50 results on '"Lizhen, Zeng"'
Search Results
2. The Estimation Method of Sensing Parameters Based on OTFS.
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Zhi-Ling Tang, Zhou Jiang, Wanghua Pan, and Lizhen Zeng
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- 2023
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3. The Estimation Method of Sensing Parameters Based on OTFS
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Zhiling Tang, Zhou Jiang, Wanghua Pan, and Lizhen Zeng
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Integrated sensing and communication (ISAC) ,signal modulation ,delay-Doppler (DD) domain super-resolution estimation ,low complexity ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 - Abstract
In an integrated sensing and communication (ISAC) system, improving the accuracy of delay and Doppler shift sensing parameter estimation is a critical task that sustains the performance of the communication system. To tackle this task, we introduce a two-stage estimation algorithm named matched filter-Fibonacci (MF-F), which employs the orthogonal time frequency space (OTFS) waveform characteristics in the delay-Doppler (DD) domain. In the first step (MF), the sensing parameters are approximated on an integer grid using the relationship between the input and output signals of the DD domain ISAC model. This approximation is executed on an integer grid using the cyclic shift property of the matrix. In the following step (F), we implement a two-dimensional (2D) searching technique based on the Fibonacci sequence, called the Fibonacci search method, to achieve sensing parameter estimation with fractional accuracy. This method decreases the number of comparisons needed and enhances the search process speed. Finally, the proposed method in this study was tested using numerical simulations and hardware experiments. The results demonstrate that the MF-F method can precisely estimate the speed and distance with millimeter-level accuracy and has the robustness and low complexity in numerical simulation. Moreover, the hardware experiment’s estimated Doppler and delay parameters can reach the centimeter and meter levels.
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- 2023
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4. Observation of Double Fano Interference in Metal-Insulator Block Arrays
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Wenchen Yang, Hongyan Yang, Shuwen Xue, Ling Guo, Lizhen Zeng, and Gongli Xiao
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Fano interference ,metal-insulator block arrays ,lattice resonances effect ,Applied optics. Photonics ,TA1501-1820 ,Optics. Light ,QC350-467 - Abstract
The coexistence of double Fano interference originating from anti-phased and in-phased lattice resonances is observed in a novel plasmonic lattice array, which being consists of a horizontal double-stacked rectangular metal-insulator block. Based on a classic model analysis of coupled harmonic oscillators, the observed double Fano interference is revealed as a result of the interaction between a bright broad resonance and a dark narrow one as well as the coupling of narrow and broad spectral lines. This allows for active tuning of the double Fano resonance to a desired spectral position by a controlled size variation of the metal-insulator block arrays. After optimizing the parameters, they display two narrow absorbance peaks with high-quality factors of 84.92 and 214.1, respectively. This is because of the utmost enhancements of local electric fields in the gap between two opposing rectangular metal blocks. We expect that double Fano interference character may gain more significant potential applications in biomedical sensing.
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- 2021
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5. Detection and Diagnosis of Multi-Fault for through Silicon Vias in 3D IC.
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Yuling Shang, Weipeng Tan, Chunquan Li 0004, Haihua Fan, and Lizhen Zeng
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- 2020
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6. Formation and Effect of Deposited Thin TiO2 Layer With Compressive Strain and Oxygen Vacancies on GaAs (001) Substrate
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Yue Li, Yunxia Zhou, Yanrong Deng, Shiwo Ta, Zhao Yang, Haiou Li, Tangyou Sun, Yonghe Chen, Fabi Zhang, Tao Fu, Peihua Wangyang, Jun Zhu, Lizhen Zeng, and Xingpeng Liu
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epitaxial ,RHEED ,TiO2 ,compressive strain ,GaAs ,Technology - Abstract
The integration of metal oxides and GaAs semiconductors is quite attractive for its potential applications, but interfacial diffusion and lattice mismatch usually cause huge challenges toward achieving high-performance electronic devices. In this article, we reported a thin layer of epitaxial TiO2 (110) on a GaAs (001) substrate with significant compressive strain, lattice distortion, and oxygen vacancies, where the oxygen vacancies proved to be the critical factor to induce the compressive strain and lattice distortion. In this case, the lattice mismatches between this compressed TiO2 (110) and GaAs (001) surface were calculated to be as small as 1.3 and 0.24% along the [110] and [001] orientations of TiO2, respectively. Further, no Ga-oxides or As-oxides were found at the interface, indicating that the TiO2 layer inhibited the diffusion of Ga and As atoms effectively. In summary, TiO2 film can be grown epitaxially on GaAs (001) substrates with non-negligible compressive strain, lattice distortion, oxygen vacancies, and a high-quality interface. This study also provides an approach to integrate different functional oxides on TiO2-buffered GaAs for various GaAs-based electronic devices with higher reliability and performance.
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- 2022
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7. Early prediction of preeclampsia and small-for-gestational-age via multi-marker model in Chinese pregnancies: a prospective screening study
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Jing Zhang, Luhao Han, Wei Li, Qiaobin Chen, Jie Lei, Min Long, Weibin Yang, Wenya Li, Lizhen Zeng, and Sifan Zeng
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Chinese ,First-trimester screening ,Preeclampsia ,Small-for-gestational-age ,Risk prediction ,Gynecology and obstetrics ,RG1-991 - Abstract
Abstract Background Recent evidence suggests early screening of preeclampsia and small-for-gestational-age (SGA) would benefit pregnancies followed by subsequent prophylactic use of aspirin. Multi-marker models have shown capability of predicting preeclampsia and SGA in first trimester. Yet the clinical feasibility of combined screening model for Chinese pregnancies has not been fully assessed. The aim of this study is to evaluate the applicability of a multi-marker screening model to the prediction of preeclampsia and SGA in first trimester particularly among Chinese population. Methods Three thousand two hundred seventy pregnancies meeting the inclusion criteria took first-trimester screening of preeclampsia and SGA. A prior risk based on maternal characteristics was evaluated, and a posterior risk was assessed by combining prior risk with multiple of median (MoM) values of mean arterial pressure (MAP), serum placental growth factor (PLGF) and pregnancy associated plasma protein A (PAPP-A). Both risks were calculated by Preeclampsia PREDICTOR™ software, Perkin Elmer. Screening performance of prior and posterior risks for early and late preeclampsia by using PREDICTOR software was shown by Receiver Operating Characteristics (ROC) curves. The estimation of detection rates and false positive rates of delivery with both preeclampsia and SGA was made. Results Eight cases developed early preeclampsia (0.24%) and 35 were diagnosed as late preeclampsia (1.07%). Five with early preeclampsia and ten with late preeclampsia later delivered SGA newborns (0.46%); 84 without preeclampsia gave birth to the SGAs (2.57%). According to ROC curves, posterior risks performed better than prior risks in terms of preeclampsia, especially in early preeclampsia. At 10% false positive rate, detection rates of early and late preeclampsia were 87.50 and 48.57%, detection rates of early and late SGA were 41.67 and 28.00%, respectively. For SGA, detection rates in cases with preeclampsia were much higher than those in absence of it. Conclusions This study demonstrates that combined screening model could be useful for predicting early preeclampsia in Chinese pregnancies. Furthermore, the performance of SGA screening by same protocol is strongly associated with preeclampsia.
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- 2019
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8. An All-Dielectric Color Filter, with a Wider Color Gamut
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Lizhen Zeng, Yuting Yang, and Gongli Xiao
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all-dielectric ,color filter ,dielectric resonators ,electric Mie resonances ,magnetic Mie resonances ,finite-difference time-domain method ,Applied optics. Photonics ,TA1501-1820 - Abstract
Due to their extraordinary abilities to manipulate light propagation at the nanoscale, dielectric resonators that generate electric and magnetic Mie resonances for minimal optical loss have recently attracted great interest. Based on an all-dielectric metasurface, made of H-type silicon nanoarrays, this study proposed and constructed a visible-wavelength-range color filter, with high-quality Mie resonance and the ability to synthesize new colors. Using the finite-difference time-domain (FDTD) approach, we can create a larger color gamut by modifying the H-type array’s structural properties. The all-dielectric color filter suggested has a high color saturation and narrow bandwidth. The Mie resonance can be adjusted by manipulating the structural characteristics. By translating the reflectance spectrum into color coordinates and using the CIE1931 chromaticity diagram, a wide range of colors can be generated. This color filter offers a larger color range and saturation than other color filters. We produced color passband filters that span the visible spectrum using Mie resonator arrays, based on an H-type nanoresonator. This technology could have many applications, including high-resolution color printing, color-tunable switches, and sensing systems.
