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Water adsorption energy, Eads, is a key physical quantity in sustainable chemical technologies such as (photo)electrocatalytic water splitting, water desalination, and water harvesting. In many of these applications, the electrode surface is operated outside the point (potential) of zero charge, which attracts counter-ions to form the electric double layer and controls the surface properties. Here, by applying density functional theory-based finite-field molecular dynamics simulations, we have studied the effect of water adsorption energy Eads on surface acidity and the Helmholtz capacitance of BiVO4 as an example of metal oxide electrodes with weakly chemisorbed water. This allows us to establish the effect of Eads on the coordination number, the H-bond network, and the orientation of chemisorbed water by comparing an oxide series composed of BiVO4, TiO2, and SnO2. In particular, it is found that a positive correlation exists between the degree of asymmetry ΔCH in the Helmholtz capacitance and the strength of Eads. This correlation is verified and extended further to graphene-like systems with physisorbed water, where the electric double layers (EDLs) are controlled by electronic charge rather than proton charge as in the oxide series. Therefore, this work reveals a general relationship between water adsorption energy Eads and EDLs, which is relevant to both electrochemical reactivity and the electrowetting of aqueous interfaces. [ABSTRACT FROM AUTHOR]

The increasing volume of textile waste in landfills and incineration poses severe environmental challenges. Waste valorisation of textile waste via anaerobic digestion (AD) is preferable, as it offers economic and environmental benefits, but it is hindered by textile complexity, necessitating effective pretreatment technologies to improve biogas production. This study aims to evaluate various pretreatment technologies for biogas production from textile fibres via AD. A weighted‐scoring analysis (WSA) assessed pretreatment methods based on technical, economic, environmental and operational criteria. Hydrothermal pretreatment emerged as the most technically effective method, scoring 140 owing to its substantial methane enhancement. Economically, shredding was the most viable option, scoring 125, as a consequence of low capital and O&M cost. Environmentally, hydrothermal and deep eutectic solvent (DES) pretreatments were top performers with 100 points owing to low environmental impact and positive heat reactions. In a case study conducted in the Auckland region, the potential environmental impact (PEI) obtained from hydrothermal and DES were 169 and 92 per year, respectively, resulting in minimal environmental impact. Operationally, ultrasonic and biological pretreatments scored highest owing to their ease of operation, and minimal health and safety requirements. Overall, hydrothermal pretreatment achieved the highest WSA score of 340, reflecting its balanced performance across all criteria. Hydrothermal pretreatment is the most promising technology for enhancing biogas production from textile waste. Its technical efficiency, economic feasibility and environmental benefits regarding the WSA score make it suitable for upscaling and providing a viable solution for managing textile waste in the AD plant. © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

BACKGROUND: Chromatographic capture is a critical step in the manufacture of protein‐based therapeutics and often dominates the overall downstream processing cost. Multicolumn systems as well as systems where the load flow rate varies over time can be employed to improve productivity and reduce the consumption of buffers and other process chemicals by enhancing utilization of the binding capacity. This work addresses the design of such systems under mass transfer control conditions using a mechanistic model. RESULTS: Generalized, dimensionless charts and interpolating functions developed based on a mechanistic model are provided to predict the operating conditions and performance attributes of periodic countercurrent, dual‐flow, and Capture SMB systems for continuous capture with adsorption columns. The underlying model is based on the Langmuir isotherm and on the assumption that mass transfer is controlling. The results cover the ranges typically encountered in the capture of biopharmaceuticals with selective adsorbent particles and can be conveniently used for practical estimations without having to resort to the numerical solution of the model equations. Illustrative examples are provided and compare favorably with previously published results. CONCLUSIONS: The results of this work provide the means to rapidly design periodic countercurrent, dual‐flow capture systems, and capture SMB units and to assess their relative advantages under varying operating conditions circumventing the need to perform computationally intensive simulations. © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

Biocatalysis has emerged in recent decades toward a widely applied catalysis technology in the chemical industry. In particular the fine chemicals and pharmaceuticals industries benefit from the advantages of biocatalysis, which made its way to a dominating industrial core technology for manufacturing chiral molecules. However, often biocatalysis is still to a certain extent away from having solved all challenges being needed for a "perfect industrial process technology". Among existing challenges are, e.g., stability under process conditions and easy separation of the catalyst from the reaction mixture with the additional option of recyclability. Here metal‐organic framework (MOF) structures offer unique advantages, which can be beneficial for biocatalysis. A particular valuable option is integration of enzymes into MOF‐subunits, thus having a potential positive impact on stability (by reducing the tendency of unfolding) and enabling compartmentalization as a beneficial strategy in, e.g., chemoenzymatic synthesis. In this "Perspective"‐article, first the state of the art in biocatalysis is briefly summarized together with current challenges. Then, a short overview about current research achievements in "merging" MOF chemistry and biocatalysis is given as well as an outlook written from a biocatalysis practitioner's view, how MOF‐enzyme hybrid systems can play a major role in future process development to overcome existing hurdles of enzymatic catalysis. [ABSTRACT FROM AUTHOR]

Sustainable hydrogen, produced from renewable sources such as solar or wind, plays a decisive role in driving industrial decarbonization. Among hydrogen production technologies, steam electrolysis, and solar‐driven thermochemical cycles using reducible solid oxides show promise but face challenges due to high operation temperatures. Microwave‐driven redox chemical looping enables the direct, contactless electrification of the process, reducing the operation temperature and complexity. Previous works showed that microwaves can efficiently drive reduction/water‐splitting cycles using Gd‐doped ceria at low temperatures (<250 °C), but adjustment of material properties is needed. Here, the key properties of materials are explored that affect the redox mechanism by screening a series of doped ceria materials to enhance microwave‐driven hydrogen production. Evaluation of trivalent dopants (La3+, Gd3+, Y3+, Yb3+, Er3+, and Nd3+) reveals that reduction correlates with lattice and electronic properties. The composition Ce0.9La0.1O2‐δ achieves 1.41 mL g−1, the highest hydrogen production among the studied series. Its narrower bandgap allows for reaching higher conductivity upon microwave‐driven reduction at lower temperatures, while a larger ionic lattice size boosts solid‐state oxygen diffusion. Overall, this research remarks on the critical properties of ceria‐based materials that enhance hydrogen production in microwave‐driven water‐splitting cycles, supporting the design of more efficient materials for sustainable chemical production technology. [ABSTRACT FROM AUTHOR]

Site‐selective chemical modifications of proteins have emerged as a potent technology in chemical biology, materials science, and medicine, facilitating precise manipulation of proteins with tailored functionalities for basic biology research and developing innovative therapeutics. Compared to traditional recombinant expression methods, one of the prominent advantages of chemical protein modification lies in its capacity to decorate proteins with a wide range of functional moieties, including non‐genetically encoded ones, enabling the generation of novel protein conjugates with enhanced or previously unexplored properties. Among these, approaches for dual or multiple modifications of proteins are increasingly garnering attention, as it has been found that single modification of proteins is inadequate to meet current demands. Therefore, in light of the rapid developments in this field, this review provides a timely and comprehensive overview of the latest advancements in chemical and biological approaches for dual functionalization of proteins. It further discusses their advantages, limitations, and potential future directions in this relatively nascent area. [ABSTRACT FROM AUTHOR]

