a maximum adsorption capacity of 83.30 mg g-1 . Subsequently, a new hydrophobic microorganisms-loaded composite aerogel (namely, Bn-HEC/LS) was obtained by doping microorganisms into the as-prepared HEC/LS in multiple enrichment followed by a hydrophobic and oleophilic surface modification. Based on its rich porous structure and oleophilic wettability, the as-synthesized Bn-HEC/LS exhibits excellent selective adsorption and degradation properties for the oil contamination, the diesel oil could be selectively absorbed in the Bn-HEC/LS and degraded by the loaded microorganisms. Among them, B5 -HEC/LS displays the highest removal efficiency of 94.50 % within 180 h, while free microorganisms and HEC/LS aerogels show degradation efficiencies of only 21.70 % and 48.10 %, respectively. The fixation of microorganisms in the aerogel increases their number within the material and enhances the relative microorganisms removal capacity. The hydrophobic and lipophilic modifications improve the selective adsorption performance of the aerogel on diesel oil, resulting in a significantly high removal rate of Bn-HEC/LS for diesel oil. The results indicate that the immobilization of microorganisms into aerogel improves the activity of microorganisms, and the hydrophobic and oleophilic modification enhances the selective adsorption performance of aerogel to diesel oil, thus resulting in a very high removal rate of Bn-HEC/LS for diesel oil. This study is expected to provide a now possibility for the green and efficient bioremediation of oils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
33. Mesoporous SO 4 2- / kit-6-catalyzed hydrocracking of waste chicken oil.
- Author
-
Shanmuganathan R, Sharma A, Alshehri MA, Kamarudin SK, and Arivalagan P
- Subjects
- Animals, Catalysis, Oils chemistry, Chickens
- Abstract
In this study, we studied the hydrocracking of waste chicken oil (WCO) catalyzed by mesoporous SO
4 2- /KIT-6. The study included WCO extraction, SO4 2- /KIT-6 catalyst synthesis, hydrocracking, and catalytic characterization. XRD patterns revealed intense peaks in the low-angle region, with shoulder peaks showing an increase in sulphate loading from 10% to 30%. The BET-specific surface area for the pure KIT-6 supports measured at 1003 m2 /g, indicative of a well-defined mesoporous structure. Thermogravimetric analysis (TGA) showed a two-stage weight loss, attributed to the elimination of hydrated water (about 200 °C) and decomposition of sulphate ions (400-450 °C). SEM analysis highlighted the surface morphology of the active SK-2 catalyst. Hydrocatalytic and catalytic cracking reactions were performed, and about 99.8% conversion was achieved with 20 mL/H H2 flow, whereas higher production of bioliquids was observed at a flow of 15 mL/h. The hydrocracking mechanism was also studied to understand the formation of lower hydrocarbons. GC analyses of simulated distilled gasoline, kerosene, and diesel showed diverse hydrocarbon compositions. For engine testing, non-hydrocracked fuel rose to 28 kW at 3000 rpm and declined to 21 kW at 3500 rpm. Emission analysis revealed decreasing trends in NOX emissions of hydrogen-rich blends, with values of 65 ppm, 54 ppm, and 48 ppm for petrol, NHBL, and HBL, respectively. Similarly, SO2 emissions reduced from petrol to NHBL and HBL at 910 ppm, 800 ppm, and 600 ppm, respectively, suggesting reduced environmental impact. CO emissions exhibited a substantial reduction in NHBL (0.90%) and HBL (0.54%) compared to petrol (2.70%), emphasizing the cleaner combustion characteristics. Our results provide a comprehensive exploration of waste chicken oil hydrocracking, emphasizing catalyst synthesis, fuel characterization, engine performance, and environmental impact, thereby contributing valuable insights to the field of sustainable bioenergy., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
34. Mechanism of color change in Antarctic krill oil during storage.
- Author
-
Zeng XB, Yin FW, Zhao GH, Guo C, Li DY, Liu HL, Qin L, Shahidi F, and Zhou DY
- Subjects
- Animals, Oils chemistry, Aldehydes, Pyrroles, Xanthophylls, Euphausiacea chemistry
- Abstract
Antarctic krill oil (AKO) is reddish-orange in color but undergoes changes during storage. To investigate the color deterioration and potential mechanisms involved, the changes in color, endogenous components (astaxanthin, fatty acids, and phospholipids), and reaction products (aldehydes, α-dicarbonyl compounds, and pyrroles) of AKO upon storage were determined. Although the visual color of AKO tended to darken upon storage, the colorimetric analysis and ultraviolet-visible spectrum analysis both indicated a fading in red and yellow due to the oxidative degradation of astaxanthin. During storage of AKO, lipid oxidation led to the formation of carbonyl compounds such as aldehydes and α-dicarbonyls. In addition, phosphatidylethanolamines (PEs) exhibited a faster loss rate than phosphatidylcholines. Moreover, hydrophobic pyrroles, the Maillard-like reaction products associated with primary amine groups in PEs accumulated. Therefore, it is suggested that the Maillard-like reaction between PEs and carbonyl compounds formed by lipid oxidation contributed to color darkening of AKO during storage., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)
- Published
- 2024
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35. A strategy to build a library of oil tracers by oleophilic silica-encapsulated DNA nanoparticles.