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- 2022
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9. Cancer Biomarkers Ultrasensitive Detection Based on Terahertz Frequency-Comb-Like
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Xuehe Hou, Fangrong Hu, Longhui Zhang, Mingzhu Jiang, Lizhen Zeng, Yingchang Zou, Dongxia Li, Shangjun Lin, Wentao Liu, and Zhongliang Hu
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Electrical and Electronic Engineering ,Instrumentation - Published
- 2023
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10. An Integrated Detection Based on a Multi-Parameter Plasmonic Optical Fiber Sensor.
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Gongli Xiao, Zetao Ou, Hongyan Yang, Yanping Xu, Jianyun Chen, Haiou Li, Qi Li, Lizhen Zeng, Yanron Den, and Jianqing Li 0001
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- 2021
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11. High Sensitivity Plasmonic Sensor Based on Fano Resonance with Inverted U-Shaped Resonator.
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Gongli Xiao, Yanping Xu, Hongyan Yang, Zetao Ou, Jianyun Chen, Haiou Li, Xingpeng Liu, Lizhen Zeng, and Jianqing Li 0001
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- 2021
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12. Structure and mechanism behind the inhibitory effect of water soluble metalloporphyrins on Aβ1–42 aggregation
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Qianqian Zhang, Yiqing Liu, Jinming Wu, Lizhen Zeng, Jingjing Wei, Shitao Fu, Huixian Ye, Hailing Li, and Zhonghong Gao
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Inorganic Chemistry ,mental disorders - Abstract
If the tetraphenylporphyrin of a metalloporphyrin and an amyloid protein have opposite charge properties, the metalloporphyrin will be an effective inhibitor of this amyloid protein.
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- 2022
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13. Molecular Mechanism Involved in Attenuated Anti-Inflammatory Action of Vasoactive Intestinal Peptide in Inflammatory Diseases: Role of Tyrosine Nitration
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Lizhen Zeng, Xuan Zhang, Mengyang Xia, Hailing Li, and Zhonghong Gao
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- 2023
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14. Terahertz metamaterial biosensor for diagnosis of hepatocellular carcinoma at early stage
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Dongxia Li, Lizhen Zeng, Yuanli Wang, Hong-Wen Tang, Wen Xing Lee, Zhencheng Chen, Longhui Zhang, Yingchang Zou, Duan Xie, and Fangrong Hu
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Liver Cirrhosis ,Carcinoma, Hepatocellular ,Liver Neoplasms ,Biomarkers, Tumor ,Humans ,alpha-Fetoproteins ,Biosensing Techniques ,Electrical and Electronic Engineering ,Engineering (miscellaneous) ,Atomic and Molecular Physics, and Optics - Abstract
We propose a method for diagnosis of cirrhosis and hepatocellular carcinoma (HCC) by using a terahertz (THz) metamaterial (MM) biosensor. The biosensor has a resonance frequency at about 0.801 THz and can measure the concentration of alpha-fetoprotein (AFP) in serum. The sensitivity of the sensor is 124 GHz/refractive index unit (RIU), and the quality-factor (Q) is 6.913, respectively. When the surface of the biosensor is covered with healthy serum ( A F P ≤ 7 n g / m L ), the maximum resonance frequency shift is 50 GHz. However, when it is covered with serum from patients with cirrhosis and early HCC ( A F P > 7 n g / m L ), the resonance frequency shift is more than 59 GHz. Positive correlation exists between the frequency shift of the biosensor and serum levels of the AFP in the HCC patients. This study provides a method for quick diagnosis and prediction of cirrhosis and HCC.
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- 2022
15. 3 bit terahertz coder based on a graphene composite metasurface
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Hong Wang, Fangrong Hu, Yumin Gong, Mingzhu Jiang, Longhui Zhang, and Lizhen Zeng
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Statistical and Nonlinear Physics ,Atomic and Molecular Physics, and Optics - Abstract
Terahertz (THz) frequency coders are indispensable components of broadband wireless communication systems of the future. However, the coding of THz wave at multiple frequencies is still a challenge. In this work, a 3 bit THz coder based on a graphene composite metasurface is proposed and simulated using a full-wave electromagnetic simulation software. The unit cell of the device consists of three graphene-embedded split-ring-resonators (SRRs), i.e., SRR1, SRR2, and SRR3. The device has three transmission peaks modulated by external voltages of V1, V2, and V3. The central frequency of the peak generated by SRR1 locates at 0.864 THz and its maximum modulation depth is 79.6%. The second peak generated by SRR2 locates at 1.161 THz and has a maximum modulation depth of 87%. The third peak at 1.541 THz is produced by SRR3 and has a maximum modulation depth of 85.3%. More importantly, the device can be used as a 3 bit coder, and the codes of 111, 110, 101, 011, 100, 010, 001, and 000 are successfully realized by controlling the voltages of V1, V2 and V3. The proposed device has potential applications in next-generation broadband wireless communications.
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- 2023
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16. TSV fault contactless testing method based on group delay
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Chunquan Li, Min Tan, Yuling Shang, Yamin Zhao, and Lizhen Zeng
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Through-silicon via ,Computer science ,business.industry ,Electrical engineering ,Integrated circuit ,Fault (power engineering) ,law.invention ,law ,Wafer testing ,Electrical and Electronic Engineering ,Current (fluid) ,Fault model ,business ,Group delay and phase delay - Abstract
As through silicon via (TSV) in three-dimensional (3-D) stacked integrated circuit (IC) has become micro-nanosized, the conventional wafer probe technology cannot fulfil the current detection requi...
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- 2021
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17. Detection and Diagnosis of Multi-Fault for through Silicon Vias in 3D IC
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Haihua Fan, Yuling Shang, Chunquan Li, Tan Weipeng, and Lizhen Zeng
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Through-silicon via ,Computer science ,020208 electrical & electronic engineering ,Particle swarm optimization ,Three-dimensional integrated circuit ,Hardware_PERFORMANCEANDRELIABILITY ,02 engineering and technology ,Integrated circuit ,Ring oscillator ,020202 computer hardware & architecture ,law.invention ,Support vector machine ,law ,Duty cycle ,Control theory ,Hardware_INTEGRATEDCIRCUITS ,0202 electrical engineering, electronic engineering, information engineering ,Electrical and Electronic Engineering ,Premature convergence - Abstract
Through silicon via (TSV) is the enabling technology for three-dimensional integrated circuit (3D IC) realization. During the TSV manufacturing process, the TSV inevitably has a multi-fault with both resistive-open and leakage faults. The multi-fault will decrease the reliability of the 3D IC seriously. A method of classifying and diagnosing TSV multi-fault is proposed by combining ring oscillator and least square support vector machine (LSSVM). Firstly, the schmidt trigger (ST) as a TSV test receiver based on the initial ring oscillator test structure is implemented. The parameters such as the oscillation period and duty cycle are measured with the TSV as load. A variety of fault types can be detected by testing the changes of these parameters. For further increase the accuracy of the fault test, the oscillation period and duty cycle of different faults are utilized as the feature vectors set, and the set is trained by LSSVM to obtain the fault diagnosis model. In order to get the optimization parameters of the LSSVM model, the particle swarm optimization (PSO) is adopted. As the problem of PSO is tend to local optimization and premature convergence, it may lead to misjudgment of TSV fault. Based on this, W-PSO that dynamically changes the inertia weight is used to optimize the LSSVM. Finally, experiment results imply that the W-PSO-LSSVM fault diagnosis model has a higher fault diagnosis accuracy rate than the PSO-LSSVM fault diagnosis model.
