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X‐ray emission spectroscopy (XES) of transition metal compounds is a powerful tool for investigating the spin and oxidation state of the metal centers. Valence‐to‐core (vtc) XES is of special interest, as it contains information on the ligand nature, hybridization, and protonation. To date, most vtc‐XES studies have been performed with high‐brightness sources, such as synchrotrons, due to the weak fluorescence lines from vtc transitions. Here, we present a systematic study of the vtc‐XES for different titanium compounds in a laboratory setting using an X‐ray tube source and energy dispersive microcalorimeter sensors. With a full‐width at half‐maximum energy resolution of approximately 4 eV at the Ti Kβ lines, we measure the XES features of different titanium compounds and compare our results for the vtc line shapes and energies to previously published and newly acquired synchrotron data as well as to new theoretical calculations. Finally, we report simulations of the feasibility of performing time‐resolved vtc‐XES studies with a laser‐based plasma source in a laboratory setting. Our results show that microcalorimeter sensors can already perform high‐quality measurements of vtc‐XES features in a laboratory setting under static conditions and that dynamic measurements will be possible in the future after reasonable technological developments. [ABSTRACT FROM AUTHOR]

We demonstrate a general-purpose solid-state refrigerator for sub-Kelvin temperatures based on the tunneling of hot electrons through normal-metal/insulator/superconductor (NIS) junctions. Previous devices using this cooling principle fell short of general-purpose refrigerators since they could not be coupled to arbitrary payloads. To create a viable refrigerator, we developed optimized NIS structures and techniques to couple multiple such structures to arbitrary objects. Using three linked NIS devices, we reduced the temperature of a 1.9 cm3 copper stage from 290 mK to 256 mK with 700 pW of cooling power at 290 mK. We present plans to achieve base temperatures near 100 mK. [ABSTRACT FROM AUTHOR]

Abstract: Normal metal–Insulator–Superconductor (NIS) tunnel junctions can be used to selectively remove the hottest electrons in the normal metal, thereby causing it to cool. NIS tunnel junctions have already been used to cool lithographically integrated payloads , but this requires integration of two disparate fabrication processes. To increase the flexibility of NIS refrigerators, we have designed a stage cooler based on NIS tunnel junctions that will be able to cool arbitrary, user-supplied payloads from 300mK to 100mK. This stage cooler can be backed by a helium-3 refrigerator to provide a lightweight and simple means of reaching 100mK in space applications. In this paper, we describe the design of our stage cooler and present calculations of the cooling power and time required to reach 100mK. [Copyright &y& Elsevier]

In a normal-metal/insulator/superconductor (NIS) tunnel junction refrigerator, the normal-metal electrons are cooled and the dissipated power heats the superconducting electrode. This paper presents a review of the mechanisms by which heat leaves the superconductor and introduces overlayer quasiparticle traps for more effective heat sinking. A comprehensive thermal model is presented that accounts for the described physics, including the behavior of athermal phonons generated by both quasiparticle recombination and trapped quasiparticles. We compare the model to measurements of a large-area (>400 μm2) NIS refrigerator with overlayer quasiparticle traps, and demonstrate that the model is in good agreement experiment. The refrigerator IV curve at a bath temperature of 300 mK is consistent with an electron temperature of 82 mK. However, evidence from independent thermometer junctions suggests that the refrigerator junction is creating an athermal electron whose total excitation energy corresponds to a higher temperature than is indicated by the refrigerator IV curve [ABSTRACT FROM AUTHOR]

X-ray nanotomography is a powerful tool for the characterization of nanoscale materials and structures, but it is difficult to implement due to the competing requirements of X-ray flux and spot size. Due to this constraint, state-of-the-art nanotomography is predominantly performed at large synchrotron facilities. We present a laboratory-scale nanotomography instrument that achieves nanoscale spatial resolution while addressing the limitations of conventional tomography tools. The instrument combines the electron beam of a scanning electron microscope (SEM) with the precise, broadband X-ray detection of a superconducting transition-edge sensor (TES) microcalorimeter. The electron beam generates a highly focused X-ray spot on a metal target held micrometers away from the sample of interest, while the TES spectrometer isolates target photons with a high signal-to-noise ratio. This combination of a focused X-ray spot, energy-resolved X-ray detection, and unique system geometry enables nanoscale, element-specific X-ray imaging in a compact footprint. The proof of concept for this approach to X-ray nanotomography is demonstrated by imaging 160 nm features in three dimensions in six layers of a Cu-SiO2 integrated circuit, and a path toward finer resolution and enhanced imaging capabilities is discussed. [ABSTRACT FROM AUTHOR]