Australians have the highest incidence of melanoma globally, despite increasing awareness of the risks of excessive sun exposure. Although excess ultraviolet radiation (UVR) can cause irreparable cell damage and lead to cancer, some exposure is vital to maintain bodily processes such as vitamin D production. For an individual, finding the balance between healthy exposure and skin damage is largely guesswork. The ability to provide a simple, individualised indicator of cumulative UVR dosage could be transformative in preventing skin cancer. This review will provide a brief overview of the variety of UVR sensor technologies and explain the important role of colourimetric dosimeters. The chemistry behind some recent examples of colourimetric dosimeters will be discussed, identifying that molecular photoswitches are ideal candidates to enable this technology. We discuss the chemical mechanisms of photoswitches and how to modify their chemical structure to optimise their properties for use as dosimeters. Through this lens, diarylethenes have been identified as prime dosimeter candidates, owing to their sensitivity, stability, adaptability and the variety of visually striking colours possible. Finally, some specific challenges are identified in the design and fabrication of personalised colourimetric dosimeters that can equitably meet the requirements of all users in our community. Rewearable colourimetric dosimeters offer an efficient, low cost and reusable solution to educate people on their risk from ultraviolet radiation (UVR) from the sun. Molecular photoswitches are a simple chemical technology for creating UVR dosimeters. Key to their translation are enhanced photochemical stability, reusability and overall stability. Beyond the chemistry, it is necessary to design these devices for the needs of all users in our community, to offer equitable protection. (Image credit: Nathan Boase.) [ABSTRACT FROM AUTHOR]

In the foreseeable future, the development of petroleum-based polymeric materials may be limited, owing to the gradual consumption of disposable resources and the increasing emphasis on environmental protection policies. Therefore, it is necessary to focus on introducing environmentally friendly renewable biobased materials as a substitute for petroleum-based feed stocks in the preparation of different types of industrially important polymers. Plant polyphenols, a kind of natural aromatic biomolecule, exist widely in some plant species. Benefiting from their special macromolecular structure, high reactivity, and broad abundance, plant polyphenols are potent candidates to replace the dwindling aromatic monomers derived from petroleum-based resources in synthesizing high-quality polymeric materials. In this review, the most related and innovative methods for elaborating novel polymeric materials from plant polyphenols are addressed. After a brief historical overview, the classification, structural characteristics, and reactivity of plant polyphenols are summarized in detail. In addition, some interesting and innovative works concerning the chemical modifications and polymerization techniques of plant polyphenols are also discussed. Importantly, the main chemical pathways to create plant polyphenol-based organic/organic–inorganic polymeric materials as well as their properties and possible applications are systematically described. We believe that this review could offer helpful references for designing multifunctional polyphenolic materials. [ABSTRACT FROM AUTHOR]

Since Strecker's discovery of multicomponent reactions (MCRs) in 1850, the strategy of applying an MCR approach has been in use for over a century. Due to their ability to quickly develop molecular diversity and structural complexity of interest, MCRs are considered an efficient approach in organic synthesis. Although MCRs such as the Ugi, Passerini, Biginelli, and Hantzsch reactions are widely studied, this review emphasizes the significance of selective MCRs to elegantly produce organic compounds of potential use in medicinal chemistry and industrial and material science applications, as well as the use of the MCR approach to sustainable methods. During synthesis, MCRs provide advantages such as atom economy, recyclable catalysts, moderate conditions, preventing waste, and avoiding solvent use. MCRs also reduce the number of sequential multiple reactions to one step. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the effect of extraction methods and solvents (Soxhlet and supercritical fluid extraction, SFE) on the chemical profile (gas chromatography [GC]/mass spectrometry and GC/flame ionization detection) and antimicrobial, antioxidant, antitumor, and anti‐inflammatory activities of quinoa Piabiru (QP) husk crude extracts. Soxhlet was applied using 100% water (QPSH2O), and ethanolic solutions of 50% ethanol (ethanol:water 50:50 v/v, QPSetOH50), 70% ethanol (QPSetOH70), and 99% ethanol (QPSetOH99) as solvents. SFE was applied using CO2 and n‐propane as solvents (QPSF). QPSH2O extract showed a higher concentration of phytosterols (stigmasterol, β‐sitosterol, 7,8‐epoxylanostan‐11‐ol,3‐acetoxy) and carotenoids (rhodopin) and oleic acid, displaying intermediate thiobarbituric acid reactive substance (TBARS) antioxidant activity. Intermediate concentrations of ethanol (QPSetOH50 and QPSetOH70 extracts) increased the extraction yields and the antibacterial activity of the extracts (Pseudomonas aeruginosa, Salmonella enterica, Bacillus cereus, and Staphylococcus aureus). Higher concentrations of ethanol (QPSetOH99 extract) contributed to increased antioxidant activity as assessed by TBARS and higher recoveries of 4‐(allyloxy)‐2‐methyl‐2‐pentanol, nonadecane, and lauric, myristic, palmitic, linoleic, stearic, arachidic, behenic, and lignoceric acids. Finally, the QPSF extract presented higher antioxidant activity by DPPH, ABTS, and ferric‐reducing antioxidant power, higher content of 5‐methoxy‐2‐pentanone, 5‐methoxy‐2‐methyl‐2‐pentanol, 1‐(1,3‐dimethylbutoxy)‐2‐propanol, oxalic, undecanoic, myristoleic, tricosanoic, pentadecanoic, elaidic, 11‐eicosenoic, and erucic acids, and better antifungal activity against Aspergillus brasiliensis than the other extracts. Crude extracts were not cytotoxic against non‐tumor cells (Vero) and did not show antitumor or anti‐inflammatory activities. Thus, antagonistic or synergistic effects of the phytochemical profile of quinoa husk crude extracts may present potential food and pharmaceutical applications. Practical Applications: The exceptional nutritional properties of quinoa seeds have boosted their cultivation in more than 123 countries. However, quinoa husks are generally considered waste. This study, which is of utmost importance, demonstrates the potential of extracting bioactive compounds from quinoa husks via pressurized fluids, turning them into a health‐promoting co‐product. This approach could minimize the current shortage of new antibiotics, antifungals, antitumor agents, and anti‐inflammatory substances in the pharmaceutical and food sectors. By converting quinoa husks into valuable bioactive extracts, we contribute significantly to developing effective natural compounds, underlining the significance of our collective work. [ABSTRACT FROM AUTHOR]

BACKGROUND: Biochars have become one of the most intensively and extensively investigated soil amendment materials in terms of their production, application and fate in the soil because of benefits such as increased soil quality and fertility. Biochar from woodchips and bone char from meat bone waste from a poultry slaughterhouse were prepared at 300 and 500 °C and then thoroughly mixed with two soils (cambisol and luvisol) that differed in their physicochemical parameters in ratios of 2% and 5% (w/w). RESULTS: The impact of bone and biochar amendments on nutrient availability was assessed during a one‐year model laboratory experiment. The feedstock origin and pyrolysis temperature affected the prepared materials' physical properties and nutrient (Ca, Cu, K, Mg, Mn, P, S, Zn) availability. With increasing temperature, the structure of woodchip biochar changed from macroporous to microporous, and bone char changed from non‐porous to mesoporous. However, when mixed with soil, the biochar‐derived change in soil pH was revealed to be the most crucial parameter affecting soil nutrient mobility. Of all the tested elements, Only Cu, Fe and Zn were unaffected by biochar addition. Furthermore, temporal changes in element mobility during incubation were also elucidated. CONCLUSION: The changes over time in element mobility indicated that soil properties were more important than bone and biochar characteristics. © 2023 The Authors. Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