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- 2020
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18. Surface-Functionalized Terahertz Metamaterial Biosensor Used for the Detection of Exosomes in Patients
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Yao Wang, Yuanli Wang, Fangrong Hu, Lizhen Zeng, Zhencheng Chen, Mingzhu Jiang, Shangjun Lin, Wei Guo, and Dongxia Li
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Microscopy, Electron, Transmission ,Electrochemistry ,Humans ,Metal Nanoparticles ,General Materials Science ,Surfaces and Interfaces ,Biosensing Techniques ,Gold ,Condensed Matter Physics ,Exosomes ,Spectroscopy ,Biomarkers - Abstract
Owing to their stability in bodily fluids, exosomes have attracted increased attention as colorectal cancer (CRC) biomarkers for early diagnosis. To validate the potential of the plasma exosomes as a novel biomarker for the monitoring of CRC, we demonstrated a terahertz (THz) metamaterials (MMs) biosensor for the detection of exosomes in this work. The biosensor with two resonant frequencies is designed using full wave electromagnetic simulation software based on the finite integration time domain (FITD) method and fabricated by a surface micromachining process. The biosensor surface is first modified using Au nanoparticles (AuNPs), and then, anti-KRAS and anti-CD147, which are specific to the exosomes, are modified on the AuNPs assembled with HS-poly(ethylene glycol)-COOH (HS-PEG-COOH). Exosomes used in the experiment are extracted via the instructions in the exosomes isolation and purification kit and identified by using transmission electron microscopy (TEM), Western blot (WB), and nanoparticle tracking analysis (NTA). The biosensor covered with plasma-derived exosomes of CRC patients has a different resonance frequency shift compared to that with healthy-control-derived exosomes. This study proposes an emerging and quick method for diagnosing the CRC.
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- 2022
19. A 3-Bit Transmission Terahertz Coder Based on Graphene Composite Metasurface
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Hong Wang, Baogang Quan, Fangrong Hu, Yumin Gong, Mingzhu Jiang, Longhui Zhang, Lizhen Zeng, and Yingchang Zou
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- 2022
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20. Terahertz phase modulator based on a metal-VO2 reconfigurable metasurface
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Wen Zhou, Mingzhu Jiang, Fangrong Hu, Yumin Gong, Longhui Zhang, Lizhen Zeng, Wenying Jiang, Dongxia Li, Hong Wang, Wentao Liu, Shangjun Lin, and Xuehe Hou
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Electrical and Electronic Engineering ,Engineering (miscellaneous) ,Atomic and Molecular Physics, and Optics - Abstract
Actively controlling the phase of a terahertz (THz) wave is of great significance for beaming, tunable focusing, and holography. We present a THz phase modulator based on an electrically triggered vanadium dioxide ( V O 2 ) reconfigurable metasurface. The unit cell of the device consists of two split-ring resonators embedded with a V O 2 ribbon. By electrically triggering the insulator-to-metal transition of V O 2 , the resonance mode and resonance intensity of the unit cell can be dynamically controlled. The simulation results show that the structure can achieve a phase shift of about 360° in the range of 1.03–1.13 THz, and the reflection amplitude can reach 80%. The device has potential applications in THz imaging, radar, broadband wireless communications, and array phase control.
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- 2023
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21. Asymmetric terahertz polarizer based on VO2 composite metasurface
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Mingxin Jia, Mingzhu Jiang, Lizhen Zeng, Haotian Du, Longhui Zhang, Yumin Gong, Wentao Liu, Wen Zhou, Xuehe Hou, and Fangrong Hu
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Condensed Matter Physics ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials - Published
- 2022
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22. Environmental impact of bamboo laminated flooring and bamboo scrimber flooring investigated via life cycle assessment
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Hankun Wang, Xiang Yu, Lizhen Zeng, and Guofang Zhang
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0106 biological sciences ,Bamboo ,Environmental Engineering ,010608 biotechnology ,Environmental science ,Bioengineering ,Environmental impact assessment ,Pulp and paper industry ,01 natural sciences ,Waste Management and Disposal ,Life-cycle assessment ,Environmentally friendly - Abstract
Bamboo floorings are the most important industrial products in the bamboo sector. With the aim of providing a useful guide for the development of bamboo floorings, this study quantitatively assessed the environmental impacts of the two primary types of bamboo floorings, laminated flooring and scrimber flooring, using life cycle assessment (LCA) software SimaPro. The purpose of this study was to find out which type of bamboo flooring is more environmentally friendly through quantitatively analyzing the input and output of materials and energy during the whole life cycle of the two types of flooring products. The present study demonstrated that the majority of the environmental burdens were associated with the process of bamboo strip production for bamboo laminated flooring (59.3%), and the process of panel processing for bamboo scrimber floorings (56.9%). In terms of environmental loads, bamboo laminated flooring was considered more sustainable than bamboo scrimber flooring, as the total environmental loads of bamboo scrimber flooring was approximately 1.6 times that of bamboo laminated flooring.
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- 2019
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23. Ni/Co-based metal-organic frameworks as electrode material for high performance supercapacitors
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Huaqiang Zeng, Lin Yu, Shaofei Zhao, Lizhen Zeng, and Gao Cheng
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Supercapacitor ,Materials science ,Doping ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,01 natural sciences ,Capacitance ,0104 chemical sciences ,Chemical engineering ,Metal-organic framework ,0210 nano-technology ,Current density ,Bimetallic strip ,Electrical conductor - Abstract
A novel bimetallic Ni/Co-based metal-organic framework (Ni/Co-MOF) was successfully synthesized via a simple solvothermal method, and used as electrode material for high performance supercapacitors. After doping of Co element, the Ni/Co-MOF materials retain the original crystalline topology structure of Ni3(BTC)2·12H2O. The as-obtained Ni/Co-MOF demonstrates an excellent specific capacitance of 1067 and 780 F/g at current density of 1 and 10 A/g, respectively, and can also retain 68.4% of the original capacitance after 2500 cycles. These results suggest that bimetallic Ni/Co-based MOFs are promising materials for the next generation supercapacitance, owing to their excellent electrochemical performance. The synthetic procedure can be applied to synthesize other bimetallic MOFs and enhance their conductive property.
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- 2019
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24. Active control of terahertz amplitude and phase based on graphene metasurface
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Yumin Gong, Baogang Quan, Fangrong Hu, Hong Wang, Longhui Zhang, Mingzhu Jiang, Lizhen Zeng, Xiaowen Zhang, and Weilin Xu
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Condensed Matter Physics ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials - Published
- 2022
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25. High Sensitivity Plasmonic Sensor Based on Fano Resonance with Inverted U-Shaped Resonator
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Haiou Li, Liu Xingpeng, Yanping Xu, Jianyun Chen, Lizhen Zeng, Gongli Xiao, Hongyan Yang, Jianqing Li, and Ou Zetao
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finite element method ,Physics::Optics ,02 engineering and technology ,Fano plane ,lcsh:Chemical technology ,01 natural sciences ,Biochemistry ,Analytical Chemistry ,010309 optics ,Resonator ,Nanosensor ,0103 physical sciences ,Figure of merit ,lcsh:TP1-1185 ,Sensitivity (control systems) ,Electrical and Electronic Engineering ,plasmonic nanosensor ,Instrumentation ,Plasmon ,Physics ,business.industry ,Communication ,Fano resonance ,021001 nanoscience & nanotechnology ,Atomic and Molecular Physics, and Optics ,Optoelectronics ,metal-dielectric-metal ,0210 nano-technology ,business ,Refractive index - Abstract
Herein, we propose a tunable plasmonic sensor with Fano resonators in an inverted U-shaped resonator. By manipulating the sharp asymmetric Fano resonance peaks, a high-sensitivity refractive index sensor can be realized. Using the multimode interference coupled-mode theory and the finite element method, we numerically simulate the influences of geometrical parameters on the plasmonic sensor. Optimizing the structure parameters, we can achieve a high plasmonic sensor with the maximum sensitivity for 840 nm/RIUand figure of merit for 3.9 × 105. The research results provide a reliable theoretical basis for designing high sensitivity to the next generation plasmonic nanosensor.
