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Stormwater treatment systems remove and accumulate microplastics from surface runoff, but some of them can be moved downward to groundwater by natural freeze-thaw cycles. Yet, it is unclear whether or how microplastic properties such as density could affect the extent to which freeze-thaw cycles would move microplastics in the subsurface. To examine the transport and redistribution of microplastics in the subsurface by freeze-thaw cycles, three types of microplastics, with density smaller than (polypropylene or PP), similar to (polystyrene or PS), or greater than (polyethylene terephthalate or PET) water, were first deposited on the top of packed sand-the most common filter media used in infiltration-based stormwater treatment systems. Then the columns were subjected to either 23 h of drying at 22 ⁰C (control) or freeze-thaw treatment (freezing at -20 ⁰C for 6 h and thawing at 22 ⁰C for 17 h) followed by a wetting event. The cycle was repeated 36 times, and the effluents were analyzed for microplastics. Microplastics were observed in effluents from the columns that were contaminated with PET and subjected to freeze-thaw cycles. Comparison of the distribution of microplastics in sand columns at the end of 36 cycles confirmed that freeze-thaw cycles could disproportionally accelerate the downward mobility of denser microplastics. Using a force balance model, we show that smaller microplastics (50 µm) can be pushed at higher velocity by the ice-water interface, irrespective of the density of microplastics. However, plastic density becomes critical when the size of microplastics is larger than 50 µm. The coupled experimental studies and theoretical framework improved the understanding of why denser microplastics such as PET and PVC may move deeper into the subsurface in the stormwater treatment systems and consequently elevate groundwater pollution risk.

Children spend many hours in urban parks and playgrounds, where the tree canopy could filter microplastics released from the surrounding urban hotspots. However, the majority of children's playgrounds also contain plastic structures that could potentially release microplastics in situ. Yet, no study to date has quantified microplastic concentrations in different parts of the park to assess if the children's playgrounds pose a higher exposure risk than other places inside the park. We evaluated the extent of microplastic contamination in the sand, soil, and leaf samples from 19 playgrounds inside urban parks in Los Angeles, CA, USA. The average microplastic concentration in sand samples collected inside the playground was 72 p g

Wastewater treatment plants (WWTPs) could reintroduce microplastics into environments via biosolid application on land. Yet, the annual emission of microplastics via wastewater biosolids is unclear...

Stormwater control measures (SCM) can remove and accumulate microplastics and may serve as a long-term source of microplastics for groundwater pollution because of their potential for downward mobility in subsurface. Furthermore, the number of microplastics accumulated in SCM may have been underestimated as the calculation typically only accounts for microplastics accumulated via episodic stormwater loading and ignores microplastic accumuation via continuous atmospheric deposition. To evaluate the source pathways of accumulated microplastics and their potential for downward mobility to groundwater, we analyzed spatial distributions of microplastics above ground on the canopy around SCM and below ground in the subsurface in and outside the boundaries of fourteen SCM in Los Angeles. Using an exponential model, we link subsurface retardation of microplastics to the median particle size of soil (D

Microplastics are continuously released into the terrestrial environment from sources where they are used and produced. These microplastics accumulate in soils, sediments, and freshwater bodies, and some are conveyed via wind and water to the oceans. The concentration gradient between terrestrial inland and coastal regions, the factors that influence the concentration, and the fundamental transport processes that could dynamically affect the distribution of microplastics are unclear. We analyzed microplastic concentration reported in 196 studies from 49 countries or territories from all continents and found that microplastic concentrations in soils or sediments and surface water could vary by up to eight orders of magnitude. Mean microplastic concentrations in inland locations such as glacier (191 n L−1) and urban stormwater (55 n L−1) were up to two orders of magnitude greater than the concentrations in rivers (0.63 n L−1) that convey microplastics from inland locations to water bodies in terrestrial boundary such as estuaries (0.15 n L−1). However, only 20% of studies reported microplastics below 20 μm, indicating the concentration in these systems can change with the improvement of microplastic detection technology. Analysis of data from laboratory studies reveals that biodegradation can also reduce the concentration and size of deposited microplastics in the terrestrial environment. Fiber percentage was higher in the sediments in the coastal areas than the sediments in inland water bodies, indicating fibers are preferentially transported to the terrestrial boundary. Finally, we provide theoretical frameworks to predict microplastics transport and identify potential hotspots where microplastics may accumulate.

Entrepreneurs creating new ventures must convince stakeholders that their organizations will survive. Job candidates must perform online research about entrepreneurs due to the lack of available history of new ventures. The information that they uncover about the entrepreneur may lead to the development of an opinion of the level of perceived organizational support that the new venture will provide. This study intends to explore what causes job candidates to accept employment with new ventures by understanding what online signals from entrepreneurial owners lead to their perception that the firm will provide them with organizational support. The study intends to provide entrepreneurs with an understanding of the implications of providing too much or too little online background information for potential stakeholders to uncover and develop opinions of entrepreneurs and the perceived level of organizational support that will be provided.