BACKGROUND: The uncontrolled discharge of untreated ballast water, which is essential for a ship's optimal operation, is one of the major causes of sea environmental pollution by shipping. Among the disinfection methods available for ballast water treatment, ozonation is a commonly used method, but its performance is limited by the rapid ozone auto‐decomposition rate. Nanobubbles (NBs) technology has attracted much scientific interest as it is characterized by a long residence time in the aqueous phase and a high surface area; therefore, ozone nanobubbles (OzNBs) are expected to enhance disinfection capacity and residual activity. The present study was designed to provide further insight into the inactivation of heterotrophic bacteria in saline water and to examine the use of OzNBs for disinfection of saline water. RESULTS: The survival rate of Escherichia coli (E. coli), which was used as indicator microorganism, along with the ozone consumption at different salinities (1.5, 4, 8 and 15 PSU) and bacterial concentrations (107, 106, and 105 CFU mL−1) with and without supplementation of OzNBs were investigated. The results indicated a statistical difference in the residual concentration of total residual oxidants (TRO) with the presence of OzNBs at salinity level 1.5 PSU and at 4 PSU only at the lowest bacterial content. At a low salinity and high bacterial concentration, the concentration of TRO was 6‐fold higher in the presence of OzNBs. CONCLUSION: The salinity of water has a strong impact on the residual concentration of ozone. When salinity is increased, ozone reacts more rapidly with the bromide and chloride ions. The use of OzNBs exhibited a greater disinfection performance and higher residual activity. © 2023 The Authors. Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

BACKGROUND: CIELAB color variables can be used to monitor a composting process and evaluate the maturity of the compost with a new, rapid, easy, and low‐cost colorimetric analysis. However, to date there are no available data to support the ability of CIELAB color changes to depict the different stages of a composting procedure. This study aims to examine the correlation of CIELAB color variables with composting time to elucidate how color changes can be used to detect the different stages of a composting process. Two green waste industrial scale composting processes with different added materials were monitored using typical physicochemical and CIELAB color analyses. RESULTS: During composting, color variables a*, b*, C*, and ΔΕ* exhibited fluctuations following a constant variation trend that correlated with each composting phase. This behavior depicts the transformation of the organic composition of compost, as described by Organic Carbon (OC), Carbon‐to‐Nitrogen ratio (C/N), Humic Acids (HA), and Fulvic Acids (FA). Moreover, color variables a*, b*, and C* showed strong relationships with OC, C/N, and HA/FA (R2 > 0.83) and with HA (R2 > 0.74). These results indicate that CIELAB color change follows the same general pattern for each composting procedure that utilizes the same main composting substrate, regardless of any differing additional materials. CONCLUSION: Monitoring the CIELAB color variables made it possible to depict the different phases of composting, especially the transformation of the organic composition of the compost. Accurately monitoring CIELAB color variables distinguishes the different stages of a composting process through a rapid analysis at radically reduced costs compared to complex physicochemical analyses. © 2023 The Authors. Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

BACKGROUND: Hospital wastewater (HWW) charges wastewater treatment plants (WWTPs) with a mixture of contaminants such as pharmaceutically active compounds (PhACs) and pathogenic bacteria. This matrix is considered highly toxic to the ecosystem and organisms, and it may induce the development of antibiotic resistant bacteria (ARB) and the transfer of antibiotic resistance genes (ARGs) within microbial communities. Conventional WWTPs cannot treat HWW effectively, because they have not been designed to confront this challenge. Therefore, this study investigated the applicability of photocatalysis to purify HWW, regarding its ecotoxicity and the removal rates of targeted substances, selected pathogenic bacteria and specific ARGs. RESULTS: The HWW samples showed high toxicity towards the bioindicator Daphnia magna population, while they also contained significant levels of ARB and ARGs. Upon application of the photocatalytic treatment, the pharmaceutical concentrations decreased at a rate of >80% and the removal rates of the examined bacteria (Escherichia coli, Enterococci, Klebsiella sp. and Staphylococcus sp.) were >80%. Importantly, the bacteria remaining after photocatalysis were sensitive to the tested antibiotics. Conversely, the examined ARGs were present in high concentrations before and after photocatalytic treatment. For example, the concentrations of the selected genes, namely ampC, sul2, tetA and qnrA, in the effluents were from 104 to 106 gene copies L−1. CONCLUSIONS: Photocatalysis may be a promising treatment technique for the elimination of PhACs and pathogenic bacteria from HWW. Moreover, it proved capable of altering the antibiotic resistance profile of the bacteria surviving after treatment, making them sensitive to certain antibiotic compounds. However, the main concern regarding public health protection remains, as the presence of ARGs in effluents in considerable concentrations may induce antibiotic resistance in bacterial communities of aquatic environments. © 2023 The Authors. Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

The development of new catalytic systems based on cobalt and iron compounds for the production of oxygen-containing compounds is an urgent task of chemical technology. The purpose of this work is the synthesis of CoFe2O4 stabilized with polyvinylpyrrolidone (PVP), the study of the catalyst by physico-chemical research methods, and the determination of the effectiveness of the CoFe2O4/PVP catalyst in the phenol oxidation reaction. In this work, magnetic composites CoFe2O4 and CoFe2O4 stabilized with polyvinylpyrrolidone were synthesized by co-deposition. A comparison of the characteristics of the properties of the synthesized cobalt (II) ferrite (CoFe2O4) and the composite material CoFe2O4/PVP based on it is carried out. The obtained samples were examined using X-ray phase analysis (XRD), the Debye–Scherrer method, scanning electron microscopy (SEM), Mossbauer and IR Fourier spectroscopy, as well as thermogravimetric analysis (TGA). The textural properties were determined based on the analysis of nitrogen isotherms. The catalytic properties of the synthesized materials in the process of phenol oxidation in the presence of hydrogen peroxide are considered. The analysis of the reaction mixtures by HPLC obtained by the oxidation of phenol in the presence of a CoFe2O4/PVP catalyst showed a decrease in the concentration of phenol in the first 15 min of the process (by 55–60%), and then within 30 min, the concentration of phenol decreased to 21.83%. After 2 h of the process, the conversion of phenol was already more than 95%. The final sample after the reaction contained 28% hydroquinone and 50% benzoquinone. It was found that the synthesized magnetic composites exhibit catalytic activity in this process. [ABSTRACT FROM AUTHOR]