- Author
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Deng J, Li N, Yang S, Qin M, Guo Y, Feng Y, Ye X, and Li C
- Subjects
- Oils chemistry, Silicon Dioxide chemistry, DNA chemistry, Nanoparticles chemistry
- Abstract
Artificially synthesized DNA is involved in the construction of a library of oil tracers due to their unlimited number and no-biological toxicity. The strategy of the construction is proposed by oleophilic Silica-encapsulated DNA nanoparticles, which offers fresh thinking in developing novel tracers, sensors, and molecular machines in engineering & applied sciences based on artificially synthesized DNA blocks., (© 2024 IOP Publishing Ltd.)
- Published
- 2024
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36. A Spatially Stable Crystal-Particle Gel to Trap Patchouli Oil for Efficient Colonic Drug Delivery.
- Author
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Guo R, Xu W, Wang Y, Yue L, Huang S, Xiu Y, Huang Y, and Wang B
- Subjects
- Animals, Drug Delivery Systems, Colon drug effects, Colon pathology, Colon metabolism, Mice, Humans, Anti-Inflammatory Agents chemistry, Anti-Inflammatory Agents pharmacology, Oils chemistry, Zebrafish, Gels chemistry, Colitis drug therapy, Colitis pathology, Colitis chemically induced
- Abstract
Patchouli oil has exhibited remarkable efficacy in the treatment of colitis. However, its volatility and potential irritancy are often drawbacks when extensively used in clinical applications. Oil gel is a semisolid and thermoreversible system that has received extensive interest for its solubility enhancement, inhibition of bioactive component recrystallization, and the facilitation of controlled bioactive release. Therefore, we present a strategy to develop an oil gel formulation that addresses this multifaceted problem. Notably, a patchouli oil gel formulation was designed to solidify and trap patchouli oil into a spatially stable crystal-particle structure and colonic released delivery, which has an advantage of the stable structure and viscosity. The patchouli oil gel treatment of zebrafish with colitis improved goblet cells and decreased macrophages. Additionally, patchouli oil gel showed superior advantages for restoring the tissue barrier. Furthermore, our investigative efforts unveiled patchouli oil's influence on TRP channels, providing evidence for its potential role in mechanisms of anti-inflammatory action. While the journey continues, these preliminary revelations provide a robust foundation for considering the adoption of patchouli oil gel as a pragmatic intervention for managing colitis.
- Published
- 2024
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37. Enhanced removal of nano-oil droplets utilizing polysilicate aluminum ferric (PSAF): Leveraging bridging and non-polar surface advantages.
- Author
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Liu Y, Zhou Y, Su H, Gu C, Shangguan B, Yan Z, and Qin J
- Subjects
- Aluminum chemistry, Oils chemistry, Surface Properties, Water Purification methods, Waste Disposal, Fluid methods, Ferric Compounds chemistry
- Abstract
Hydraulic oil leaks during mechanical maintenance, resulting in flushing wastewater contaminated with dispersed nano-oil droplets. In this study, 75 mg L
-1 of polysilicate aluminum ferric (PSAF) was stirred at 350 rpm and the optimal chemical oxygen demand (COD) removal was 71%. The increase of PSAF led to more hydrolysis of Fe, and 1,175 cm-1 hydroxyl bridged with negative oil droplets. At the same molar concentration, PSAF hydrolyzes cationic metals more rapidly than polymeric aluminum chloride (PAC). PSAF forms flocs of smaller complex structures with greater bridging. The Al-O and Si-O peaks occurred at 611 and 1,138 cm-1 , indicating the formation of Si-O-Fe and Si-O-Al bonds on the flocs surface. Higher stirring speeds did not change the free energy of the flocs surface γTot , mainly because the decrease in the van der Waals force ( γLW ) offset the increase of Lewis acid-base force ( γAB ). Preserving the non-polar surface, in summary, owing to its bridging abilities and affinity for non-polar surfaces, PSAF demonstrates superior efficiency over PAC in capturing and removing oil droplets., Competing Interests: The authors declare there is no conflict., (© 2024 The Authors This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY 4.0), which permits copying, adaptation and redistribution, provided the original work is properly cited (http://creativecommons.org/licenses/by/4.0/).)- Published
- 2024
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38. Durable, multifunctional cotton fabrics with in situ deposited micro/nanomaterials for effective self-cleaning, oil-water separation and antibacterial activity.
