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Your search keyword '"Jaka Šturm"' showing total 4 results
Start Over Author "Jaka Šturm"
4 results on '"Jaka Šturm"'

1. Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination

Author

Jaka Šturm and Barbara Modec

Subjects
pentachloridooxomolybdate(V), molybdenum, coordination chemistry, crystal structure, Inorganic chemistry, QD146-197
Abstract

(PyH)2[MoOCl5] was obtained in the form of emerald green crystals unintentionally from (PyH)5[MoOCl4(H2O)]3Cl2 in acetonitrile. (PyH)2[MoOCl5] has been used as a starting material in molybdenum(V) coordination chemistry for decades, yet its true identity has not been known until now. The X-ray structure analysis has undoubtedly confirmed the existence of this compound. The [MoOCl5]2− ion displays the usual structural characteristics of the mononuclear MoO3+-containing compounds.

Published
2021
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3. Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination

Author

Barbara Modec and Jaka Šturm

Subjects
crystal structure, chemistry.chemical_element, 02 engineering and technology, Crystal structure, 010402 general chemistry, 01 natural sciences, Biochemistry, Ion, Coordination complex, chemistry.chemical_compound, molybdenum, Physical and Theoretical Chemistry, pentachloridooxomolybdate(V), Acetonitrile, QD146-197, chemistry.chemical_classification, Organic Chemistry, X-ray, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Crystallography, chemistry, Molybdenum, coordination chemistry, Pyridinium, 0210 nano-technology, Single crystal, Inorganic chemistry
Abstract

(PyH)2[MoOCl5] was obtained in the form of emerald green crystals unintentionally from (PyH)5[MoOCl4(H2O)]3Cl2 in acetonitrile. (PyH)2[MoOCl5] has been used as a starting material in molybdenum(V) coordination chemistry for decades, yet its true identity has not been known until now. The X-ray structure analysis has undoubtedly confirmed the existence of this compound. The [MoOCl5]2− ion displays the usual structural characteristics of the mononuclear MoO3+-containing compounds.

Published
2021

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