Lithium‐ion batteries (LIBs) built on inorganic anodes have achieved great commercial success. By contrast, the practical application of organic anode materials encounters key bottlenecks including electronic insulation, high solubility, and poor initial coulombic efficiency (ICE). Among them, improving ICEs (normally 30–60%) faces enormous challenges in both theory and technology, and there has been no substantial breakthrough yet. Herein, a wet chemical pretreatment technology to increase the ICE of maleic acid (MA)‐based anodes from 43.2% to nearly 100% is proposed for the first time, and this strategy demonstrates universal applicability. Typically, the wet chemical pretreatment involves reacting with lithium‐biphenyl to form LixMA intermediates (x = 4–6) and further forming a compact artificial solid‐electrolyte interphase (SEI) film through the spontaneous reaction between active LixMA and battery organic electrolytes. This wet chemically‐constructed artificial SEI layer can almost completely suppress lithium loss in the initial cycle of the MA electrode and significantly boost the actual output energy density, rate capability, and cycling durability of MA anode‐based full batteries. Significantly, the study further demonstrated that a series of organic anode materials with high ICEs can be achieved through similar wet chemical pretreatment. This work will open up the true application of high‐ICE organic anodes in LIBs. [ABSTRACT FROM AUTHOR]

A compact and responsive thermoelectric photodetector is introduced for the mid‐infrared. By resonantly coupling mid‐infrared light to a Sb2Te3‐Bi2Te3 thermoelectric junction, a thermocouple is formed that is directly heated by narrow‐band mid‐infrared radiation. Near‐perfect absorption is achieved at this hot junction through the resonantly enhanced coupling of light to free‐electrons in the Bi2Te3 and Sb2Te3 materials. The fabricated devices operate at 3.6 µm and demonstrate a responsivity of 10.2 V W−1, a specific detectivity of 4.6  × 106 cm Hz1/2 W−1, and a bandwidth in the order of 1 kHz. The optimal detection wavelength can be spectrally tuned by changing the resonant cavity dimensions. This work shows a path toward miniaturized mid‐infrared detectors and spectrometers with high sensitivity, responsivity, and bandwidth. Importantly, the device presented here is ideal for industrial production, which it is hoped will provide wider access to mid‐infrared technologies for chemical sensing, medicine, and security. [ABSTRACT FROM AUTHOR]

AbstractEmerging contaminants (ECs) have become a significant threat to the aquatic environment due to their persistence and potential to harm living organisms exposed to them over extended periods. The identification of a broad range of ECs in various water bodies has accelerated research into their harmful effects and removal methods. The presence and durability of ECs, such as endocrine-disrupting substances, personal care products, pharmaceuticals, and their transformation products pose important environmental and health challenges. Traditional wastewater treatment processes often fail to eliminate ECs due to their ability to form hazardous derivatives, complexes, dynamic partitioning, and transformation products. Membrane processes have become increasingly important in pollution control, as their performance has been proven from technological, economic, energy, and environmental perspectives. This review article aims to provide a comprehensive summary of the origins and effects of ECs on humans and the environment. It discusses various membrane technologies for the efficient and ecologically responsible removal of emerging pollutants from wastewater. Reverse Osmosis (RO), Microfiltration (MF), Ultrafiltration (UF), and Nanofiltration (NF) membranes demonstrated outstanding removal efficiency for a variety of ECs; nevertheless, both methods are hindered by fouling problems. The paper highlights the methods used by hybrid membrane technology to eliminate emerging pollutants. Additionally, the use of ceramic membrane technology in removing emerging pollutants has been investigated. Ceramic membrane technology is particularly appealing due to its inherent benefits, such as chemical and thermal stability, low fouling propensity, and extended lifespan. Future research avenues for the removal of emerging pollutants using green, sustainable technologies and hybrid membranes are also presented. [ABSTRACT FROM AUTHOR]

The advancement of technologies for producing chemicals and materials from non‐fossil resources is of critical importance. An illustrative example is the dehydrogenation of glucose, to yield gluconic acid, a specialty chemical. In this study, we propose an innovative production route for gluconic acid while generating H2 as a co‐product. Our concept involves a dual‐function membrane, serving both as a catalyst for glucose dehydrogenation into gluconic acid and as a means to efficiently remove the produced H2 from the reaction mixture. To achieve this two membranes were developed, one catalytically active and one dense aimed at H2 removal. The catalytic membrane showed significant activity, yielding 16 % gluconic acid (t=120 min) with a catalyst selectivity of 93 % and stable performance over five consecutive cycles. Incorporating the H2 separating membrane showed the significance of H2 removal in driving the reaction forward. Its inclusion led to a twofold increase in gluconic acid yield, aligning with Le Chatelier's principles. As a future prospect the two layers can be combined into a dual‐layer membrane which opens the way for a new production route to simultaneously produce gluconic acid and H2, using high‐throughput reactors such as hollow‐fiber systems. [ABSTRACT FROM AUTHOR]

Coal is a rich and affordable source of energy that is extensively used for different industrial purposes. However, its extensive utilization have caused a number of environmental problems. Especially, the release of different oxides of sulfur during combustion have resulted in the ongoing acid rain and global warming issues. To tackle the issue, sequential chemical and biological technologies were applied for the desulfurization of a coal sample, collected from Shahrag coal mines, in Baluchistan, Pakistan. The coal was initially de-pyritized with a 15% nitric acid (HNO3) solution. The chemically treated coal was subsequently biodesulfurized with iron oxide (Fe3O4) coated bacterial consortium IQMJ-5. The de-pyritized and biodesulfurized coal was analyzed with proximate, ultimate, FTIR, XRD, and EDX analysis. The calorific value was determined through an oxygen bomb analyzer. Following desulfurization, about 61% organic sulfur and 86.57% total sulfur were removed from the coal sample. Similarly, an increase of about 93 kcal/kg in the calorific value was detected after the treatment. These results clearly depicts the potentiality of the technology for the desulfurization of fossil fuels at the industrial scale. [ABSTRACT FROM AUTHOR]

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The article discusses the use of enzymes in organic chemistry and the limitations of natural enzymes in catalyzing certain reactions. Researchers at Jiangnan University in China have developed a method to create artificial enzymes by modifying a peptide fragment. This approach has shown successful catalysis and may lead to the development of more artificial enzymes in the future. The article also highlights various scientific advancements in applied chemistry, including the development of devices, techniques, and materials that have the potential to contribute to sustainable energy conversion and reduce greenhouse gas emissions. [Extracted from the article]

The construction of flexible circuits is a crucial and challenging aspect in the design and fabrication of fabric‐based flexible electronics, which hold significant potential for various applications. In this study, we successfully developed high‐precision and durable fabric‐based flexible circuits by ingeniously combining ultraviolet light (UV)‐curing technology with chemical plating. Specifically, a UV coating containing Ag/Fe3O4 catalysts was applied onto polyester fabric surface, followed by printing the designed circuit structure diagram onto the fabric using UV light‐directed curing of the coating, and fabric‐based flexible circuits were then fabricated through chemical plating process. The fabric‐based flexible circuits exhibit only minimal increases in resistance following durability testing, including bending (8000 times), abrasion (2000 times), high and low temperature stability (−30 to 60°C), and high temperature/humidity stability (65°C, RH = 95%, 48 h), which remains consistently stable. This developed technology holds immense potential across various applications for smart wearable devices. [ABSTRACT FROM AUTHOR]

In this study, onium‐ion‐added nanoclay (NC)/microcellular polypropylene (PP) composites were created using a conventional injection molding machine. A chemical foaming agent was utilized to facilitate mixing. The primary focus was to analyze how altering the NC content affects the mechanical characteristics and the properties of the endothermic chemical foaming agent added PP/NC composites. The composites were created using a chemical foaming agent at a weight ratio of 1 wt% and NC at weight ratios of 0 wt%, 2.5 wt% and 5 wt%. The findings indicated that an increase in the NC ratio led to higher cell count and cell density, along with a reduction in cell diameter. Additionally, the outcomes demonstrated that the foaming of PP/NC composites resulted in decreased modulus of elasticity and tensile strength while enhancing impact strength. © 2024 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