- Author
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Jiao C, Liu D, Chen X, Chen J, and Ye D
- Subjects
- Zeolites chemistry, Silicon Dioxide chemistry, Textiles, Cotton Fiber, Anti-Bacterial Agents chemistry, Anti-Bacterial Agents pharmacology, Hydrophobic and Hydrophilic Interactions, Oils chemistry, Water chemistry, Staphylococcus aureus drug effects, Escherichia coli drug effects, Nanostructures chemistry
- Abstract
The facile modification of cotton fabrics for excellent self-cleaning, oil-water separation, and antibacterial activity is of great interest for multifunctional requirements. Herein, a durable, robust, fluorine-free multifunctional cotton fabric was fabricated via in-situ growing zeolitic imidazolate framework-67 (ZIF-67) on the cotton surface, followed by depositing hydrophobic SiO
2 (H-SiO2 ) nanoparticles synthesized via an improved Stöber reaction. Meanwhile, the abundant hydroxyls of the cotton fabrics provided the necessary ion interaction sites for the uniform deposition of micro/nanomaterials, confirmed by the visualized Raman imaging technology. The resultant H-SiO2 /ZIF-67@cotton fabric exhibited superhydrophobicity with a water contact angle of 159° and versatile self-cleaning, antifouling, oil-water separation, as well as prominent antibacterial activity against S. aureus and E. coli. At the same time, the superhydrophobic cotton fabric possessed excellent durability and stability against harsh environments, including abrasion, washing, acid, base, salt, and organic solvents. This facile technique can be applied for large-scale production of multifunctional superhydrophobic cotton fabrics due to its easy operation, low cost, and environmental friendliness., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
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39. A multifunctional Ag NPs/guar gum hydrogel as versatile platform for catalysts, antibacterial agents, and construction of oil-water separation interfaces.
- Author
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Chen T, Li X, Wang Q, Li Y, Xu L, Yang Y, Qiao Y, Dai Y, Ke J, Wan H, Zhou S, and Gao Z
- Subjects
- Catalysis, Wastewater chemistry, Water Purification methods, Water chemistry, Water Pollutants, Chemical chemistry, Water Pollutants, Chemical isolation & purification, Oils chemistry, Galactans chemistry, Plant Gums chemistry, Silver chemistry, Mannans chemistry, Anti-Bacterial Agents chemistry, Anti-Bacterial Agents pharmacology, Metal Nanoparticles chemistry, Hydrogels chemistry
- Abstract
The frequently encountered wastewater contaminations, including soluble aromatic compound and dye pollutants, pathogenic bacteria, and insoluble oils, have resulted in significant environmental and human health issues. It poses a challenge to utilize identical materials for the treatment of complex wastewater. Herein, in this research, multifunctional Ag NPs/guar gum hybrid hydrogels were fabricated using a facile in situ reduction and self-crosslinking method for efficient remediation of complex wastewater. The Ag NPs/guar gum hybrid hydrogel showed remarkable remodeling, adhesive, and self-healing characteristics, which was favorable for its versatile applications. The combination of Ag NPs with the guar gum skeleton endowed the hybrid hydrogel with exceptional catalytic activity for reducing aromatic compounds and dye pollutants, as well as remarkable antibacterial efficacy against pathogenic bacteria. In addition, the Ag NPs/guar gum hybrid hydrogel could be employed to coat a variety of substrates, including cotton fabrics and stainless steel meshes. The hydrogel coated cotton fabrics and meshes presented superhydrophilicity/underwater superoleophobicity, excellent antifouling capacity, and outstanding recyclability, which could be successfully applied for efficient separation of oil-water mixtures. The findings of this work provide a feasible and cost-effective approach for the remediation of intricate wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)
- Published
- 2024
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40. Construction of biodegradable superhydrophilic/underwater superoleophobic materials with CNF (cellulose nanofiber) fence-like attached on the surface for efficient oil/water emulsion separation.
