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1. Direct arene trifluoromethylation enabled by promiscuous activity of fungal laccase.

Author

Goh YL, Long SYP, Wong MFE, Tan LL, Tiong E, Wong FT, and Liu Z

Subjects
Catalysis, Biocatalysis, Laccase metabolism, Trametes metabolism
Abstract

Laccase from Trametes versicolor was found to oxidize non-phenolic arenes and enable the trifluoromethylation of arenes in the presence of in situ generated CF 3 radicals at a catalyst loading as low as 0.0034%. The biocatalytic trifluoromethylation proceeded under mild conditions and could increase the yield by up to 12 fold, compared to the control.

Published
2023
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