Although epoxy resin (EP) has been widely used in many fields, it is still urgent to effectively improve its flame retardancy by halogen‐free strategies. Herein, a silicon‐containing cyclotriphosphazene derivative (HEP‐Si) was synthesized by nucleophilic substitution and silicon–hydrogen addition reaction using eugenol, hexachlorophosphazene and triethylsilane as raw materials. Then it served as a halogen‐free flame retardant for an EP/4,4′‐diaminodiphenylmethane system, and its performance was compared with that of commercial flame retardant hexaphenoxycyclotriphosphazene (HPP). The results showed that although the initial thermal decomposition temperature (T5%) of the cured products of EP/HEP‐Si was slightly lower than that of pure EP, T5% did not decrease further as the amount of HEP‐Si increased, indicating that good thermal stability was maintained. In addition, the char yield of the cured products of EP/HEP‐Si was significantly increased (more than 20 wt%) compared to that of pure EP. The cured EP with the addition of HPP and HEP‐Si both achieved a V‐0 rating in UL‐94 vertical burning test at 0.5 wt% phosphorus content, while the limiting oxygen index of the EP/HEP‐Si system was higher, reaching 33.2%. From cone calorimetric test results, the peak heat release rate, total heat release and total smoke production of the cured products of EP/HEP‐Si decreased by 61.5%, 37.1% and 26.2%, respectively, compared with that of pure EP. The cured EP/HEP‐Si materials also exhibited good thermomechanical and mechanical properties. Therefore, HEP‐Si is suggested to be a promising P/N/Si‐containing halogen‐free flame retardant for EP. © 2024 Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

In this study, we look into how poly[(4‐styrenesulfonic acid)‐co‐(4‐vinylpyridine)] crosslinked with divinylbenzene can be used as a copolymeric material to effectively recognize l‐epinephrine (L‐EP) and chirally separate (±)‐EP. It was first possible to synthesize and analyze L‐EP‐styrene‐4‐sulfonamide (L‐EP‐SSA). The resulting chiral sulfonamide was used to copolymerize with a 4‐vinylpyridine–divinylbenzene mixture. The integrated L‐EP species were removed by heating the polymer materials under strong alkaline conditions to degrade the sulfonamide links, followed by acidification in HCl solution. The imprinted L‐EP‐IP materials were analyzed using Fourier transform infrared spectroscopy and scanning electron microscopy. The produced L‐EP‐IP displayed selectivity characteristics indicative of an affinity for L‐EP almost eleven times higher than that for d‐epinephrine (D‐EP). At a pH of 7, Langmuir adsorption experiments demonstrated a maximal capacity of 165 mg g−1. Following optical separation by means of a column method, enantiomeric excess levels of L‐ and D‐EP in the initial feeding and subsequent recovering solutions were calculated to be 93% and 80%, respectively. © 2024 Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

The Haber–Bosch process is a cornerstone in the field of ammonia production and represents a decisive advance in industrial chemistry. This method, developed in the early 20th century, revolutionizes agriculture and enables the mass production of fertilizers. As the world strives for sustainable energy and environmental protection, alternative methods such as the photo/photoelectrocatalytic nitrogen reduction reaction (NRR) are gaining momentum. By using sunlight, electricity, or a combination of both, these approaches promise sustainable ammonia production with renewable energy sources and innovative materials. Researchers are trying to understand the underlying principles, mechanisms, and advances of these methods to overcome the challenges and optimize their effectiveness. This research is a step toward sustainable energy and agriculture, and offers a greener and more efficient way forward. This review looks at advances in sustainable ammonia production, particularly through photo‐ and photoelectrocatalytic NRRs. It examines the hurdles in implementing these methods and provides an overview of the fundamentals of nitrogen fixation and a comparison of current mechanisms. In addition, thermodynamic, theoretical, and computational studies of these processes are summarized. Various photocatalysts and photoelectrocatalysts used for ammonia production are also presented. [ABSTRACT FROM AUTHOR]

BACKGROUND: Adsorption is a promising affinity separation technique to target a sorbate in extremely dilute solutions. In this work, methacrylonitrile (MAN)‐functionalized resins were investigated to recover volatile fatty acids (VFAs) from a mimicked fermentation broth as an alternative for the already known amine‐based resins and non‐functionalized poly(styrene‐divinylbenzene) (PS‐DVB), aiming for high VFA capacity and selectivity. RESULTS: Next to comparison with commercial PS‐DVB resin, also several PS‐DVB resins were synthesized as non‐functionalized analogues for the new MAN‐functionalized resins. For MAN‐functionalized resins, the maximum equilibrium VFA loading of about 153 (g acid/kg adsorbent) was found, which is higher than the 125 (g acid/kg adsorbent) for the PS‐DVB non‐functionalized resins. The water uptake of the PS‐DVB resins was with 0.53–0.87 (g water/g adsorbent) significantly lower than for the MAN‐DVB resins taking up 0.99–1.85 (g water/g adsorbent). CONCLUSION: Overall, the MAN‐functionalized adsorbents retained higher loading capacity for corresponding acid, compared to the PS‐DVB resins, while also taking in more water. Acid uptake is due to the hydrogen bonding between the nitrile groups of the resins with carboxyl group of the acids. Moreover, none of the adsorbents displayed an affinity towards the salts present in the fermentation broth. © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

Chemistry is a highly technical field that relies heavily on a range of symbolic and imagic formalisms. These formalisms conceptualize specific chemical knowledge into semiotic resources that are rarely used elsewhere in most other academic fields or contexts. To develop an understanding of semiosis in highly technical fields such as chemistry, key questions include what this range of formalisms do and why they occur. These are key questions not only for our understanding of semiosis, but also if we wish to develop integrated literacy programs that can support students to marshal the multimodal discourse of chemistry. This paper explores these questions by examining how three key chemical formalisms organize their meaning: symbolic formalisms known as chemical formulas and chemical equations, and an imagic formalism known as structural formulas. Drawing on Systemic Functional Linguistics and using a corpus of formalisms from secondary school chemistry, these formalisms are explored in terms of their overarching grammatical organization and the content meanings they realize through the concept of "field." This is used to compare and contrast each formalism in terms of a semiotic typology so as to understand how they work and what meanings they realize. By exploring chemical formalisms in this way, this paper establishes a means of seeing the similarities and differences in meaning-making across formalisms and explaining why different formalisms occur. This then begins to provide a base upon which applied programs can interpret the literacy needs of chemistry. [ABSTRACT FROM AUTHOR]

In this work, we investigate the properties and stability of the combustion waves propagating in a system of layered solid fuel material in which the neighbouring fuel sheets can recuperate heat via thermal electromagnetic radiation. The analysis is undertaken within the flame sheet model, which allows to determine the combustion wave speed and structure and derive the dispersion relation characterising the stability of the reaction front. The proper choice of parameters leads to superadiabatic combustion temperature and significant increase of the combustion wave speed. In addition, the stable steady regimes of combustion can be substantially extended in the space of parameters. Such an enhancement of stability and ability to control the characteristics of the combustion wave propagation can be very attractive for the combustion synthesis of new layered materials, similarly to the chemical furnace technology proposed earlier. [ABSTRACT FROM AUTHOR]