- Published
- 2021
26. Switchable terahertz polarization converter based on VO2 metamaterial
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Haotian Du, Mingzhu Jiang, Lizhen Zeng, Longhui Zhang, Weilin Xu, Xiaowen Zhang, and Fangrong Hu
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General Physics and Astronomy - Abstract
A switchable terahertz (THz) polarization converter based on vanadium dioxide (VO2) metamaterial is proposed. It is a 5-layer structure which containing metal split-ring-resonator (SRR), the first polyimide (PI) spacer, VO2 film, the second PI spacer, and metal grating. It is an array structure and the period in x and y directions is 100 μm. The performance is simulated by using finite integration technology. The simulation results show that, when the VO2 is in insulating state, the device is a transmission polarization converter. The cross-linear polarization conversion can be realized in a broadband of 0.70 THz, and the polarization conversion rate (PCR) is higher than 99%. Under thermal stimulus, the VO2 changes from insulating state to metallic state, and the device is a reflective polarization converter. The linear-to-circular polarization conversion can be successfully realized in a broadband of 0.50 THz, and the PCR is higher than 88%.
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- 2022
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27. An Integrated Detection Based on a Multi-Parameter Plasmonic Optical Fiber Sensor
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Qi Li, Hongyan Yang, Yanping Xu, Haiou Li, Lizhen Zeng, Gongli Xiao, Jianqing Li, Ou Zetao, Jianyun Chen, and Yanron Den
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Materials science ,Physics::Optics ,02 engineering and technology ,lcsh:Chemical technology ,biosensor ,01 natural sciences ,Biochemistry ,Article ,Analytical Chemistry ,010309 optics ,0103 physical sciences ,multi-parameter ,lcsh:TP1-1185 ,Fiber ,Electrical and Electronic Engineering ,Surface plasmon resonance ,Instrumentation ,Plasmon ,business.industry ,graphene ,021001 nanoscience & nanotechnology ,Atomic and Molecular Physics, and Optics ,Magnetic field ,Core (optical fiber) ,D-type photonic crystal fiber (PCF) ,Fiber optic sensor ,Optoelectronics ,0210 nano-technology ,business ,Refractive index ,Photonic-crystal fiber - Abstract
In this paper, a multi-parameter integrated detection photonic crystal fiber (PCF) sensor based on surface plasmon resonance (SPR) is proposed for its application in detecting temperature, magnetic field, and refractive index. The air holes on both sides of the fiber core were coated with gold film and introduced to the temperature-sensitive medium (PDMS) and magnetic fluid (MF), detecting temperature and magnetic field, respectively. The graphene layer is also presented on the gold film of the D-type side polished surface to improve the sensor sensitivity. The sensor&rsquo, s critical parameters&rsquo, influence on its performance is investigated using a mode solver based on the finite element method (FEM). Simulation results show when the samples refractive index (RI) detection is a range of 1.36~1.43, magnetic field detection is a range of 20~550 Oe, and the temperature detection is a range of 5~55 °, C, the maximum sensor&rsquo, s sensitivity obtains 76,000 nm/RIU, magnetic field intensity sensitivity produces 164.06 pm/Oe, and temperature sensitivity obtains &minus, 5001.31 pm/°, C.
- Published
- 2020
28. Peroxynitrite scavenger FeTPPS effectively inhibits hIAPP aggregation and protects against amyloid induced cytotoxicity
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Lizhen Zeng, Hailing Li, Zhonghong Gao, Pengfei Zhang, and Wanxia Gao
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Amyloid ,Metalloporphyrins ,02 engineering and technology ,Molecular Dynamics Simulation ,medicine.disease_cause ,Fibril ,Biochemistry ,Protein Aggregation, Pathological ,Scavenger ,03 medical and health sciences ,chemistry.chemical_compound ,Protein Aggregates ,Structure-Activity Relationship ,Structural Biology ,Peroxynitrous Acid ,medicine ,Animals ,Humans ,Cytotoxicity ,Molecular Biology ,Heme ,030304 developmental biology ,0303 health sciences ,geography ,geography.geographical_feature_category ,Molecular Structure ,Spectrum Analysis ,General Medicine ,021001 nanoscience & nanotechnology ,Islet ,Islet Amyloid Polypeptide ,Rats ,Molecular Docking Simulation ,Oxidative Stress ,chemistry ,Biophysics ,0210 nano-technology ,Reactive Oxygen Species ,Oxidative stress ,Peroxynitrite - Abstract
Type 2 diabetes (T2D) is associated with pancreatic β-cell dysfunction, which can be induced by oxidative stress or/and the aggregation of human islet amyloid polypeptide (hIAPP). Therefore, ONOO- and hIAPP become the crucial targets of T2D treatment. Previously, we found heme could be an effective inhibitor of hIAPP aggregation. However, heme causes serious toxic effects on cells, tissues and organs through oxidative stress, which block it as a potential drug candidate for T2D treatment. 5,10,15,20-tetrakis(4-sulfonatophenyl) porphyrinato iron(III) chloride (FeTPPS), a water-soluble derivative of heme, is recognized as a high-efficient ONOO- decomposition catalyst, which is reported to have a great therapeutic potential in ONOO- -related diseases, including T2D. Here, we explored the potentiality of FeTPPS to be an inhibitor of hIAPP aggregation and the protective effects on cytotoxicity of hIAPP aggregation. It was found that the interaction between FeTPPS and hIAPP remarkably affected hIAPP fibrillation by both stabilizing hIAPP monomers and disaggregating the long fibrils into small oligomeric species. Furthermore, unlike heme, the addition of FeTPPS completely reversed the cytotoxicity and ROS level induced by hIAPP, which was consistent with its strong inhibitory activity. These results implied that FeTPPS could be a promising agent for the treatment of T2D.
- Published
- 2020
29. Highly dispersed polydopamine-modified Mo2C/MoO2 nanoparticles as anode electrocatalyst for microbial fuel cells
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Juan Xiong, Weishan Li, Xiaofen Chen, Xin Li, Lizhen Zeng, Meihua Hu, and Hongying Li
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Microbial fuel cell ,Materials science ,General Chemical Engineering ,Composite number ,Nanoparticle ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrochemistry ,Electrocatalyst ,01 natural sciences ,0104 chemical sciences ,Anode ,Chemical engineering ,chemistry ,0210 nano-technology ,Carbon ,Power density - Abstract
A novel composite, polydopamine-modified Mo2C/MoO2 nanoparticles (HD-Mo2C/MoO2), as anode electrocatalyst for microbial fuel cells (MFCs), is synthesized via carbon thermal reduction and following in situ polydopamine modification. The physical and electrochemical characterizations show that Mo2C/MoO2 nanoparticles can be well dispersed through polydopamine modification and the resulting HD-Mo2C/MoO2 exhibits excellent electrocatalytic activity compared with unmodified Mo2C/MoO2. The MFC using HD-Mo2C/MoO2 as anode electrocatalyst achieves a maximum output power density of 1.64 ± 0.09 W m−2, which is 39% higher than that using Mo2C/MoO2 (1.18 ± 0.08 W m−2) as anode electrocatalyst. This excellent performance is attributed to modification of PDA, HD-Mo2C/MoO2 shows better hydrophilicity and electrocatalytic activity toward the direct oxidation of bacterial metabolites than unmodified Mo2C/MoO2.