- Author
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Liu L, Yang D, Bai Y, Li X, Tan F, Ma J, and Wang Y
- Subjects
- Surface Properties, Biodegradation, Environmental, Mannans chemistry, Emulsions chemistry, Nanofibers chemistry, Hydrophobic and Hydrophilic Interactions, Oils chemistry, Water chemistry, Cellulose chemistry
- Abstract
Superhydrophilic/underwater superoleophobic materials for the separation of oil-water emulsions by filtration have received much attention in order to solve the pollution problem of oil-water emulsion. In this paper, a fence-like structure on the surface of CNF/KGM (Konjac Glucomannan) materials by a simple method using CNF instead of metal nanowires was successfully developed based on the hydrogen bonding of KGM and CNF. The resulted organic CNF/KGM materials surface has outstanding superhydrophilic (WCA = 0°) in air and superoleophobicity (OCA≥151°) in water, which could separate oil-water mixtures with high separation efficiency above 99.14 % under the pressure of the emulsion itself. The material shows good mechanical properties because of the addition of CNF and has outstanding anti-fouling property and reusability. More importantly, the material can be completely biodegraded after buried in soil for 4 weeks since both of KGM and CNF are organic substances. Therefore, it may have a broad application prospect in the separation of oil-water emulsion because of its outstanding separation properties, simply preparation method and biodegradability., Competing Interests: Declaration of competing interest There are no conflicts of interest to declare., (Copyright © 2024. Published by Elsevier B.V.)
- Published
- 2024
- Full Text
- View/download PDF
41. Water-in-oil Pickering emulsion using ergosterol as an emulsifier solely.
- Author
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Wang Y, Guo Y, Dong P, Lin K, Du P, Cao J, Cheng Y, Cheng F, Yun S, and Feng C
- Subjects
- Viscosity, Antioxidants chemistry, Oils chemistry, Hydrogen-Ion Concentration, Ergosterol chemistry, Emulsions chemistry, Emulsifying Agents chemistry, Water chemistry, Chlorogenic Acid chemistry, Particle Size
- Abstract
As a crucial component of the fungal cell membranes, ergosterol has been demonstrated to possess surface activity attributed to its hydrophobic region and polar group. However, further investigation is required to explore its emulsification behavior upon migration to the oil-water interface. Therefore, this study was conducted to analyze the interface properties of ergosterol as a stabilizer for water in oil (W/O) emulsion. Moreover, the emulsion prepared under the optimal conditions was utilized to load the water-soluble bioactive substance with the chlorogenic acid as the model molecules. Our results showed that the contact angle of ergosterol was 117.017°, and its dynamic interfacial tension was obviously lower than that of a pure water-oil system. When the ratio of water to oil was 4: 6, and the content of ergosterol was 3.5 % (ergosterol/oil phase, w/w), the W/O emulsion had smaller particle size (438 nm), higher apparent viscosity, and better stability. Meanwhile, the stability of loaded chlorogenic acid was improved under unfavorable conditions (pH 1.2, 90 °C, ultraviolet irradiation, and oxidation), which were 73.87 %, 59.53 %, 62.53 %, and 69.73 %, respectively. Additionally, the bioaccessibility of chlorogenic acid (38.75 %) and ergosterol (33.69 %), and the scavenging rates of the emulsion on DPPH radicals (81.00 %) and hydroxyl radicals (82.30 %) were also enhanced. Therefore, a novel W/O Pickering emulsion was prepared in this work using ergosterol as an emulsifier solely, which has great potential for application in oil-based food and nutraceutical formulations., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
- Published
- 2024
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42. Separation of oil-water emulsion by cellulose acetate ultrafiltration membranes.
- Author
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Shoba B and Jeyanthi J
- Subjects
- Porosity, Water chemistry, Water Purification methods, Oils chemistry, Water Pollutants, Chemical chemistry, Water Pollutants, Chemical isolation & purification, Temperature, Cellulose analogs & derivatives, Cellulose chemistry, Ultrafiltration methods, Membranes, Artificial, Emulsions chemistry
- Abstract
This study reports the separation of oil from water using cellulose acetate (CA) ultrafiltration (UF) membranes. The CA membranes were fabricated by varying bath temperatures such as 5 ± 2°C, 25 ± 2°C and 45 ± 2°C using the phase inversion technique and assess their performance based on the oil removal efficiency. Changing the coagulation bath temperature (CBT) at that stage of membrane formations affects the porosity, pore size, hydraulic resistance, morphological structure and performance of membranes. The obtained results revealed increased porosity and pore size and also decreased hydraulic resistance of the membranes as the CBT increases. Field Emission Scanning Electron Microscopy (FESEM) images indicate that a large number of surface pores are visibly found at the higher bath temperature. Atomic force Microscopy (AFM) images show increased average roughness ( R
a ) of the membrane as the CBT of the membrane increases. The water flux and permeate flux of all the membranes tend to increase with an increase in CBT. From Chemical Oxygen Demand (COD) studies, the oil removal efficiency was maximum for the lower bath temperature membrane. The results indicate that conditions of the coagulation bath significantly affect the porous structure, morphology and performance of the membrane.- Published
- 2024
- Full Text
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43. Insight into oil-water interfacial adsorption of protein particles towards regulating Pickering emulsions: A review.
