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1. Fast [O.sub.2] binding at dicopper complexes containing Schiff-Base dinucleating ligands

Author

Company, Anna, Gomez, Laura, Mas-Balleste, Ruben, Korendovych, Ivan V., Ibas, Xavi, Poater, Albert, Parella, Teodor, Fontrodona, Xavier, Benet-Buchholz, Jordi, Sola, Miquel, Que, Lawrence, Jr., Rybak-Akimova, Elena V., and Costas, Miquel

Subjects
Ligands -- Chemical properties, Copper compounds -- Chemical properties, Schiff bases -- Analysis, Chemistry
Abstract

The preparation and characterization of a new family of dicopper(I) complexes containing Schiff-base ligands containing two tridentate binding sites linked by a xylyl spacer revealed the complexes to react very rapidly with [O.sub.2] to generate metastable [[[Cu.sup.III.sub.2][([mu]-O).sub.2](L)].sup.2} species.

Published
2007

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