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- 2018
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30. Oxidation-Induced para -Selective Formylation of N,N-Substituted Aniline
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Meng Gao, Li Sun, Anjin Yao, Haiyan Wang, Zhiliang Huang, Limei Zhang, Lizhen Zeng, and Aiwen Lei
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chemistry.chemical_compound ,Aniline ,chemistry ,010405 organic chemistry ,Organic Chemistry ,Regioselectivity ,010402 general chemistry ,01 natural sciences ,Medicinal chemistry ,0104 chemical sciences ,Formylation - Published
- 2018
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31. Porous Ni0.1Mn0.9O1.45 microellipsoids as high-performance anode electrocatalyst for microbial fuel cells
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Wenqiang Tu, Pan Xia, Miao He, Changchun Ye, Lizhen Zeng, and Wenguang Zhang
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Materials science ,Microbial fuel cell ,Coprecipitation ,Inorganic chemistry ,Composite number ,Biomedical Engineering ,Biophysics ,02 engineering and technology ,General Medicine ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrocatalyst ,01 natural sciences ,0104 chemical sciences ,Anode ,law.invention ,Chemical engineering ,law ,Specific surface area ,Electrochemistry ,Calcination ,0210 nano-technology ,Porosity ,Biotechnology - Abstract
A novel bi-component composite of porous self-assembled micro-/nanostructured Ni0.1Mn0.9O1.45 microellipsoids as high-performance anode electrocatalyst for microbial fuel cells (MFCs) is successfully synthesized via a simple coprecipitation reaction in microemulsion and calcination method in air atmosphere. The morphology and structural characterization indicate that the as-fabricated Ni0.1Mn0.9O1.45 product is consist of Mn2O3 and NiMn2O4 (n(Mn2O3): n(NiMn2O4) = 0.35: 0.1) and has a porous microellipsoidal morphology. The microellipsoids are compose of numerous layered micro-/nanostructured blocks and the special porous microellipsoids structure of Ni0.1Mn0.9O1.45 offers a large specific surface area for bacteria adhesion. The porous Ni0.1Mn0.9O1.45 microellipsoids as anode electrocatalyst for MFCs exhibits excellent electrocatalytic activity to promote the extracellular electron transfer (EET) between the anode and bacteria, hence improves the performance of MFC. The MFC equipped with Ni0.1Mn0.9O1.45/CF anode achieves a maximum power density of 1.39 ± 0.02 W m−2, is significantly higher than that of commercial carbon felt anode. This work proposes a new method for the synthesis of high-performance and environmentally friendly anode electrocatalyst for MFCs.
- Published
- 2018
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32. Macroscale porous carbonized polydopamine-modified cotton textile for application as electrode in microbial fuel cells
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Shaofei Zhao, Miao He, and Lizhen Zeng
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Microbial fuel cell ,Materials science ,Textile ,Waste management ,Renewable Energy, Sustainability and the Environment ,Carbonization ,business.industry ,Energy Engineering and Power Technology ,Environmental pollution ,02 engineering and technology ,010501 environmental sciences ,Raw material ,021001 nanoscience & nanotechnology ,01 natural sciences ,Anode ,Chemical engineering ,Specific surface area ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,In situ polymerization ,0210 nano-technology ,business ,0105 earth and related environmental sciences - Abstract
The anode material is a crucial factor that significantly affects the cost and performance of microbial fuel cells (MFCs). In this study, a novel macroscale porous, biocompatible, highly conductive and low cost electrode, carbonized polydopamine-modified cotton textile (NC@CCT), is fabricated by using normal cheap waste cotton textiles as raw material via a simple in situ polymerization and carbonization treatment as anode of MFCs. The physical and chemical characterizations show that the macroscale porous and biocompatible NC@CCT electrode is coated by nitrogen-doped carbon nanoparticles and offers a large specific surface area (888.67 m 2 g −1 ) for bacterial cells growth, accordingly greatly increases the loading amount of bacterial cells and facilitates extracellular electron transfer (EET). As a result, the MFC equipped with the NC@CCT anode achieves a maximum power density of 931 ± 61 mW m −2 , which is 80.5% higher than that of commercial carbon felt (516 ± 27 mW m −2 ) anode. Moreover, making full use of the normal cheap waste cotton textiles can greatly reduce the cost of MFCs and the environmental pollution problem.
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- 2018
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33. A facile synthesis of molybdenum carbide nanoparticles-modified carbonized cotton textile as an anode material for high-performance microbial fuel cells
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Lixia Zhang, Lizhen Zeng, Miao He, and Shaofei Zhao
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Microbial fuel cell ,Textile ,Materials science ,Biocompatibility ,Carbonization ,business.industry ,General Chemical Engineering ,Nanoparticle ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Anode ,Chemical engineering ,Specific surface area ,0210 nano-technology ,Porosity ,business - Abstract
A novel macroscale porous structure electrode, molybdenum carbide nanoparticles-modified carbonized cotton textile (Mo2C/CCT), was synthesized by a facile two-step method and used as an anode material for high-performance microbial fuel cells (MFCs). The characterization results show that the carbonized cotton textile modified with Mo2C nanoparticles offers a great specific surface area (832.17 m2 g−1) for bacterial adhesion. The MFC using Mo2C/CCT anode delivers the maximum power density of 1.12 W m−2, which is 51% and 116% higher than that of CCT and unmodified carbon felt anodes under the same conditions. The high power density is mainly due to the Mo2C nanoparticles with good biocompatibility and high conductivity and superior electrochemical activity, as well as the macroscale porous structure of carbonized cotton textile, which facilitate the formation of electroactive biofilm and improve the electron transfer. This paper introduces a feasible way to synthesize cost-effective and high-performance anode materials for MFCs.
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- 2018
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34. Co-modified MoO
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Xin, Li, Meihua, Hu, Lizhen, Zeng, Juan, Xiong, Binhao, Tang, Zhangmin, Hu, Lidan, Xing, Qiming, Huang, and Weishan, Li
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Molybdenum ,Nanotubes ,Bioelectric Energy Sources ,Nitrogen ,Nanoparticles ,Oxides ,Biosensing Techniques ,Cell Separation ,Cobalt ,Carbon - Abstract
Cobalt-modified molybdenum dioxide nanoparticles highly dispersed on nitrogen-doped carbon nanorods (Co-MoO
- Published
- 2019
35. Nano-Fe
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Meihua, Hu, Xin, Li, Juan, Xiong, Lizhen, Zeng, Yingshan, Huang, Yuping, Wu, Guozhong, Cao, and Weishan, Li
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Bioelectric Energy Sources ,Carbon Compounds, Inorganic ,Electric Conductivity ,Nanoparticles ,Graphite ,Equipment Design ,Electrodes ,Porosity ,Catalysis ,Iron Compounds ,Nanostructures - Abstract
We report a novel anode electrocatalyst, iron carbide nanoparticles dispersed in porous graphitized carbon (Nano-Fe
- Published
- 2019
36. Terthiophene as electrolyte additive for stabilizing lithium nickel manganese oxide cathode for high energy density lithium-ion batteries
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Pan Xia, Weishan Li, Le Yu, Wenqiang Tu, Jianhui Li, Mengqing Xu, Zhang Liping, Lidan Xing, Lizhen Zeng, and Weizhen Fan
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Materials science ,Scanning electron microscope ,General Chemical Engineering ,Inorganic chemistry ,chemistry.chemical_element ,02 engineering and technology ,Electrolyte ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Cathode ,0104 chemical sciences ,law.invention ,chemistry.chemical_compound ,Nickel ,Terthiophene ,chemistry ,X-ray photoelectron spectroscopy ,law ,Transmission electron microscopy ,Electrochemistry ,Lithium ,0210 nano-technology - Abstract
Terthiophene (3THP) is evaluated as an electrolyte additive for improving cyclic stability of lithium nickel manganese oxide (LiNi 0.5 Mn 1.5 O 4 ) cathode for high energy density lithium-ion batteries. Charge/discharge tests demonstrate that 3THP is effective for improving the cyclic stability of LiNi 0.5 Mn 1.5 O 4 . With applying only 0.25% 3THP in a standard (1 M LiPF 6 in EC and DMC, 1/2 in volume) electrolyte, the capacity retention of Li/LiNi 0.5 Mn 1.5 O 4 cell after 350 cycles at 1C (1C = 147 mA g −1 ) under 4.9 V was improved from 50% to 91%, which is among the best that have been reported in literatures although the content of 3THP is far lower than those achieved by applying other additives. The physical characterizations from scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction, indicate that a thin cathode film has been formed on LiNi 0.5 Mn 1.5 O 4 particles, which suppresses the decomposition of electrolyte and protects LiNi 0.5 Mn 1.5 O 4 from structural destruction.