- Author
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Li M, Yu H, Gantumur MA, Guo L, Lian L, Wang B, Yu C, and Jiang Z
- Subjects
- Adsorption, Particle Size, Surface Properties, Rheology, Wettability, Emulsions chemistry, Water chemistry, Oils chemistry, Proteins chemistry
- Abstract
Over the past decade, Pickering emulsions (PEs) stabilized by protein particles have been the focus of researches. The characteristics of protein particles at the oil-water interface are crucial for stabilizing PEs. The unique adsorption behaviors of protein particles and various modification methods enable oil-water interface to exhibit controllable regulation strategies. However, from the perspective of the interface, studies on the regulation of PEs by the adsorption behaviors of protein particles at oil-water interface are limited. Therefore, this review provides an in-depth study on oil-water interfacial adsorption of protein particles and their regulation on PEs. Specifically, the formation of interfacial layer and effects of their interfacial characteristics on PEs stabilized by protein particles are elaborated. Particularly, complicated behaviors, including adsorption, arrangement and deformation of protein particles at the oil-water interface are the premise of affecting the formation of interfacial layer. Moreover, the particle size, surface charge, shape and wettability greatly affect interfacial adsorption behaviors of protein particles. Importantly, stabilities of protein particles-based PEs also depend on properties of interfacial layers, including interfacial layer thickness and interfacial rheology. This review provides useful insights for the development of PEs stabilized by protein particles based on interfacial design., Competing Interests: Declaration of competing interest The authors declare no conflict of interest., (Copyright © 2024 Elsevier B.V. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
44. [Determination of fatty acid composition after saponification of common oil pharmaceutical excipients by supercritical fluid-evaporative light scattering method and its application in oil identification].
- Author
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Wang ZY, Shi HW, Ma CY, Liu WY, Chen L, Liu Z, Yuan YZ, Zhang M, and Tang S
- Subjects
- Scattering, Radiation, Light, Oils chemistry, Oils analysis, Fatty Acids analysis, Fatty Acids chemistry, Chromatography, Supercritical Fluid methods, Excipients analysis, Excipients chemistry
- Abstract
Oils and fats are commonly used in the pharmaceutical industry as solvents, emulsifiers, wetting agents, and dispersants, and are an important category of pharmaceutical excipients. Fatty acids with unique compositions are important components of oil pharmaceutical excipients. The Chinese Pharmacopoeia provides clear descriptions of the fatty acid types and limits suitable for individual oil pharmaceutical excipient. An unqualified fatty acid composition or content may indicate adulteration or deterioration. The fatty acid composition, as a key indicator for the identification and adulteration evaluation of oil pharmaceutical excipients, can directly affect the quality and safety of oil pharmaceutical excipients and preparations. Gas chromatography is the most widely used technique for fatty acid analysis, but it generally requires derivatization, which affects quantitative accuracy. Supercritical fluid chromatography (SFC), an environmentally friendly technique with excellent separation capability, offers an efficient method for detecting fatty acids without derivatization. Unlike other chromatographic methods, SFC does not use nonvolatile solvents (e. g., water) as the mobile phase, rendering it compatible with an evaporative light-scattering detector (ELSD) for enhanced detection sensitivity. However, the fatty acids in oil pharmaceutical excipients exist in the free and bound forms, and the low content of free fatty acids in these oil pharmaceutical excipients not only poses challenges for their detection but also complicates the determination of characteristic fatty acid compositions and contents. Moreover, the compositions and ratios of fatty acids are influenced by environmental factors, leading to interconversion between their two forms. In this context, saponification provides a simpler and faster alternative to derivatization. Saponification degrades oils and fats by utilizing the reaction between esters and an alkaline solution, ultimately releasing the corresponding fatty acids. Because this method is more cost effective than derivatization, it is a suitable pretreatment method for the detection of fatty acids in oil pharmaceutical excipients using the SFC-ELSD approach. In this study, we employed SFC-ELSD to simultaneously determine six fatty acids, namely, myristic acid, palmitic acid, stearic acid, arachidic acid, docosanoic acid, and lignoceric acid, in oil pharmaceutical excipients. Saponification of the oil pharmaceutical excipients using sodium hydroxide methanol solution effectively avoided the bias in the determination of fatty acid species and contents caused by the interconversion of fatty acids and esters. The separation of the six fatty acids was achieved within 12 min, with good linearity within their respective mass concentration ranges. The limits of detection and quantification were 5-10 mg/L and 10-25 mg/L, respectively, and the spiked recoveries were 80.93%-111.66%. The method proved to be sensitive, reproducible, and stable, adequately meeting requirements for the analysis of fatty acids in oil pharmaceutical excipients. Finally, the analytical method was successfully applied to the determination of six fatty acids in five types of oil pharmaceutical excipients, namely, corn oil, soybean oil, coconut oil, olive oil, and peanut oil. It can be combined with principal component analysis to accurately differentiate different types of oil pharmaceutical excipients, providing technical support for the rapid identification and quality control of oil pharmaceutical excipients. Thus, the proposed method may potentially be applied to the analysis of complex systems adulterated with oil pharmaceutical excipients.