Microcalorimeters based on transition-edge sensors (TESs) have been successfully deployed in numerous spectroscopic instruments that operate over a large range of incident photon energies. TES microcalorimeter arrays combine unmatched energy resolution with broadband spectral coverage and high quantum efficiency. An important application requiring these characteristics is nondestructive isotopic analysis via gamma-ray spectroscopy of the complex mixtures of actinide isotopes found in the nuclear fuel cycle. Steady progress has been made over the last ten years to develop TES microcalorimeter instruments for this application, leading to arrays that demonstrate significantly better energy resolution than the state-of-the-art high-purity germanium (HPGe) sensors. However, further algorithm development and automation of the data analysis procedure have been required to bring these systems closer to being ready for production use. In this article, we describe recent advances in data analysis techniques for gamma-ray data acquired with microcalorimeter systems. In particular, we discuss new approaches to automated calibration of our spectra, and a new approach for quantifying the uncertainty of peak area estimation for isolated peaks. Our data analysis pipeline has also been automated, requiring minimal manual intervention for full processing of data sets, with performance that is sufficient to allow future deployment of real-time spectrum generation. We show that, using this pipeline, we are able to achieve ~0.25% statistical uncertainty in isotope ratios, which indicates that if systematic errors are controlled, microcalorimeter arrays can achieve better than 1% total uncertainty in these measurements. [ABSTRACT FROM AUTHOR]

Superconducting transition-edge sensor (TES) microcalorimeters have great utility in X-ray applications owing to their high energy resolution, good collecting efficiency and the feasibility of being multiplexed into large arrays. In this work, we develop hard X-ray TESs to measure the absolute energies of muonic-argon (μ-Ar) transition lines around 44 keV and 20 keV. TESs with sidecar absorbers of different heat capacities were fabricated and characterized for their energy resolution and calibration uncertainty. We achieved ~ 1 eV absolute energy measurement accuracy at 44 keV, and < 12 eV energy resolution at 17.5 keV. [ABSTRACT FROM AUTHOR]

We present X-ray absorption spectroscopy and resonant inelastic X-ray scattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueous ferricyanide. These measurements demonstrate the ability of high-throughput transition-edge-sensor (TES) spectrometers to access the rich soft X-ray (100-2000 eV) spectroscopy regime for dilute and radiation-sensitive samples. Our low-concentration data are in agreement with high-concentration measurements recorded by grating spectrometers. These results show that soft-X-ray RIXS spectroscopy acquired by high-throughput TES spectrometers can be used to study the local electronic structure of dilute metal-centered complexes relevant to biology, chemistry, and catalysis. In particular, TES spectrometers have a unique ability to characterize frozen solutions of radiation- and temperature-sensitive samples. [ABSTRACT FROM AUTHOR]

We have examined the role of the substrate on electron-phonon coupling in normal-metal films of Mndoped Al at temperatures below 1 K. Normal metal-insulator-superconductor junctions were used to measure the electron temperature in the films as a function of Joule heating power and phonon temperature. Theory suggests that the distribution of phonons available for interaction with electrons in metal films may depend on the acoustic properties of the substrate, namely, that the electron-phonon coupling constant Σ would be larger on the substrate with smaller sound speed. In contrast, our results indicate that within experimental error (typically ± 10%), Σ is unchanged among the two acoustically distinct substrates used in our investigation. [ABSTRACT FROM AUTHOR]

Time division multiplexing (TDM) is being developed as the readout technology of the X-ray integral field unit (X-IFU), a 3,168-pixel X-ray transition-edge sensor (TES) imaging spectrometer that is part of the European Space Agency's Athena satellite mission. Recent improvements in the low X-ray event count rate performance of TDM have been driven by increases in multiplexer bandwidth and the mitigation of settling transients. These methods and design changes have improved the 32-row multiplexed resolution of a NASA LPA 2.5a array from an initial (2.73 ± 0.03) eV to (1.97 ± 0.01) eV resolution at 5.9 keV. We discuss these recent advances in TDM readout, which have been implemented in an 8-column × 32-row spectrometer that will be deployed at the Lawrence Livermore National Laboratory electron beam ion trap (EBIT) facility, and present a model that will inform the design of future systems. [ABSTRACT FROM AUTHOR]