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- 2016
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37. Porous Ni
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Lizhen, Zeng, Wenguang, Zhang, Pan, Xia, Wenqiang, Tu, Changchun, Ye, and Miao, He
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Manganese ,Bacteria ,Bioelectric Energy Sources ,Nickel ,Biosensing Techniques ,Porosity ,Bacterial Adhesion ,Carbon ,Nanostructures - Abstract
A novel bi-component composite of porous self-assembled micro-/nanostructured Ni
- Published
- 2017
38. Tiotropium in Early-Stage Chronic Obstructive Pulmonary Disease
- Author
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Weimin Yao, Biao Liang, Yong-jian Xu, Lizhen Zeng, Xiongbin Li, Xiangyan Zhang, Yan Chen, Xiwei Hu, Lingshan Zeng, Pixin Ran, Bin Hu, Nanshan Zhong, Gang Chen, Qianli Ma, Jia Tian, Xiaodan Zhu, Rongchang Zhi, Jianping Zhao, Chunxue Bai, Weishu Ye, Ying Li, Yumin Zhou, Fenglei Li, Shengming Liu, Guoping Hu, Liping Wei, Juan Du, Shuqing Yu, Minjing Li, Zhe Shi, Ping Huang, Xiaochen Li, Jinping Zheng, Ronghuan Yu, Changzheng Wang, Xitao Ma, Changxiu Ye, Dongxing Zhao, Changli Yang, Canmao Xie, Wei-jie Guan, Yinhuan Li, Tao Chen, Xiufang Du, Shuyun Chen, Xiangwen Luo, Yingxiang Lin, Hui Tan, Xianwei Ye, Bingwen He, and Jianping Gui
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Male ,medicine.medical_specialty ,medicine.drug_class ,Placebo ,law.invention ,03 medical and health sciences ,Pulmonary Disease, Chronic Obstructive ,0302 clinical medicine ,Randomized controlled trial ,Double-Blind Method ,law ,Internal medicine ,Bronchodilator ,Forced Expiratory Volume ,Administration, Inhalation ,Clinical endpoint ,Medicine ,Humans ,030212 general & internal medicine ,Tiotropium Bromide ,Aged ,COPD ,business.industry ,General Medicine ,Tiotropium bromide ,Middle Aged ,medicine.disease ,Obstructive lung disease ,respiratory tract diseases ,Bronchodilator Agents ,030228 respiratory system ,Anesthesia ,Disease Progression ,Quality of Life ,Female ,business ,medicine.drug - Abstract
BackgroundPatients with mild or moderate chronic obstructive pulmonary disease (COPD) rarely receive medications, because they have few symptoms. We hypothesized that long-term use of tiotropium would improve lung function and ameliorate the decline in lung function in patients with mild or moderate COPD. MethodsIn a multicenter, randomized, double-blind, placebo-controlled trial that was conducted in China, we randomly assigned 841 patients with COPD of Global Initiative for Chronic Obstructive Lung Disease (GOLD) stage 1 (mild) or 2 (moderate) severity to receive a once-daily inhaled dose (18 μg) of tiotropium (419 patients) or matching placebo (422) for 2 years. The primary end point was the between-group difference in the change from baseline to 24 months in the forced expiratory volume in 1 second (FEV1) before bronchodilator use. Secondary end points included the between-group difference in the change from baseline to 24 months in the FEV1 after bronchodilator use and the between-group difference in...
- Published
- 2017
39. Co-modified MoO2 nanoparticles highly dispersed on N-doped carbon nanorods as anode electrocatalyst of microbial fuel cells
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Lizhen Zeng, Juan Xiong, Qiming Huang, Xin Li, Weishan Li, Meihua Hu, Binhao Tang, Zhangmin Hu, and Lidan Xing
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Microbial fuel cell ,Materials science ,010401 analytical chemistry ,Biomedical Engineering ,Biophysics ,chemistry.chemical_element ,02 engineering and technology ,General Medicine ,021001 nanoscience & nanotechnology ,Electrocatalyst ,Electrochemistry ,01 natural sciences ,Redox ,0104 chemical sciences ,Anode ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Nanorod ,0210 nano-technology ,Molybdenum dioxide ,Carbon ,Biotechnology - Abstract
Cobalt-modified molybdenum dioxide nanoparticles highly dispersed on nitrogen-doped carbon nanorods (Co–MoO2/NCND), are synthesized from anilinium trimolybdate dihydrate nanorods, for the performance improvement of microbial fuel cell based on a mixed bacterial culture. Electrochemical measurements demonstrate that the as-synthesized Co–MoO2/NCND exhibits excellent electrocatalytic activity for the charge transfer on anode, providing the cell with a maximum power density of 2.06 ± 0.05 W m−2, which is strikingly higher than the bare carbon felt anode (0.49 ± 0.04 W m−2). The excellent performance of Co–MoO2/NCND is ascribed to the increased electronic conductivity of carbon nanorods by N-doping, the high ability of MoO2 to enrich electroactive bacteria, as demonstrated by high-throughput sequencing, and the enhanced activity of MoO2 by Co-modifying toward redox reactions in electroactive bacteria. This report provides a new concept of anode electrocatalyst fabrications for the application of microbial fuel cells in electricity generation and wastewater treatment.
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- 2019
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40. Nano-Fe3C@PGC as a novel low-cost anode electrocatalyst for superior performance microbial fuel cells
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Meihua Hu, Weishan Li, Xin Li, Yuping Wu, Juan Xiong, Guozhong Cao, Huang Yingshan, and Lizhen Zeng
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Materials science ,Microbial fuel cell ,010401 analytical chemistry ,technology, industry, and agriculture ,Biomedical Engineering ,Biophysics ,chemistry.chemical_element ,Nanoparticle ,02 engineering and technology ,General Medicine ,021001 nanoscience & nanotechnology ,Electrochemistry ,Electrocatalyst ,01 natural sciences ,Redox ,0104 chemical sciences ,Anode ,Carbide ,chemistry ,Chemical engineering ,0210 nano-technology ,Carbon ,Biotechnology - Abstract
We report a novel anode electrocatalyst, iron carbide nanoparticles dispersed in porous graphitized carbon (Nano-Fe3C@PGC), which is synthesized by facile approach involving a direct pyrolysis of ferrous gluconate and a following removal of free iron, but provides microbial fuel cells with superior performances. The physical characterizations confirm the unique configuration of iron carbide nanoparticles with porous graphitized carbon. Electrochemical measurements demonstrate that the as-synthesized Nano-Fe3C@PGC exhibits an outstanding electrocatalytic activity toward the charge transfer between bacteria and anode. Equipped with Nano-Fe3C@PGC, the microbial fuel cells based on a mixed bacterium culture yields a power density of 1856 mW m−2. The resulting excellent performance is attributed to the large electrochemical active area and the high electronic conductivity that porous graphitized carbon provides and the enriched electrochemically active microorganisms and enhanced activity towards the redox reactions in microorganisms by Fe3C nanoparticles.
- Published
- 2019
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41. Arrayed titanium dioxide shells architecture as anode of lithium ion microbattery
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Weishan Li, Lizhen Zeng, Jianfei Lei, and Xiaoping Li
- Subjects
Materials science ,Renewable Energy, Sustainability and the Environment ,Energy Engineering and Power Technology ,chemistry.chemical_element ,Ionic bonding ,Nanotechnology ,Electrochemistry ,Lithium-ion battery ,Ion ,Anode ,chemistry.chemical_compound ,chemistry ,Titanium dioxide ,Lithium ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,Mesoporous material - Abstract
TiO2 nanocones (TiO2-NCs) are constructed into arrayed spherical shells through a liquid-phase deposition reaction with polymer template, to improve the performance of TiO2 as anode of lithium ion microbattery. The morphology and structure characterizations indicate that TiO2 grows into nanocones with exposed {001} facets and is self-assembled into mesoporous structure. Meanwhile, macroporous channels are formed among the arrayed shells. Electrochemical measurements demonstrate that the TiO2-NCs reveal excellent performance in terms of improved lithium storage property and rate capability. The improved performance can be ascribed to the channel structure for the convenience of ionic transportation and the high-energy facets for the improvement of ionic reactivity.