- Published
- 2024
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45. Supercritical CO 2 extrusion foaming of highly open-cell poly(lactic acid) foam with superior oil adsorption performance.
- Author
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Cui S, Wu M, Xu M, Li X, Ren Q, Wang L, and Zheng W
- Subjects
- Adsorption, Oils chemistry, Polyurethanes chemistry, Kinetics, Polyesters chemistry, Carbon Dioxide chemistry
- Abstract
Addressing marine oil spills and industrial water pollution necessitates the development of eco-efficient oil-absorbing materials. With increasing concern for the environment, there is a consensus to decrease the use of petroleum-based polymers. Herein, lightweight poly(lactic acid) (PLA) blend foams with varying thermoplastic polyurethane (TPU) content were fabricated via a solvent-free, eco-friendly supercritical carbon dioxide (scCO
2 ) extrusion foaming technology. The incorporation of TPU significantly enhanced the crystallization rate of PLA, with the semi-crystallization time of PT30 and PT50 blends at 105 °C exhibiting a reduction of 77.2 % and 47.9 %, respectively, compared to neat PLA. The resulting foams exhibited an open-cell structure with excellent selective oil adsorption capabilities. Notably, the PT30 foam achieved a remarkable maximum expansion ratio of 36.0, while the PT50 foam attained the highest open-cell content of 96.2 %. The PT50 foam demonstrated an outstanding adsorption capacity, spanning from 4.7 to 18.8 g/g for diverse oils and solvents, with rapid adsorption kinetics, reaching 94.9 % of the equilibrium adsorption capacity for CCl4 within just 1 min. Furthermore, the PT50 foam retained 95.2 % of its adsorption capacity for CCl4 over 10 adsorption-desorption cycles. This study presents a scalable and sustainable approach for large-scale production of high-performance, bio-based foams, facilitating efficient oil-water separation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
46. Silane and fluorine free facile hydrophobicization of water hyacinth biomass for oil-water separations.
- Author
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Bajpai S and Nemade PR
- Subjects
- Eichhornia chemistry, Water chemistry, Fluorine chemistry, Oils chemistry, Hydrophobic and Hydrophilic Interactions, Cellulose chemistry, Cellulose analogs & derivatives, Biomass, Silanes chemistry
- Abstract
As the adverse effects of using plastics and perfluorinated alkyl substances become more apparent, there is a growing need for sustainable hydrophobic products. Cellulose and its derivatives are the most abundant and widely used polymers, and cellulose-based products have great potential in industries where plastics and other hydrophobic polymers are used, such as stain-resistant fabrics, food packaging, and oil-water separation applications. In this study, we extracted cellulose from water hyacinth (WH) biomass, known for its negative environmental impact, and converted it into hydrophobic cellulose. This addresses the issue of managing WH waste and creating an environmentally friendly hydrophobic material. Initially, aldehyde groups were introduced through oxidation with periodate, followed by direct octadecyl amine (ODA) grafting onto dialdehyde cellulose (DAC) via a Schiff base condensation. The resulting ODA modified cellulose (ODA-C) was dispersed in ethanol and used to coat various materials, including cotton fabric, cellulose filter paper, and packaging paper. The modified materials showed excellent hydrophobicity as measured by their water contact angles (WCAs), and the application of the coating was demonstrated for oil-water separation, stain-resistant hydrophobic fabric, and paper-based packaging materials. FTIR, XRD, and WCA analysis confirmed the successful modification of cellulose. A high separation efficiency of 99% was achieved for diesel/water separation using modified filter paper (MoFP), under gravity. On application of the coating, cotton fabric became hydrophobic and resisted staining from dye, and paper-based packaging materials became more robust by becoming water-resistant. Overall, the facile synthesis, low cost, high efficiency, and use of environmentally friendly sustainable materials make this a promising strategy for hydrophobically modifying surfaces for a wide range of applications while reducing the menace of water hyacinth., Competing Interests: Declaration of competing interest We declare that we have no known competing financial interests or personal relationships that could influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)
- Published
- 2024
- Full Text
- View/download PDF
47. Conventional dendritic cells 2, the targeted antigen-presenting-cell, induces enhanced type 1 immune responses in mice immunized with CVC1302 in oil formulation.