The characteristics and hazards of acid coal mine drainage (ACMD) were introduced, and the treatment methods of ACMD were described. Techniques that could be used for source prevention and process containment were analyzed. The widely used terminal treatment technologies at present were summarized, such as the active treatment technology based on neutralization, sulfidation, adsorption and membrane technology, and the passive treatment technology based on chemical, biological and chemical-biological combined method. It was summarized and concluded that the multi-technology combination process was the main trend of engineering application and an effective way for large-scale collaborative treatment of ACMD. Finally, the development prospect of ACMD treatment method was prospected. [ABSTRACT FROM AUTHOR]

This study described the chemical engineering technology to signify the utilization of non-edible Faidherbia albida seeds as a promising botanical source for biofuel production, regarding their potential to address both energy needs and environmental concerns. This research offers valuable description into sustainable fuel production technology, along with the objectives to achieve the chemical engineering to develop solutions for a more sustainable future. The utilization of non-edible F. albida as a source for biofuel production, utilized phytonanoctalyst to enhance its catalytic efficiency. F. albida seed oil concentration of 38% (w/w), non-edible feedstock presents a valuable solution for producing high-quality biofuel. The application of an innovative green nanocatalyst of calcium oxide (CaO) and Tamarindus indica pods extract proved beneficial to enhance the transesterification process. The characterization tools such as SEM, EDX, XRD, FTIR, and HPLC were performed. The verification of methyl ester synthesis was confirmed through FTIR and HPLC analysis. The average nanoparticle size was determined 25.93 nm, while the diffraction peaks elaborate the hexagonal polycrystalline structure. This research provides implications for the advancement of biofuel production, explained the vital role of this interdisciplinary catalysis approach to address the global energy challenges and paving the way for a more sustainable future. [ABSTRACT FROM AUTHOR]

Microplastics (MPs), as an emerging pollutant, have attracted widespread attention from scholars both domestically and internationally due to their potential harm to the ecosystems. At present, the presences of MPs have been widely detected in the global water environment, so the removal of MPs in water bodies is particularly important. There is no treatment technology that can completely remove MPs from water presently. This article introduces typical MPs removal technologies from the aspects of methods, influencing factors, and removal results based on existing research, and looks forward to future related research. The physical technology operation process is simple and currently has relatively more practical applications. Chemical technology has a high removal efficiency, but further research and promotion are still needed; Biotechnology is relatively energy-efficient and economical, but it is not yet suitable for promotion and use in practical applications. Future research should focus more on the treatment of small-sized MPs and strengthen the combination of multiple treatment technologies. The article will provide a research foundation and direction for the removal of MPs in water bodies, in order to better solve the problem of MPs pollution. [ABSTRACT FROM AUTHOR]

Nowadays, there is a rising interest in the packaging industry regarding more environment‐friendly (i.e. biodegradable and/or compostable) polymer‐based solutions, especially for film blowing applications. However, replacing traditional, fossil resource‐based polymers typically used for such applications is not an easy task, since the more environment‐friendly solutions must have adequate features in terms of processability and final properties. In this work, three commercial biodegradable (and, at least partially, biobased) polymers were investigated by a preliminary rheological and mechanical analysis, in order to perform film manufacturing experiments in laboratory equipment. Furthermore, oxygen and water vapour barrier properties were studied by permeability measurements. The investigation was ultimately performed on films produced in industrial equipment, and the results were compared to those for a typical, standard polypropylene (PP) film used in flexible packaging applications. It was found that the mechanical properties were adequate (in some cases, even up to 25–30% higher than for the PP counterpart), as well as oxygen permeability. On the other hand, water permeability was significantly higher than that of PP films, and this should be taken into account in cases where high water vapour barrier properties are required. © 2024 Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

Mankind has erected monoliths and stone structures for millennia to ensure stories and culture are passed on to future generations. In the modern era, monuments and architecture are designed with the intention of lasting several decades to hundreds of years and may utilize an arrangement of natural and synthetic materials. Choice of substrate helps ensure the longevity of these structures, but coatings are utilized to provide additional characteristics and subsequent protection to the finished product. Protective coatings come in a variety of base materials and are utilized to address specific degradation concerns. Advances in this field focus on protection of the surface while preventing any unintended damage to the substrate. This mini review summarizes the advances in protective coatings useful for historical monuments and architecture up to January 2024. © 2024 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

Integrating flame‐retardant additives into epoxy resins is an essential strategy for improving their fire resistance. However, introducing flame‐retardant groups often compromises the processability and mechanical integrity of such resins. In this research, we synthesized a novel, biobased flame retardant, referred to as DPN, using naringenin and chlorodiphenylphosphine as precursors via a straightforward single‐step process. The addition of DPN markedly decreased the viscosity of hydantoin epoxy resin, from 7468 to 1285 mPa s. Furthermore, when cured with 4,4‐diaminodiphenylmethane, the composite containing five equivalents of DPN (DPN‐5) exhibited a marked improvement in mechanical strength, reaching 190 MPa, significantly outperforming the pure thermoset (DPN‐0: 104 MPa), while preserving high transparency. Combustion tests further confirmed that DPN significantly boosts the flame resistance of the thermoset, with DPN‐5 achieving a limiting oxygen index of 37% and securing a UL‐94 V‐0 rating. Cone calorimetry analysis showed that DPN‐5 effectively reduced heat and smoke production during combustion, achieving a 13.4% reduction in peak heat release rate and a 28.2% decrease in total heat release compared to DPN‐0. This study underscores the potential of multifunctional biobased flame retardants derived from renewable resources in advancing the development of high‐performance materials. © 2024 Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

Amphiphilic block copolymers are characterized by the presence of distinct hydrophilic and hydrophobic regions, which are usually arranged in alternating blocks. This unique structure allows these copolymers to self‐assemble into well‐defined nanostructures that exhibit remarkable resistance to enzymatic hydrolysis, high biocompatibility and the ability to be customized with specific structures. These properties make them highly desirable in various applications. Self‐assembled amphiphilic polypeptoids are currently under development as a promising class of pharmaceutical agents. However, the utilization of these peptides as drug carriers for efficient delivery presents a number of challenges. These challenges include less‐than‐optimal loading efficacy and restricted biocompatibility. Herein, a series of stable amphiphilic block copolypeptoids (PNEG‐b‐PNBG and PNEG‐b‐PNHG) were designed and synthesized by controlled ring‐opening polymerization. PNEG chain segments provide hydrophilicity, while PNBG and PNHG chain segments provide hydrophobicity. The hydrophobic molecular chains aggregate in aqueous solutions, resulting in the formation of nano‐assemblies. The self‐assembled amphiphilic block polypeptoid copolymers were investigated. The morphologies of copolymers take the form of micelles from tens of nanometers to a few hundred nanometers. The properties of amphiphilic block copolypeptoids used as drug carriers were further investigated by conducting drug release and cytotoxicity tests. The results indicate that the cumulative release efficiency of self‐assembled polypeptoid copolymers can reach up to about 91%. And they have good biocompatibility and can be expected to be safe materials for efficient drug delivery. This work could provide a facile method for the preparation of amphiphilic block peptoid copolymers for biopharmaceutical applications. © 2024 Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