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- 2013
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42. Polyaniline/mesoporous tungsten trioxide composite as anode electrocatalyst for high-performance microbial fuel cells
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Bin Li, Weishan Li, Lizhen Zeng, Yaqiong Wang, Xingde Xiang, and Dan Cui
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Materials science ,Microbial fuel cell ,Bioelectric Energy Sources ,Composite number ,Inorganic chemistry ,Biomedical Engineering ,Biophysics ,Electrocatalyst ,Catalysis ,Tungsten ,chemistry.chemical_compound ,Polyaniline ,Escherichia coli ,Electrochemistry ,Electrodes ,Aniline Compounds ,Oxides ,Equipment Design ,General Medicine ,Chronoamperometry ,Tungsten trioxide ,Equipment Failure Analysis ,Energy Transfer ,chemistry ,Chemical engineering ,Cyclic voltammetry ,Mesoporous material ,Porosity ,Biotechnology - Abstract
A composite, polyaniline (PANI)/mesoporous tungsten trioxide (m-WO(3)), was developed as a platinum-free and biocompatible anodic electrocatalyst of microbial fuel cells (MFCs). The m-WO(3) was synthesized by a replicating route and PANI was loaded on the m-WO(3) through the chemical oxidation of aniline. The composite was characterized by using X-ray diffraction, Fourier transform infrared spectrum, field emission scanning electron microscopy, and transmission electron microscopy. The activity of the composite as the anode electrocatalyst of MFC based on Escherichia coli (E. coli) was investigated with cyclic voltammetry, chronoamperometry, and cell discharge test. It is found that the composite exhibits a unique electrocatalytic activity. The maximum power density is 0.98 W m(-2) for MFC using the composite electrocatalyst, while only 0.76 W m(-2) and 0.48 W m(-2) for the MFC using individual m-WO(3) and PANI electrocatalyst, respectively. The improved electrocatalytic activity of the composite can be ascribed to the combination of m-WO(3) and PANI. The m-WO(3) has good biocompatibility and PANI has good electrical conductivity. Most importantly, the combination of m-WO(3) and PANI improves the electrochemical activity of PANI for proton insertion and de-insertion.
- Published
- 2013
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43. Ni/β-Mo2C as noble-metal-free anodic electrocatalyst of microbial fuel cell based on Klebsiella pneumoniae
- Author
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Yuxin Wang, Hao Li, S.F. Zhao, W.S. Li, and Lizhen Zeng
- Subjects
Materials science ,Microbial fuel cell ,Renewable Energy, Sustainability and the Environment ,Scanning electron microscope ,Inorganic chemistry ,Energy Engineering and Power Technology ,chemistry.chemical_element ,engineering.material ,Condensed Matter Physics ,Electrochemistry ,Electrocatalyst ,Carbide ,chemistry.chemical_compound ,Nickel ,Fuel Technology ,chemistry ,engineering ,Formate ,Noble metal - Abstract
A composite of nickel and β-molybdenum carbide (Ni/β-Mo2C) was prepared from solution derived precursor and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). The activity of Ni/β-Mo2C as noble-metal-free anodic electrocatalyst of microbial fuel cell (MFC) based on Klebsiella pneumoniae (K. pneumoniae) was investigated by electrochemical measurements. The results from voltammetric measurements show that Ni/β-Mo2C has high electrocatalytic activity towards the oxidation of formate, lactate, ethanol, and 2,6-di-tert-butyl-p-benzoquinon (2,6-DTBBQ), which are the main metabolites of K. pneumoniae. The results from polarization curve measurement indicate that the MFC using Ni/β-Mo2C as anodic electrocatalyst delivers a higher power density than the MFC using β-Mo2C as anodic electrocatalyst. Ni/β-Mo2C provides the MFC based on K. pneumoniae with a novel noble-metal-free anodic electrocatalyst of high activity.
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- 2012
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44. Catalytic activity and stability toward methanol oxidation of PtRu/CNTs prepared by adsorption in aqueous solution and reduction in ethylene glycol
- Author
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H. Y. Yang, Zhihui Zhou, Weishan Li, Xingde Xiang, Lizhen Zeng, P. P. Guo, and Fu Zhao
- Subjects
Materials science ,Aqueous solution ,Inorganic chemistry ,Chronoamperometry ,Condensed Matter Physics ,Electrochemistry ,Catalysis ,chemistry.chemical_compound ,Adsorption ,Chemical engineering ,chemistry ,General Materials Science ,Methanol ,Electrical and Electronic Engineering ,Cyclic voltammetry ,Ethylene glycol - Abstract
In this paper, we reported an improved process for the preparation of PtRu/CNTs, which involves the adsorption of Pt and Ru ions on CNTs in aqueous solution and the reduction of the adsorbed Pt and Ru ions on CNTs in ethylene glycol. The surface morphology, structure, and compositions of the prepared catalyst were studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), and energy-dispersive spectrometer. TEM observation showed that the particles size of the prepared PtRu alloy was in the range of 2–5 nm, XRD patterns confirmed a face-centered cubic crystal structure. The activity and stability of the prepared catalyst toward methanol oxidation were studied in 0.5 M H2SO4 + 1 M CH3OH solution by cyclic voltammetry, chronoamperometry, and chronopotentiometry. The electrochemical results showed that the prepared catalyst exhibited higher activity and stability toward methanol oxidation than commercial PtRu/C with the same loading amount of Pt and Ru.
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- 2009
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45. Effect of Carbon Sources on the Catalytic Performance of Ni/β-Mo2C
- Author
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Shao-fei Zhao, Lizhen Zeng, and Weishan Li
- Subjects
Materials science ,Microbial fuel cell ,Formates ,Scanning electron microscope ,Bioelectric Energy Sources ,Inorganic chemistry ,chemistry.chemical_element ,Bioengineering ,Electrocatalyst ,Applied Microbiology and Biotechnology ,Biochemistry ,Catalysis ,chemistry.chemical_compound ,Crystallinity ,Nickel ,Formate ,Lactic Acid ,Molecular Biology ,Electrodes ,Molybdenum ,Ethanol ,Starch ,General Medicine ,Klebsiella pneumoniae ,Glucose ,chemistry ,Biocatalysis ,Carbon ,Oxidation-Reduction ,Biotechnology ,Nuclear chemistry ,BET theory - Abstract
In this paper, Ni/β-Mo2C(S) and Ni/β-Mo2C(G) were prepared from solution-derived precursor with two different carbon sources (starch and glucose) and tested as anodic noble-metal-free catalysts in air-cathode microbial fuel cells (MFCs). The carburized catalyst samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and Brunauer-Emmett-Teller (BET). The activity of the electrocatalyst towards the oxidation of several common microbial fermentation products (formate, lactate, and ethanol) was studied for MFC based on Klebsiella pneumoniae conditions. The composite MFC anodes were fabricated, and their catalytic behavior was investigated. With different carbon sources, the crystalline structure does not change and the crystallinity and surface area increase. The electrocatalytic experiments show that the Ni/β-Mo2C(G) gives the better bio- and electrocatalytic performance than Ni/β-Mo2C(S) due to its higher crystallinity and BET surface area.
- Published
- 2015
46. Environmental Impact of Bamboo Laminated Flooring and Bamboo Scrimber Flooring Investigated via Life Cycle Assessment.
- Author
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Xiang Yu, Lizhen Zeng, Guofang Zhang, and Hankun Wang
- Abstract
Bamboo floorings are the most important industrial products in the bamboo sector. With the aim of providing a useful guide for the development of bamboo floorings, this study quantitatively assessed the environmental impacts of the two primary types of bamboo floorings, laminated flooring and scrimber flooring, using life cycle assessment (LCA) software SimaPro. The purpose of this study was to find out which type of bamboo flooring is more environmentally friendly through quantitatively analyzing the input and output of materials and energy during the whole life cycle of the two types of flooring products. The present study demonstrated that the majority of the environmental burdens were associated with the process of bamboo strip production for bamboo laminated flooring (59.3%), and the process of panel processing for bamboo scrimber floorings (56.9%). In terms of environmental loads, bamboo laminated flooring was considered more sustainable than bamboo scrimber flooring, as the total environmental loads of bamboo scrimber flooring was approximately 1.6 times that of bamboo laminated flooring. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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47. Ni3Mo3C as anode catalyst for high-performance microbial fuel cells
- Author
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Shao-fei Zhao, Weishan Li, and Lizhen Zeng
- Subjects
Microbial fuel cell ,Materials science ,Bioelectric Energy Sources ,Inorganic chemistry ,chemistry.chemical_element ,Bioengineering ,engineering.material ,Electrocatalyst ,Applied Microbiology and Biotechnology ,Biochemistry ,Catalysis ,Nickel ,Molecular Biology ,Electrodes ,Molybdenum ,General Medicine ,Carbon ,Dielectric spectroscopy ,Anode ,Klebsiella pneumoniae ,Chemical engineering ,chemistry ,Dielectric Spectroscopy ,engineering ,Noble metal ,Cyclic voltammetry ,Platinum ,Biotechnology ,BET theory - Abstract
Ni3Mo3C was prepared by a modified organic colloid method and explored as anode catalyst for high-performance microbial fuel cell (MFC) based on Klebsiella pneumoniae (K. pneumoniae). The prepared sample was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and Brunauer-Emmett-Teller (BET). The activity of the sample as anode catalyst for MFC based on K. pneumoniae was investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and polarization curve measurement. The results show that the adding of nickel in Mo2C increases the BET surface area of Mo2C and improves the electrocatalytic activity of Mo2C towards the oxidation of microbial fermentation products. The power density of MFC with 3 mg cm(-2) Ni3Mo3C anode is far higher than that of the MFC with carbon felt as anode without any catalyst, which is 19 % higher than that of Mo2C anode and produced 62 % as much as that of Pt anode, indicating that Ni3Mo3C is comparative to noble metal platinum as anode electrocatalyst for MFCs by increasing the loading.