- Author
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Du L, Lu H, Qiao X, Zhang Y, Hou L, Yu X, Cheng H, Chen J, Zheng Q, Hou J, and Tong G
- Subjects
- Animals, Mice, Lymph Nodes immunology, Cell Differentiation drug effects, Ovalbumin immunology, Antigen-Presenting Cells immunology, Antigen-Presenting Cells metabolism, Female, Lymphocyte Activation immunology, Lymphocyte Activation drug effects, Oils chemistry, Mice, Inbred C57BL, Dendritic Cells immunology, Th1 Cells immunology, Cytokines metabolism, Immunization
- Abstract
Multifunctional CD4
+ T helper 1 (Th1) cells, producing IFN-γ, TNF-α and IL-2, define a correlate of vaccine-mediated protection against intracellular infection. In our previous study, we found that CVC1302 in oil formulation promoted the differentiation of IFN-γ+ /TNF-α+ /IL-2+ Th1 cells. In order to extend the application of CVC1302 in oil formulation, this study aimed to elucidate the mechanism of action in improving the Th1 immune response. Considering the signals required for the differentiation of CD4+ T cells to Th1 cells, we detected the distribution of innate immune cells and the model antigen OVA-FITC in lymph node (LN), as well as the quantity of cytokines produced by the innate immune cells. The results of these experiments show that, cDC2 and OVA-FITC localized to interfollicular region (IFR) of the draining lymph nodes, inflammatory monocytes localized to both IFR and T cell zone, which mainly infiltrate from the blood. In this inflammatory niche within LN, CD4+ T cells were attracted into IFR by CXCL10, secreted by inflammatory monocytes, then activated by cDC2, secreting IL-12. Above all, CVC1302 in oil formulation, on the one hand, targeted antigen and inflammatory monocytes into the LN IFR in order to attract CD4+ T cells, on the other hand, targeted cDC2 to produce IL-12 in order to promote optimal Th1 differentiation. The new finding will provide a blueprint for application of immunopotentiators in optimal formulations., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could appear to have influenced the work reported in this paper., (Copyright © 2024 European Federation of Immunological Societies. Published by Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
48. Elucidating the impact of sanitary waste on the formation of fat, oil and grease deposits in sewer systems.
- Author
-
Yadav S and Kumar Pramanik B
- Subjects
- Iron chemistry, Iron analysis, Waste Disposal, Fluid methods, Drainage, Sanitary, Sewage chemistry, Fats analysis, Fats chemistry, Fatty Acids analysis, Oils chemistry
- Abstract
The accumulation of fat, oil and grease (FOG) deposits in sanitary sewer systems is a significant cause of sewer overflows, mainly due to their tendency to adhere to pipe walls. The aim of this study is to (i) develop laboratory-prepared FOG deposits using a mixture of iron (Fe) and aluminium (Al) metal ions, fatty acids, saccharides and cooked oils, in addition to various sanitary waste materials such as paper towels, wipes and pads and (ii) examine the characteristics of these FOG deposits. The goals of this study were to (i) gain a deeper understanding of the impact of sanitary waste on the formation of FOG deposits and (ii) discuss the detailed physiochemical properties of these FOG deposits. The findings revealed that FOG deposits can vary in nature, appearing as either a smooth, paste-like substance or a coarse, semi-solid material, depending on the types of waste present in the sewer. Analysis of the fatty acid profile indicated that the FOG deposits with wipes have the highest viscosity (3.2 × 10
4 Pa s) and larger composition of smaller chain saturated fatty acids (caprylic acid 0.64%, undecanoic acid 5.61%, lauric acid 4.65%, myristic acid 3.21% and palmitic 8.38%). In contrast, FOG deposits with Fe and Al metal impurities have higher heat resistance and thermal stability (melting point of 125 °C) and have larger composition of long chain fatty acids. Furthermore, FTIR analysis confirmed that these FOG deposits are composed of metallic salts of fatty acids, aligning with samples from sewer lines. Our results suggest that FOG deposit formation involves the aggregation of excess calcium, which compresses free fatty acid micelles, and a saponification reaction between the calcium aggregates and free fatty acids. This research illuminates the complex processes behind FOG deposit formation and their varied characteristics, providing valuable insights into potential strategies for preventing FOG-related sewer blockages., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF
49. All-natural polysaccharide and protein complex nanoparticles from Clitocybe squamulosa as unique Pickering stabilizers for oil-in-water emulsions.
