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Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination
- Source :
- Molbank, Vol 2021, Iss 3, p M1249 (2021)
- Publication Year :
- 2021
- Publisher :
- MDPI AG, 2021.
-
Abstract
- (PyH)2[MoOCl5] was obtained in the form of emerald green crystals unintentionally from (PyH)5[MoOCl4(H2O)]3Cl2 in acetonitrile. (PyH)2[MoOCl5] has been used as a starting material in molybdenum(V) coordination chemistry for decades, yet its true identity has not been known until now. The X-ray structure analysis has undoubtedly confirmed the existence of this compound. The [MoOCl5]2− ion displays the usual structural characteristics of the mononuclear MoO3+-containing compounds.
Details
- Language :
- English
- ISSN :
- 14228599
- Volume :
- 2021
- Issue :
- 3
- Database :
- Directory of Open Access Journals
- Journal :
- Molbank
- Publication Type :
- Academic Journal
- Accession number :
- edsdoj.72838b83dccc4e7299b83764572c24e9
- Document Type :
- article
- Full Text :
- https://doi.org/10.3390/M1249