- Published
- 2014
48. Molybdenum carbide as anodic catalyst for microbial fuel cell based on Klebsiella pneumoniae
- Author
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Weishan Li, Jianfei Lei, Lizhen Zeng, Lixia Zhang, Shaofei Zhao, and Zhihui Zhou
- Subjects
Materials science ,Microbial fuel cell ,Bioelectric Energy Sources ,Inorganic chemistry ,Biomedical Engineering ,Biophysics ,chemistry.chemical_element ,Metal Nanoparticles ,Electrochemistry ,Crystallography, X-Ray ,Catalysis ,Carbide ,Electric Impedance ,Molybdenum ,Spectrum Analysis ,General Medicine ,Electrochemical Techniques ,Dielectric spectroscopy ,Klebsiella pneumoniae ,chemistry ,Microscopy, Electron, Scanning ,Cyclic voltammetry ,Platinum ,Energy source ,Biotechnology - Abstract
A pure beta-molybdenum carbide (M(O2)C) with a Brunauer-Emmett-Teller (BET) special surface area of 77.5 m2/g, prepared by solution derived precursor, was used as anodic catalyst of microbial fuel cell (MFC) based on Klebsiella pneumoniae (K. pneumoniae). The electrochemical activity of the prepared M(O2)C and the performance of the MFC were investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and polarization curve measurement. The results show that the prepared M(O2)C has high electrocatalytic activity and is a potential alternative to platinum as the anodic catalyst of MFCs. The maximum power density of single-cube MFC with 6.0 mg/cm2 M(O2)C as anodic catalyst is 2.39 W/m3. This power density is far higher than that of the MFC with carbon felt as anode without any catalyst (0.61 W/m3), and comparable to that of the MFC using 0.5 mg/cm2 Pt as anodic catalyst (3.64 W/m3).
- Published
- 2009
49. Rhodosporidium paludigenum induced resistance in Ponkan mandarin against Penicillium digitatum requires ethylene-dependent signaling pathway.
- Author
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Laifeng Lu, Shixiang Xu, Lizhen Zeng, Xiaodong Zheng, and Ting Yu
- Subjects
- *
PENICILLIUM digitatum , *ETHYLENE , *CELLULAR signal transduction , *PLANT defenses , *DISEASE resistance of plants , *1-Methylcyclopropene - Abstract
This work determined if the ethylene dependent signal pathway was required for antagonist-mediated fruit defense mechanisms through investigation of disease resistance against Penicillium digitatum in Ponkan mandarin induced by 1-methylcyclopropene (1-MCP), an inhibitor of ethylene perception, and Rhodosporidium paludigenum. Blocking ethylene perception with 1-MCP resulted in an increase in ACS1, ACS2 and ACO expression, and consequently an increase in ethylene production during mechanical wounding and resistance induction. The expression of the ethylene receptors ETR1, ETR2 and ETR4 as well as ethylene response factor (ERF) were observed with similar responses to yeast and 1-MCP stimuli, with ETR3 mRNA accumulation being the most sensitive to yeast application while ERS1 was the least sensitive. When applied at concentrations greater than 500 nL L-1, 1-MCP pre-fumigation significantly reduced the fruit's natural protection and R. paludigenum induced disease resistance to Penicillium decay, indicating that ethylene perception was involved in inducting disease resistance. Moreover, expression of the defensive genes CHI, β-1,3-glucanase, PAL and CIN up-regulated by yeast was inhibited to different degrees by the 1-MCP pre-treatment. This study provides evidence that the biocontrol yeast R. paludigenum increased disease resistance in Ponkan mandarin against P. digitatum infection due to ethylene and signaling pathway dependent mechanisms. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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50. Tiotropium in Early-Stage Chronic Obstructive Pulmonary Disease.
- Author
-
Zhou Y, Zhong NS, Li X, Chen S, Zheng J, Zhao D, Yao W, Zhi R, Wei L, He B, Zhang X, Yang C, Li Y, Li F, Du J, Gui J, Hu B, Bai C, Huang P, Chen G, Xu Y, Wang C, Liang B, Li Y, Hu G, Tan H, Ye X, Ma X, Chen Y, Hu X, Tian J, Zhu X, Shi Z, Du X, Li M, Liu S, Yu R, Zhao J, Ma Q, Xie C, Li X, Chen T, Lin Y, Zeng L, Ye C, Ye W, Luo X, Zeng L, Yu S, Guan WJ, and Ran P
- Subjects
- Administration, Inhalation, Aged, Bronchodilator Agents adverse effects, Disease Progression, Double-Blind Method, Female, Forced Expiratory Volume drug effects, Humans, Male, Middle Aged, Pulmonary Disease, Chronic Obstructive physiopathology, Quality of Life, Tiotropium Bromide adverse effects, Bronchodilator Agents therapeutic use, Pulmonary Disease, Chronic Obstructive drug therapy, Tiotropium Bromide therapeutic use
- Abstract
Background: Patients with mild or moderate chronic obstructive pulmonary disease (COPD) rarely receive medications, because they have few symptoms. We hypothesized that long-term use of tiotropium would improve lung function and ameliorate the decline in lung function in patients with mild or moderate COPD., Methods: In a multicenter, randomized, double-blind, placebo-controlled trial that was conducted in China, we randomly assigned 841 patients with COPD of Global Initiative for Chronic Obstructive Lung Disease (GOLD) stage 1 (mild) or 2 (moderate) severity to receive a once-daily inhaled dose (18 μg) of tiotropium (419 patients) or matching placebo (422) for 2 years. The primary end point was the between-group difference in the change from baseline to 24 months in the forced expiratory volume in 1 second (FEV
1 ) before bronchodilator use. Secondary end points included the between-group difference in the change from baseline to 24 months in the FEV1 after bronchodilator use and the between-group difference in the annual decline in the FEV1 before and after bronchodilator use from day 30 to month 24., Results: Of 841 patients who underwent randomization, 388 patients in the tiotropium group and 383 in the placebo group were included in the full analysis set. The FEV1 in patients who received tiotropium was higher than in those who received placebo throughout the trial (ranges of mean differences, 127 to 169 ml before bronchodilator use and 71 to 133 ml after bronchodilator use; P<0.001 for all comparisons). There was no significant amelioration of the mean (±SE) annual decline in the FEV1 before bronchodilator use: the decline was 38±6 ml per year in the tiotropium group and 53±6 ml per year in the placebo group (difference, 15 ml per year; 95% confidence interval [CI], -1 to 31; P=0.06). In contrast, the annual decline in the FEV1 after bronchodilator use was significantly less in the tiotropium group than in the placebo group (29±5 ml per year vs. 51±6 ml per year; difference, 22 ml per year [95% CI, 6 to 37]; P=0.006). The incidence of adverse events was generally similar in the two groups., Conclusions: Tiotropium resulted in a higher FEV1 than placebo at 24 months and ameliorated the annual decline in the FEV1 after bronchodilator use in patients with COPD of GOLD stage 1 or 2. (Funded by Boehringer Ingelheim and others; Tie-COPD ClinicalTrials.gov number, NCT01455129 .).- Published
- 2017
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