- Author
-
Xu L, Xu Y, Hou S, Zheng X, Cao Q, Chang M, Feng C, Cheng Y, Geng X, and Meng J
- Subjects
- Rheology, Particle Size, Hydrogen-Ion Concentration, Oils chemistry, Emulsions chemistry, Nanoparticles chemistry, Polysaccharides chemistry, Water chemistry
- Abstract
This study aimed to develop novel nanoparticles that can serve as an excellent oil-in-water (O/W) Pickering stabilizer. The polysaccharide-protein complex nanoparticles (PPCNs-20 and PPCNs-40) were prepared at different ultrasonication amplitudes (20 % and 40 %, respectively) from the polysaccharide-protein complexes (PPCs) which were extracted from the residue of Clitocybe squamulose. Compared with PPCs and PPCNs-20, the PPCNs-40 exhibited dispersed blade and rod shape, smaller average size, and larger zeta potential, which indicated significant potential in O/W Pickering emulsion stabilizers. Subsequently, PPCNs-40 stabilized Pickering emulsions were characterized at different concentrations, pHs, and oil phase contents. The average size, micromorphology, rheological properties, and storage stability of the emulsions were improved as the concentration of PPCNs-40, the ratio of the soybean oil phase and pH value increased. Pickering emulsions showed the best stability when the concentration of PPCNs-40 was 3 wt%, and the soybean oil fraction was 30 % under both neutral and alkaline conditions. The emulsions demonstrated shear thinning and gelation behavior. These findings have implications for the use of eco-friendly nanoparticles as stabilizers for Pickering emulsions and provide strategies for increasing the added value of C. squamulosa., Competing Interests: Declaration of competing interest We confirm that there are not any conflicts of interest with respect to this publication and there has been no financial support for this article that could influence the outcome., (Copyright © 2024. Published by Elsevier B.V.)
- Published
- 2024
- Full Text
- View/download PDF
50. Preparation of Newly Polymer-Coated Microbial Pellets and Their Adsorption and Degradation Properties for Oil-Containing Wastewater.
- Author
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Lu H, Zhang Y, Zhang B, Jiang S, Qu N, Xiao C, Li L, Li G, and Chen L
- Subjects
- Adsorption, Water Pollutants, Chemical chemistry, Alginates chemistry, Cellulose chemistry, Oils chemistry, Biodegradation, Environmental, Polymers chemistry, Wastewater chemistry
- Abstract
Water is the lifeblood of everything on earth, nourishing and nurturing all forms of life, while also contributing to the development of civilization. However, with the rapid development of economic construction, especially the accelerated process of modern industrialization, the pollution of oily sewage is becoming increasingly serious, affecting the ecological balance and human health. The efficient elimination of pollutants in sewage is, therefore, particularly urgent. In this paper, a core-shell microbial reactor (MPFA@CNF-SA-AM) was fabricated by using nanocellulose and sodium alginate (SA) particles embedded with microorganisms as the core and lipophilic and hydrophobic fly ash as the outer shell layer. Compared with that of free microorganisms and cellulose and SA aerogel pellets loading with microorganisms (CNF-SA-AM), which has a degradation efficiency of 60.69 and 82.89%, respectively, the MPFA@CNF-SA-AM possesses a highest degradation efficiency of 90.60% within 240 h. So that this self-floating microbial reactor has selective adsorption properties to achieve oil-water separation in oily wastewater and high effective degradation of organic pollutants with low cost. The adsorption curves of MPFA@CNF-SA-AM for diesel and n -hexadecane were studied. The results showed that the adsorption follows the Freundlich model and is a multimolecular layer of physical adsorption. In addition, the degradation mechanism of diesel oil was studied by gas chromatography-mass spectrometry. The results showed that diesel oil was selectively adsorbed to the interior of MPFA@CNF-SA-AM, and it was degraded by enzymes in microorganisms into n -hexadecanol, n -hexadecaldehyde, and n -hexadecanoic acid in turn, and finally converted to water and carbon dioxide. Compared with existing oily wastewater treatment methods, this green and pollution-free dual-functional core-shell microbial reactor has the characteristics of easy preparation, high efficiency, flexibility, and large-scale degradation. It provides a new, effective green choice for oily wastewater purification and on-site oil spill accidents.
- Published
- 2024
- Full Text
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