The demands of cost‐driven industrial applications can be satisfied by manufacturing composites with a low volume fraction of carbon fibres as phenolic carbon fibre‐reinforced composites and C/C composites, both with acceptable performances, for low‐ or high‐temperature applications, respectively. Polymeric composites reinforced with a low volume fraction (7.5% v/v) of carbon fibres were fabricated using laboratory‐produced phenolic resins, novolac (N) and resole (R), as matrices after different curing/post‐curing temperature profiles. By optimising the manufacturing conditions, the N‐based polymeric composites exhibited higher flexural strength, whereas the R‐based composites showed higher shear strength. C/C composites, namely N‐based and R‐based, were manufactured by pyrolysis of the previously prepared polymeric composites up to 1000 °C. The pyrolysed composites were then densified by impregnation with an appropriate resin solution, followed by curing and new pyrolysis, and particularly by employing 1 up to 4 consecutive cycles of 'impregnation–curing/pyrolysis'. Weight changes resulting from the impregnation–curing and pyrolysis stages were determined. The curing of both resins was verified by Fourier Transform Infrared Analysis. The apparent density and X‐ray diffraction data of the C/C composites were used to calculate their total percent porosities. The morphology and elemental composition of the C/C composites at their failure region (after flexural testing) were examined by Scanning Electron Microscopy/Energy‐Dispersive X‐ray Analyses. In comparison to the N‐based C/C composites, the R‐based ones exhibited: higher shear strength, lower flexural strength, higher Shore D hardness, slightly higher surface conductivity and lower volume conductivity. The optimum conditions for the manufacture of C/C composites were achieved by applying two consecutive cycles of 'pyrolysis–impregnation–pyrolysis' to the polymeric composites. © 2024 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

Due to their unique properties and use in high performance materials, the ability to obtain fluorinated polymers utilizing straightforward synthetic methods remains of interest. In this study, we report the facile synthesis of new fluoropolymers via nucleophilic addition of a di‐thiol to perfluorocyclopentene. Initially, model studies were completed with perfluorocyclopentene, benzenethiol and tetramethylsilane‐protected benzenethiol to identify the optimal reaction conditions for the polymerization. These reaction conditions were then utilized to prepare perfluorocyclopentene‐thioether polymers from perfluorocyclopentene and 4,4′‐thiobisbenzenethiol. The isolated polymers had molecular weight distributions consistent with step‐growth polymers and 19F NMR spectroscopy revealed that the addition of the nucleophile to perfluorocyclopentene was controlled. Analysis by DSC showed that the polymers were amorphous with glass transition temperatures around 65 °C. TGA in both air and nitrogen showed an initial degradation temperature around 370 °C, while the air analysis produced an additional plateau with a degradation temperature near 592 °C. This is the first known report of utilizing perfluorocyclopentene for the preparation of perfluorinated‐thioether polymers. © 2024 Society of Industrial Chemistry. This article has been contributed to by U.S. Government employees and their work is in the public domain in the USA. [ABSTRACT FROM AUTHOR]

Poly(ethylene terephthalate) (PET), both bottle grade (PET‐B) and thermoform grade (PET‐T), are widely used in the packaging sector. However, only PET‐B is recycled and reused, while PET‐T needs to be separated from recycled PET bales. This study aims to assess the impact of solid‐state polymerization (SSP), chain extension and the combination of chain extension–SSP to transform PET‐B and PET‐T blends into PET‐T‐like material. The intrinsic viscosity (IV) values for PET‐B blends with 10–20 wt% of PET‐T are measured for the samples obtained in this study. The mechanical properties, such as tensile strength, modulus, elongation and impact strength, were also determined. The glass transition temperature, melting temperature, crystallinity and thermal degradation were also investigated. The findings suggest that the combination of SSP and chain extension leads to a significant improvement in IV and tensile strength, while SSP alone is less suitable to offer the desired IV values. © 2024 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

Graphene and its derivatives are promising energy storage devices due to their high specific surface area, chemical and thermal durability and high charge transfer power. Still, their stacking and aggregate behavior can limit their practical application. To address this issue, reversible addition–fragmentation chain‐transfer (RAFT) polymerization as controlled radical polymerization was applied to functionalize the surface of graphene oxide with poly(N,N‐dimethylaminoethyl methacrylate) (PDMAEMA) via the 'grafting from' method. This strategy enhances the distance between graphene sheets by occupying physical volume while improving effective charge transfer through tertiary amine groups participating in the doping process. X‐ray diffraction was used to determine interlayer spacing after polymer grafting, which increased from 0.28 to 1.71 nm after polymer grafting. The hybridization of materials with diverse properties was used to enhance charge transfer capability for supercapacitor applications. PDMAEMA‐functionalized graphene oxide, nano‐manganese dioxide and polyaniline were combined to create a successful nanocomposite as electrode active material. The morphological structure and chemical composition of the synthesized nanocomposite were analyzed, and its electrochemical performance was evaluated using cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy. The nanocomposite exhibited a maximum specific capacitance, energy density and power density of 364.72 F g−1 (at a scan rate of 50 mV s−1), 239.08 Wh kg−1 and 678.34 W kg−1, respectively. The final nanocomposite's energy storage capacity significantly increased compared to the individual components due to hybridization's synergistic impact, reducing charge transfer resistance. © 2024 Society of Industrial Chemistry. [ABSTRACT FROM AUTHOR]

BACKGROUND: Biodegradable polymers are gaining a reputation as demand is increasing globally. Amongst these Polyhydroxyalkanoates (PHA) are attracting market attention as a consequence of their properties similar to those of conventional plastics. PHA is a natural polyester that is stored as an intracellular carbon (C) energy reserve of bacteria. This biopolymer can be extracted and used in place of petrochemical plastic. Medium chain‐length (mcl) PHA, specifically poly hydroxybutyrate‐co‐hydroxyhexanoate P (HB‐co‐HHx) copolymer produced by Bacillus, has gained practical attention owing to its superior physicochemical properties compared to the commonly synthesized PHB homopolymer. Co‐polymer production is dependent on C sources provided in the growth medium. In the present study we have employed palm oil and palm oil effluent as C source. RESULTS: In the current study, it was observed that a significant amount of PHA and biomass was produced when the effluent was prepared at a concentration of 100% instead of water for preparing the growth medium. The production of biomass and PHA showed a range of 4.8–8and 1.5–4 g L−1, respectively. This means that the PHA yield obtained using the effluent was 50–80% of the control, whereas the control yielded only 40–50%. CONCLUSION: Palm industry waste can be used as a substrate in bioprocessing industries. Proton nuclear magnetic resonance analysis of PHA obtained herein indicates that it consists of the mcl polymer P (HB‐co‐HHx). © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

BACKGROUND: The addition of conductive materials or the application of external voltage is a promising novel methodology to enhance methane production in anaerobic digesters. However, there is limited knowledge about their individual or combined effects on the anaerobic digestion of dairy wastewater. The aim of this study was to examine the effects of granular activated carbon (GAC) or magnetite addition and external voltage application, both individually and in combination, for the anaerobic digestion of real, undiluted dairy wastewater. RESULTS: The results showed that the estimated maximum methane production rate increased significantly (P < 0.05) from 143 ± 8 mL gVSadded−1 day−1 in the control reactors to 163 ± 11 mL gVSadded−1 day−1 and 166 ± 11 mL gVSadded−1 day−1 in the reactors containing GAC, with or without the combination of external voltage, respectively. The addition of GAC, in both cases, resulted in higher consumption rate of acetate, indicating a promotion of the methanogenesis step. By contrast, the application of external voltage or the addition of magnetite had no significant effect on either methane production rate nor methane yield. Moreover, the analysis of the microbial community showed that the addition of GAC resulted in the enrichment of Desulfobacterota, Methanosarcina, Candidatus Methanofastidiosum and Methanolinea. CONCLUSION: Overall, GAC addition seems a promising strategy to increase methane production in anaerobic digesters treating dairy wastewater. © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI). [ABSTRACT FROM AUTHOR]

The perspectives of technological advances needed for short term energetic transition are briefly reviewed and discussed critically. In particular, the technologies for the greenhouse gas emission-free production of electrical energy, its storage and transport, the production, transport, storage and use of hydrogen, and the use of biomass derived technologies are shortly and critically reviewed. Critical aspects are emphasized. The role of chemistry, and in particular materials chemistry and engineering, in short-term developments are underlined. [ABSTRACT FROM AUTHOR]

In the process of fuel utilization, traditional combustion technologies result in the conversion of nitrogen elements in fuels into nitrogen oxides, which are released into the atmosphere, posing serious threats to the environment and human health. The chemical looping process (CLP) is an effective technology for reducing nitrogen-containing (N-containing) pollutants during fuel utilization. During the CLP, the oxygen carrier (OC) can oxidize nitrogen oxide precursors (NH3 and HCN) released from the fuel to N2, while the reduced OC can reduce nitrogen oxides to N2. The achievement of efficient nitrogen pollutant removal relies on the development of highly active oxygen carriers (OCs). This review summarizes the recent progress in the removal of nitrogen pollutants within chemical looping processes (CLPs). It delineates the formation pathways of N-containing pollutants (NH3, HCN, NO, NO2 and N2O) and highlights the performance of various OCs. The influence of reaction conditions and feedstock characteristics is also discussed. Ni-based OCs have demonstrated superior performance in the removal of N-containing pollutants, exhibiting strong oxidation capabilities and excellent catalytic properties. Moreover, iron ore, as a cost-effective and environmentally friendly feedstock, holds promise for wide-scale application. Future research should focus on further optimizing OCs strategies and refining reaction conditions to achieve more efficient and economical N-containing pollutant removal, thereby fostering the widespread application of chemical looping technology in the energy sector. [ABSTRACT FROM AUTHOR]

While the mild production of syngas (a mixture of H2 and CO) from CO2 and H2O is a promising alternative to the coal‐based chemical engineering technologies, the inert nature of CO2 molecules, unfavorable splitting pathways of H2O and unsatisfactory catalysts lead to the challenge in the difficult integration of high CO2 conversion efficiency with produced syngas with controllable H2/CO ratios in a wide range. Herein, we report an efficient plasma‐driven catalytic system for mild production of pure syngas over porous metal–organic framework (MOF) catalysts with rich confined H2O molecules, where their syngas production capacity is regulated by the in situ evolved ligand defects and the plasma‐activated intermediate species of CO2 molecules. Specially, the Cu‐based catalyst system achieves 61.9 % of CO2 conversion and the production of pure syngas with wide H2/CO ratios of 0.05 : 1–4.3 : 1. As revealed by the experimental and theoretical calculation results, the in situ dynamic structure evolution of Cu‐containing MOF catalysts favors the generation of coordinatively unsaturated metal active sites with optimized geometric and electronic characteristics, the adsorption of reactants, and the reduced energy barriers of syngas‐production potential‐determining steps of the hydrogenation of CO2 to *COOH and the protonation of H2O to *H. [ABSTRACT FROM AUTHOR]

This document is a special issue of the journal Catalysts, featuring contributions from scientists in various fields discussing the topic of catalysis on zeolites and zeolite-like materials. The articles cover a wide range of topics, including the preparation and modification of zeolite-containing catalysts for the petrochemical industry, the synthesis of micro-mesoporous materials for efficient catalysis, the development of new zeolite systems for environmental catalysis, and the synthesis and characterization of nanoscale zeolites with various applications. The contributions emphasize the potential of zeolites and zeolite-like materials as catalysts due to their unique pore structures and surface properties. [Extracted from the article]

Context: Organic halides stand as invaluable reagents with diverse applications in synthetic chemistry and various industrial processes. Despite their utility, concerns arise due to their inherent toxicity. Addressing these apprehensions, hydro-dehalogenation has emerged as a promising strategy involving the replacement of halogen atoms with hydrogen atoms to transform toxic organic halides into hydrocarbons. This study delves into the computational exploration of hydro-dehalogenation reactions of benzyl halide, mediated by frustrated Lewis pairs (FLPs), using density functional theory (DFT). The reactions entail the formation of FLP1 or FLP2 in the presence of TMP or lutidine with B(C6F5)3, respectively. This is followed by heterolytic cleavage of dihydrogen and subsequent reaction with benzyl halides. Non-covalent interaction analysis underscores the significance of π–π stacking and CH–π interactions in stabilizing transition states. Additionally, the activation strain model (ASM) dissects activation energies, revealing the substantial impact of strain energy on reaction barriers. Energy decomposition analysis (EDA) offers insights into the contributions of electrostatic, orbital, and dispersion energies to the overall attractive interaction energy. The investigation extends to hydro-dehalogenation reactions of ethyl halides, uncovering distinct mechanisms and activation barriers. This comprehensive analysis illuminates the intricacies of hydro-dehalogenation reactions, providing valuable insights into their mechanisms and paving the way for future studies in this field. Methods: Geometry optimizations were carried out at the M06-2X/def2-SVP level of theory, which was performed using the Gaussian 16 program. Solvent-corrected single-point energies were also calculated using the polarizable continuum model (PCM) at the PCM(chloroform)-M06-2X/def2-TZVP//M06-2X/def2-SVP level of theory. The Gibbs free energy correction was determined from computations performed at the M06-2X/def2-SVP level of theory. Principal interacting orbital (PIO) analysis was conducted using the NBO 6.0 software. The nature of bonding in the respective transition state (TS) structures was analyzed using atoms-in-molecules (AIM) analyses. Additionally, the presence of non-covalent interactions (NCI) was exemplified using Multiwfn software. [ABSTRACT FROM AUTHOR]

A new study from Canada has developed a process for efficiently extracting and recycling metals from used alkaline batteries. This method, called hydrometallurgy, uses aqueous solutions to extract the metals and is more cost-effective and energy-efficient than other methods. The researchers are now working on scaling up the technique for industrial use. The document also highlights various scientific studies in applied chemistry, including the conversion of carbon dioxide to carbon monoxide, the synthesis of synthetic diamonds, the growth of hydrocarbons from biogas, the reduction of CO2 to syngas and C2 hydrocarbons, the development of electronic spider silk sensors, the creation of reflective black paint for autonomous cars, the production of vanillin from ferulic acid, and the development of reversible supramolecular adhesives. Each study offers unique findings and potential applications in different fields. [Extracted from the article]